31-08-2025

0999DJM262103250005 JM

PART-1 : PHYSICS
2) Find out equivalent capacitance between A and B.

SECTION-I
(A)

1) In the given circuit, charge Q2 on the 2µF capacitor changes as C is varied from 1µF to 3µF. Q2 as (B)
a function of 'C' is given properly by : (figures are drawn schematically and are not to scale):-
(C)

(D)

3) The potential difference between the points P and Q in the adjoining circuit will be :-

(A) (A)

(B)

(C)

(B) (D)

4) The diagram shows four capacitors with capacitances and break down voltages as mentioned.
What should be the maximum value of the external emf source such that no capacitor breaks down ?

(C)

(A) 2.5 kV
(B) 10/3 kV
(C) 3 kV
(D) (D) 1 kV

5) The plates S and T of an uncharged parallel plate capacitor are connected across a battery. The
battery is then disconnected in a system as shown in the figure. The system shown is in equilibrium.
All the strings are insulating and massless. The magnitude of charge on one of the capacitor plates is
: [Area of plates = A] :-

(A)

(B)
(A) 30µC
(C)
(B) 40µC
(D) (C) 24µC
(D) 54µC
6) Seven capacitors each of capacitance 2μF are to be connected so as to have a total capacity of
9) In the circuit shown here C1 = 6μ F, C2 = 3μ F and battery B = 20V. The switch S1 is first closed. It
. Which will be the combination shown ?

(A) is then opened and afterwards S2 is closed. What is the charge finally on C2

(A) 120 µC
(B) 80 µC
(B) (C) 40 µC
(D) 20 µC

(C) 10) Six equal capacitors each of capacitance C are connected as shown in the figure. Then the

(D)

7) Two identical parallel plate air filled capacitors are placed in series and connected to a constant
voltage source of V0 volt. If one of the capacitors is completely immersed in a liquid with dielectric equivalent capacitance between A and B is :-
constant K, the potential difference between the plates of the other capacitor will change to :-
(A) 6C
(A) (B) C
(C) 2C
(B) (D) C/2

(C) 11) An elevator with passengers has a total mass of 800 kg and moves slowly a vertical distance of
20.0 m in 10.0 s. What is the average power expended in lifting this mass?

(D)
(A) 1.57 × 102 W
(B) 1.57 × 104 W
8) For the circuit shown in the figure, the charge on 4µF capacitor is :-
(C) 1.57 × 105 W
(A)
(D) 1.57 × 106 W

(B)
12) A body of mass 2 kg makes an elastic collision with another body at rest and continues to move
in the original direction with one fourth of its original speed. The mass of second body is :-
(C)
(A) 2 kg
(B) 1.2 kg (D)
(C) 3 kg
(D) 1.5 kg 2
16) F = 2x – 3x – 2. Choose correct option :-

(A) x = –1/2 is position of stable equilibrium

13) A force acting on a particle moving in the xy-plane is given by where x and y
(B) x = 2 is position of stable equilibrium
are in m. The particle moves along a straight line from the origin to (5, 5). The work done by F is :-
(C) x = –1/2 is position of unstable equilibrium
(A) 125 J (D) x = 2 is position of neutral equilibrium
(B) 66.7 J
17) A ball of mass m moving with a velocity v strikes the bob of a pendulum (mass m) at rest. If the
(C) 35 J
collision is perfectly inelastic, the height to which both will rise is given by :-
(D) 25 J

14) A particle is placed at the origin and a force F = kx is acting on it (where k is a positive (A)
constant). If U(0) = 0, the graph of U(x) versus x will be (where U is the potential energy function)
(B)

(A) (C)

(D)

(B) 18) A box of books that weighs 40 N is dragged at a speed of 1.5 m/s across a rough floor. If the
coefficient of friction between the floor and the box is 0.20, what is the rate at which heat energy is
dissipated?

(A) 5.3 W
(C) (B) 12 W
(C) 60 W
(D) 300 W

19) A particle of mass m at rest is acted upon by a force F for a time t. Its kinetic energy after an
(D) interval t is :

(A)

15) A particle in a certain conservative force field has a potential energy given by . The (B)
force exerted on it is :
(C)
(D)

20) An object of mass 5 kg drops from rest from a high plate form 20 m above ground and strike
ground at 10 m/s work done by air-resistance is :- 1) P?
P will be :
(A) 1000 J
(B) –250 J
(C) – 750 J (A)
(D) 250 J

SECTION-II
(B)

(C)
1) The net current flowing in the given circuit is _______ A.

2) A 60 pF capacitor is fully charged by a 20 V supply. It is then disconnected from the supply and is (D)
connected to another uncharged 60 pF capactior is parallel. The electrostatic energy that is lost in
this process by the time the charge is redistributed between them is (in nJ) ____.

3) Find the amount of charge (in µC) flown through the battery after switch is closed.

2) The major product in the following reaction + HCl is :-

(A)

4) Power on a particle is P = (3t2 – 2t + 1) watt change in kinetic energy is t = 2 sec to t = 4 sec is

(in J)

(B)

5) Under a force an object of mass 2 kg moves such that x = where x is in metre and t is in
second. Work done in first 2 sec is (in J):-

PART-2 : CHEMISTRY
(C)

SECTION-I
 (B)

(D)

(C)

(D)

3)
6) Identify correct order of stability :

(A)
(A)
>

(B) (B)
<

(C)
(C)
<

(D) (D)
<

4) An optically active compound 'X' has molecular formula C4H8O3. It evolves CO2 with NaHCO3. 'X' 7) Which of the following represents the correct match as per the number of hyperconjugated
reacts with LiAlH4 to give an achiral compound 'X' is : structures involving σ(C–H) bonds?
Species No. of hyperconjugated
structures involving
(A)
σ(C–H) bond

(B) (A)
8

(B)
(C)
6

(D)
(C)

6
5) Which of the following carbocation is less stable than :

(D)
(A) 2

8) Arrange the following carbon-hydrogen (C–H) bond x, y & z in decreasing order of energy of
 11) The major product of the following reaction is :

homolysis (A)

(A) x > y > z

(B) y > x > z (B)
(C) x > z > y
(D) z > x > y
(C)

(D)
9)
Reagent (R) should be
12) If X and Y are functional group isomers, then what is the structure of reactant (Alkyne)?
(A) H2, Pt
(B) Na, NH3(ℓ)
(C) Li, C6H5NH2
(D) H2, Pd-CaCO3, Quinoline

10) The major product the following reaction is :

(A) CH3–C≡C–CH3
(B) CH3–CH2–C≡C–H
(C) CH2 = CH – CH = CH2
(A) (D) CH3–CH=C=CH2

(B)
13)
The final product (B) is :

(C)
(A)

(D)

(B)
 (D)
(C)

17) Identify reaction correctly match with its major product :

(A)
(D)

(B)

14) What is the final product of given reaction: (C)

CH3—C CH product

(A) CH2 = CH—CH2CH3 (D)

Me–C C–Me
(B) CH3—CH2—C C—CH2—CH3
(C) CH C—CH2—CH2CH3
(D) CH3—C C—CH2CH3

18) The IUPAC name of is :

(A) 5-Hydroxy benzene carboxylate

(B) 3-Hydroxy benzene carboxylate
15) P (Major product)
(C) 3-Methoxy carbonyl benzene-1-ol
(D) Methyl 3-hydroxy benzoate
(A)
19) Which among these compounds is not a Heterocyclic Compound ?

(B)
(A)

(C)

(B)
(D)

16) An unknown alcohol is treated with the "Lucas reagent' to determine whether the alcohol is (C)
primary, secondary or tertiary. Which alcohol reacts fastest and mechanism used is :

(A) (D)

(B)
20) The incorrect IUPAC name is :

(C)
(A) (vi) (vii) (viii) (ix)
(x) (CH3)3C–Cl

(B)

Ethyl-6-hydroxycyclohex-2-ene carboxylate
CCl3–CH2–CHO
(C) 4) The total number of hyperconjugation hydrogen for the following carbocation is :
3,3,3-trichloroethanol

(D) 5) How many functional group present in following structure :-

SECTION-II

PART-3 : MATHEMATICS

SECTION-I

1) What is the DU (degree of unsaturation) in the given structure ? 1) Two sides of a parallelogram are along the lines, x + y = 3 and x – y + 3 = 0. If its diagonals
intersect at (2,4), then one of its vertex is :

2) How many compounds are aromatic (A) (2,6)

(B) (2,1)
(C) (3,5)
(D) (3,6)
(i) (ii) (iii)
2) If a straight line passing through the point P(–3, 4) is such that its intercepted portion between
the coordinate axes is bisected at P, then its equation is :

(iv) (v) (vi)

(A) x – y + 7 = 0
(B) 3x – 4y + 25 = 0
(C) 4x + 3y = 0
3) How many given compounds shows faster rate of SN2 than (n-propyl chloride) (D) 4x – 3y + 24 = 0
with NaI / dry acetone is :
3) The equation of a straight line passing through (3,2) and cutting an intercept of 2 units between
the lines 3x + 4y = 11 and 3x + 4y = 1 is :-
(i) (ii) CH3Cl (iii) CH3Br (iv) (v)
(A) 2x + y – 8 = 0
(B) 3y – 4x + 6 = 0
(C) 3x + 4y – 17 = 0 (B)
(D) 2x – y – 4 = 0
(C)
4) The set of lines ax + by + c = 0, where 5a + 6b + 7c = 0 are concurrent at the point :-
(D)
(A) (5, 6)

(B)

(C)
9) is equal to :-

(D) (A) 0
(B) ab + bc + ca
5) A ray of light coming from the point (1, 2) is reflected at a point A on the x-axis and then passes (C) a b c
through the point (5, 3). The coordinates of the point A are-
(D) a + b + c

(A) (13/5, 0)
10) If 0 ≤ [x]< 3, –1 ≤ [y] < 2 and 1 ≤[z] < 4 where [ . ] denotes the greatest integer function then
(B) (5/13, 0) the maximum value of the determinant
(C) (–7, 0)
(D) None of these

6) Two consecutive sides of a parallelogram are 4x+5y = 0 and 7x+2y = 0. If the equation to one
diagonal is 11x +7y = 9, then the equation to the other diagonal is :-
is:-

(A) 3x + 7y = 0
(A) 2
(B) 11x – 7y = 0
(B) 4
(C) x – y = 0
(C) 7
(D) x + y = 0
(D) 8

7) The line 3x – 4y + 7 = 0 is rotated through an angle π/4 in the clockwise direction about the
point (–1, 1). The equation of the line in its new position is :–

(A) 7y + x – 6 = 0 11) Value of is :-

(B) 7y – x – 6 = 0
(A) x + y + z
(C) 7y + x + 6 = 0
(B) –(x + y + z)
(D) 7y – x + 6 = 0
(C) 0

8) (D) 2(x + y + z)

If 0 < θ < π and the system of equations

(sinθ) x + y + z = 0
x + (cosθ) y + z = 0 12) equals -
(sinθ)x + (cosθ)y + z = 0
(A) abc + pqr + xyz
has non-trivial solution then :-
(B) (a–x) (b–y) (c–z)
(A) (C) 0
(D) (a–x) (y–z) (r–p)
 (B) 2
(C) 3
13) If g(x) = , then : (D)

(A) g(x) + g(–x) = 0

(B) g(x) –g(–x) = 0
(C) g (x) × g(–x) = 0 18) , [.] GIF

(D) None of these

(A) 1
(B) 2
(C) –1
(D) –2

14) If = 0 ∀ x ∈ R; where n ∈ N the value of 'a' is

(A) n
19) If In = , n ∈ N then I7 – 7I6 =
(B) n – 1
(C) n + 1
(A)
(D) 1
(B)

(C)
15) If f(x) is continuous function such that , n ∈ z then = 1–

(A) 16 (D)
–
(B) 0
(C) 2
(D) None of these
20) Value of dx is

(A) 2
(B) 1
16) (C) 5
(D) None
(A)
SECTION-II
(B)
1) The value of a for which the image of the point (a, a – 1) w.r.t. the line mirror 3x + y = 6a is the
(C) point (a2 + 1, a) is
(D) None
2) If the line passing through intersection of lines x – 2y = 1 and x + 3y = 2 and parallel to 3x + 4y =
0 is 3x + 4y = k then value of k is.

17) If and then the value of is

3)
(A) 1
If the straight line, 2x – 3y + 17 = 0 is perpendicular to the line passing through the points (7, 17)
and (15, β), then β is equal to ANSWER KEYS

PART-1 : PHYSICS
4) In a triangle ABC is equal to ?
SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B C A A A B C C C B B B A B A A B B C

5) is equal to
SECTION-II

Q. 21 22 23 24 25
A. 1 6 4 46 16

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A A C A A C D D D B B A D C D B D C C

SECTION-II

Q. 46 47 48 49 50
A. 9 4 7 6 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D D B D A C A D A C C C A C B B B B D D

SECTION-II

Q. 71 72 73 74 75
A. 2 5 5 0 20
 SOLUTIONS

PART-1 : PHYSICS Hence

4) Q1max = 3 C × 10 C.
3

Q2max = 4 C × 10 C.
3

Qmax for first branch 3C × 103 C

1)
Similarly for second branch
V1 =
Charge on 2μF Q2 = 2V1

Q2 = The two branches are in parallel. So in order to find max value of voltage for which no
capacitor breaks down
Q2 = < .

As C increase slope of graph decrease 5)

Force between capacitor plates is equal to .

2) Let . Equivalent circuit
As the system is in equilibrium

= mg

Alternative Method : Let charge distribution on plates as shown :

6)
Potential of 1 and 4 is same (Where C = 2μF)

y = 2x
⇒

⇒ CAB = = = =

3) C1 and C2 are in series, charge on each will remain same.

(VP – 0).C1= (E – VP)C2 7) V1 =

C3 & C4 are in series, charge on each will remain same,

(VQ – 0).C3 = (E – VQ)C4
 …(1)
By energy conservation

8) …(2)
q = CeqV solving (1) & (2)
m2 = 1.2 kg
=
= 24µC
13) y = mx + c

9) Vcommon = w= =

Vcommon = = 25 + = 66.7 J

Charge on C2 = 3 × = 40μC
14)

10) F = Kx

The given network of capacitors can be redrawn as follows : U=–

=–
Work energy theorem

15)

Put
C4 is in parallel to a balanced Wheatstone bridge made from the rest five
capacitors as shown in the figure. Therefore, equivalent capacitance = C + C = 2C

11) Average power = 16) 2x2 – 3x – 2 = 0

12) ⇒
By momentum conservation
m1u1+ m2u2 = m1v1 + m2v2
⇒
 = (5) > 0 (stable) 23) Initially charges on all capacitors

On closing the switch 'S', charge is accumulated on 2µF capacitor only i.e.
Qf = 2 × 6 = 12 µC

17)
By conservation of momentum
mv = 2mv'

v =
1

By conservation of mechanical energy

So, charge flown across battery

= (12 µC – 8µC) = 4µC

18) P = (µ.mg). v = 0.2 × 40 × 1.5 = 12

24)

wtotal = t3 – t2 + t
19) Kinetic energy E = = =
ΔKE = (43 – 42 + 4) – (23 – 22 + 2)
[As P = F t]
= 46 J

20)

[NCERT pg # 136 Q. 6.13]

Wgravity + Wair = mv2 = 0

Wair = mv2 – mgh

25)
21) Req = 2Ω dW = Fdx
= madx
I= = 1A
= m2t (t dt)
2

W = 4t3dt
W = t4
W0–2 = 24 – 0 = 16 J
22)
Q = CV
PART-2 : CHEMISTRY

ΔQL =
26) Vicinal diol compounds breakdown by HIO4.
= CV
2

= × 60 × 10–12 × 4 × 102
= 6nJ
 4. Incorrect order.
Final Answer: 1
27)

28)
Correct choice : A

32)

33)

29)

30) A is unstable due to anti-aromaticity.

31) Explanation:
To Compare Stability of alkenes
∴ EHomolysis = z > x > y
Concept:
This Question is based on Comparision of stability of alkene on the basic of Hyperconjugation.
34)

H2 Pd/CaCO3 Quinoline selectively reduces the triple bond to a double bond (cis-alkene) in the
presence of a double bond.
1. Correct order

35)
I) Br2 addition occurs to the double bond which is anti addtion.
2. Incorrect order

3. Incorrect order
Better Hypercojnugation in (i) Makes it more Stable + Br - Br
II) EtOH alkeks on allylic position through SN mechanism
 39)
CH3—C C—CH2CH3

40)

36)

37)
Butan-2-one (X) and Butanal(Y) are functional group isomers.

41) Explain Question : Lucas test of alcohols → Asking the most reactive alcohol and
mechanism.
Concept :
Mechanism is SN1 reaction.
38) A = Rate of SN1 ∝ stability of intermediate carbocation.
Solution :

B = After Hydrolysis
Hint :
→ 3° Alcohols reacts immediate with Lucas reagent.
→ 2° Alcohols reacts in 5 minute with Lucas reagent.
→ 1° Alcohols do not react appreciably with Lucas reagent.
Final Answer : (D)
After heating
42) Explain Question :
Asking about the reaction in which major product is correct.
 Concept : 46) Fact
(1) Markovnikov addition of water on alkyne (Kucherov reaction)
(2) Free radical addition of HBr [Peroxide effect]
(3) Wurtz reaction of alkyl halides 47) i, iv, v, vi
(4) Birch reduction of alkynes.
Solution : 48) Explain Question :
Correct products are as follows :
Question is asking the compounds more reactive than towards SN2 reaction with
NaI + Acetone.
(1) Concept :
Rate of SN2 ∝ Stability of transition state

(2)

(3) Solution :

(4)
(i) (ii) (iii)
Final Answer (B)

43) Concept:
IUPAC rules of nomenclature (iv) (vi) (viii)

Soln/Explanation:
(ix)

Note : are 2° and more crowded so less reactive than n-propyl chloride.

: Methyl-3-hydroxy benzoate Final Answer : (7)

• It is ester, so alkyl group attached with oxygen of ester is written first.
• Principal functional group is ester & –OH is substituent.
• –OH(hydroxy) is at C-3 of cyclic parent carbon chain.
• Ring carbon attached with ester is given lowest number followed by substituent.

44) Heterocyclic compounds have at-least one heteroatom as ring member atom. Compound C
has all ring atoms as carbon atoms, hence it is not heterocyclic.

49)

45) = Correct IUPAC ;

3,3,3-Trichloro propanal

A. PFG is aldehyde and 3 'Cl' are substituents

B. Suffix for aldehyde: al.
 lines and passes through (3,2).
∴ The required equation is
3y – 4x + 6 = 0

54) ax + by + c = 0

50)
5 functional group

PART-3 : MATHEMATICS

55)

Equation of CD
51)
y+2= (x – 1)
Put y = 0

⇒ x=
= 2; xi = 4 similarly y1 = 5
C ⇒ (4, 5) ∴ A≡
Now equation of BC is x – y = –1
and equation of CD is x + y = 9
Solving x + y = 9 and x – y = –3
Point D is (3, 6)
Option (D)

56)
4x + 5y = 0 ...........(i)
7x + 2y = 0 ...........(ii)
11x + 7y = 9 ...........(iii)
Solving (i) and (iii)

52) A≡
Solving (ii) and (iii)
Let the line be =1
C≡
(–3, 4) = Co-ordinates of middle point of AC
a = –6, b = 8
equation of line is 4x – 3y + 24 = 0 M≡
∴ Equation of other diagonal which passes through O and M is
53) Distance between the given parallel lines
y–0= (x – 0)
= =2
∴ Required line is perpendicular to the given
 62) Appling ; C1 ⇒ C1 + C2 + C3
57) As (–1, 1) is a point on 3x – 4y + 7 = 0, the rotation is possible. Slope of the given line =

Slope of the line in its new position = 63) g(x) = (∵ )

The required equation is y – 1 = – (x + 1)

or 7y + x – 6 = 0.
⇒ g(–x) =
on Interchanging Ist and IInd columns ,
58) d1 = d2 = d3 = 0 ⇒ D1 = D2 = D3 = 0

g(–x) = –
= –g(x)

64) Taking x common from R3, then

5

⇒ (sinθ – 1) (1 – cosθ) = 0 ⇒ sinθ = 1 or cosθ =1

⇒ θ = π/2 (∵ 0 < θ < π)
x5 =0 ∀x∈R
⇒a+1=n+2⇒a=n+1
59) R3 → R3 – 2R2

65) = n3 ⇒ = + + + +

Δ=

= –8[–1+2] – 1(0 + 1) + 0 + 1(2 – 1) + 8 (3 – 2)

= –8 – 1 + 1 + 8 = 0.

= –(a + b + c)
⇒ Δ=0
66) 11
60) [x] = 0, 1, 2, [y] = –1, 0, 1, [z] = 1, 2, 3
So Maximum value of [x], [y], [z] are 2, 1, 3 respectively = 11 = .

67)
Now = 1+ [x]+[y]+[z]

= 1+ 2+ 1 + 3 = 7 68) = 0, 1, 2, 3, .....
x = 0, 1, 4

61) Value of odd order skew symmetric determinant is zero.

 Use slope = –3/4 and find λ

73)
β=5

69) I7 =
by part

74)
I7 =
Δ=0
I7 – 7I6 = –

75)
70) I =
= 20
king

I=–
Add I = 0

71) L ≡

Since L lines on line AB

∴ 3 = 6a

⇒ 3a – 7a + 2 = 0
2
⇒ a = 2,
Also PQ ⊥ AB

⇒ –3 =–1
⇒ a2 – a – 2 = 0 ⇒ a = 2, – 1
∴ Common value of a = 2

72) (x – 2y – 1) + λ(x + 3y – 2) = 0