05-05-2025

7001CJA101029240078 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Two infinite current carrying wires lie overlapping each other along x & y axes carrying current

I2 = I0cos and I1 = 2I0sin . A rectangular frame of negligible resistance with

capacitor of capacitance C is placed in the xy plane as shown. Select correct options.

(A)
Maximum emf induced in frame is

(B)
Maximum emf induced in frame is

(C)
Maximum charge on capacitor is

(D)
Current in frame at t = is zero

2) In the YDSE setup shown in figure a monochromatic of light of wavelength λ is incident on slit S.
Distance D is very large as compared to separation d between slits S1 and S2. Choose the correct

alternative(s):

Minimum value of d for which there is a bright fringe at O is

(A)
 Minimum value of d for which there is a bright fringe at O is
(B)

(C)
Position of central bright fringe for minimum value of d is above O
(D) Position of central bright fringe for minimum value of d is above O

3) A charged particle (+q) is moving simple harmonically on the x-axis with its mean position at
origin. Amplitude of the particle is A and its angular frequency is ω. Then choose the correct

option(s) :

(A) The magnitude of magnetic field at (2A, 0) will change periodically with period 2π/ω.
The maximum magnitude of the magnetic field at (0, A) is
(B)

The magnetic field at (A, A) at the moment the particle passes through , will be
(C)

(D) The magnitudes of magnetic field at (0, A) and (0, –A) will be same at any time.

4) An ideal liquid of density ρ is filled in a cylindrical container upto (3/4)th height. Now the liquid is
being rotated about vertical axis passing through its axis of symmetry with constant angular velocity
ω, such that liquid is on the verge of falling out of the container and free surface of liquid forms a
paraboloid. Whole situation is shown in the figure. Choose the correct option(s).
(A) 0
h =
ω=
(B)

(C)
= ρω2x

(D)
= ρg

5) The radii of a spherical capacitor are equal to a and b (b > a). The space between them is filled
with a dielectric of dielectric constant K and resistivity ρ. At t = 0, the inner electrode is given a
charge q0. Choose the correct option(s) :

(A)
Charge q on the inner electrode as a function of time is given by q =
(B) In a short time, the charge on the inner electrode will become zero
(C) After a long time, the charge on the outer sphere will become q0
The total amount of heat generated during the spreading of charge will be given by H =
(D)

6) A small object moves counter clockwise along the circular path whose centre is at origin as shown
in figure. As it moves along the path, its acceleration vector continuously points towards point S.
Then the object

(A) Speed up as it moves from A to C via B.

(B) Slows down as it moves from A to C via B.
(C) Slows down as it moves from C to A via D.
(D) Speed up as it moves from C to A via D.

SECTION-I (ii)

Common Content for Question No. 1 to 2

If a plane simple harmonic wave is traveling towards positive x axis, its wave function is given by S
=S0 sin (ωt – kx) Here S is longitudinal displacement of any particle. If we take a plane parallel to yz
plane all particles in this plane have same phase. This plane is called wavefront.
If a plane wave is traveling along direction , its wave function can be written as : S = S0 sin (ωt – k
) Let's call k (a wave vector) S = S0 sin(ωt – ) Wave vector points in direction of phase
velocity. In other words, the wave vector points in the normal direction to the wavefront.

1) Consider a wave function :

S = S0 sin(ωt – 2x + 2y + z) Here all variables are in SI units.
Select correct Statement :

(A)
Wavelength of the wave is .
(B) Particle (0, 0, 0) and (1, 1, 2) are on same wavefront.

(C)
The wave vector is at angle cos–1 from x-axis.
(D) The wave vector is at equal angle from positive x-axis and negative z-axis.

2) Consider following time wave function. S1 = S0 sin(ωt – 2x + 2y + z)

S2 = S0 sin(ωt + 2x – 2y – z) An observer is traveling towards +x axis with speed π m/s. The beat
frequency observed by the observer is :

(A)

(B) 2
(C) 1
(D)

Common Content for Question No. 3 to 4

A long rectangular slab of transparent medium of thickness d is placed on table with length parallel
to x-axis and width parallel to the y-axis. A ray of light traveling nearly along y-axis at origin. The
refractive index μ of the medium varies as μ = . The refractive index of the air is 1.

3) Determine the x-coordinate of the point A, where the ray intersect the upper surface of the slab-
air boundary.

(A) d(ln2)
(B) 2d(ln2)

(C)

(D) None of these

4) Write down the refractive index of the medium at A.

(A)
(B)
(C)
(D)

SECTION-II

1) Four short electric dipoles, 3 each of dipole moment P and the fourth of dipole moment 2P are
fixed at the vertices of an square of side length r. The dipole moments are oriented as shown in
diagram and the centre of the square lies at the origin. The electric field strength vector at the
origin is given as , then find value of (x + y).

2) An inductor (L), a resistance (R) and a ideal battery (emf ε) are connected in series. Circuit is
switched on at t = 0. The ratio of energy stored in the inductor at time t = L/R and energy dissipated

in resistance up to that instant is . Here α, β, γ and δ are integers, e is natural

logarithm. Find (α + β + γ + δ).

3) Consider the shown diagram where the two chambers separated by piston-spring arrangement
contain equal amounts of same ideal gas. Initially when the temperatures of the gas in both the
chambers are kept at 300 K, the compression in the spring is 10 cm. The temperature of the left and
the right chambers are now raised slowly to 400 K and 500 K respectively. The pistons are free to
slide (i.e. no friction between piston and chamber). Final compression in the spring is found to

be m. Find α. (Use = 22 )

4) A uniform heavy plank of length L is resting on two rods A and B of identical length and same
area of cross section but made up of different materials. It is observed that to keep the
plank horizontal, one rod is to be at the end of the plank (say rod A) and another rod (say rod B) is to

be at separation from centre of plank as shown in figure. Now the rods are kept between two rigid
walls such that separation between the walls is equal to the natural length of the rod. Now
temperature of both the rods is gradually increased in same manner, it is observed that thermal
stress developed in rod A is always thrice the thermal stress developed in rod B. Ratio of coefficient
of linear expansion of rod A to coefficient of linear expansion of rod B will be :
5) The chain of length L is released from rest on a smooth fixed incline with x = 0 as shown in the
figure. Determine velocity v of the chain when a half of the length has fallen of incline (Take L

= m) in m/s. (Neglect edge effect of inclined). (Take g = 10 m/s2)

6) A right angled prism is placed with air all around it. A horizontal incident ray strikes the face PQ
of prism normally, then undergoes total internal reflection twice as shown and exists the prism from

face PR horizontally. The refractive index of prism is μ and angle θ = 15º. If the value of μ is

then find n.

7) Starting from t = 0, activity of a radioactive sample is A1 at time t1 and A2 at time t2. If τ is average
life of sample then the number of nuclei decayed in time (t2 – t1) is β(A1 – A2) in proper unit. Here β is
an integer. Find β. (Given that t1 = 5 sec, t2 = 8 sec and τ = 7 sec)

8) In a screw gauge whose least count is 0.005 mm, when no object is present and the screw gauge
gap is completely closed the 4th division on its circular scale coincides with the reference line on
main scale reading zero. Now a wire is placed in it to measure its diameter, the reading on the main
scale advances by 6 divisions, whereas the circular scale reading becomes 3 times to the
corresponding reading when no object was placed. If there are 200 divisions on circular scale,
then find the diameter of wire in mm.

PART-2 : CHEMISTRY

SECTION-I (i)

1) A, B and C are three complexes of chromium (III) with empirical formula H12O6Cl3Cr. All the three
complexes have water and chloride ion as ligands. Complex A does not react with concentrated
H2SO4, whereas complexes B and C lose 6.75% and 13.5% of their original mass, respectively, on
treatment with concentrated H2SO4. The compound A,B and C respectively are

(A) A = [Cr(HO)5Cl] Cl2 ⋅ H2O,B = [Cr(H2O)4] Cl3, C = [Cr(H2O)6Cl2]

(B) A = [Cr(H2O)6] Cl3, B = [Cr(H2O)5Cl] Cl2 ⋅ H2O, C = [Cr(H2O)4Cl2]Cl ⋅ 2H2O
(C) A = [Cr(H2O)5] Cl3 ⋅ H2O, B = [Cr(H2O)6] Cl3, C = [Cr(H2O)4 Cl2] Cl ⋅ H2O
(D) A = [Cr(H2O)6 ] Cl3, B = [Cr(H2O)4 Cl2] Cl ⋅ 2H2O, C = [Cr(H2O)5Cl] Cl2 ⋅ H2O

2)

Attainment of the equilibrium A(g) ⇌ 2C(g) + B(g) gave the following of graph. Find the correct
option(s).

2
(A) Equilibrium const. KC for above reaction is 128 M .
(B) At equilibrium % dissociation of A is 40%
(C) At equilibrium % dissociation of A is 30%
(D) None of these

3) Which of the following statement(s) is/are correct?

(A) The degree of hydration decreases on moving down the group from Li+ to Cs+
Li2O2 is prepared by adding hydrogen peroxide and alcohol to a concentrated solution of lithium
(B)
hydroxide
Lattice energy of ionic solids having the same anion decreases with increase in the size of the
(C)
cation
(D) Lithium nitrate evolves nitrogen monoxide and oxygen on heating

4) A compound 'X' evolves CO2 when treated with NaHCO3 but gives negative test with tollen's
reagent and fehling's solution. On treatment with CHCI3, KOH, afoul smelling organic compound is
formed. If 'X' do not give positive iodoform test, which of the following satisfy the conditions to be
'X'.

(A)

(B)

(C)

(D)

5) Among the following, which reaction will give N-ethylcyclopentylamine as major product?

(A)

(B)
(C)

(D)

6) Consider the following reversible processes and choose the correct answer(s) from the options

given below:

(A) ΔSx→y = 95.74 JK

–1

(B) ΔSx→z = 0
(C) ΔSx→y = ΔSx→z + ΔSz→y = 95.74 JK
–1

(D) ΔSx→z→y = 0

SECTION-I (ii)

Common Content for Question No. 1 to 2

An organic compound A, C8H4O3 , in dry benzene in the presence of anhydrous AlCl3, gives compound
B. The compound B on treatment with PCl5 followed by reaction withH2/Pd, BaSO4 gives compound
C, which on reaction with hydrazine gives a cyclised compound D(C14H10N2).

1) The compound ‘B’ is

(A)
(B)

(C)

(D)

2) The compound ‘D’ is

(A)

(B)

(C)
(D)

Common Content for Question No. 3 to 4

Two moles of an ideal monoatomic gas is taken along the path ABC as shown in following figure.

Given TB = 2TA

3) Increase in internal energy in AB process is

(A) 3RTA

(B)
RTA

(C)
RTB

(D)
RTA

4) Work done by the gas in process ABC

(A) 2RTA
(B) –2RTA
(C) 4RTA
(D) None of these

SECTION-II

1) Among the given molecules, the number of metal sulphides precipitated by passing H2S in acidic
medium are .......... ZnS, PbS, CuS, NiS, MnS, CdS, CoS, HgS, SnS

2)
X = number of reaction in which will form as final product.

(1) (2)

(3) (4)

(5)
Find value of 'X' ?

3) A cube shaped crystal of an alkali metal, 2 mm on an edge, was vaporised in a 500.00 mL flask.
The pressure of the resulting vapour was 6.08 mm at 727° C. The structure of the solid metal is
known to be body centred cubic. If volume of each unit cell of this crystal is [P × 10–28 m3] then find
value of 'P'?
[Given : R = 0.08 L-atm mol–1K–1 , NA = 6 × 1023]

4) The ionisation constant of benzoic acid is 6.46 × 10–6 and Ksp for silver benzoate is 2.5 × 10–13. The
number of times silver benzoate is more soluble in a buffer of pH 3.19 compared to its solubility in
pure water will be ………
[Given : Antilog [–3.19] = 6.46 × 10–4 M]

5) X = total number of β-elimination products. Find the value of X ?

6) A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 320 torr at 300 K.
Calculate moles of ethyl alcohol in vapour phase if total moles of mixture in vapour phase are 10.29.
Given : Vapour pressure of pure ethyl alcohol = 350 torr ; Vapour pressure of pure propyl alcohol =
200 torr.
7) 40 ml of 0.5 M aqueous solution of oxalic acid (molar mass = 126) is shaken with 25.2 g of wood
charcoal. The final concentration of the solution after adsorption of oxalic acid is 0.25 M. If the
weight of oxalic acid adsorbed per g of carbon is represented as y × 10–2 then find the value of y.
(Assume volume of oxalic acid remains constant)

8) Two solid compounds A and B dissociates into gaseous products at 293 K as

(i) A(s) ⇌ X(g) + H2S(g).
(ii) B (s) ⇌ Y(g) + H2S(g).
Under the given condition, pressure over excess solid A when taken alone in a vessel is 68 mm and
that over excess solid B when taken alone in a vessel is 50 mm. The total pressure [in mm Hg] if
decomposition of both solids A & B takes place in the same vessel is ……… .

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let J = dx and K = . Then which of the following alternative(s)

is/are correct?

(A) 2J + 3K = 11π
(B) 4J2 + K2 = 26π2

(C)
J is period of

(D)
=4

2) A fair dice is rolled four times. Find the probability that each number is not greater than the
preceding number. When it is known that it shows '1' only once & that too in the fourth round.

(A)

(B)
less than
greater than
(C)

(D)

3) Let AB be a chord of the parabola x2 = 4y. A circle drawn with AB as diameter passes through the
vertex C of the parabola. If area of ΔABC = 20 [Link] then the coordinates of A can be

(A) (6, 9)
(B) (–6, 9)
(C) (–8, 16)
(D) (8, 16)

4) For a 3 × 3 invertible matrix A satisfying the characteristic equation , which

of the following is/are true [Here tr(A) = trace of matrix A, det(A)=determinant value of matrix A]

(A)

(B)

(C)

(D)

5) Given that a1,a2,a3 is an A.P in that order, a1 + a2 + a3 = 15; b1,b2,b3 is a G.P. in that order, and
b1b2b3 = 27. If a1 + b1,a2 + b2,a3 + b3 are positive integers and form a G.P. in that order, then

(A) maximum possible value of a3 is 15 (a1,a2,a3 are positive integer and unequal)
(B) minimum possible value of a3 is 3 (a1,a2,a3 are positive integer and unequal)

(C)
maximum possible value of a3 is

(D)
maximum possible value of a3 is

6) Let , x ≠ 0 and h(x) = tan(cos–1(sinx)) then

(A)
h(ƒ(x)) + h(g(x)) = ∀x>0
(B) h(ƒ(x)) + h(g(x)) = x ∀ x > 0
(C) h(ƒ(x)) + h(g(x)) = 0 ∀ x < 0
(D) 2h(ƒ(x)) + 4h(g(x)) = 3x ∀ x > 0

SECTION-I (ii)

Common Content for Question No. 1 to 2

Consider a plane P whose equation is x – y = 0 and two points A(3,2,4) and B(7,0,–10)

1) Coordinates of point P, which lies on plane Π such that |PA + PB| is minimum, are-

(A) (21,21,9)

(B)

(C)
(D)

2) Angle between and vector perpendicular to plane Π is-

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4

Let A,B,C be 3 sets such that

Let C1,C2 be the curves represented by A and B respectively while R be the region represented by C.

3) A points P(x1,y1) and Q(x2,y2) be such that P,Q ∈ A ∩ B, then point of intersection of tangents
drawn to C1 at P and Q is

(A) (2,3)
(B) (–4,4)
(C) (3,–3)
(D) (–5,5)

4) If minimum value of 'a' for which A ∩ C = A is α, then length of curve C2 lying in R corresponding
to
a = α, is

(A)
(B)
(C)
(D)

SECTION-II

1) Let x ln equals where m and n are relatively prime positive integer. Find
2m – n.
2) Let t100 = and S100 = , then the value of sec equals

3) A curve passes through (1, 5/6) and the slope of tangent at any point (x, y) is x2 – 3x ∀ x ∈ R. The
point of minimum ordinate on the curve where x > 0 is (a, b), then find the value of 2(a + b).

4) If reciprocal of radius of the smaller circle which touches all the lines represented by the equation

x2y – 2xy2 – 4xy = 0 is k , then find the value of (p – k) is

(where k and p are integers)

5) Let f be monic cubic polynomial such that f(1) = 14 – 1, f(2) = 24 – 2 and f(3) = 34 – 3. If f(4) = N,
then find the number of prime factors of N.

6) The quadratic polynomial P(x) satisfy the equation P(x) – P(x + 1) = 2x – 1 ∀ x ∈ R. If the greatest
value of P(x) in (–∞, 0] is 2, then value of P(–1) + P(1) is equal to

7) If the locus of middle point of point of contact of tangent drawn to the parabola y2 = 8x and the
foot of perpendicular drawn from its focus to the tangent is a conic then find the length of latus
rectum of the conic.

8) Let ƒ be a differentiable function such that 1 < ƒ'(x) < 2 ∀ x ∈ R and ƒ(3) = 1. If range of ƒ(5) is

(λ,μ), then value of is equal to

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. B,C,D B,D B,C,D B,C,D A,C,D A,C

SECTION-I (ii)

Q. 7 8 9 10
A. A B B A

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 2.00 8.00 9.00 6.00 2.00 0.75 7.00 6.04

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. B B A,B,C B,C A,B,C A,B,C

SECTION-I (ii)

Q. 25 26 27 28
A. B C A B

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 5.00 5.00 5.33 10.00 6.00 9.00 5.00 84.40

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,C,D A,B C,D A,B,C B,C B,C,D

SECTION-I (ii)

Q. 43 44 45 46
A. C A B C
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 4.00 3.00 1.00 3.00 3.00 2.00 9.00 1.20
 SOLUTIONS

PART-1 : PHYSICS

1)

I1 = 2I0sin

I2 = I0cos

ϕ1 =

ϕ2 =

ϕTotal =

ε=

εmax. =

Qmax = C
Q = CE

=C

Current in frame at t = is zero.

2)
Path difference = SS1 – SS2 + S1O – S2O

= –D+

=D –D+

∴ Δx = +

At O, y =

∴ Δx = + =λ

∴ dmin =
For central maxima,
Δx = 0

∴y=–

∴ Distance from O is
= 2dmin
=

3) (a) For (2A, 0), θ = 0° or 180°

∴ B = 0 permanent zero
(b) Magnetic field will be max at (0, A) when the particle passes through (0, 0)

Bmax = (c) sin θ =

 r=

V=ω =

B= =

= =
(d) same r, same θ

⇒ same B

0
4) h =

y= ⇒

ω=

= ρω2x

= –ρg

5) C =

R=
τ = RC = ρKε0
q = q0e–t/τ

q=
t = ∞, q = 0
Amount of heat generated H =

6) As the object moves from A to C via B the angle between acceleration vector and velocity
vector decreases from 90° and then increases back to 90°. Since the angle between velocity
and acceleration is acute, the object speeds up.
As the object moves from C to A via D the angle between acceleration vector and velocity
vector increases from 90° and then decreases back to 90°. Since the angle between velocity

and acceleration is obtuse, the object slows down.

7) (A)

∴λ=
(D) for angle between wave vector and +ve x-axis
= 2 ⇒ (3) (1) cosθ = 2

⇒ cosθ =
for angle between wave vector and –ve y-axis
= 2 ⇒ (3) (1) cosθ = 2

⇒ cosθ =

8) Component of velocity along the wave vector = =

Time between time consecutive beat =

=
Frequency = 2 Ans.

9)
μsini = 1⋅sin90º = constant

sin i =

x = 2dln2

10) μ =
Put x = 2dℓn2
μ=

11) Er =

Er = = 2E

Eθ =

Eθ = =E

∴x+y= =2
12) U1 =

U1 = ....(i)

U2 =

U2 =

13) Let ℓ1 and ℓ2 be the final length of the two parts, then from gas equation

........ (i)
Considering the equilibrium of the piston in initial and final states, we get
P0A = k x0, PA = kx.

⇒ ........(ii)
decrease in the length of spring = total increase in the length of the two chambers
x – x0 = ℓ1 + ℓ2 – 2ℓ0 ........ (iii)
from relation (i)

ℓ1 = , ℓ2 =
using (ii)

ℓ1 = , ℓ2 =
putting these in (iii)

0 0
x–x = (T1 + T2) – 2ℓ

putting values and solving, we get x = m

14) compression in rod A = ; young modulus = YA

compression in another rod = ; young modulus = YB

Since compression in both rod is same

⇒ ⇒2
Given
YA αA ΔT = 3YB αB ΔT

=6

15) εi = εf
mg sinθ + 0 = m1g sinθ – mg mv2

mg sinθ = (L2 + x2 – 2Lx)sinθ – + v2

gL sinθ = (L2 + x2 – 2Lx)sinθ – g+ v2

v=

16) In ΔABC,
θ + 90 – x + 2 (x + θ) = 180
∴ x = 90 – 3θ
⇒ μsinx = sin(90 – θ)

μ=

=
∴ n = 0.75

17) Let N0 be the initial number of nuclei, then

N1 = N0e–λt 1

and N2 = N0e–λt 2

∴ number of nuclei decayed = N1 – N2

= N0(e–λt – e–λt )
1 2

= (e–λt – e–λt )
1 2

= = (A1 – A2)τ.

18) Zero error = 4 × 0.005 = 0.02 mm

LC =
Pitch = 0.005 × 200 = 1mm
Measured diameter = (6 ×MSD) + (12 × 0.005)
= (6 × 1mm) + 0.06
 Measured value = 6.06 mm
Actual diameter = 6.06 – e
= 6.06 – 0.02
= 6.04 mm

PART-2 : CHEMISTRY

19) In complexes A and B, one halide (Cl− or Br−) is outside the coordination sphere and
complexes are :
[Cr(NH3)4Br2]Cl and [Cr(NH3)4BrCl]Br ‘A’ gives white precipitate of AgCl with excess of AgNO3
which dissolve in excess ammonia. Therefore, A must be [Cr(NH3)4Br2]Cl.
B gives a pale yellow precipitate with excess of AgNO3, which dissolve in concentrated
ammonia solution. Therefore, precipitate is AgBr and complex B is [Cr(NH3)4ClBr]Br. In both A
and B, hybridisation of chromium is d2sp3 and magnetic
moment (μ = BM) is 0.

20)

Degree of dissociation % α = × 100

%α = × 100
= 40%

21) Li+ ion being the smallest in size and has the highest charge/size ratio amongst the alkali
metal ions, get much more hydrated (i.e. holds more water molecules in its hydration sphere)
than Na+ ion and the latter gets more hydrated than K+ ion and so on.

23) Reaction (a, b, c) all give N-ethylcyclopentylamine as major product.

24) ΔS( x → y) taking place at constant temperature.

∴ ΔS = 2.303nR log

= 2.303nR log

= 2.303 × 5 × 8.314log
−1
= 95.74 JK
Thus, (a) is the correct option.
(b) ∵ q = 0,

∴ ΔS(x → z) = = 0
Thus, (b) is the correct option.
(c) x → z takes place adiabatically, hence temperature falls to 118.6 K.

ΔSx→z = 0,Cp = ;
For monoatomic gas

ΔSz→y = 2.303nCplog

= 2.303 × 5 × 2.5 × 8.314log

= 95.76 J K–1
Thus, ΔSx→y = ΔSx→z + ΔSz→y
= 95.76 J K–1
∴ (c) is the correct option
(d) ΔSx→z → y≠ 0, thus (d) is the incorrect option.

25)

26)

27) ΔU = nCv, mΔT

ΔU = 2 × × R × TA

28) WAB = –nRΔT

= – 2 × R × TA
= –2RTA

29) II group radicalsPb2+, Cu2+, Cd2+, Hg2+, Sn2+ are precipitated with H2S in acidic medium. IV
group cations Zn2+, Mn2+, Co2+, Ni2+ are precipitated with H2S in alkaline medium.

30)
(1) → →

(2) → →

(3) → →

(4) →

(5) →

31) Moles of metal =

= 9 33 × 10−5.
⇒ Total number of atoms = 9.33 × 10−5 × 6.023 × 1023
= 5.62 × 1019 atoms
∵ In bcc, there are 2 atoms per unit cell.
⇒ Number of unit cells in given sample

= × 5.62 × 1019 = 2.81 × 1019

⇒ Volume of one unit cell =

= 5.33 × 10−22 cm3

32) C6H5COOAg(s) ⇌ C6H5COO− + Ag+, K1 = Ksp

C6H5COO– + H+ ⇌ C6H5COOH; K2 =
C6H5COOAg(s) + H+ ⇌ C6H5COOH + Ag+

K3 =
Let x is the solubility of C6H5COOAg in a buffer of pH = 3.19
∴ [H+] = 10−3.19 = 6.46 × 10−4 M

∵ K3 = =

∴x=
x = 1.6 × 10−6 M
In aqueous solution, solubility

S= = 5 × 10–7 M

∴ = 3.20

33) Three different β-hydrogens are present in the reactant

∴ 5 different products will be form

34) PT = XAPAº + XBPBº

320 = XA × 350 + (1 – XA) × 200
XA = 0.8
XAPAº = YAPT

YA =

YA =

Number of moles of ethylalcohol in vapour phase = × 10.29 = 9

35) Millimoles of oxalic acid absorbed

= 40 × 0.5 – 0.25 × 40 = 10
∴ Number of moles of oxalic acid = 10 × 10–3
amount of oxalic acid = 10 × 10–3 × 126g
= 1.26 g
∴ Amount of oxalic acid adsorbed by per gram of charcoal

= = 5 × 10–2 = 0.05
 36) A(s) ⇌ X(g) + H2S(g)
KA = p × pH2S
∵ px = pH2S = 34 mm [∵ px = pH2S]
∴ KA = (34 × 34) = 1156 mm2
Similarly,
B(s) ⇌ Y(g) + H2S(g)
KB py × pH2S
∵ py + pH2S = 50mm
∴ py = pH2S = 25mm [∵ py = pH2S]
⇒ KB = 625.2 mm
In the mixture let, px = x, py = y, then total pH2S = (x + y)
∴ KA = px ⋅ pH2S = x( x + y) = 1156
…(i)
KB = py ⋅ pH2S = (x + y) = 625 …(ii)

∴ = 1.85 ⇒ x = 1.85 y
On putting value of x in Eq. (i), we have 1.85y(1.85y + y) = 1156
⇒ y = 14.81mm and x = 27.40mm
∴ Total pressure = px + py + pH2S
= 2( x + y)
= 2(14.81 + 27.40)
= 84.42 mm

PART-3 : MATHEMATICS

37) We have, and tan–1 x + cot–1x = ∀ x ∈ R Also is

also period of tan4(ax) + cot4(ax) is π/2a

38) Take any four number

Ex : 5, 1, 3, 3
They can be arranged only in one way such that each number is not greater than the
preceding i.e. 5, 3, 3, 1

Probability = =

39) A(2t1, t12) B(2t2, t22)

t1t2 = –4

Area = = 20
solving t1 = ±4, ±1

40)

⇒ + |A| = 0
Using Cayley Hamilton,

41) Correct Ans B,C

Let a1 = 5 – d, a2 = 5, a3 = 5 + d, b1 = , b2 = 3, b3 = 3q, then the given conditions indicate that

5–d+ and 5 + d + 3q are all positive integers and

.
It is easy to check that for getting maximum positive d, there are only four possibilities for

and (8,8).
(i) By solving the system of equations corresponding to (1,64), it follows that

(ii) By solving the system of equations corresponding to (2,32), it follows that

(iii) By solving the system of equation corresponding to (4,16), it follows that

or , = 2 or 10 ⇒ dmax = 10
(iv) By solving the system of equations corresponding to (8,8), it follows that

In summary, , hence the maximum possible value of a3 is

42)
h(x) = tan(cos–1(sinx))

h(x) = cotx
h(ƒ(x)) = cot(ƒ(x))

Now check options

43)
A + B lie on same side of plane, for
|PA + PB|minimum P must be point of intersects of line A'B with plane where A' is mirror image of
A

Line

44)

45) C1 : x2 + y2 = 4
C2 : y = x + 1

while region R is the disc centered at and radius = a

Let P(x1,y1)
Clearly AB : y – x = 1 ......(1)
is chord of contact
∴ AB : xx1 + yy1 = 4 ......(2)
(1) & (2) are identical
⇒ (x1y1) = (–4, 4)

46) Smallest possible value of 'a' for which

A ∩ C = A is a = 4.
∴
CD : y = x + 1

47) l = x ln (∞ × 0 form)

= x

put x = ; as x → ∞, t → 0

Hence l =

=1+ where ln(1 + t) = y; 1 + t = ey, hence t = ey – 1

=1+

48) We have,

S100 = + ... + .... (1)

Also,

S100 = + ... + ..... (2)

∴ On adding (1) and (2), we get
2S100 = 100 t100 + 100 ⇒ S100 –50 = 50t100

Hence, sec =3

49) f'(x) = x2 – 3x f(x) = – x2 + c

f(1) =

∴ +c=
⇒c=2

f(x) = +2
Minimum ordinate will be at x = 3

∴ f(3) =

∴ point (a, b) =
2(a + b) = 1

50) x2y – 2xy2 – 4xy = 0 ⇒ xy (x – 2y – 4) = 0

r=

= = 4cos2
= = 2cos2

51) f(x) = (x – 1) (x – 2) (x – 3) (c – x) + x4 – x
coefficient of x3 = 1
∴ c + 1 + 2 + 3 = 1 ⇒ c = – 5.
f(x) = (x – 1) (x – 2) (x – 3) (–5 – x) + x4 – x
f(4) = 3 ⋅ 2 ⋅ 1 (–9) + 44 – 4
= 198 = 2 × 32 × 11.

52) P(x) – P(x + 1) = 2x – 1 ∀ x ∈ R

P(x) = ax2 + bx + c
ax2 + bx + c – [a(x + 1)2 + b(x + 1) + c] = 2x – 1
ax2 + bx – [ax2 + 2ax + a + bx + b] = 2x – 1
–2ax – (a + b) = 2x – 1
–2a = 2 a+b=1
a = –1 b=2
2
P(x) = –x + 2x + c
∵ Greatest value of
P(x) in (–∞, 0] is 2

∴ P (0) = c = 2
∴ P(x) = –x2 + 2x + 2
P(1) = –1 + 2 + 2 = 3
P(–1) = –1 –2 + 2 = –1
P(1) + P(–1) = 2

53)
(h, k) is mid point of PT then

⇒
⇒ 2y2 = 9ax
a=2
y2 = 9x
 L.R = 9

54) (By LMVT)

∴
⇒ 3 < ƒ(5) < 5 ∴ λ = 3, µ = 5