Solution of DPP # 6
TARGET : JEE (ADVANCED) 2015
Course : VIJETA & VIJAY (ADP & ADR)
CHEMISTRY
P4O10 MeMgBr Ca( OH)
1. X
2
H3O I2
(H ) ( H O)
7. 2
Nucleophilic addition-elimination reaction of amines with carbonyl compounds. The primary aromatic amine
generates a quinoline derivative with -diketones.
9.
O
|| ..-
12. Ph – CH – CH – C – O Ph – CH = CH – Br
| |
Br Br
19. NaHS
Br / KOH
2
CH NH / Cu O /
3 2 2
Zn / HCl
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20.
21. NaHSO3 on addition of carbonyl compound forms a salt. 22. Self explanatory.
23._ G.R. can not prepared in aqueous solution due to acid base reaction.
24. 2NaNO HCl
3 CH – CH – CH Cl
29. 2 2
AlCl3
34. The product is :
I = (+, +) (E) II = (+, +) (Z) III = (–, +) (E) IV = (–, +) (Z)
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O / dil. H SO /
36. 2
2
4
+ + + + +
major
[Total product 6]
37. O3 NH OH / H
2
excess
cis - cis
trans - trans
cis R trans
trans S cis
Total isomeric product = 4
38. (i) H PO / (ii) H PO /
3
2 3
2
(iii) H PO /
3
2
39. (C=O), (–OH), (CCH), (COOEt), (COOH)
Total = 5
41.
H2N – CH2 – CH2 – CH2 – COOH
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OH
42. (A) +
cannizarro
CH CHO / OH
3
(B) + CH3 — CH — CH2 — CHO
Aldol condansati on |
OH
(D) KCN / H (d + )
OH
43. (A) int ramolecula r H2O
aldol condensati on
O Et
(B) Dieckmann Re action
(Intra claisen condensati on )
(C) Perkin's condensation reaction.
(D) Benzil-Benzilic acid rearrangement.
45. (A) Nu-addition on C=O group,
Electrophilic substitution on ring
(B) Aliphatic Nu-substitution on C–Br, Elimination of R–X,
Electrophilic substitution on ring.
(C) Aliphatic Nu-substitution on C–Br, Elimination of R–X
Electrophilic addition on C=C
(D) Electrophilic addition on C=C
Electrophilic substitution on ring.
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Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029