07-06-2025

4602CJA101001250005 JM

PART-1 : PHYSICS

SECTION-I

1) The equation of a projectile is .

The angle of projection is :-

(A) 30º
(B) 60º
(C) 45º
(D) None

2) A particle moves from the point at t = 0, with an initial

velocity It is acted upon by a constant force which produces a constant acceleration

What is the distance of the particle from the origin at time 2 s?

(A)
(B) 15 m
(C)
(D) 5 m

3) A water fountain on the ground sprinkles water all around it. If the speed of water coming out of
the fountain is v, the maximum area around the fountain that gets wet is :-

(A)

(B)

(C)

(D)

4) The velocity of the bullet becomes one third after it penetrates 4 cm in a wooden block. Assuming
that bullet is facing a constant resistance during its motion in the block. The bullet stops completely
after travelling at (4 + x) cm inside the block. The value of x is :

(A) 0.5
(B) 1
(C) 2
(D) None of these

5) A river is flowing from west to east with a speed of 5 m/min. A man can swim in still water with a
velocity 10 m/min. In which direction should the man swim, so as to take the shortest possible path
to go to the south?

(A) 30o with downstream

(B) 60o with downstream
(C) 120o with downstream
(D) towards south

6) Six person of same mass travel with same speed u along a regular hexagon of side “d” such that
each one always faces the person next to him after how much time will they meet each other ?

(A)

(B)

(C)

(D)

7) A horizontal wind is blowing with a velocity v towards north-east. A man starts running towards
north with acceleration a. The time after which man will feel the wind blowing towards east is :

(A)

(B)

(C)

(D)

8) A particle is projected at an angle ‘α’ to the horizontal, up and down on an inclined plane; inclined

at an angle β to the horizontal. If the ratio of time of flights be 1 : 2, then the ratio is equal to :
(A)

(B)

(C)

(D)

9) To a man walking at the rate of 3 km/h the rain appears to fall vertically. When the increases his
speed to 6 km/h it appears to meet him at an angle 45° with vertical. Find the speed of rain.

(A)
(B)

(C)

(D)

10) A man holds an umbrella at 30º with the vertical to keep himself dry. He, then, runs at a speed of
10 ms–1, and finds the rain drops to be hitting vertically :

(A) Velocity of rain w.r.t. earth is 40 ms–1

(B) Velocity of rain w.r.t. man is ms
–1

(C) Velocity of rain w.r.t. earth is 30 ms–1

(D) Velocity of rain w.r.t. man is ms–1

11) Two bodies of masses m1 = 5 kg and m2 = 3 kg are connected by a light string going over a
smooth light pulley on a smooth inclined plane as shown in the figure. The system is at rest. The
force exerted by the inclined plane on the body of mass m1 will be :[Take g = 10 ms–2]

(A) 30 N
(B) 40 N
(C) 50 N
(D) 60 N
12) The adjoining figure shows a block of mass 10 kg connected to free end of a rope of mass 10 kg

and length of 10 m. The tension of the rope at point A is (g = 10 m/s2):-

(A) 170 N
(B) 30 N
(C) 130 N
(D) 70 N

13) A boy throws a ball with velocity v0 = 20 m/s. The wind imparts a horizontal acceleration of 4
m/s2 to the left. The angle θ with the vertical at which the ball must be thrown so that the ball
returns to the boy’s hand is : (g = 10 m/s2)

(A) tan–1 (1.2)

(B) tan–1 (0.2)
(C) tan–1 (2)
(D) tan–1 (0.4)

14) A 1 kg mass is suspended from the ceiling by a rope of length 4m. A horizontal force 'F' is
applied at the mid point of the rope so that the rope makes an angle of 45° with respect to the

vertical axis as shown in figure. The magnitude of F is :

(A)

(B) 1 N

(C)

(D) 10 N

15) Two blocks A and B are placed as shown in figure. There is no friction anywhere then F.B.D. of
block A

(A)

(B)

(C)
(D)

16) A boy can throw a stone up to a maximum height of 10m. The maximum horizontal distance that
the boy can throw the same stone up to will be ________ (in m)

(A) 10
(B)
(C) 20
(D)

17) Two projectiles are fired with same initial speed from same point on ground at angles of (45° – α)
and (45° + α), respectively, with the horizontal direction. The ratio of their maximum heights
attained is :

(A)

(B)

(C)

(D)

18) A stone projected with a velocity u at an angle θ with the horizontal reaches maximum height
H1 . When it is projected with velocity u at an angle (π/2 – θ) with the horizontal reaches maximum
height H2 . The relation between horizontal range R of the projectile, H1 and H2 is :

(A)

(B)
(C)

(D)

19) What force must the man exert on the rope to keep the platform in equilibrium?
(A) 100 N
(B) 200 N
(C) 300 N
(D) 500 N

20) Calculate the tensions T1, T2 and T3 in the three threads shown in the following figure. (All

threads are mass less) (g = 10 m/s2) :-

(A) 30 N, 40 N, 50 N
(B) 50 N, 30 N, 40 N
(C) 35 N, 45 N, 40 N
(D) 30 N, 50 N, 40 N

SECTION-II

1) The pulleys and strings shown in the figure are smooth and of negligible mass. For the system to

remain in equilibrium, the angle θ (in degree) should be :

2) A mass M is suspended by a rope from a rigid support at A as shown in figure. Another rope is
tied at the end B, and it is pulled horizontally with a force [Link] the tension in the string AB is nF
when the rope AB makes an angle 30° with the vertical in equilibrium. Find n ?
3) Two bodies are projected from ground with same speeds 40 ms-1 at two different angles with
respect to horizontal. The bodies were found to have same range. If one of the body was projected at
an angle of 60°, with horizontal then sum of the maximum heights, attained by the two projectiles, is
_______m. (Given g=10ms-2)

4) If the angle of projection corresponds to horizontal range being equal to the maximum height
then find the value of

5)

Two points are moving on the X and Y axis as shown. At the time t = 0 point 1 is located at a
distance of l1 = 10 cm, and point 2 at a distance of l2 = 5 cm from the origin. The first point moves
with velocity
u1 = 2 cm/s, and the second with a speed u2 = 4 cm/sec.

What is the minimum distance (in cm) between them? Round off to
nearest integer.

PART-2 : CHEMISTRY

SECTION-I

1) Possible number of orbitals if n + ℓ ≤ 4 are:

(A) 20
(B) 6
(C) 8
(D) 10

2) Quantum number of some electrons are given below on the basis of it, arrange them from lowest
to highest energy order:

n ℓ m s
 (P) 4 1 0

(Q) 5 0 0

(R) 6 2 0

(S) 6 3 –1

(A) P < Q < R < S

(B) Q < R < P < S
(C) Q < R < S < P
(D) S < Q < R < P

3) What will be the uncertainty in electron velocity, if uncertainty in momentum is equal to

(A)
(B)
(C)
(D)

4) What are the values of the angular momentum of an electron in the orbitals 1s, 3s, 3d and 2p :

(A)
(B)
(C)
(D)

5) Calculate de Broglie wavelength of a neutron

(mass, m= 1.6 × 10–27 kg) moving with kinetic energy of 0.04 eV :

(A) 146 Å
(B) 14.6 Å
(C) 1460 Å
(D) 1.46 Å

6) If proton and α-particle accelarate by same voltage, find out ratio of de-broglie wavelength
:-

(A)
(B)
(C)
(D)
7) Given curve represents

(A) 3s orbital
(B) 4s orbital
(C) 2s orbital
(D) 5s orbital

8) Which of the following plots of radial probability function is incorrectly labelled ?

(A)

(B)

(C)

(D)

9) The number of radial nodes of 3s & 2p orbitals are respectively -

(A) 2, 0
(B) 0, 2
(C) 1, 2
(D) 2, 1

10) Which of the following sequences is correct for decreasing order of ionic radius ?

(A) O2– , F– , I– , Br–

(B) I– , O2– , Br– , F–
(C) I– , Br– , F– , O2–
(D) I– , Br– , O2– , F–

11)

The correct order of size would be

(A)
(B)
(C)
(D)

12) The correct values of ionization enthalpies (in kJ mol–1) of Si, P, Cl and S respectively are :-

(A) 786, 1012, 999, 1256

(B) 1012, 786, 999, 1256
(C) 786, 1012, 1256, 999
(D) 786, 999, 1012, 1256

13)

The outermost electronic configuration of second most electronegative atom element amongst the
following is :

(A) ns2 np3

(B) ns2 np4
(C) ns2 np5
(D) ns2 np6

14) Which of the following statement is not correct

(A) Noble gases have a different number of electrons in outermost shell than their group number
(B) In the sixth period the orbitals being filled are 6s, 4f, 5d, 6p
(C) The second transition series contains the elements from Y to Cd.
(D) O–2 has the same no. of e–s in its outermost as well as penultimate shell

15) The elements of Group 13 with highest and lowest first ionisation enthalpies are respectively:

(A) B & Ga
(B) B & Tl
(C) Tl & B
(D) B & In

16) Which set does not show correct matching according to Modern periodic table :

(A) Cr = [Ar] 3d5 4s1 ; element belongs to 6th group

(B) Fe2+ = [Ar] 3d6 ; element Fe belongs to 8th group
(C) Sc3+ = [Ne] 3s2 3p6; element Sc belongs to zero/eighteen group
(D) Both (A) & (B)

17) For one of the element various successive ionization enthalpies (in kJ mol–1)are given below:

1st 2nd 3rd 4th 5th

I.E.
577.5 1810 2750 11,580 14,820
The element is
(A) P
(B) Mg
(C) Si
(D) Al

18) In the isoelectronic species, the radii (Å) of N3-, Ne and Al3+ are respectively given by

(A) 1.36, 1.40, 1.71

(B) 1.36, 1.71, 1.40
(C) 1.71, 1.40,1.36
(D) 1.71, 1.36, 1.40

19) Which of the following pair of orbitals, the probability of finding the electron is zero in xy plane ?

(A)
(B)
(C)
(D)

20) Which of the following statement is CORRECT regarding following processes

(A)

(B)
(C)
(D)

SECTION-II

1) Each orbital can accomodate maximum 3e– then how many element are present in 3rd period?

2) I.P.1 and I.P.2 of Mg are 178 and 348 kcal mol-1.

The enthalpy required for the reaction
Mg(g) → Mg(g)2+ + 2e— is............. kcal.

3) In an atom, the total number of electrons having quantum numbers n = 4, |ml| = 1 and ms = – is

4) Find maximum number of electron in 'P' (phosphorus) for which (n + ℓ + m) = 3

5) The wave function ψ of 2s – orbital is given by

At r = r0, radial node is formed. Calculate the value of (r0/ a0)

PART-3 : MATHEMATICS

SECTION-I

1) If then
is equal to

(A)

(B) k
(C) 1 – k
(D) 1 + k

2) If A=tan6° tan42° and B=cot66° cot78°, then

(A) A = 2B

(B)

(C) A = B
(D) 3A = 2B

3)

If , then the value of the

expression is

(A)
–cot
 cot
(B)

tan
(C)

– tan
(D)

4) If cos A = , then 32

(A) 8
(B) 9
(C) 10
(D) 11

5) =

(A)

(B)

(C)

(D)

6) The value of
sin10° + sin20° + sin30°+ ....+ sin360°
is equal to

(A) 0
(B) 1
(C)
(D) 2

7) Let fK (x)= where x ∈ R and k ≥ 1.

Then f4 (x)-f6 (x) equals

(A)

(B)

(C)
(D)

8) Let x, y, z be positive real numbers such

that x + y + z = 12 and x3y4z5 = (0.1) (600)3.
Then x3 + y3 + z3 is equal to

(A) 270
(B) 258
(C) 216
(D) 342

9)

The sum of infinite series

1 – 3x + 5x2 – 7x3 + ......∞, |x| < 1
is equal to 2, then x is

(A)

(B)

(C)

(D) None of these

10) The sum

upto 11-terms is

(A)

(B)

(C)

(D)

11) If ,
then the remainder when K is divided by 6 is

(A) 1
(B) 2
(C) 3
(D) 5

12) If x ∈ R, the numbers (51+x + 51–x), a/2, (25x + 25–x)

form an A.P. then 'a' must lie in the interval

(A) [1, 5]
(B) [2, 5]
(C) [5, 12]
(D) [12, ∞)

13) If a, b, c are positive real numbers such that ab2c3 = 64, then minimum value of is
equal to

(A) 6
(B) 2
(C) 3
(D) None of these

14)

If a ≠ 1 and ln a2 + (ln a2)2 + (ln a2)3 + .......

= 3(ln a + (ln a)2 + (ln a)3 + (ln a)4 + ....... )
then 'a' is equal to

(A) e1⁄5
(B)
(C)
(D)

15) If the sum of the first 11 terms of an arithmetical progression equals to the sum of the first 19
terms, then the sum of its first 30 terms, is

(A) equal to 0
(B) equal to –1
(C) equal to 1
(D) non-unique

16) The quadratic equation whose roots are the A.M. and H.M. between the roots of the equation,
2x2 – 3x + 5 = 0 is

(A) 4x2 – 25x + 10 = 0

(B) 12x2 – 49x + 30 = 0
(C) 14x2 – 12x + 35 = 0
(D) 2x2 + 3x + 5 = 0

17) The sum of the series

upto n terms is
(A)

(B)

(C)

(D)

18) The sum of the first n terms of

is

(A)

(B)

(C)

(D)

19) If the sum of the first 40 terms of the series,

3 + 4 + 8 + 9 + 13 + 14 + 18 + 19 +… is (102)m,
then m is equal to

(A) 20
(B) 5
(C) 10
(D) 25

20) The product

to ∞ is equal to . Then, n is equal to

(A) 2
(B)
(C)
(D) 1

SECTION-II

1) The minimum value of the sum of real numbers

a–5, a–4, 3a–3, 1, a8 and a10 with a > 0 is ____

2) If 1 + sin3x + sin6x + sin9x + ...... ∞ = 2,

then value of 9 sinx – 3 sin3x is equal to

3)

log (a + c), log(a + b), log(b + c) are in A.P.

and a, c, b are in H.P., where a, b, c > 0.

If a + b = , then the value of k is

4) In a G.P. consisting of positive numbers the product of the first four terms is 4 and the second
term is the reciprocal of the fourth term. Then sum of the G.P. up to infinite term is -

5) If 5cos2α – 2sinα – 2 = 0 and

Value of
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B A D A C C C B A B B C D D D C C A C D

SECTION-II

Q. 21 22 23 24 25
A. 45.00 2.00 80.00 4.00 7.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A A A D A B A A D A C B D D C D C C C

SECTION-II

Q. 46 47 48 49 50
A. 12.00 526.00 6.00 5.00 2.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C D D D A D C C D D D C D A B A C A A

SECTION-II

Q. 71 72 73 74 75
A. 8.00 6.00 8.00 8.00 1.00
 SOLUTIONS

PART-1 : PHYSICS

1) tan θ =
θ = 60º

2)

3)

4) S = 4 cm

a = constant
v4+x = 0

(v2 – 0) = 2a(4 + x)

5) For shrotest possible path man should swim at an angel of (90 + θ) with downstream. From
the figure,
6)

7)

So,

8)

⇒ 2 sin α cos β – 2 cos α sin β

= sin α cos β + cos α sin β
⇒ sin α cos β = 3 cos α sin β

9) Let and be the unit vectors in horizontal and vertical directions respectively.
Let velocity of rain
...(1)
Then speed of rain will be

In the first case = velocity of man =

∴
It seems to be in vertical direction. Hence,
a – 3 = 0 or a = 3
In the second case
∴
This seems to be at 45° with vertical.
Hence, |b| = 3
Therefore, from Eq. (2) speed of rain is

10)

is vertical, so vx = 10 m/s
So,

11)

For equilibrium m2g = m1g sinθ

Normal force on m1 = 5g cosθ

12) T = 130 N
14) T1sin45° = F
T1 cos45° = T2 = 1×g

∴ tan45° =
∴ F = 10N

16)

17)

20)

T3 = 40 N

⇒
T2 = cos37° = 40 ⇒ T2 = 50 N

T2sin 37° = T1 ⇒ T1 = T2 = 30 N
∴ T1 = 30 N, T2 = 50 N, T3 = 40 N

21)
2T cos θ = Mg
 2 M g cos θ = Mg

cos θ =
θ = 45°

23) If angle of projection for projectile 1 is 60° then angle of projectile 2 is 30° for same range

24)

25)

After time t
Distance of 1 from origin
= 10 – 2t
Distance of 2 from origin
= 5 – 4t
Distance between the particles

D=
For minima differentiating wrt time

–10 + 2t – 10 + 8t = 0
20 = 10t
t=2
Minimum distance

PART-2 : CHEMISTRY

26)
n l (n + l) subshell Number of orbitals
1 0 1 1s 1
2 0 2 2s 1
2 1 3 2p 3
3 0 3 3s 1
3 1 4 3p 3
4 0 4 4s 1

27) Use (n + ℓ) rule

28)

29) orbital angular momentum

&

30) KE = 0.04 × 1.6 × 10–19 J ⇒

31)

32) For graph radial node = 3

R.N = n – l – 1
=4–0–1=3
4s

33) In (A) height of peak is decreasing so incorrect

34) Number of radial nodes = n – l –1

35) I–, Br–, O2–, F–

36)

37) Order of IE
Si < P < S < Cl
3s 3p 3s 3p 3s 3p 3s23p5
2 2 2 3 2 4

38)

Second most electronegative element → O

1s2 2s2 2p4
ns2 np4

39) (i) Group number of noble gas = zero group

(ii)
(iii) 2nd T.s. = Y–Cd

(iv)

40) IE order
B > Tl > Ga > Al > In

41) Sc or Sc3+ belongs to 3rd group

42) Large jump between IE3 and IE4 suggest that the element has three valence electrons.

43) Size of isoelectronic species N3— > Ne > Al3+

44) Nodal plane = xy

45)

46) ID

47) I.E. = I.E.1 + I.E.2

 48)

n = 4, | | = 1, ms = –
For n = 4, l= 0 1 2 3
= 0 – 1, 0, +1 –2, –1, 0, +1 + 2 –3, –2, –1, 0, +1, +2, +3

Since | |=1
∴ Total no. of e– = 6

49) 1s2 2s2 2p6 3s2 3p2

n= 1 2 2 3 3
ℓ= 0 0 1 0 1
m=0 0 –10, +1 0 –1, 0, +1
____________________________________
(n + ℓ + m) = 1 2 3 3 3
↓ ↓ ↓
– – –
2e 2e 1e
__________________________________
Ans = 5

50) At r = r0

It is possible only when

∴ r0 = 2a0

PART-3 : MATHEMATICS

51)

52) We have

Multiply & divide by tan54°

⇒ tan6°tan42°tan66°tan78° ×

⇒
[∴ tan(60° – θ)tanθ tan(60° + θ) = tan3θ]

⇒
⇒A=B

53) On rationalizing ; we get

54)
= 16(2 cos2A – 1 – 4 cos3A + 3 cosA)
= 18 – 16 – 27 + 36 = 11

55)

56)

α = 10°; n = 36; β = 10°

57) fK (x) =

∴
=

= =

58)

x + y + z = 12, x3y4z5 = (0.1) (600)3

AM ≥ GM ⇒
x3y4z5 ≤ (60)3(4×25) ⇒ AM = GM

⇒
⇒

59)

Multiply the series with - x and subtract from original series.

60)

= = = =

61)
K = 29 + 28 · 3 + 27 · 32 + ..... + 39

Now, 310 – 210 = (35 – 25)(35 + 25)

= (211)(275)
= (35 × 6 + 1)(45 × 6 + 5)
= 6λ + 5
Remainder is 5.
62)

⇒
5(5x + 5–x) + 52x + 5-2x
5x + 5–x ≥ 2
Minimum value at x = 0
52x + 5–2x ≥ 2
Minimum value at x = 0
⇒ Range = [12, ∞)

63)
AM ≥ GM

Minimum value = 3

64) ℓna2 + (ℓn a2)2 + (ℓn a2)3 + ....... = 3(ℓn a + (ℓn a)2 + (ℓn a)3 + (ℓn a)4 + .......)

⇒
⇒ ⇒

⇒ ⇒

65) S11 = S19 (given)

11(a + 5d) = 19(a + 9d)

11a + 55d = 19a + 171d
–116d = 8a
–29d = 2a

From equation (i)

⇒ ⇒ S30 = 0

66)

2x2 – 3x + 5 = 0

Let roots are α and β then ,

1st roots A.M. of α and β

2nd root H.M. of α and β

Sum of roots are

Products of root are

Now equation is

⇒ 12x2 – 49x + 30 = 0

67)

69)

Sum of the 40 terms of

3 + 4 + 8 + 9 + 13 + 14 + 18 + 19…
= (3 + 8 + 13 +…upto 20 term) + [4 + 9 + 15 +… upto 20 terms]
= 10 [{6 + 19 × 5} + {8 + 19 × 5}]
= 10 × 204 = 20 × 102

70)

∴n=2

71) As a > 0
and all the given terms are positive
Hence considering A.M. G.M. for given numbers:

⇒ =7
–5 –4 –3 8 10
where a = a = a = a = a i.e. a = 1
⇒ (a–5 + a–4 + 3a–3 + a8 + a10 + 1)min = 8 when a = 1
72) ⇒ 9 sinx – 3sin3x = 6

73)

74)

75)

as