03-08-2025

0999DJA161103250005 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Consider east as positive x-axis, north as positive y-axis. A girl walks 10 m east first time then 10
m in a direction 30° west of north for the second time and then third time in unknown direction and
magnitude so as to return to her initial position. What is her third displacement in unit vector
notation?

(A)
(B)
(C)
(D) She can not return

2) Precession is the result of the angular velocity of rotation (spin) and the angular velocity produced
by the torque. It is an angular velocity about a line that makes an angle θ with the permanent
rotation axis. In the diagram, a top of mass m is performing precession motion. The torque due to
gravitational force Fg causes a change in the angular momentum L in the direction of that torque
causing the top to process with angular velocity ωP which is given by: (Given r is the distance of
COM from point of rotation ‘P’. Is & ωs are the moment of inertia and angular velocity of top about

spin axis respectively.)

(A)

(B)

(C)

(D)

3) A horizontal electric wire is stretched at a height h = 10 m above the ground. A boy standing on
the ground can throw a stone at a speed u = 20 ms–1. The maximum horizontal distance x at which a
bird sitting on the wire can be hit by the stone is (Assume that the height of boy is negligible and
stone does not strike with wire.)
(A) m
(B)
(C)
(D)

4) After falling from rest through a distance y, a body of mass m begins to raise. A body of mass M
(M > m) that is connected to it by means of a light inextensible string passing over a fixed smooth

pulley. The time it will take for the body of mass M to return to its original position is :-

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Two infinite, parallel, nonconducting sheets carry equal positive charge density σ. One is placed
in the y-z plane at x= 0 and the other at distance x = a. Take potential V = 0 at x = 0. If Vx is the
potential at a distance x from y-z plane, then :-

(A) For , potential Vx = 0

(B)
For , potential

(C)
For , potential

(D)
For , potential

2) PQ is a smooth inclined plane whose angle of inclination θ can be raised in such away that point Q
remains fixed & P moves in a vertical line RS. A particle slides from point P. At different values of θ,
the time of descent Td (from P to Q) is noted. Which of the following is true about Td ? (QS = ℓ)

Td minimum is
(A)

(B) Td is minimum when θ approaches 90°

(C) Td first increases & then decreases
(D) Td first decreases & then increases

3) A spherical planet of radius R has spherically symmetrical distribution of mass density, varying as
square of the distance from the centre, from zero at centre to maximum value ρ0 at its surface.

(A)
The value of escape velocity of a mass m at the surface of planet is .
The value of acceleration due to gravity 'g' varies inside the planet as cube of the distance from
(B)
centre.
The value of escape velocity is same as the escape velocity from another planet of same total
(C)
mass & radius but having uniform mass density.
The energy required to impart escape velocity to particles of masses 'm' & '2m', at the surface
(D)
of planet, will be in ratio 1 : 2.

SECTION-I (iii)

1) A bird in air is diving vertically over a tank with speed 6 m/s and a fish in the tank is rising
upward along the same line with speed 4 m/sec. Base of tank is silvered. [Take µ = 4/3]
 List-I List-II

Speed of the image of fish as seen by bird

(P) (1) 3 m/s
directly

Speed of image of fish formed after reflection

(Q) (2) 4 m/s
from the mirror as seen by bird

Speed of image of bird relative to fish looking

(R) (3)
upwards m/s

Speed of image of bird relative to the fish

(S) (4) 9 m/s
looking downward in the mirror

(5) 12 m/s
(A) P → 4;Q → 2;R → 5;S → 3
(B) P → 4;Q → 1;R → 5;S → 2
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 3;Q → 1;R → 5;S → 2

2) Two transparent media of refractive indices µ1 and µ3 have a solid lens shaped transparent
material of refractive index µ2 between them as shown in figures in List-II. A ray traversing these
media is also shown in the figures. In List-I different relationships between µ1, µ2 and µ3 are given.
Match them to the ray diagrams shown in List-II.

List-I List-II

(P) µ1 < µ2 (1)

(Q) µ1 > µ2 (2)

(R) µ2 = µ3 (3)

(S) µ2 > µ3 (4)

 (5)

(A) P → 1;Q → 3;R → 2;S → 4

(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 2;Q → 3;R → 2;S → 4
(D) P → 1;Q → 3;R → 5;S → 3

3)

Match the entries on left side with entries on right side when left most plate is grounded. Then

List-I List-II
(P) The charge appearing on outer surface of right most plate is (1) 0
(Q) The charge appearing on outer surface of left most plate is (2) Q
(R) The charge appearing on left surface of middle plate is (3) –Q
(S) The charge appearing on right surface of middle plate is (4) 2Q
(5) –2Q
(A) P → 1;Q → 2;R → 3;S → 5
(B) P → 1;Q → 1;R → 5;S → 5
(C) P → 1;Q → 1;R → 5;S → 4
(D) P → 2;Q → 2;R → 3;S → 4

4) List-I shows different charge distributions and short electric dipole at a distance x from the
charge distributions. List-II gives the dependence of force acting on the dipole as of function of x.

List - I List - II

(P) (1) x–2

Uniformly charged thin infinite disc.

 (Q) (2) x–3

Uniformly charged thick infinite sheet. Dipole is placed inside

the sheet.

0
(R) (3) x

Uniform infinite line of charge.

(S) (4) x–∞

Uniformly charged sphere. Dipole is placed outside the

sphere.

(5) x–4
(A) P → 4;Q → 1;R → 3;S → 2
(B) P → 4;Q → 3;R → 1;S → 2
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 3;Q → 4;R → 1;S → 2

SECTION-II

1) A point object is located at a distance of 100 cm from a screen. A lens of focal length 23 cm
mounted on a movable frictionless stand is kept between the source and the screen. The stand is
attached to a spring of natural length 50 cm and spring constant 800 N/m as shown. Mass of the
stand with lens is 2 kg. How much minimum impulse P (in kg m/s) should be imparted to the stand
so that a real image of the object is formed on the screen four times during a complete oscillation.
All these are separated by same time interval. (Neglect width of the stand.)
2) A man walking downhill with velocity u finds that his umbrella gives him maximum protection
from rain when he holds it such that the stick is perpendicular to the hill surface. When the man
turns back and climbs the hill with velocity u, he find that it is most appropriate to hold the umbrella
stick vertical. Find the speed o0f raindrops (in m/s) w.r.t. ground. The inclination of the hill is θ =

30°.

3) A cart is moving with a constant acceleration of 2 m/s2 as shown in figure. A person of mass 6 kg
is pulling a block of mass 3kg with the help of string. The coefficient of friction between cart and
block is 0.5 then minimum value of force applied by the person to slide the block on the cart is given

by N. Fill the value of α.

4) A tunnel is dug along the chord of the earth at a perpendicular distance from the earth’s centre.
Walls of tunnel are frictionless. A particle of mass m is released into tunnel. Find the ratio of normal

reactions at point P & Q between tunnel and particle as shown in the figure.

5)

A sphere of radius R has charge density given by , where ρ0 is a constant, r is

distance from centre of sphere. For a spherical gaussian surface of radius R centered at the centre
of sphere, the flux is zero. Find 'n'.

6) In the arcade game shown, the object of the game is to propel the small ball from the ejector
device at O in such a way that is passes through the small aperture at A and strikes the contact point
at B. The player controls the angle θ at which the ball is ejected and the initial velocity v0. The
trajectory is confined to the frictionless xy-plane, which is vertical. Find the value of θ that gives
success. The coordinates of A and B are (2ℓ, 2ℓ) and (3ℓ, 2ℓ), respectively. [Given tan–1(5/3) = 59°].

Write approximately θ/12 (in degrees).

PART-2 : CHEMISTRY

SECTION-I (i)

1) For different aqueous solutions of 0.1M urea, 0.1M NaCl, 0.1M BaCl2, the incorrect statement(s)
is /are :

(A) Order of vapour pressure is Urea > NaCl > BaCl2

(B) Order of boiling point of solution is BaCl2 > NaCl > Urea
(C) Order of freezing point of solution is Urea > NaCl > BaCl2
(D) Order of osmotic pressure is Urea > NaCl > BaCl2

2) Among the following, the most acidic oxide is

(A) Na2O
(B) SO3
(C) N2O
(D) Cl2O7

3) 2 mole carbon reacts with 1.5 mole O2 such that no any reactant will be left and simultaneously
produced CO and CO2 gases. Molar mass of final gaseous mixture is :

(A) 36 g/mole
(B) 30 g/mole
(C) 12 g/mole
(D) 32 g/mole

4)

The Henry's law constant for solubility of a gas A in water is 105 atm at 300 K. The mole fraction of
gas A in gaseous mixture is 0.4. Calculate the number of mole of gas A from gaseous mixture
dissolved in 25 mol of water at 300 K and 10 atm pressure.
(A) 0.1
(B) 0.01
(C) 0.001
(D) 2.5 × 10–3

SECTION-I (ii)

1) Which of the following set of quantum number is/are not possible for Ac ?

(A) n = 3, = 3, m = 0 s = +1/2
(B) n = 6, = 2, m = –1 s = –1/2
(C) n = 6, = 0, m = –2 s = +1/2
(D) n = 7, = 0, m = 0 s = –1/2

2)

For the reaction A + B → product, following data is given

A0 B0 Rate0
Exp. No.
M M M/s
1 0.02 0.03 4 × 10–3
2 0.04 0.06 1.6 × 10–2
3 0.01 0.06 4 × 10–3
which of the following is correct -
(A) Given reaction may be elementary
(B) Value of rate constant is 6.67 M–1s–1
(C) Given reaction may be complex
(D) If volume of container is doubled in first experiment, rate becomes 10–3 M s–1

3) Metallic magnesium has a hexagonal close-packed structure and a density of 2 g/cm3. Assume
magnesium atoms to be spheres of radius(r). 74% of the space of crystal is occupied by atoms.
(Given : NA = 6 × 1023, (1.52)3 = 3.53, Atomic mass of Mg = 24)
Select the correct statement(s).

(A) Volume of unit cell is 8.88 × 10–23 cm3.

(B) Mass of one unit cell is 144 g.
(C) Each magnesium atom is surround by 12 other magnesium atoms.
(D) Volume occupied by the each atom is approximately 1.48 × 10–23 cm3.

SECTION-I (iii)

1) Match the list:

List- I List- II
 Maximum
number
Chemical species of atom
in one
plane

(P) SF4 (1) 3

(Q) (2) 4

(R) SF6 (3) 5

(S) IF7 (4) 6

(5) 7
The correct option is
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 2;Q → 3;R → 3;S → 3
(C) P → 1;Q → 3;R → 3;S → 4
(D) P → 2;Q → 3;R → 2;S → 4

2) Answer the following by appropriately matching the lists based on the information given in the
paragraph.

List-I List-II

(P) C2H5Br + C2H5Cl (1) ΔHmix = 0

(Q) CH3COCH3 + C2H5OH (2) ΔHmix > 0

(R) CH3COCH3 + CHCl3 (3) ΔHmix < 0

(S) H2O + C2H5OH (4) can form maximum boiling azeotrope

(5) can form minimum boiling azeotrope

Which of the following is an CORRECT match ?

(A) P → 2;Q → 1;R → 3;S → 4
(B) P → 1;Q → 3;R → 4;S → 5
(C) P → 4;Q → 1;R → 2;S → 3
(D) P → 5;Q → 1;R → 2;S → 2

3) A metal crystallises in FCC lattice. The unit cell edge length is 'a'. Match the parameters given in
List-I with the correct distance in List-II.

List-I List-II

(P) Shortest distance between two atoms. (1)

(Q) Shortest distance between tetrahedral voids. (2)

 (R) Shortest distance between octahedral voids. (3)

Shortest distance between tetrahedral and octahedral

(S) (4)
voids.

(5) a
(A) P → 2;Q → 1;R → 3;S → 4
(B) P → 1;Q → 2;R → 1;S → 3
(C) P → 1;Q → 3;R → 2;S → 1
(D) P → 5;Q → 3;R → 1;S → 3

4) Answer the following by appropriately matching the lists based on the information given
in the paragraph.

List-I List-II

(P) A + B → C + D, rexp. = k [A] (1) , when two

moles of A are taken for
each mole of B

Pseudo first order reaction

(Q) A + B → C + D, rexp. = k [A][B] (2) with respect to A, when B is
in large excess

(R) 2A + B → C + D, rexp. = k [B] (3) , when one

moles of A are taken for
each mole of B

(S) 2A + B → C + D, rexp. = k[A][B]2 (4) May be elementary reaction

Pseudo second order

(5) reaction with respect to B,
when A is in large excess
Which of the following options has the INCORRECT combination considering List-I and List-II ?
(A) P → 3;Q → 1;R → 4;S → 5
(B) P → 2;Q → 1;R → 4;S → 5
(C) P → 3;Q → 2;R → 4;S → 2
(D) P → 1;Q → 3;R → 4;S → 2

SECTION-II

1) Rate constant k varies with temperature by equation , log k(min–1) = 5 – . Value of Ea = ?

(Multiple your answer by 100)

2) The molality of 1 litre solution with y % (w/v) of CaCO3 is 2. The weight of the solvent present in
the solution is 450 g then, value of y is : [At. wt. : Ca = 40 ; C = 12 ; O = 16]
3)

The number of units, which are used to express concentration of solutions from the following is
_________.
Mass percent, Mole, Mole fraction, Molarity, ppm, Molality.

4) Calculate the packing fraction of ideal NaCl solid if ions along an axis connecting opposite face
centres are removed. (Given : = 1.414, (0.414)3 = 0.07, π = 3.14)
(Multiple your answer by 100)

5) 1 g mixture, consisting of equal number of moles of carbonates of two alkali metals, required
44.26 ml of 0.5 M HCl for complete reaction. If the atomic mass of one metal is 7. If mass of metal
carbonate having metal of atomic mass 7 in the original mixture is X × 10–4 gram. Find the value of
X.

6) The vapour density of a sample of N2O4(g) is at 4.8 atm at 127ºC. The value of Kp (in atm) of
the reaction :
N2O4(g) 2NO2(g) , at 127ºC, is :
(Multiply your answer by 10)

PART-3 : MATHEMATICS

SECTION-I (i)

1) If the tangent at a point P, with parameter t1, on the curve x = 4t2+3, y=8t3–1, t ∈ R, meets the
curve again at a point Q, then the coordinates of Q are

2 3
(A) (t1 + 3, –t1 – 1)
2 3
(B) (4t1 + 3, –8t1 – 1)
2 3
(C) (t1 + 3, t1 –1)
2 3
(D) (16t1 + 3, –64t1 – 1)

2) The shaded region in the figure is

(A)
(B)
(C)
(D)

3) If ƒ(x) = 2|x – 1| + 3|x + 1| – |x – 3|, then value of (ƒ'(5) + ƒ'(0)) is -

(A) 6
(B) 0
(C) 8
(D) 4

4) Let ƒ(x) = tan–1(2ℓn(cos(sin–1(2x – x2)))), then value of is equal to -

(A) 0
(B) 4
(C) 8
(D) –8

SECTION-I (ii)

1)

If the equation (x2+x+2)2–(a–3) (x2+x+2) (x2+x+1) + (a – 4) (x2+x+1)2 = 0 has at least one real root.
Then 'a' can be ?

(A) 6

(B)

(C) 5
(D) 7

2) Let , where n ∈ integer, then choose the correct option -

(A) ƒ(x) is periodic with period = 2

(B)

(C) ƒ(x) is an even function

(D) = does not exist

3) Consider the function ƒ(x) = , then

(A) ƒ(x) is continuous at positive odd integral multiple of π

(B) ƒ(x) is discontinuous at positive even integral multiple of π

(C)
ƒ(x) is discontinuous at positive odd integral multiple of

(D)
ƒ(x) is continuous at positive even integral multiples of

SECTION-I (iii)
1) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

The value of x for which

(P) (1) 2
is

The sum of the real roots of the

(Q) (2) 4
equation is

If and βα = 9, then
(R) (3) 3
value is equal to

(S) (4) 5
is
equal to

(5)

The correct option is

(A) P → 1;Q → 2;R → 2;S → 5
(B) P → 3;Q → 4;R → 2;S → 5
(C) P → 1;Q → 2;R → 4;S → 1
(D) P → 3;Q → 4;R → 4;S → 1

2) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) The number of values of x which satisfy the equation (1) 12

is

(Q) (log3(x + 1) – 1)2 + (3(y+2) – 27)2 = 0, then x + y is (2) 6

(R) Minimum value of 4tan2θ + 9cot2θ is (3) 2

Let x2 + (sinθ)x + cosθ = 0 is having the roots x = α, β and maximum

(S) (4) 3
value of (1 – α)(1 – β) is λ, then is

(5) 5
(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 3;Q → 1;R → 2;S → 4
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 3;Q → 4;R → 1;S → 2

3) Match List-I with List-II and select the correct answer using the code given below the list.
 List-I List-II

(P) (1) 1
If , then the value of a is equal to

ƒ:(0, ∞) → R such that ƒ(x) = (a – 7) log3x + (b–2)ex + sinx ƒ(x) is

(Q) (2) 2
bounded function, then a + b – 7 is

Let ƒ(x) = x2 + px + 10 and ƒ(x) is an even function ∀ x ∈ R. If

(R) (3) 5
is , (where m & n are co-prime) then m + n is
equal to

The sum of all values of x for which the

(S) (4) 9
function is continuous but not differentiable is

(5) 11
(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 4;Q → 3;R → 1;S → 2
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 1;Q → 3;R → 4;S → 2

4) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) If then absolute value of difference of let and right limit (1) 4
is

Let ƒ(x) = x2 – 4x + 1, then the number of points where |ƒ(|x|)| is non-

(Q) (2) 5
differentiable is

(R) (3) 1
If is continuous at x = 0, then
ƒ'(0) is (where [.] represents greatest integer function)

(S) (4) 2
Let , the is
(where [.] represents greatest integer function)

(5) 8
(A) P → 3;Q → 2;R → 4;S → 1
(B) P → 4;Q → 2;R → 3;S → 1
(C) P → 1;Q → 4;R → 3;S → 2
(D) P → 4;Q → 1;R → 2;S → 3

SECTION-II

1) Let a function ƒ(x) = min{e–x, {x}}, then number of points in x ∈ (–2,4), where ƒ(x) is non
differentiable, is (where {.} denotes fractional part function)

2) Value of the expression is

3) Let . If ƒ'(0) exist and is equal to non-zero value b, then value

of is

4) Let P(x) = x10 + ax8 + bx6 + cx4 + dx2 – 1 be polynomial with real coefficients. If P(1) = 1, P(2) = –1
then the minimum number of real zeroes of P(x) is :-

5) Let ƒ(x) = x + 1, g–1(x) = x3 + x + 1 and h(x) = g(ƒ(x)), then is equal to :-

6) Let , then |πℓnL| is equal to

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A D C D

SECTION-I (ii)

Q. 5 6 7
A. A,C,D A,D B,C,D

SECTION-I (iii)

Q. 8 9 10 11
A. B B C B

SECTION-II

Q. 12 13 14 15 16 17
A. 8 26 9 1 4 5

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. D D A C

SECTION-I (ii)

Q. 22 23 24
A. A,C A,B,C,D C,D

SECTION-I (iii)

Q. 25 26 27 28
A. A B B C

SECTION-II

Q. 29 30 31 32 33 34
A. 921 9 5 59 4094 8

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. A D A C

SECTION-I (ii)

Q. 39 40 41
A. A,B A,D A,C,D

SECTION-I (iii)

Q. 42 43 44 45
A. D D C B

SECTION-II

Q. 46 47 48 49 50 51
A. 9 0 7 6 4 8
 SOLUTIONS

PART-1 : PHYSICS

1)

+ =0

2)

Check for dimensionally correct option.

3) If the stone is thrown at an angle of

θ = 45°, its range is . In this case the maximum height attained by the

stone will be . But a stone thrown at θ > 45° can have a path as shown in
path 2 in the figure and thereby it can hit the bird sitting at a larger distance therefore, we
need to calculate the maximum possible x co-ordinate of the projectile for a given height h =
10 m. Trajectory equation is

Put y = 10 m, g = 10 m/s2 and u = 20 m/s

⇒ 800 = (80 tan θ) x – x2 – x2 . tan2 θ

⇒ (x2) tan2 θ – (80x) tan θ + (800 + x2) = 0
This is a quadratic equation in tan θ. For tan θ be real we must have
(80x)2 – 4(x2) (800 + x2) ≥ 0
⇒ 1600 x3 – 800 x2 – x4 ≥ 0 ⇒ 800 ≥ x2
⇒
∴

4)

geff = a =

T=

5)

(as Ex = 0)

6) S = ℓsecθ = 1/2 g sinθ Td2 = Td =

7) ρ = kr2 =

(A) vesc =

M= =

so
 (B) g = =
g ∝ r3

(C) as vesc = so will be same for other planet also.

(D) Energy required =

so

8)

= 9 m/s

9)

(P) Right Surface ray bends towards normal µ2 > µ1

Left surface undeviated µ2 = µ3

(Q) Right Surface away from normal µ1 > µ2

left surface away from normal µ2 > µ3

(R) Right Surface towards normal µ2 > µ1

left surface undeviated µ2 = µ3

(S) Right Surface away from normal µ1 > µ2

left surface away from normal µ2 > µ3

(T) Right Surface away from normal µ1 > µ2

left surface undeviated µ2 = µ3

10)

As potential of left most plate is zero. By using Gauss law we get above options.

11) (P)
F = qE– – qE+
F=0

(Q)

(R)

(S)

12) Let the distance of the lens from the object be l when a real image is formed on the screen.
Then

– =
On solving, we get l = (50 ± 10 ) cm.
Now, if the lens performs SHM and a real image is formed after a fixed time gap, then this
time gap must be one-fourth of the time period.

∴ Phase difference between the two positions of real image must be . As the two positions are
symmetrically located about the origin, phase difference of any of these positions from origin

must be .
⇒ 10 cm = A sin ⇒ A = 20 cm
To achieve this velocity at the mean position,

0
υ = Aω = A
∴ Required impulse p = mυ0 = A = 8 kg m/s.

13) Velocity of rain relative to the man is perpendicular to the incline in this case (i.e. along
the umbrella stick. This keeps umbrella perpendicular to the rainfall and provides maximum
safely)

=
Since has no component
∴ Vx = u
when the man is walking up, is directed vertically downward.

= =
14)
ma + Tcosθ = for = µN
ma + Tcosθ = µ [mg – Tsinθ]
T(cosθ + µsinθ) = m(µg – a)

T=
for tenstion T to be minimum

⇒ [tanθ = µ]

Tmin =

15)
Field at any position R inside sphere ∝ R

∴ N ∝ R cosθ ∝
∴ NP = NQ

16)

For flux to be zero, net charge should be zero.

17)
 ...(1)

...(2)

PART-2 : CHEMISTRY

18) "i" for Urea = 1, NaCl = 2, BaCl2 = 3 for vapour Pressure : = xb . i, A: Solvent, B:
Non-Volatile, Solute
P = (1 – xB . i) . P°A
i ↑ ⇒ V.P. (P) ↑
V.P. ⇒ Urea > NaCl > BaCl2
For Boiling Point : ΔTb = Kb.m.i
Tb = Kb.m.i + T°b
i ↑ ⇒ Tb (B.P.) ↑
B.P. ⇒ BaCl2 > NaCl > Urea
For freezing Point :
ΔTf = Kf.m.i
Tf = T°f –Kf.m.i
i ↑ = Tf (F.P.) ↓
F.P. ⇒ Urea > NaCl > BaCl2
for Osmotic Pressure : π = CRT × i
i↑⇒π↑
osmotic pressure : BaCl2 > NaCl > Urea

19)

Generally metal oxides are basic and non-metal oxides are acidic.

20) C + O2 → CO
2 mol 1.5 mol
0 0.5 2
L.R.

CO + O2 → CO2
2 mol 0.5 mol
1 mol 0 1 mol
Final gaseous mixture contains 1 mol CO and 1 mol CO2.

Mavg = = 36 g/mole.

21) 0.4 × 10 = 105 ×

nA = 10–3 mole

22)

Ac (89) : (Rn) 6d1 7s2

(A) Highest value of ℓ < value of 'n'
(C) For ℓ = 0, m= 0

23)

For experiment no. 2 and 3, [B] = constant

and also,
1
Rate ∝ [A] i.e. the reaction is of first order w.r.t. A.
For experiment no. 1 and 2.

Solving, x = 1 or rate α[B]1

i.e. reaction is of first order w.r.t. B also
∴ Rate = K[A0]1 [B0]1
(A) Correct
The mechanism of reaction not provided, so it may be elementary.
(B) Correct
Rate = K[A] [B]
using data of experiment no.1, 4 × 10–3 = K[0.02] [0.03]
⇒ K = 6.67 m–1 s–1.
(C) Correct
The mechanism of reaction is not provided so it may be complex.
(D) Correct
Rate, r1 = K[A] [B] = 4 × 10–3
Volume is doubled ⇒ concentration is halved.

24) Density =

or, 2 =
or, Volume of unit cell, V = 1.2 × 10–22 cm3.

Now, the volume occupied by the atoms = × V = 8.88 × 10–23 cm3

Hence, the volume of each atom = = 1.48 × 10–23 cm3.

25)

26) (P) : Ideal solution

(Q) : Negative deviation
(R) : Negative deviation
(S) : Positive deviation

27)

In FCC lattice matching is correct As per answar (FCC)

shortest distance between two atoms =

shortest distance between T.V. voids =

shortest distance between T.V. voids =

shortest distance btween T.V. voids =

28) (P) I → R
A+B→C+D

r = K[A] for 1st

(correct)
(Q) III → S
2A + B → C + D r = K[B]
Order ≠ Sum of stoichiometric coefficient.
(Incorrect)
(R) II → Q
r = K[A] [B] A + B → C + D
[B] = Excess r = K’[A] [K’ = K[B]]
Pseudo 1st order w.r.t. A
(Correct)
(S) IV → Q
 2A + B → C + D r = K[A] [B]2
[B] = excess [K’ = K[B]2]
r = K’[A]
(correct)

29)

log K =

log K = log A
Compare
(A) log A = 5 A = 105
Ea = 2.303R × 2000
= 9.21 KCal R=2

30)
⇒ y=9

31)

Mass percent, mole fraction, molarity, ppm, molality are used for measuring concentration
terms.

32) Number of Na+ = 3, Number of Cl– = 3

Packing fraction =

33) Mass of metal A (atomic mass = 7) = x

Mass of metal B = 1 – x

x = 0.4094

34) ⇒ = 1 + α ⇒ α = 0.2

Kp = 4Peq

PART-3 : MATHEMATICS

35) P(x = 4t2 + 3, y = 8t3 – 1)

let Q(4t12 + 3, 8t13 – 1)

at
∴ tangent at P is y – 8t3 + 1 = 3t (x – 4t2 – 3)
Q will satisfy it
∴ 8t13 – 8t3 = 3t (4t12 – 4t2)
8(t1 – t)(t12 + t1t + t2) = 3t. 4(t1 – t) (t1 + t)
2(t12 + t1t + t2) = 3t(t1 + t)
2t12 + 2t1t + 2t2 = 3t t1 + 3t2
2t12 – t1t – t2 = 0
(t1 – t) (2t1 + t) = 0

∴ Q (t2 + 3, – t3 – 1)

36) Shaded region is A ∩ (B ∪ C)′ = A – (B ∪ C)

37) at x = 5
ƒ(x) = 4x + 4
∴ ƒ'(5) = 4
at x = 0 ƒ(x) = 2x + 2
ƒ'(0) = 2

38)

39)

y2 – (a – 3) y + (a – 4) = 0
⇒ (y2+3y – 4) – a (y – 1) = 0

⇒ (y –1) (y + 4 – a) = 0 ⇒ 1 < a – 4 <

40)
41) ƒ(x) =

ƒ(x) is discontinuous at all positive odd integral multiple of

ƒ(x) is continuous at integral multiple of π

42) (P) Let 2x = t

t2 – 12t + 32 = 0 ⇒ t = 4 or t = 8
∴ x = 2 (rejected) or x = 3
(Q) Take log both sides to base '10'

x = 1 or x = 4
Hence, sum = 5
(R)

(S)

43) (P) Let

t = 27 or t = 3

&
 &

or
(Q) x + 1 = 3 and y + 2 = 3
x = 2 and y = 1
x+y=3
(R) 2 × 2 × 3 = min value
min. value = 12
(S) (1 – α) (1 – β) = 1 + (sinθ + cosθ)
∴ maximum value =

44) (P)

(Q) ƒ(x) = (a – 7) log3x + (b – 2)ex + sinx for function to be bounded a = 7; b = 2

(R) ƒ(x) = x2 + px + 10; for ƒ(x) to be even p=0

then m + n = 9
(S) Point is are x = 2,3

45) (P)
Jump = 2

(Q)

(R)
ƒ(0) = ƒ(0 + h) = ƒ(0 – h) ⇒ b = 0

ƒ'(0+) = ƒ'(0–) = 1

(S)
46)

47)

=0

48)

b is finite if a – 2 = 0 ⇒ a=2

& ⇒

49) P(x) → ∞ and P(x) → ∞.

P(0) = –1 and P(x) is even this P(1) = P(–1) = 1 & P(2) = P(–2) = –1.
Hence, from IVT minimum no. of zeroes are 6.

50) Required limit is

∵ ƒ–1(x) = x – 1; g–1(x) = x3 + x + 1
Also h(x) = g(ƒ(x))
⇒ h–1(x) = ƒ–1(g–1(x)) = x3 + x
51)

L = e–8/π ⇒ ⇒ |π ℓnL| = 8