Roto Inject Fluid Ndurance

Atlas Copco Airpower NV

Chemwatch: 5247-56 Issue Date: 23/12/2024
Version No: 21.1 Print Date: 16/05/2025
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) [Link].E

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Product name Roto Inject Fluid Ndurance
Synonyms RIF Ndurance

Chemical formula Not Applicable

Other means of
Not Available
identification

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Compressor oil
Uses advised against No specific uses advised against are identified.

1.3. Details of the manufacturer or importer of the safety data sheet

Registered company name Atlas Copco Airpower NV

Address Boomsesteenweg 957 Wilrijk B2610 Belgium

Telephone +32 3 870 2111

Fax +32 3 870 2903

Website [Link]

Email [Link]@[Link]

1.4. Emergency telephone number

Association / Organisation CHEMWATCH EMERGENCY RESPONSE (24/7)

Emergency telephone
+32 2 700 63 06 (ID#: 5247-56)
number(s)
Other emergency
+61 3 9573 3188
telephone number(s)

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

Classification according to
regulation (EC) No
Non hazardous
1272/2008 [CLP] and
amendments [1]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

2.2. Label elements

Hazard pictogram(s) Not Applicable

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Signal word Not Applicable

Hazard statement(s)
Not Applicable

Supplementary statement(s)
EUH208 Contains Alkaryl Carboxylic Acid Derivative. May produce an allergic reaction.
EUH210 Safety data sheet available on request.

Precautionary statement(s) Prevention

Not Applicable

Precautionary statement(s) Response

Not Applicable

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

Material contains interchangeable low viscosity base oil (<20.5 cSt @40C), octylated diphenylamines, 4-nonylphenoxyactic acid.

2.3. Other hazards

REACH - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

SECTION 3 Composition / information on ingredients

[Link]
See 'Composition on ingredients' in Section 3.2

[Link]
1. CAS No
Nanoform
[Link] No % Classification according to regulation (EC) SCL / M-
Name Particle
[Link] No [weight] No 1272/2008 [CLP] and amendments Factor
Characteristics
[Link] No

SCL: Not
Available

1. Not Available interchangeable low Acute M

[Link] Available factor: Not
0-90 viscosity base oil (<20.5 Aspiration Hazard Category 1; H304 [1] Not Available
[Link] Available Applicable
[Link] Available cSt @40C)
Chronic M
factor: Not
Applicable

(DMSO <3% w/w - Not

Not Available Not Applicable Not Available
IP346) Applicable

* contains one or more

of the following CAS- Not
Not Available Not Applicable Not Available
numbers (REACH Applicable
registration numbers):

64742-53-6 (01-
2119480375-34), 64742- Not
Not Available Not Applicable Not Available
54-7 (01-2119484627- Applicable
25),

64742-55-8 (01-
2119487077-29), 64742- Not
Not Available Not Applicable Not Available
56-9 (01-2119480132- Applicable
48),
64742-65-0 (01-
2119471299-27), 68037- Not
Not Available Not Applicable Not Available
01-4 (01-2119486452- Applicable
34),

72623-86-0 (01-
2119474878-16), 72623- Not
Not Available Not Applicable Not Available
87-1 (01-2119474889- Applicable
13),

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1. CAS No
Nanoform
[Link] No % Classification according to regulation (EC) SCL / M-
Name Particle
[Link] No [weight] No 1272/2008 [CLP] and amendments Factor
Characteristics
[Link] No

8042-47-5 (01-
2119487078-27), Not
Not Available Not Applicable Not Available
848301-69-9 (01- Applicable
0000020163-82)

68649-12-7 (01-
2119527646-33), Not
Not Available Not Applicable Not Available
151006-60-9 (01- Applicable
2119523580-47)
63149-28-8 (01-
2119543695-30), 64741- Not
Not Available Not Applicable Not Available
88-4 (01-2119488706- Applicable
23)
64741-89-5 (01- Not
Not Available Not Applicable Not Available
2119487067-30) Applicable

SCL: Not
Available

1. 68411-46-1 Acute M
2.270-128-1 octylated factor: Not
1-2.9 Reproductive Toxicity Category 2; H361f [1] Not Available
[Link] Available diphenylamines Applicable
4.01-2119491299-23-XXXX
Chronic M
factor: Not
Applicable

SCL: Not
Acute Toxicity (Oral) Category 4,Skin
Available
Corrosion/Irritation Category 1B,Serious Eye
1. 3115-49-9 Damage/Eye Irritation Category 1,Sensitisation Acute M
2.221-486-2 0.01- 4-nonylphenoxyactic (Skin) Category 1A,Hazardous to the Aquatic factor: Not
Environment Acute Hazard Category Not Available
[Link] Available 0.099 acid Applicable
4.01-2119982392-31-XXXX 1,Hazardous to the Aquatic Environment Long-
Chronic M
Term Hazard Category 1; H302, H314, H318,
factor: Not
H317, H400, H410 [1]
Applicable

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

SECTION 4 First aid measures

4.1. Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact
lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.

If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.

If swallowed do NOT induce vomiting.

If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
Ingestion Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

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Heavy and persistent skin contamination over many years may lead to dysplastic changes. Pre-existing skin disorders may be aggravated by exposure to this
product.
In general, emesis induction is unnecessary with high viscosity, low volatility products, i.e. most oils and greases.
High pressure accidental injection through the skin should be assessed for possible incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may become swollen, discoloured and extremely painful with extensive subcutaneous
necrosis. Product may be forced through considerable distances along tissue planes.

SECTION 5 Firefighting measures

5.1. Extinguishing media

Foam.
Dry chemical powder.
Carbon dioxide.
Water spray or fog - Large fires only.
Do not use water jets.

5.2. Special hazards arising from the substrate or mixture

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may
Fire Incompatibility
result

5.3. Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Fire Fighting
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Fire/Explosion Hazard Combustion products include:
carbon dioxide (CO2)
other pyrolysis products typical of burning organic material.
CARE: Water in contact with hot liquid may cause foaming and a steam explosion with wide scattering of hot oil and possible
severe burns. Foaming may cause overflow of containers and may result in possible fire.

SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See section 8

6.2. Environmental precautions

See section 12

6.3. Methods and material for containment and cleaning up

Slippery when spilt.
Remove all ignition sources.
Minor Spills Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Slippery when spilt.
Moderate hazard.
Major Spills Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.

6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

7.1. Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Safe handling
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.

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Fire and explosion

See section 5
protection
Store in original containers.
Keep containers securely sealed.
Other information
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.

7.2. Conditions for safe storage, including any incompatibilities

For containers, use:
Mild steel
Suitable container High-density polyethylene (HDPE)
Unsuitable containers:
Polyvinyl chloride (PVC)
· CARE: Water in contact with heated material may cause foaming or a steam explosion with possible severe burns from wide
scattering of hot material. Resultant overflow of containers may result in fire.
· Oil leaks in a pressurized circuit may result in a fine flammable spray (the lower flammability limit for oil mist is reached for a
concentration of about 45 g/m3
Storage incompatibility
· Autoignition temperatures may be significantly lower under particular conditions (slow oxidation on finely divided materials..
Avoid reaction with oxidising agents
Extremely high temperatures.
Do not store in direct sunlight.
Hazard categories in
accordance with
Not Available
Regulation (EC) No
2012/18/EU (Seveso III)

Qualifying quantity
(tonnes) of dangerous
substances as referred to Not Available
in Article 3(10) for the
application of

7.3. Specific end use(s)

See section 1.2

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
0.034 mg/L (Water (Fresh))
0.51 mg/L (Water - Intermittent release)
Dermal 0.44 mg/kg bw/day (Systemic, Chronic)
0.003 mg/L (Water (Marine))
Inhalation 0.31 mg/m³ (Systemic, Chronic)
0.446 mg/kg sediment dw (Sediment (Fresh Water))
octylated diphenylamines Dermal 0.22 mg/kg bw/day (Systemic, Chronic) *
0.045 mg/kg sediment dw (Sediment (Marine))
Inhalation 0.00008 mg/m³ (Systemic, Chronic) *
17.6 mg/kg soil dw (Soil)
Oral 0.05 mg/kg bw/day (Systemic, Chronic) *
10 mg/L (STP)
0.833 mg/kg food (Oral)
Dermal 0.5 mg/kg bw/day (Systemic, Chronic) 0.001 mg/L (Water (Fresh))
Inhalation 1.76 mg/m³ (Systemic, Chronic) 0.009 mg/L (Water - Intermittent release)
Inhalation 17.6 mg/m³ (Systemic, Acute) 0 mg/L (Water (Marine))
4-nonylphenoxyactic acid Dermal 0.25 mg/kg bw/day (Systemic, Chronic) * 0.02 mg/kg sediment dw (Sediment (Fresh Water))
Inhalation 0.00043 mg/m³ (Systemic, Chronic) * 0.002 mg/kg sediment dw (Sediment (Marine))
Oral 0.25 mg/kg bw/day (Systemic, Chronic) * 0.004 mg/kg soil dw (Soil)
Inhalation 4.3 mg/m³ (Systemic, Acute) * 1 mg/L (STP)

* Values for General Population

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

European Union Directive
Mineral oils that have been
2004/37/EC on the (10) Substantial
interchangeable low used before in internal
protection of workers from Not Not Not contribution to the total
viscosity base oil combustion engines to lubricate
the risks related to exposure Available Available Available body burden via dermal
(<20.5 cSt @40C) and cool the moving parts
to carcinogens or mutagens exposure possible.
within the engine
at work
Belgium Occupational interchangeable low Huiles minérales (brouillards) 5 mg/m3 10 Not Not Available
Exposure Limits (French) viscosity base oil mg/m3 Available
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Source (<20.5 cSt @40C)

Ingredient Material name TWA STEL Peak Notes
Belgium Occupational octylated Particules non classifiées 10 Not Not
Not Available
Exposure Limits (French) diphenylamines autrement (fraction inhalable) mg/m3 Available Available
Belgium Occupational octylated Particules non classifiées Not Not
3 mg/m3 Not Available
Exposure Limits (French) diphenylamines autrement (fraction alvéolaire) Available Available

Ingredient Original IDLH Revised IDLH

interchangeable low viscosity

2,500 mg/m3 Not Available
base oil (<20.5 cSt @40C)
octylated diphenylamines Not Available Not Available
4-nonylphenoxyactic acid Not Available Not Available

8.2. Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
8.2.1. Appropriate
The basic types of engineering controls are:
engineering controls
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment.

8.2.2. Individual protection

measures, such as
personal protective
equipment

Safety glasses with side shields

Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Eye and face protection Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should
include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.
Skin protection See Hand protection below
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
Hands/feet protection
observed when making a final choice.
Personal hygiene is a key element of effective hand care.
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
Body protection See Other protection below

Overalls.
P.V.C apron.
Other protection
Barrier cream.
Skin cleansing cream.

Respiratory protection
Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content.
The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask
is not functioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of
cartridge respirators is considered appropriate.
Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than
75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used

8.2.3. Environmental exposure controls

See section 12

SECTION 9 Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Light brown liquid; does not mix with water.

Relative density (Water =

Physical state Liquid 0.87
1)

Partition coefficient n-
Odour Not Available >6
octanol / water

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Auto-ignition temperature
Odour threshold Not Available >320
(°C)

Decomposition
pH (as supplied) Not Applicable Not Available
temperature (°C)

Melting point / freezing

-30 (pour pt) Viscosity (cSt) 55 @ 40C
point (°C)

Initial boiling point and

>280 Molecular weight (g/mol) Not Applicable
boiling range (°C)

Flash point (°C) 240 (COC) Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Surface Tension (dyn/cm

Upper Explosive Limit (%) 10 Not Available
or mN/m)

Lower Explosive Limit (%) 1 Volatile Component (%vol) Not Available

Vapour pressure (kPa) <0.0005 @ 20C Gas group Not Available

Solubility in water Immiscible pH as a solution (1%) Not Available

Vapour density (Air = 1) >5 VOC g/L Not Available

Heat of Combustion (kJ/g) Not Available Ignition Distance (cm) Not Available

Flame Height (cm) Not Available Flame Duration (s) Not Available

Enclosed Space Ignition

Enclosed Space Ignition
Not Available Deflagration Density Not Available
Time Equivalent (s/m3)
(g/m3)
Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics
Particle Size Not Available

9.2. Other information

Not Available

SECTION 10 Stability and reactivity

[Link] See section 7.2

Unstable in the presence of incompatible materials.

10.2. Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.

10.3. Possibility of
See section 7.2
hazardous reactions

10.4. Conditions to avoid See section 7.2

10.5. Incompatible
See section 7.2
materials

10.6. Hazardous
See section 5.3
decomposition products

SECTION 11 Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

a) Acute Toxicity Based on available data, the classification criteria are not met.
b) Skin Irritation/Corrosion Based on available data, the classification criteria are not met.

c) Serious Eye
Based on available data, the classification criteria are not met.
Damage/Irritation

d) Respiratory or Skin
Based on available data, the classification criteria are not met.
sensitisation

e) Mutagenicity Based on available data, the classification criteria are not met.

f) Carcinogenicity Based on available data, the classification criteria are not met.
g) Reproductivity Based on available data, the classification criteria are not met.

h) STOT - Single Exposure Based on available data, the classification criteria are not met.

i) STOT - Repeated
Based on available data, the classification criteria are not met.
Exposure

j) Aspiration Hazard Based on available data, the classification criteria are not met.

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Inhalation hazard is increased at higher temperatures.

Inhaled
Inhalation of oil droplets or aerosols may cause discomfort and may produce chemical inflammation of the lungs.

Although ingestion is not thought to produce harmful effects (as classified under EC Directives), the material may still be
Ingestion damaging to the health of the individual, following ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is
evident.

The liquid may be able to be mixed with fats or oils and may degrease the skin, producing a skin reaction described as non-
allergic contact dermatitis. The material is unlikely to produce an irritant dermatitis as described in EC Directives.
Skin Contact
The material may accentuate any pre-existing dermatitis condition
Open cuts, abraded or irritated skin should not be exposed to this material
Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce
Eye
transient discomfort characterised by tearing or conjunctival redness (as with windburn).
Oil may contact the skin or be inhaled. Extended exposure can lead to eczema, inflammation of hair follicles, pigmentation of the
face and warts on the soles of the feet.
NOTE L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3% DMSO
Chronic
extract as measured by IP 346.
European Union (EU) List of harmonised classification and labelling hazardous substances, Table 3.1, Annex VI, Regulation (EC)
No 1272/2008 (CLP) - up to the latest ATP

TOXICITY IRRITATION

Roto Inject Fluid Ndurance Dermal (Rabbit) LD50: >5000 mg/kg*[2] Not Available

Oral (Rat) LD50: >5000 mg/kg[2]

interchangeable low TOXICITY IRRITATION

viscosity base oil (<20.5
cSt @40C) Not Available Not Available

Toxicity Irritation

octylated diphenylamines Dermal (rabbit) LD50: >2000 mg/kg[1] Eye:Mild[1]

Oral (Rat) LD50: >2000mg/kg[2] Skin:Mild[1]

TOXICITY IRRITATION

4-nonylphenoxyactic acid Oral (Rat) LD50: 1554 mg/kg[1] Eye: adverse effect observed (irritating)[1]

Skin: adverse effect observed (corrosive)[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

Potential sensitiser producing contact allergies.

OCTYLATED Heating of substituted diphenylamines may generate vapours which can irritate the eyes and airways. Drying of skin and mucous
DIPHENYLAMINES membranes leading to irritation may occur with prolonged or repeated contact. Overexposure may cause skin and airway
irritation with dizziness and flu-like symptoms. All show a slight to very low order of toxicity following oral or topical administration.

Sensitiser: Guinea pig assay *Ciba SDS

For acid mists, aerosols, vapours
Test results suggest that eukaryotic cells are susceptible to genetic damage when the pH falls to about 6.5. Cells from the
respiratory tract have not been examined in this respect. Mucous secretion may protect the cells of the airway from direct
exposure to inhaled acidic mists (which also protects the stomach lining from the hydrochloric acid secreted there).
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-
4-NONYLPHENOXYACTIC
allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
ACID
highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to severe
bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without
eosinophilia.
The material may produce respiratory tract irritation, and result in damage to the lung including reduced lung function.
Roto Inject Fluid Ndurance NOTE L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3% DMSO
& INTERCHANGEABLE extract as measured by IP 346.
LOW VISCOSITY BASE OIL European Union (EU) List of harmonised classification and labelling hazardous substances, Table 3.1, Annex VI, Regulation (EC)
(<20.5 CST @40C) No 1272/2008 (CLP) - up to the latest ATP

OCTYLATED The following information refers to contact allergens as a group and may not be specific to this product.
DIPHENYLAMINES & 4- Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The
NONYLPHENOXYACTIC pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic
ACID skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

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Serious Eye
STOT - Single Exposure
Damage/Irritation

Respiratory or Skin
STOT - Repeated Exposure
sensitisation

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

11.2 Information on other hazards

11.2.1. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

11.2.2. Other information

See Section 11.1

SECTION 12 Ecological information

12.1. Toxicity

Endpoint Test Duration (hr) Species Value Source

LL/EL/IL50 Not Available Fish >100mg/L 8
Roto Inject Fluid Ndurance
LL/EL/IL50 Not Available Algae or other aquatic plants >100mg/L 8

LL/EL/IL50 Not Available Daphnia Magna >100mg/L 8

interchangeable low Endpoint Test Duration (hr) Species Value Source

viscosity base oil (<20.5 Not Not Not
cSt @40C) Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

EC50 48h Crustacea 51mg/l 2

EC50 72h Algae or other aquatic plants >100mg/l 2

octylated diphenylamines
LC50 96h Fish >100mg/l 2

EC50 96h Algae or other aquatic plants 870mg/l 2

EC10(ECx) 72h Algae or other aquatic plants 0.06mg/l 2

Endpoint Test Duration (hr) Species Value Source

EC50 48h Crustacea 0.88mg/l 2
EC50 72h Algae or other aquatic plants 18.37mg/l 2
4-nonylphenoxyactic acid
Not
EC50(ECx) 24h Crustacea 7mg/l
Available

Not
LC50 96h Fish 9mg/l
Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

DO NOT discharge into sewer or waterways.

12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

octylated diphenylamines HIGH HIGH

4-nonylphenoxyactic acid LOW LOW

12.3. Bioaccumulative potential

Ingredient Bioaccumulation
octylated diphenylamines LOW (BCF = 5.5)

4-nonylphenoxyactic acid HIGH (LogKOW = 5.8)

12.4. Mobility in soil

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Ingredient Mobility

octylated diphenylamines LOW (Log KOC = 28640000)

4-nonylphenoxyactic acid LOW (Log KOC = 2496)

12.5. Results of PBT and vPvB assessment

PBT criteria vPvB criteria
P B T vP vB
fulfilled? fulfilled?

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interchangeable low viscosity No data No data No data No data No data
No No
base oil (<20.5 cSt @40C) available available available available available
octylated diphenylamines No No

4-nonylphenoxyactic acid No No

12.6. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

12.7. Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

SECTION 13 Disposal considerations

13.1. Waste treatment methods

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Disposal (if all else fails)
Product / Packaging This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.
disposal DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.

Waste treatment options EU Waste Disposal Code: 13 02 05

Sewage disposal options Not Available

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.1. UN number or ID
Not Applicable
number

14.2. UN proper shipping

Not Applicable
name

14.3. Transport hazard Class Not Applicable

class(es) Subsidiary Hazard Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

14.6. Special precautions

Hazard identification (Kemler) Not Applicable
for user
Classification code Not Applicable

Hazard Label Not Applicable

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Special provisions Not Applicable

Limited quantity Not Applicable

Transport Category Not Applicable

Tunnel Restriction Code Not Applicable

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable

14.2. UN proper shipping

Not Applicable
name

ICAO/IATA Class Not Applicable

14.3. Transport hazard
ICAO / IATA Subsidiary Hazard Not Applicable
class(es)
ERG Code Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

Special provisions Not Applicable

Cargo Only Packing Instructions Not Applicable

Cargo Only Maximum Qty / Pack Not Applicable
14.6. Special precautions
Passenger and Cargo Packing Instructions Not Applicable
for user
Passenger and Cargo Maximum Qty / Pack Not Applicable
Passenger and Cargo Limited Quantity Packing Instructions Not Applicable

Passenger and Cargo Limited Maximum Qty / Pack Not Applicable

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name

14.3. Transport hazard IMDG Class Not Applicable

class(es) IMDG Subsidiary Hazard Not Applicable

14.4. Packing group Not Applicable

14.5 Environmental hazard Not Applicable

EMS Number Not Applicable

14.6. Special precautions
Special provisions Not Applicable
for user
Limited Quantities Not Applicable

Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable

14.2. UN proper shipping

Not Applicable
name

14.3. Transport hazard

Not Applicable Not Applicable
class(es)

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

Classification code Not Applicable

Special provisions Not Applicable
14.6. Special precautions
Limited quantity Not Applicable
for user
Equipment required Not Applicable
Fire cones number Not Applicable

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
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Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
interchangeable low viscosity
Not Available
base oil (<20.5 cSt @40C)

octylated diphenylamines Not Available

4-nonylphenoxyactic acid Not Available

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type
interchangeable low viscosity
Not Available
base oil (<20.5 cSt @40C)
octylated diphenylamines Not Available
4-nonylphenoxyactic acid Not Available

SECTION 15 Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

interchangeable low viscosity base oil (<20.5 cSt @40C) is found on the following regulatory lists
Belgium Occupational Exposure Limits (French)
Chemical Footprint Project - Chemicals of High Concern List
European Union Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens or mutagens at work
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Group 1: Carcinogenic to humans
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Not Classified as Carcinogenic

octylated diphenylamines is found on the following regulatory lists

Belgium Occupational Exposure Limits (French)

EU European Chemicals Agency (ECHA) Community Rolling Action Plan (CoRAP) List of Substances
Europe EC Inventory
European Union - European Inventory of Existing Commercial Chemical Substances (EINECS)
International WHO List of Proposed Occupational Exposure Limit (OEL) Values for Manufactured Nanomaterials (MNMS)

4-nonylphenoxyactic acid is found on the following regulatory lists

Chemical Footprint Project - Chemicals of High Concern List
Europe EC Inventory
European Union - European Inventory of Existing Commercial Chemical Substances (EINECS)

Additional Regulatory Information

Not Applicable

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

Information according to 2012/18/EU (Seveso III):

Seveso Category Not Available

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

National Inventory Status

National Inventory Status

Australia - AIIC / Australia

Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (octylated diphenylamines; 4-nonylphenoxyactic acid)

China - IECSC Yes

Europe - EINEC / ELINCS /
Yes
NLP

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National Inventory Status

Japan - ENCS Yes

Korea - KECI Yes
New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA All chemical substances in this product have been designated as TSCA Inventory ‘Active'
Taiwan - TCSI Yes

Mexico - INSQ No (4-nonylphenoxyactic acid)

Vietnam - NCI Yes
Russia - FBEPH Yes

Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 23/12/2024

Initial Date 12/04/2017

Full text Risk and Hazard codes

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.

H317 May cause an allergic skin reaction.

H361f Suspected of damaging fertility.
H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

SDS Version Summary

Date of
Version Sections Updated
Update
Toxicological information - Chronic Health, Hazards identification - Classification, Composition / information on
20.1 18/07/2023
ingredients - Ingredients

Toxicological information - Acute Health (inhaled), Physical and chemical properties - Appearance, Hazards
21.1 23/12/2024 identification - Classification, Composition / information on ingredients - Ingredients, Handling and storage -
Storage (suitable container), Toxicological information - Toxicity and Irritation (Toxicity Figure)

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

Definitions and abbreviations

PC TWA: Permissible Concentration-Time Weighted Average
PC STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard

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OSF: Odour Safety Factor

NOAEL: No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
DNEL: Derived No-Effect Level
PNEC: Predicted no-effect concentration
MARPOL: International Convention for the Prevention of Pollution from Ships
IMSBC: International Maritime Solid Bulk Cargoes Code
IGC: International Gas Carrier Code
IBC: International Bulk Chemical Code

AIIC: Australian Inventory of Industrial Chemicals

DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]
Classification according to
regulation (EC) No
Classification Procedure
1272/2008 [CLP] and
amendments
, EUH208 Calculation method
, EUH210 Expert judgement

This document is copyright.

Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any
process without written permission from CHEMWATCH.
TEL (+61 3) 9572 4700.

end of SDS