TARGET : MHT-CET
CHEMISTRY
DPP (DAILY PRACTICE PROBLEMS) No. – 2
DPP Syllabus : d and f – Block Elements, Coordination Compounds, Halogen Derivatives of Alkanes and
Arenes, Alcohols, Phenols and Ethers
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1. Transition metal with low oxidation number will act as
(A) A base (B) An acid (C) An oxidising agent (D) None of these
2. Arrange Ce 3 , La 3 , Pm 3 and Yb 3 in increasing order of their ionic radii
(A) Yb 3 Pm 3 Ce 3 La 3 (B) Ce 3 Yb 3 Pm 3 La 3
(C) Yb 3 Pm 3 La 3 Ce 3 (D) Pm 3 La 3 Ce 3 Yb 3
KMnO 4 reacts with ferrous sulphate according to the equation
3.
MnO 4 5 Fe 2 8 H Mn 2 5 Fe 3 4 H 2 O
Here 10 ml of 0 .1 M KMnO 4 is equivalent to
(A) 20 ml of 0 .1 M FeSO 4 (B) 30 ml of 0 .1 M FeSO 4
(C) 40 ml of 0 .1 M FeSO 4 (D) 50 ml of 0 .1 M FeSO 4
2
4. The number of d-electrons in Fe (at no. of Fe 26 ) is not equal to that of the
(A) p - electrons in Ne (at. no. = 10) (B) s - electrons in Mg (at. no. = 12)
(C) d - electrons in Fe (D) p - electrons in Cl (at. no. of Cl 17 )
5. Among the following, the compound that is both paramagnetic and coloured is
(A) K 2 Cr 2 O 7 (B) ( NH 4 ) 2 (TiCl 6 ) (C) VOSO 4 (D) K 3 Cu (CN 4 )
6. In following reaction yMnO 4 xH C 2 O 4 yMn 2 CO 2 x H 2 O , x and y are
2
(A) 2 and 16 (B) 16 and 2 (C) 8 and 16 (D) 5 and 2
7. In which compound chromium has 6 oxidation state?
(A) K 2 Cr 2 O 7 (B) CrCl 3 (C) Cr (SO 4 )3 (D) None of these
8. Which of the following has highest paramagnetic character
(A) Mn (II) (B) Fe (II) (C) Co (II) (D) Ni (II)
9. The correct order of ionic radii of Y 3 ,La3 ,Eu3 and Lu 3 is
(A) La 3 Eu 3 Lu 3 Y 3 (B) Y3 La3 Eu3 Lu3
(C) Lu 3 Y 3 Eu 3 La 3 (D) Lu 3 Eu 3 La 3 Y 3
(Atomic No. Y = 39, La = 57, Eu = 63, Lu = 71)
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10. Oxidation number of Mn in K 2 MnO 4 and in KMnO 4 are respectively
(A) + 6 and + 7 (B) + 6 and + 6 (C) + 7 and + 7 (D) + 7 and + 6
11. When phosphine is passed through aqueous solution of copper sulphate, the product produced is
(A) Cu (OH ) 2 (B) Cu 3 P2 (C) Cu (PH 3 ) 4 2 (D) Cu (PH 3 ) 2 2
12. Cerium (Z 58) is an important member of the lanthanoids. Which of the following statements about
cerium is incorrect
(A) The +4 oxidation state of cerium is not known in solutions
(B) The +3 oxidation state of cerium is more stable than the +4 oxidation state
(C) The common oxidation states of cerium are +3 and +4
(D) Cerium (IV) acts as an oxidizing agent
13. A complex compound in which the oxidation number of a metal is zero, is
(A) K4[Fe(CN)6] (B) K3[Fe(CN)6] (C) [Ni(CO)4] (D) [Pt(NH3)4]Cl2
14. The name of the ring structure complex compound formed between metal ion and polydentate lignand
is
(A) simple complex (B) chelate complex
(C) polynuclear complex (D) None of these
15. The ionization isomer of Cr H2 O 4 Cl NO 2 Cl is
(A) Cr H2 O 4 O2N Cl2 (B) Cr H2 O 4 Cl2 NO2
(C) Cr H2 O 4 Cl ONO Cl (D) Cr H2 O 4 Cl2 NO 2 . H2 O
16. Which of the following show optical isomerism?
(en = ethylenediamine)
2 3
(A) Zn en NH3 2 (B) Co en 3
3 2
(C) Co H 2O 4 en (D) Zn en 2
17. One mole of the complex CoCl3 . 6H2O on reaction with excess of AgNO3 gives two moles of white
precipitate. Thus, complex is
(A) Co H2 O 6 Cl3 (B) Co H2 O 5 Cl Cl2 .H2 O
(C) Co H2 O 4 Cl2 Cl.2H2 O (D) Co H2 O 3 Cl3 .3H2 O
18. Which of the following complex species does not involve inner orbital hybridisation?
3 3 3 3
(A) CoF6 (B) Co NH3 6 (C) Fe CN6 (D) Cr NH3 6
19. The increasing order of the crystal field splitting power of some common ligands is
(A) H2O OH Cl F CN (B) H2O Cl OH CN F
(C) CN H2 O OH F Cl (D) Cl F OH H2 O CN
20. In which compound synergic effect is present?
2 2 2
(A) Ni CO 4 (B) NiCl4 (C) CuCl4 (D) Mn H2 O 6
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21. The metal ion in complex A has EAN identical to the atomic number of krypton. A is
(Atomic no. of Cr = 24, Fe = 26, Pd = 46)
(A) Pd NH3 6 Cl4 (B) Cr NH3 5 Cl SO 4
(C) Na 4 Fe CN 6 (D) K 3 Fe CN6
22. The donor site SCN– can be
(A) C (B) S (C) N (D) Both (B) and (C)
23. The complex shown below can exhibit
(A) Optical isomerism only (B) Geometrical isomerism only
(C) Both optical and geometrical isomerism (D) None of these
24. Which of the following complex will not show colour?
3 2
(A) Cr NH 3 6 Cl3 (B) K 3 VF6 (C) Sc H2 O 6 (D) NiCl4
25. Give the structure of : 2-Chloro-3-methylpentane
(A) (B)
(C) (D)
26. The correct structure of 4-bromo-3-methylbut-1-ene is
(A) Br CH C CH3 2 (B) CH2 CH CH CH3 CH2Br
(C) CH2 C CH3 CHCH2 Br (D) CH3 C CH3 CHCH2 Br
27. The reaction of toluene with Cl2 inpresence of FeCl3 gives predominantly
(A) m-chlorotoluene (B) Benzoyl chloride
(C) Benzyl chloride (D) o- and p-chlorotoluene
28. The catalyst used in the preparation of an alkyl chloride by the action of dry HCl on an alcohol is
(A) Anhydrous AlCl3 (B) FeCl3 (C) Anhydrous ZnCl2 (D) Cu
29. The reaction
Light
C3H8 Cl2 C3H7 Cl HCl
Is an example of
(A) Electrophilic Addition reaction (B) Free radical substitution reaction
(C) Oxidation reaction (D) Additional of halogen reaction
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aq. KOH
30. The major product formed in the following reaction is CH3CH Cl CH2 CH2OH
(A) CH3CH=CHCH2OH (B) CH2=CH-CH2CH2OH
(C) (D)
31. Identify the end product (C) in the following sequence:
SOCl2 KCN alc
C2H5 OH
Pyridine
A
H2 O / H
B C
(A) C5H5 CH2NH2 (B) C2H5 CONH2 (C) C2H5 COOH (D) C2H5 NH2 HCOOH
32. A compound is formed by the substitution of two chlorine atoms for two H atoms in propane. The
number of possible structural isomers are
(A) 4 (B) 3 (C) 2 (D)1
33. HBr reacts fastest with
(A) 2-Methyl propan-2-ol (B) Propan-1-ol
(C) Propan-2-ol (D) 2-Methyl propon-1-ol
34. The chirality of the compound
(A) d (B) R (C) S (D) l
35. For an organic compound
The correct statement is
(A) CH3 and Cl groups are coming out of the page
(B) H and OH groups are coming out of the page
(C) CH3 group is coming out while Cl group is going into the page
(D) All the above statements are incorrect
36. In which of the following – Cl is not replaceable easily?
(A) CH3Cl (B) CH3 – CH2 – Cl (C) CH2 = CH-CH2 – Cl (D)
ether,
37. The reaction 2C6H5 2Na C6H5 C6H5 2Na is called
(A) Fitting reaction (B) Wurtz-Fiting reaction
(C) Ulmann reaction (D) Wurtz reaction
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38. Which of the following does not give iodoform test?
(A) C2H5 OH (B) C6H5 OH (C) (CH3 )2 CHOH (D) All of these
39. Hydroboration-oxidation of propene yield
(A) CH3 CH2 CHO (B) CH3 CHOHCH3 (C) CH3 CHOHCH2OH (D) CH3 CH2CH2OH
40. The alcohol with highest boiling point is
(A) CH3 CH2CH2CH2OH (B) CH3 CH2CH(OH)CH3
(C) CH3 CH2C(CH3 )2 OH (D) CH3 C(CH3 )2 CH2 OH
41. The order for the acidic strength of 10 , 20 , 3 0 alcohols, H2 O and R C CH is
(A) RC CH 30 20 10 H2 O (B) 10 20 30 H2 O RC CH
(C) H2 O 10 20 30 RC CH (D) 30 20 10 H2 O RC CH
42. CH2OH CH2OH on heating with periodic acid gives
CHO H
(A) 2CO2 (B) 2HCOOH (C) (D) 2 C O
CHO H
43. In which molecule, cleavage by HlO 4 is not observed?
OH
OH OH
(A) (B)
OH
HO OH OH
OH
HO
HO O
(C) O (D)
O OH
HO OH
44. C 4H10 O gives white precipitate immediately with conc. HCl in the presence of anhydrous ZnCl2 . Alcohol
can be
OH
(A) (B)
O H
(C) OH (D)
OH
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45. Hydrolysis of alkyl halides has been compared. Which is incorrect comparison?
(A) CH3 CHBr CH2 CHCH2Br (B) CH2Br Br
(C) CH3l CH3 Cl (D) (CH3 )2 CHBr CH3 CH2CH2Br
46. Following alkene will give same product by any method out hydration, hydroboration-oxidation and
oxymercuration-demercuration
(A) CH3 CH CH2 (B) CH3 CH CHCH3
CH3 CHCH CH2
(C) l (D) CH2
CH3
47. Which is incorrect order dehydration of alcohol?
OH CHCH3
(A) OH OH (B)
OH
CH3 CH2CHCH3 CH3 CH2 CH2CH2OH
(C) OH CH3 CH2OH (D) l
OH
48. The product of the following reaction is
OH
Conc. HNO 3
?
Conc. H2 SO 4
(A) o-nitrophenol (B)m-Nitrophenol (C) 2, 4-dinitrophenol (D)2, 4, 6-trinitrophenol
49. Which of the following is most acidic?
OH
OH
(A) (B)
CHO
CHO
CH2 OH
(C) OH CHO (D)
(i) NaOH H /H O
50. Phenol 0
(ii) CO / 140 C
A B
2
In theis reaction, the end product B is
(A) Salicylaldehyde (B) Salicylic acid (C) Phenyl acetate (D) aspirin
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ANSWER KEY
MHT-CET_(DPP – 2)
Q. 1 2 3 4 5 6 7 8 9 10
Ans. C A D D C B A A C A
Q. 11 12 13 14 15 16 17 18 19 20
Ans. B A C B B B B A D A
Q. 21 22 23 24 25 26 27 28 29 30
Ans. C D C C A B D C B D
Q. 31 32 33 34 35 36 37 38 39 40
Ans. C A A B A D A B D A
Q. 41 42 43 44 45 46 47 48 49 50
Ans. C D A C A B B D C B
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