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Understanding Pure Substances and Mixtures

A pure substance consists of a single type of particle with uniform chemical nature, while mixtures contain two or more pure substances. Mixtures can be homogeneous, with uniform composition, or heterogeneous, with distinct parts. Solutions, suspensions, and colloidal solutions are types of mixtures, each with unique properties and methods of separation.

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0% found this document useful (0 votes)
11 views7 pages

Understanding Pure Substances and Mixtures

A pure substance consists of a single type of particle with uniform chemical nature, while mixtures contain two or more pure substances. Mixtures can be homogeneous, with uniform composition, or heterogeneous, with distinct parts. Solutions, suspensions, and colloidal solutions are types of mixtures, each with unique properties and methods of separation.

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What is a Pure Substance?

In everyday language, "pure" means unadulterated. However, in science, a pure


substance has constituent particles that are the same in chemical nature. It
consists of a single type of particle and is a single form of matter. Most matter
around us exists as mixtures of two or more pure components (e.g., seawater,
minerals, and soil).
What is a Mixture?
Mixtures are constituted by more than one kind of pure form of matter.
Dissolved sodium chloride can be separated from water through evaporation,
but sodium chloride itself cannot be separated into its chemical constituents by
physical processes.
A mixture contains more than one pure substance.
Types of Mixtures
Depending on the nature of their components, mixtures can be either
homogeneous or heterogeneous.
a) Homogeneous Mixtures- Homogeneous mixtures, also known as solutions,
have a uniform composition throughout.
Examples:
∙ Salt dissolved in water
∙ Sugar dissolved in water
∙ Homogeneous mixtures can have variable compositions, meaning the
intensity of colour or concentration can differ between samples.

b) Heterogeneous Mixtures- Heterogeneous mixtures contain physically distinct


parts and have non-uniform compositions.
Examples:
∙ Sodium chloride and iron fillings,
∙ Salt and sulphur
∙ Oil and water
Solutions
A solution is a homogeneous mixture of two or more substances. Examples
include lemonade and soda water. Solutions can be solid (alloys), liquid, or
gaseous (air).

∙ There is homogeneity at the particle level


∙ Particles of sugar or salt are evenly distributed
Alloys
An alloy is a mixture of two or more metals, or a metal and a non-metal,
that cannot be separated into components by physical methods. Alloys
are considered mixtures because they show the properties of their
constituents and can have variable composition.
Example:
Brass: Approximately 30% zinc and 70% copper.

Components of a Solution

∙ Solvent: The component that dissolves the other component (usually present
in larger amount).
∙ Solute: The component that is dissolved in the solvent (usually present in
lesser quantity).
Examples:
1. Sugar solution: Sugar is the solute, and water is the solvent.
2. Tincture of iodine: Iodine (solid) is the solute, and alcohol (liquid) is the
solvent. 3. Aerated drinks: Carbon dioxide (gas) is the solute, and water (liquid) is
the solvent.
4. Air: Oxygen (21%) and nitrogen (78%) are the main constituents.

Properties of a Solution

∙ Homogeneous mixture.
∙ Particle size is smaller than 1 nm (10-9 metre).
∙ Particles cannot be seen with the naked eye.
∙ Does not scatter a beam of light passing through the solution. ∙
Solute particles cannot be separated by filtration.
∙ Stable (particles do not settle).

Concentration of a Solution
The concentration is the relative proportion of solute and solvent. Solutions can
be dilute, concentrated, or saturated.

∙ Dilute and concentrated are comparative terms.


At any particular temperature, a solution that has dissolved as much solute as it is
capable of dissolving is a saturated solution. When no more solute can be
dissolved in a solution at a given temperature, it is called a saturated solution.

∙ The solubility is the amount of solute present in a saturated solution at a


special temperature.
∙ An unsaturated solution contains less solute than the saturation level. The

concentration of a solution is the amount of solute present in a given amount of


solution.

Expressing Concentrion
1. Mass by mass percentage:

2. Volume by volume percentage:

Example: A solution contains 40 g of common salt in 320 g of water.


Calculate
the concentration in terms of mass percentage.

∙ Mass of solute (salt) = 40 g


∙ Mass of solvent (water) = 320 g
∙ Mass of solution = 40 g + 320 g = 360 g

40
Mass percentage =
360X 100 = 11.1%

Suspensions
A suspension is a heterogeneous mixture in which the solute particles
do not dissolve but remain suspended throughout the bulk of the
medium. Particles are visible to the naked eye.

Properties of a Suspension

∙ Heterogeneous mixture.
∙ Particles can be seen with the naked eye.
∙ Scatters a beam of light, making its path visible.
∙ Unstable (particles settle down when left undisturbed).
∙ Can be separated by Filtration.
∙ Breaks and does not scatter light anymore when particles settle.

Colloidal Solutions
A colloid or colloidal solution has particles uniformly spread
throughout the solution. It appears homogeneous but is actually a
heterogeneous mixture.
Example: milk

∙ Particles cannot be seen with the naked eye.


∙ Particles can scatter a beam of visible light.

Tyndall Effect
The Tyndall effect is the scattering of a beam of light by colloidal particles.
Observed when sunlight passes through the canopy of a dense forest. Mist
contains tiny droplets of water, which act as particles of colloid dispersed in
air.

∙ Properties of a Colloid
∙ Heterogeneous mixture.
∙ Particle size is too small to be individually seen with the naked eye. ∙
Scatters a beam of light, making its path visible.
∙ Quite stable (particles do not settle down when left undisturbed). ∙
Cannot be separated by filtration, but centrifugation can be used.

Components of a Colloidal Solution


Dispersed Phase: The solute-like component or the dispersed
particles. Dispersion Medium: The component in which the dispersed
phase is suspended.
Colloids are classified according to the state (solid, liquid, or gas) of the
dispersing medium and the dispersed phase.
Common Examples of Colloids
Dispersed Phase Dispersing Type Example
Medium

Liquid Gas Aerosol Fog, clouds, mist

Solid Gas Aerosol Smoke,


automobile
exhaust

Gas Liquid Foam Shaving cream

Liquid Liquid Emulsion Milk, face cream

Solid Liquid Sol Milk of


magnesia, mud

Gas Solid Foam Foam, rubber,


sponge, pumice

Liquid Solid Gel Jelly, cheese,


butter

Solid Solid Solid Sol Coloured


gemstone,
milky glass

Physical and Chemical Changes


Physical Properties
Properties that can be observed and specified.

∙ Colour, hardness, rigidity, fluidity, density, melting point, boiling point, etc.

Interconversion of states is a physical change because it occurs without a change


in composition, where the chemical nature of the substance stays the same.
Chemical Properties
Chemical characteristics, such as Odor and inflammability.
Burning is a chemical change where one substance reacts with another,
undergoing a change in chemical composition. This change brings change in the
chemical properties of matter.

Types of Pure Substances


Based on chemical composition, substances are classified as elements
or compounds.
Elements
An element is a basic form of matter that cannot be broken down
into simpler substances by chemical reactions.
Elements are normally divided into metals, non-metals, and
metalloids. Metals typically exhibit the following properties:

∙ Lustre (shine).
∙ Silvery-grey or golden-yellow colour.
∙ Conduct heat and electricity.
∙ Ductile (can be drawn into wires).
∙ Malleable (can be hammered into thin sheets).
∙ Sonorous (make a ringing sound when hit).
Examples: gold, silver, copper, iron, sodium, potassium. Mercury is the only metal
that is liquid at room temperature.
Non-metals
Non-metals usually exhibit the following properties:

∙ Display a variety of colours.


∙ Poor conductors of heat and electricity.
∙ Not lustrous, sonorous, or malleable.
Examples: hydrogen, oxygen, iodine, carbon (coal, coke),
bromine. Metalloids
Metalloids have properties intermediate between those of metals
and non-metals.
Examples: boron, silicon, germanium

Compounds
A compound is a substance composed of two or more
elements, chemically combined in a fixed proportion.
When two or more elements are combined, they form a

compound. Mixtures vs. Compounds


Features Mixtures Compounds

Formation Elements/Compounds Elements react to


mix together form new
compounds

Composition Variable Fixed

Properties Shows properties of New substance has


constituent substances totally new properties

Separation of constituents Fairly easily separated Separated only by


by physical methods chemical or
electrochemical reactions.

Common questions

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The Tyndall effect is the phenomenon where light is scattered by particles within a colloid, making the path of the light visible. This effect occurs because the particle size in colloids is large enough to scatter light, unlike in true solutions, where particle size is too small to scatter light. Therefore, when a beam of light passes through a colloid, like milk, the light path becomes visible, a characteristic not observed in true homogeneous solutions such as sugar water .

Alloys are considered mixtures even though they appear uniform at the macroscopic level because they retain the properties of their constituent metals or metalloids and exhibit variable composition. For example, brass, which typically consists of 30% zinc and 70% copper, demonstrates characteristics of both components. Unlike chemical compounds, the elements in alloys do not form fixed proportions and can be tuned to produce different material properties .

The stability of colloidal solutions is influenced by factors such as particle charge, dispersion medium viscosity, and stabilizing agents which prevent the particles from settling. Colloids remain stable as long as the balance of repulsive forces among particles is maintained. In contrast, true solutions are inherently stable due to their molecular-level homogeneity and very small particle size that prevents settling. Suspensions are the least stable, as particles are large, settle upon standing, and are mainly influenced by gravity. External factors like pH or ionic strength can destabilize colloids, while agitating suspensions or changing temperature can affect stability in all systems .

Physical changes involve alterations in the state or appearance of a substance without changing its molecular structure, such as melting or boiling, with typically low energy requirements. For instance, ice melting into water is a physical change where molecular rearrangement occurs without altering chemical identity. Chemical changes, however, involve the reorganization of molecular structures leading to new substances with different chemical properties, like in combustion, which requires significant energy to break and form new bonds, such as wood burning to ash and gases .

A pure substance consists of a single type of particle with a uniform composition, meaning it cannot be separated into different substances by physical methods. In contrast, a mixture comprises two or more pure substances whose individual components can often be separated by physical processes. For example, sodium chloride in a mixture can be physically separated from water through evaporation, whereas the compound itself cannot be separated into its constituent elements by simple physical means .

Suspensions have the largest particle sizes, with visible particles that settle upon standing, making them unstable and easily separable by filtration. Colloids have smaller particles than suspensions but larger than those in solutions, making them scatter light while remaining stable without settling, requiring methods like centrifugation for separation. True solutions, characterized by homogeneous particle distribution and the smallest particles, do not scatter light and are stable with particles not settling upon standing or being separable by standard filtration .

Metalloids exhibit a combination of physical and chemical properties that are intermediate between metals and non-metals. They can display metallic luster yet be poor conductors of heat and electricity compared to metals. For example, silicon has a shiny appearance like a metal but acts as a semiconductor, a property typical of non-metals. This duality places them in a transitional segment of the periodic table, demonstrating properties influenced by their environment and conditions .

Compounds have a fixed chemical composition, formed by the chemical reaction of elements, resulting in new properties distinct from the original elements, and can only be separated by chemical reactions. Mixtures, however, consist of physically combined substances with variable composition, retaining the properties of their individual components, and can often be separated by physical methods such as filtration or evaporation. For example, sodium chloride is a compound of sodium and chloride in a fixed ratio, whereas seawater is a mixture that can be separated by physical means .

Homogeneous mixtures, or solutions, have a uniform composition throughout, meaning the individual components are intermingled at the molecular level and not visibly distinct. Examples include sugar dissolved in water. Heterogeneous mixtures consist of two or more clearly distinguishable components, which may be visibly separate, such as oil and water or a mixture of sand and salt .

The classification of solutions as dilute, concentrated, or saturated relates directly to solubility—the maximum amount of solute that can dissolve in a solvent at a given temperature. Dilute solutions contain relatively low amounts of solute compared to solvent, while concentrated solutions have a high solute concentration. A saturated solution represents the equilibrium point where no more solute can dissolve at the current temperature, corresponding directly to the solubility limit of the solute in the solvent .

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