SAFETY DATA SHEET RAMPART® FUNGICIDE
SDS NUMBER: 30654-16B-LPI SDS REVISIONS: SEC. 1 DATE OF ISSUE: 10/25/16 SUPERSEDES: 06/09/16
FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CALL DAY OR NIGHT 1-800-561-8273 or
CHEMTREC – DAY OR NIGHT 1 800-424-9300
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1.1 PRODUCT IDENTIFIER:
TRADE NAME: RAMPART® FUNGICIDE
1.2 RECOMMENDED USE: FUNGICIDE FOR SUPPRESSION OF DOWNY MILDEW AND VARIOUS OTHER DISEASES
1.3 DISTRIBUTED BY:
LOVELAND PRODUCTS CANADA, INC.
PO Box 5234 | 64137 Hwy 543 E • High River, Alberta T1V 1M4
1.4 24 Hour Emergency Phone: (Chemtrec): 1-800-424-9300 (Toll Free) - Additional Emergency Phone 1-800-561-8273
Loveland Technical Service: 1-800-328-4678
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
Eye Damage/Irritation Category 2B H320
2.2 Label elements
None
Signal word: WARNING
Hazard Statement: H320 – Causes eye irritation.
Precautionary
Statement: P264 – Wash hands and face thoroughly after handling.
(Prevention):
Precautionary P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
Statement: easy to do. Continue rinsing.
(Response): P337+P313 – If eye irritation persists: Get medical advice/attention.
2.3 Other hazards
None known
PAGE 1 OF 6
SAFETY DATA SHEET RAMPART® FUNGICIDE
SDS NUMBER: 30654-16B-LPI SDS REVISIONS: SEC. 1 DATE OF ISSUE: 10/25/16 SUPERSEDES: 06/09/16
3. COMPOSITION, INFORMATION ON INGREDIENTS
3.1 Substances
3.2 Mixtures
Chemical Name: CAS No. Concentration
[%]
Monopotassium salts of Phosphorous acid 13977-65-6 0 – 60
Dipotassium salts of Phosphorous acid 13492-26-7 0 – 60
4. FIRST AID MEASURES
4.1 Description of First Aid Measures
General Advice: Get medical attention if symptoms occur.
Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control centre or doctor for treatment advice.
Ingestion: Call a poison control centre or doctor immediately for treatment advice. Have person sip a glass of water if able to
swallow. Do not induce vomiting unless told to do so by a poison control centre or doctor. Do not give anything by mouth
to an unconscious person.
Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centre or
doctor for treatment advice.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferable by
mouth-to-mouth, if possible. Call a poison control centre or doctor for treatment advice.
4.2 Most Important Symptoms and Effects, Acute and Delayed
Symptoms: Causes eye irritation.
4.3 Immediate Medical Attention and Special Treatment
Treatment: NOTES TO PHYSICIAN: There is no specific antidote.
FOR A MEDICAL EMERGENCY INVOLVING THIS PRODUCT CALL: 1-800-561-8273
Take container, label or product name and Fertilizers Act Registration Number with you when seeking medical attention.
5. FIRE FIGHTING MEASURES
5.1 EXTINGUISHING MEDIA:
Suitable Extinguishing Media: Foam, carbon dioxide (CO2), dry powder, water spray. Do not use water jet as this will spread the fire.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
Specific Hazards During Firefighting: During a fire, oxides of carbon and silicon dioxide can be released.
5.3 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS
Special Protective Equipment for Firefighters: Self-contained breathing apparatus and full protective gear should be worn in fighting large fires
involving chemicals. Use water spray to keep fire exposed containers cool. Keep people away. Isolate
fire and deny unnecessary entry.
PAGE 2 OF 6
SAFETY DATA SHEET RAMPART® FUNGICIDE
SDS NUMBER: 30654-16B-LPI SDS REVISIONS: SEC. 1 DATE OF ISSUE: 10/25/16 SUPERSEDES: 06/09/16
6. ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Personal Precautions: Avoid inhalation of vapours and dusts and contact with skin and eyes. Ensure adequate ventilation.
Wear suitable protective clothing.
6.2 ENVIRONMENTAL PRECAUTIONS
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water. Do not allow to enter
drains, sewers, or watercourses.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN-UP
Methods for Clean-Up: Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. After removal flush
contaminated area thoroughly with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
Remove residual contamination.
Never return spills to original containers for re-use.
7. HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING:
Advice on Safe Handling: Avoid inhalation of dusts, vapours / spray and contact with eyes, skin and clothing. Do not breathe
dusts, mist or vapour. Wear personal protective equipment. Do not use in areas without adequate
ventilation. Avoid prolonged exposure. Wash thoroughly after handling. Do not empty into drains.
Handle and open container with care. Use care in handling/storage. Wash before eating, drinking
and/or smoking.
7.2 CONDITIONS FOR SAFE STORAGE:
Requirements for Storage Areas and Containers: Store in a cool, dry well-ventilated area away from direct sunlight, preferably in a locked storage area
away from children, feed and food products and seed. Keep containers tightly closed when not in use.
Do not contaminate water, food or feed by storage or disposal.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS
U.S. Workplace Exposure Level (ACGIH) TLVs
Components Type Value
No listings
U.S. Workplace Exposure Level (OSHA) PELs
Components Type Value
No listings TWA
Biological limit values
ACGIH Biological Exposure Indices
Components Value Specimen
No listings
8.2 EXPOSURE CONTROLS:
Engineering Measures
Provide adequate general and local exhaust ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors and spray
mists. Provide eyewash station and safety shower.
Individual Protection Measures:
Eye / Face Protection: Goggles or shielded safety glasses are recommended.
Skin Protection: Chemical resistant clothing is recommended. Routinely wash work clothing and protective equipment to remove
contaminants. The use of chemical-resistant gloves is recommended when handling undiluted product. Be aware
that the liquid may penetrate the gloves. Frequent change is advisable.
Respiratory Protection: In case of inadequate ventilation or risk of inhalation of mists or vapours, use suitable respiratory equipment
approved by MSHA/NIOSH. Wear respiratory protection during operations where spraying or misting occurs. If
respirators are used, a program should be in place to assure compliance with national or provincial standards. Wear
air supplied respiratory protection if exposure concentrations are unknown.
PAGE 3 OF 6
SAFETY DATA SHEET RAMPART® FUNGICIDE
SDS NUMBER: 30654-16B-LPI SDS REVISIONS: SEC. 1 DATE OF ISSUE: 10/25/16 SUPERSEDES: 06/09/16
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 APPEARANCE : Liquid.
ODOUR: None.
ODOUR THRESHOLD: No data available.
COLOUR: Colourless.
pH: 6.1 - 6.5.
MELTING POINT / FREEZING POINT: -15 °C / 5 °F (Freezing point).
BOILING POINT: 212 °F / 100 °C
FLASH POINT: No data available.
FLAMMABILILITY (solid, gas): No data available.
UPPER / LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: No data available.
VAPOUR PRESSURE: No data available.
SOLUBILITY: Soluble.
PARTITION CO-EFFICIENT, n-OCTANOL / WATER: No data available.
AUTO-IGNITION TEMPERATURE: No data available.
DECOMPOSITION TEMPERATURE: No data available.
VISCOSITY: No data available.
SPECIFIC GRAVITY (Water = 1): 1.41 g/ml.
DENSITY: 1.41 kg/L / 11.77 lbs./gal.
Note: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items.
10. STABILITY AND REACTIVITY
10.1 REACTIVITY
Stable
10.2 CHEMICAL STABILITY
Stable under normal temperature conditions
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No reactions known under normal use conditions. Will not polymerize.
10.4 CONDITIONS TO AVOID
Heat.
10.5 INCOMPATIBILE MATERIALS
None known.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
None known.
11 TOXICOLOGICAL INFORMATION
11.3 LIKELY ROUTES OF EXPOSURE
Eye contact, skin contact.
LC50 (rat): > 4.1 mg/L 4HR.
LD50 Oral (rat): > 5000 mg/kg.
LD50 Dermal (rabbit): > 3000 mg/kg.
Acute Toxicity Estimates: No data available.
Eye Irritation (rabbit): Irritant.
Skin Irritation (rabbit): Not an irritant.
Inhalation: No data available.
Ingestion: No data available.
Specific Target Organ Toxicity: No data available.
Aspiration: No data available.
Skin Sensitization (guinea pig): Not a sensitizer
Carcinogenicity: None listed.
Germ Cell Mutagenicity: No data available.
Interactive Effects: None known.
PAGE 4 OF 6
SAFETY DATA SHEET RAMPART® FUNGICIDE
SDS NUMBER: 30654-16B-LPI SDS REVISIONS: SEC. 1 DATE OF ISSUE: 10/25/16 SUPERSEDES: 06/09/16
12 ECOLOGICAL INFORMATION
12.3 ECOTOXICITY
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a
harmful or damaging effect on the environment. This product is not intended for use in aquatic settings.
Ecotoxicological Data
Species Test Results______________________________
No data available.
Drift or runoff may adversely affect non-target plants.
Do not apply directly to water.
Do not contaminate water when disposing of equipment wash water.
Do not apply when weather conditions favor drift from target area.
12.2 PERSISTENCE AND DEGRADABILITY
Biodegradability: No data available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation: No data available.
12.4 MOBILITY IN SOIL
Soluble in water and may disperse in soil.
12.5 OTHER ADVERSE EFFECTS
Assessment: No data available.
13 DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Do not reuse containers for any purpose. Make the empty container unsuitable for further use. If there is no container collection site in your
area, dispose of the container in accordance with provincial requirements. For information on disposal of unused, unwanted product, contact
the manufacturer or the provincial regulatory agency. Do not contaminate water, food, or feed by storage or disposal. For disposal, the
container may be returned to the point of purchase (distributor/dealer). It must be refilled by the distributor/dealer with the same product. Do
not reuse the product container for any other purpose.
14 TRANSPORT INFORMATION
14.3 LAND TRANSPORT
TDG Shipping Description: NOT REGULATED.
PAGE 5 OF 6
SAFETY DATA SHEET RAMPART® FUNGICIDE
SDS NUMBER: 30654-16B-LPI SDS REVISIONS: SEC. 1 DATE OF ISSUE: 10/25/16 SUPERSEDES: 06/09/16
15 REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS
NFPA & HMIS Hazard Ratings: NFPA HMIS
1 Health 0 Least 1 Health
0 Flammability 1 Slight 0 Flammability
0 Instability 2 Moderate 0 Reactivity
3 High B PPE
4 Severe
SARA Hazard Notification/Reporting
SARA Title III Hazard Category: Immediate __Y__ Fire __N__ Sudden Release of Pressure __N__
Delayed __N__ Reactive __N__
Reportable Quantity (RQ) under U.S. CERCLA: Not listed.
SARA, Title III, Section 313: Not listed.
RCRA Waste Code: Not applicable.
CA Proposition 65: Not applicable.
WHMIS [Canada]: Not controlled under WHMIS.
16 OTHER INFORMATION
SDS STATUS: Section 1 revised.
PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental Health and Safety
PEST CONTROL PRODUCTS ACT REG. NO.: 30654
®Rampart is a registered trademark of Loveland Products Canada, Inc.
Disclaimer and Limitation of Liability: This data sheet was developed from information on the constituent materials identified herein and does not
relate to the use of such materials in combination with any other material or process. No warranty is expressed or implied with respect to the
completeness or ongoing accuracy of the information contained in this data sheet, and LOVELAND PRODUCTS CANADA, INC. disclaims all liability for
reliance on such information. This data sheet is not a guarantee of safety. Users are responsible for ensuring that they have all current information
necessary to safely use the product described by this data sheet for their specific purpose.
PAGE 6 OF 6