POLYMERCHEMISTRY
CLASSIFICATION OF POLYMER
Based on synthesis
A 1 A
NaturalPolymer semisyntheticPolymer synthetic polymer
The Polymerswhich are d
obtained from plants and from naturally occurringpolymers polymers
chemical modifications
by
1 Stayin I cellulosenitrate 2 Buna N
3 PVC
3 Protein 4 Navolac
4 Nucleicacids
immature
Fibres
3 Thermoplastics
4 Thermosetting polymers
Elastomers 1 Weakest intermolecularforces
2 Elastic character like Rubber
3 Buna S Buna N neoprene isoprene
dipoleinteraction
Fibres 1 Strong intermolecularforcesforces can be m bonding or dipole
2 nylon 66 terylene Silk
Thermoplastic Thermosetting
I Permanent on heating
1 Polymers which can easily softenedwhen changing
and hardened when cool
Soft gg Hard
is present So 3 D structures
No crosslinkage
2 Cross inking
2
3 The softening occurs as the polymerchains
move more and more because oflack
of crosslinking
Bakelite
q 1 Polythene eg
eg Melamine
2 Polystyrene
3 Polyvinyl chloride
g mon
Elastomers
orderof Molecularforces
Thermosetting fibre Thermoplastic
Compare the following
1 Nylon 6 polythene Isoprene
Bakelite
Nylon6,6 Buna s polythene
2
order nylons 6 polyethene Buna s
Based on modeofpolymerization
COPolymer Homopolymer
A A A A A
A B AB AB
Molecular masses of polymers
A polymer sample contains chain of varying lengths and therefore its molecular mass is
expressed as an average
always
mass
1 Number Average molecular
no of molecules
No MaM3
Mi MzM3 molecular mass
Mm Mm t NzMztN3M3
Nit NatNz
MN Ni Mi
Ni
2 Weight Average molecular mass
massof species
Ma Ma Ma
molecular mass
Mi Mz Mz
Mm MMatMaMa M3M3
mitmatmz
Mm Mimi
Emi
Mi Mimi
Mw NiMi 2
Enimi
Polydispersity Index
Ratio of Mn to Mn
PDI
Mtg
Mm Mm t NzMztN3M3
Nit NatNz
Mn 30 20000 40 30000 30 60000
100
Tn 3600
Mw Mimi
Enimi
3012000012 4013000032 3016000072
30 20000 40 30000 30 60000
Mw 43333
suitable
microorganisms within a
BIODEGRADABLE POLYMERS 1Polymers which are degraded by
period
2 Do not cause
serious affects on environment
any
1 PHBU
o
in ansd
a
3 hydroxybutanoic
Ight 3 hydroxypentanoicacid
To he o in cnidt
let
poly p hydroxybutyrate co p hydroxy
valerate PHBV
2 Polyglycolicand
HO CH COOH HOCha É
3 Nylon 2 Nylon 6
x NHChal I NH chat In
Han chat COOH t Han cha soon Amide
Glycine Amino Capronacid BIODEGRADABLE
MODE OF SYNTHESIS
MOS
t t
ADDITIONPOLYMER CONDENSATIONPOLYMER
1 Cha IH freeRadical f chachat
Removal
ofwater
CHIEH EH Ma
im i Tin ERICH Cha fChaChin
2 HI CH 142 ILI CHIn
cha Puc
3 A cha cha f cry
At Ph ch cha fin Chf Polystyrene
5A Me c Cha
I ICHI
Q cha cha IN chat JEE ADVANCED
Cha Chat Me CH Cha
6 Fac CFL ICE Eth TEFLON
7 Cha ch CN CH Myth acrylonitrile
PAN
8 1 Ior Inc Eph
tafia I
a
Tim ten
no I u
a man
g
MHz h
T y
o y
o
much comma
y I J GuttaPancha transform
1,3butadiene
f ISOPRENE cisform
n 79 79
Ese y
03 mess
i v
OHC
RUBBER
I 1
NATURALRUBBER SyntheticRubber
GuttaPancha transform Buns
Ismene
r t t 11.3butadiene
T
f r I t Ph
1 Isoprene cisform
i t Bunas
p
2
Yuna
I chron on
in in an
In Buna N
3 NEOPRENE
I I l
CONDENSATION POLYMER
to
A
Polyamide Polyester MCHONE
Phenol Mavolacllineart
Dalton Terylon Hchot
Hchotphenol Bakelite
A Glyptal
Homopolymer Copolymer Icrosslinkedl
puppy
Nylonx NylonX Y H melamine
x Numberofcarbon Nylon x Nylon Y K Urea Ureaformaldehyde
POLYAMIDES Nylon
MOMOPOLYMER
Nylon x
Han kHz i COOH
fun cha I
BE AWARE I O will notbepresent inthe
Y
Ham chat Coon 4mn che t
Nylon3 Man final Coon thatch It
Nylon4
Han final Coon thatch It
Nylon 6
Man final Coon hatches t W
aminocaproicacid
COPOLYMER
Nylon 2 Nylon 6
x NHChal I NH Chat In
Han chat COOH t Han cha soon Amide
Glycine Aminocaproicacid BIODEGRADABLE
Nylon X Y
HanKhal MHz MOOC KH yzCOOH
Haly2004 NH hyena É cha In
ManKHzzMHzt0c
Nylon 6,12
COOH
Han female NH t 400CKhalaf NH Khalq NH É cha h
POLYESTER
Terylene
400C 0004
Ho on I co o kHz
ofn
ITerylen Dacron
Glyptal
Yoon
soon
oh
I o ha ok
no
Thalyptal
PHBU Vater154
Polyhydroxybutyr
om
É o in cnidt
a
3hydroxybutanoic
Etfs 3 hydroxypentanoicaced
in
To he on
let
HCHO XX
Phenol
pm 8 chaOH chon Mocha Chao
n dimwit t
Cheon Choon
pm
8
chimp
tf
cmon
Polymerization
cha
8 oh
8 en
8
Hf CH
NAVOLAC
n
Linear
cha
8 oh
8 en
8
Hf CH
n
Cha
Cha Cha Cha
l t d BAKELITE
cha cha cha
Hf CH
n crosslinked
Melamine
IN h
p M
N
M HCHO
N N N
Hinz Tina y
No of lonepairs in melamine 6 JEEAd2013 mains 22
Area
É Machon fun É much
Man
Katy h s Man
O
LowDensity Polymers HighDensity polymers
flexible Poorconductors RigidHanoi
Plastic bottles Toys Buckets dustbins
11000102000atm LowT LowP 16 7atm
Hight HighP 33334314
Free Radicalmechasim I tales ofOz
zigglerNatta TideAleta
Iuseofcatalyst
Branched
Linear