Practice numerical problems in Quantum Mechanics
Ranjani Seshadri
August 6, 2025
1. Blackbody Radiation / Photon Energy: A red laser pointer emits light with a
wavelength of 630 nm.
(a) Calculate the frequency of this light.
(b) Calculate the energy of a single photon emitted by this laser.
2. Blackbody Radiation / Photon Energy:A certain star has a surface temperature
of 5800 K. Using Wien’s Displacement Law (λmax T = 2.898 × 10−3 m · K), calculate
the wavelength at which it emits the most radiation. What ”color” of light does this
correspond to?
3. de Broglie Hypothesis:
(a) Define deBroglie wavelength. Calculate the de Broglie wavelength of a bowling
ball of mass 6.0 kg rolling at a velocity of 5.0 m/s.
(b) An electron is accelerated to a speed of 0.9c (where c is the speed of light).
Calculate its relativisticp
de Broglie wavelength. (Hint: Relativistic momentum
p = γme v, where γ = 1/ 1 − v 2 /c2 ).
4. Heisenberg Uncertainty Principle:
(a) An electron is confined to a region of space of 5.0 nm. What is the minimum
uncertainty in its momentum?
(b) If the electron’s momentum is measured with an uncertainty of 1.0×10−28 kg·m/s,
what is the minimum uncertainty in its position?
5. Particle in a 1-D Box and Wavefunction Probability: An electron is confined
to a one-dimensional infinite potential well of widthqL = 0.3 nm. The normalized
wavefunction for the ground state (n = 1) is ψ1 (x) = L2 sin πx
L
.
(a) Calculate the energy of the ground state (n = 1) in electron-volts (eV).
(b) Calculate the probability of finding the electron in the ground state (n = 1) within
the region 0 ≤ x ≤ L/4.
(c) Sketch the states corresponding to n = 1, 2, 3. What are the corresponding ener-
gies?
1
6. Quantum Tunneling (Decay Constant): Consider the tunneling problem we dis-
cussed in class. For a tall, wide barrier (where κL ≫ 1), the transmission coefficient is
approximately given by:
16E(V0 − E) −2κL
T ≈ e
V02
A proton (mass mp = 1.67 × 10−27 kg) with an energy of 3.0 MeV is incident on a
potential barrier of height 5.0 MeV and width 2.0 fm (1 fm = 10−15 m).
(a) Qualitatively sketch the wavefunction in the three regions
(b) Calculate the decay constant, κ, for the proton’s wavefunction inside the barrier.
(c) Briefly discuss how this value of κ would change if the barrier were wider or taller.