01-09-2025

2302CJA101021250040 JA

PART-A-PHYSICS

SECTION-I(i)

1) A slab of thickness 3 cm and refractive index is placed infront of a plane mirror as shown in
figure. A point object O is placed at a distance of 4 cm from the slab. After all possible reflections
and refractions, the distance of final image of point object O from plane mirror will be :

(A) 30 cm
(B) 31 cm
(C) 29 cm
(D) \2 cm

2) An object moves with a uniform velocity u0 = 5m/s along the axis of a concave spherical mirror (f
= –10 cm.). Consider the instant shown in diagram, If object is at the centre of curvature at this
instant then the magnitude of acceleration of image at this instant will be.

(A) 25
(B) 50
(C) 250
(D) 500

3) A light ray is incident on a glass sphere at an angle of incidence 60° as shown. Find the total

deviation after two refractions.

(A) 60° Clockwise
(B) 180° Clockwise
(C) 120° Clockwise
(D) 90° Clockwise

4) A light ray (AB) incident parallel to principal axis (XY) at a distance of R/2 (R is radius of
curvature of the concave mirror) from principal axis as shown. BCD is the reflected ray which
intersects principal axis at C. The value of x, if O be centre of curvature and P is the pole of the

mirror, is :-

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Converging rays strike a spherical convex mirror such that they can form the image (in the
absence of mirror) between pole and focus. Now what can you say about final image formed by

mirror?

(A) Real
(B) Virtual
(C) Erect
(D) Inverted

2) A horizontal light ray is incident on a right angled prism. It emerges horizontally from prism after

two total internal reflections as shown in figure. Which of the

following option(s) is/are correct?

(A)

(B)

(C)

(D)

3) Two infinite plane mirrors are inclined at an acute angle such that a ray incident on a mirror
undergoes a total deviation of after two reflections. Then

(A) the angle between the mirrors is

the number of images formed by this system will be 5, if an object is placed symmetrically
(B)
between the mirrors
(C) the number of images will be 5 if an object is kept unsymmetrical between the mirrors
a ray will retrace its path after 2 successive reflections, if the angle of incidence on one mirror
(D)
is

SECTION-I(iii)

1) List I contains four combinations of two lenses (1 and 2) whose focal lengths (in cm) are indicated
in the figures. In all cases, the object is placed 20 cm from the first lens on the left, and the distance
between the two lenses is 5 cm. List II contains the positions of the final images. Which one of the
following options is correct ?

List-I List-II

Final image is formed at

(I) (P) 7.5 cm on the right side of
lens 2.

Final image is formed at

(II) (Q) 60.0 cm on the right side of
lens 2.

Final image is formed at

(III) (R) 30.0 cm on the left side of
lens 2.
 Final image is formed at
(IV) (S) 6.0 cm on the right side of
lens 2.

Final image is formed at

(T) 30.0 cm on the right side of
lens 2.
(A) I → P;II → R;III → Q;IV → T
(B) I → Q;II → P;III → T;IV → S
(C) I → P;II → T;III → R;IV → Q
(D) I → T;II → S;III → Q;IV → R

Common Content for Question No. 2 to 3

When a point object, in a medium of refractive index µ2 is observed by an observer in medium of

refractive index µ1, along the normal incidence, then apparent distance . Hence,

velocity of image of object as directly seen by observer is

2) Answer the following by appropriately matching the lists based on the information given
in the paragraph. A bird in air is diving vertically over a tank with speed 6 m/s and a fish in the
tank is rising upward along the same line with speed 4 m/sec. Base of tank is silvered. [Take µ = 4/3]

List-I List-II

(I) Speed of the fish as seen by bird directly (P) 3 m/s

Speed of image of fish formed after

(II) (Q) 4 m/s
reflection from the mirror as seen by bird

Speed of bird (as seen by) fish looking

(III) (R)
upwards m/s
 Speed of image of bird (as seen by) the fish
(IV) (S) 9 m/s
looking downward in the mirror

(T) 12 m/s

(U)

(A) I → S;II → P;III → T;IV → R

(B) I → S;II → P;III → T;IV → Q
(C) I → U;II → P;III → S;IV → Q
(D) I → U;II → P;III → T;IV → R

3) List-I shows some optical elements and an object with their velocities

List-I List-II

I. (P) Speed of image 2 m/s

II. (Q) Speed of image 4 m/s

μ2 = 3/2 R =
40 cm (consider thin lens)

III. (R) Speed of image 18 m/s

IV. (S) Speed of image 2.5 m/s

Image and object are

(T) moving in opposite
direction

(A) I → PT;II → Q;III → RT;IV → S

(B) I → ST;II → R;III → PT;IV → S
(C) I → PT;II → Q;III → RS;IV → R
(D) I → PQ;II → R;III → QR;IV → S

SECTION-II

1) Consider a concave mirror of focal length 10 cm with its pole as origin of coordinate system,
principal axis along x-axis. The centre of curvature lies on -X axis A point object is moving with
velocity cm/s, find y component in velocity of the image at the instant object passes through
(–15.0 cm, 0.5 cm).

2) Refractive index of a prism of refracting angle 8° varies with wavelength of incident light

according to relation , where λ is in nm.

If a lamp emits voilet light having wavelengths between 400 nm and 420 nm, find angular dispersion
(in degree).

3) Radius of curvature of the silvered face is 20 cm. If final image of object O forms on the object

itself, find radius of curvature of the other surface (in cm).

4) Refractive index of a prism is and the angle of prism is 60º. The minimum angle of incidence
is 10α of a ray that will be transmitted through the prism. Find the value of α.

5) The final image I of the object O shown in the arrangement is formed at point 20 cm below a thin
equi-concave lens, which is at a depth of 65 cm from principal axis. Calculate the magnitude of

common radius of curvature (in cm) of lens kept at "A".

6) A convex lens of focal length 15 cm is placed at the origin with its optical axis coinciding with the

x-axis. A ray of light given by is incident on the lens. The equation of refracted ray is y = –

0.1mx + c. (x and y are in cm). Find the value of m.

PART-B-CHEMISTRY
 SECTION-I(i)

1) Given that (at T = 298 K)

Cu(s) | Cu2+ (1.0 M) || Ag+ (1.0 M) | Ag(s) Eºcell = 0.46 V
Zn(s) | Zn2+ (1.0 M) || Cu2+ (1.0 M) | Cu(s) Eºcell = 1.10 V
Then Ecell for
Zn | Zn2+ (0.1 M) || Ag+ (1.0 M) | Ag at 298 K will be

(A) 1.59 V
(B) 1.53 V
(C) 2.53 V
(D) cannot be calculated due to insufficient data

2) A graph was plotted between molar conductivity of various electrolytes (NaCl, HC1 and NH4OH)

and . Correct set is :

(A) I (NaCl), II (HC1), III, (NH4OH)

(B) I (HC1), II (NaCl), III, (NH4OH)
(C) I (NH4OH), II (NaCl), III, (HC1)
(D) I (NH4OH), H (HC1), III, (NaCl)

3) A crystalline solid is made of X, Y and Z elements. Atoms of X form FCC packing; atoms of Y
occupy octahedral voids while atoms of Z occupy tetrahedral voids. What will be the simplest
formula of solid if atoms along one body diagonal are removed

(A)
(B)
(C)
(D)

4) Efficiency of the following cell is 84%.

A(s) + B2+ (aq) A2+ (aq) + B(s); ΔH° = –285 kJ
Then the standard electrode potential of the cell will be :-

(A) 1.20 V
(B) 2.40 V
(C) 1.10 V
(D) 1.24 V
 SECTION-I(ii)

1) For the given cell at 25°C, select the correct statement(s) -

Given :

(A) Electrode oxidation potential is negative for anodic compartment.

(B) The left electrode in the given figure above behaves as anode.
(C) Standard Emf of the cell is zero
(D) Emf of the cell is 0.059 volts.

2) Which of the following statement(s) for crystal having schottky defect is/are correct.

Schottky defect arises due to absence of cations & anion from positions which they are expected
(A)
to occupy
(B) The density of crystal having schottky defect is smaller than that of perfect crystal.
(C) Schottky defect are more common in compounds with higher co-ordination number.
(D) The crystal having schottky defect is electrically neutral as a whole.

3) Select the correct statement -

(A) Number of lattice points in bcc unit cell are 4

Packing fraction in hcp & fcc is same even when different atoms are used in both
(B)
arrangements
(C) If same atoms are used then density of fcc is maximum in cubic system.
(D) If a = b = c & α = β = γ ≠ 90o then it may be trigonal crystal system

SECTION-I(iii)

1)

List-I
(Ionic compound List-II
structure)

Closest distance between

(P) NaCl (Rock salt) (1)
oppositely charged ions =

Closest distance between cation-

(Q) ZnS (Zinc blende) (2)
cation =

Closest distance between

(R) CaF2 (Flourite) (3)
oppositely charged ions =
 (S) Li2O (Anti flourite) (4) Co-ordinaton number of cation = 6

(5) Co-ordinaton number of anion = 4

[a = Edge length of given unit cell]
Select the correct option :
(A) P → 3,4;Q → 1,5;R → 1,4;S → 1,2,5
(B) P → 3,5;Q → 1,4;R → 1,5;S → 1,2,5
(C) P → 3;Q → 5;R → 4;S → 1,2,5
(D) P → 3,4;Q → 5;R → 5;S → 2

2)

Match the column

Column-I Column-II
(Arrangement of the atoms/ions) (Planes in fcc lattice)

(P) (1)

(Q) (2)

(R) (3)

(S) (4)

(A) P → 4;Q → 3;R → 1;S → 2

(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 3;Q → 2;R → 1;S → 4
(D) P → 1;Q → 2;R → 4;S → 3

3) An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List-I. The

variation in conductivity of these reactions is given in List-II. Match List-I with List-II and select the
correct answer using the code given below the lists : [JEE (Advanced) 2013]

List-I List-II

(P) (C2H5)3N + CH3COOH (1) Conductivity decreases and then

X Y increases

(Q) KI(0.1M) + AgNO3(0.01M) (2) Conductivity decreases and then

X Y does not change much

(R) CH3COOH + KOH (3) Conductivity increases and then

X Y does not change much
 (S) NaOH + HI (4) Conductivity does not change
X Y much and then increases
(A) P → 3;Q → 4;R → 2;S → 1
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 2;Q → 3;R → 4;S → 1
(D) P → 1;Q → 4;R → 3;S → 2

SECTION-II

1) At 298 K, the conductivity of a saturated solution of AgCl in water is 2.6 × 10–6 ohm–1 cm–1. Given,
(Ag+) = 63 ohm–1 cm2 mol–1 & m (Cl–) = 67 ohm–1 cm2 mol–1 The solubility product of AgCl is
.

x10-10 , then value of ' x ' is ____.

2) A resistance of 100Ω is registered when two electrodes are suspended into a beaker containing a
dilute solution of a strong electrolyte such that exactly half of the them are submerged into solution.
If the solution is diluted by adding pure water (negligible conductivity) so as to just completely
submerge the electrodes, the new resistance offered by the solution would be :

3) Consider the cell

Given :

If the potential of the cell is 0.712 V the ratio of concentration of Fe2+ to Fe3+ is _______ .(Nearest
integer)

4) The standard reduction potential for Cu2+|Cu electrode is +0.34 V. The solubility product of
Cu(OH)2 is 1.0 × 10−19. The pH of solution at which the reduction potential for the above electrode
becomes 0.31 V, is (2.303 RT/F = 0.06)

5) The density of solid argon is at 40K. If the argon atom is assumed to be sphere of radius

A° what percentage of solid argon is apparently without anything. (Atomic mass of Ar = 40

amu)

6) An element X (atomic weight = 24 gm/mole ) forms a face centered cubic lattice. If the edge
length of the lattice is 4 × 10–8 cm and the observed density is 2.40 × 103 kg/m3 , calculate the
percentage occupancy of lattice points by X element. (Given NA = 6 × 1023 )

PART-C-MATHEMATICS

SECTION-I(i)

1) Let f : be a continuous function such that , .

Then

(A) f(2)=6e4
(B) f(1)=4e
(C) f(2)=10e4
(D) f(3)=8e3

2) Let be a thrice differentiable function in (–5, 5). Let the tangents to the curve y = f(x) at

(1, f(1)) and (3, f(3)) make angles and , respectively with positive x-axis. If

where α, β are integers, then the value of α + β equals

(A) –14
(B) 26
(C) –16
(D) 36

3) Let be a function which satisfies

Then (a + b) is equal to

(A) –π(π + 2)
(B) –π(π – 2)
(C) –2π(π – 2)
(D) –2π(π + 2)

4) Let f (x) = . If g (x) is the inverse of f (x) then g'(0) has the value equal to

(A)

(B) 11
(C)
(D)

SECTION-I(ii)

1) If and then

(A)

(B)

(C)

(D)

2) Let , for all x > 0.. Then

(A)

(B)

(C) f' (2) ≤ 0

(D)

3) Let R be a continuous function such that f(0) = 1 and dt = 0

Then which of the following statements is (are) TRUE ?

(A)
The equation f(x) – 3 cos 3x = 0 has at least one solution in

(B)
The equation f(x) – 3 sin 3x = has at least one solution in

(C)

(D)

SECTION-I(iii)

1) Match the following List-I with List-II.

 List-I List-I

(I) (P) 8
Let 2g(x) = and = 3 , then g"(1) is

(II) (Q)
x
Let g(x) = e + x + 1, then is

Let g : R → R be a differentiable function such that =

(III) (R) 4
∀ x, y ∈ R. If g(0) = 1, g'(0) = 1, then area bounded by
y = g(x) and co-ordinate axes is

If the area bounded by |x| ≤ 2, |y| ≤ 2, 2xy ≤ x + y ≤ x2 + y2 is A,

(IV) (S) 3
then A + ln 15 is

(T)

The correct option is :

(A) I → S;II → Q;III → P;IV → T
(B) I → S;II → T;III → P;IV → Q
(C) I → S;II → T;III → Q;IV → P
(D) I → S;II → T;III → Q;IV → R

2)
Match the following List-I with List-II

LIST-I LIST-II

(I) (P) 5
Let then the value of is

Let f : R → R, f(x) = 2x – x2 and g : R → R, g(x) = xn, n ∈ N.

(II) (Q)
If area between f(x) and g(x) in first quadrant is then n is

(III) If and S = f(5) + f(4) + f(3) + ..... + f(–3) + f(–4) + f(–5), (R)
then the value of S is

(IV) (S)
If then

(T) 4
(A) I → T;II → P;III → R;IV → S
(B) I → S;II → P;III → Q;IV → T
(C) I → S;II → P;III → T;IV → Q
(D) I → T;II → P;III → S;IV → S

3) and be two curves, satisfying the

relation

The correct option is

(A) I → S;II → Q;III → P;IV → T

(B) I → S;II → R;III → P;IV → Q
(C) I → Q;II → P;III → R;IV → S
(D) I → Q;II → R;III → P;IV → T

SECTION-II

1)

Let f (α) =

and g (α) =

where α ∈ (0, ∞) – . If f (200) – g (50) = π ln a , then the value of 'a' is

2) Value of is equal to
3) is equal to (where [.] denotes greatest integer function) :

4) Consider the function f, g : R → R defined

by and If is the area of the region , then the value

of is

5) Let S be the set of ordered pairs (x, y) such that 0 < x ≤ 1, 0 < y ≤ 1, and and

are both even. Given that the area of the graph of S is m/n, where m and n are relatively
prime positive integers, find m + n. The notation [z] denotes the greatest integer that is less than or
equal to z.

6) The area of the region given by and is equal to (in square units)

where a, b, c are integers & a & b are co-prime, then equals

 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. C D A C

SECTION-I(ii)

Q. 5 6 7
A. A,C B,C A,B,C,D

SECTION-I(iii)

Q. 8 9 10
A. A B A

SECTION-II

Q. 11 12 13 14 15 16
A. 0 0.05 40.00 3.00 60.00 4.00

PART-B-CHEMISTRY

SECTION-I(i)

Q. 17 18 19 20
A. A B A D

SECTION-I(ii)

Q. 21 22 23
A. A,B,C,D A,B,C,D B,C,D

SECTION-I(iii)

Q. 24 25 26
A. D A A

SECTION-II

Q. 27 28 29 30 31 32
A. 4.00 100.00 10.00 5.00 40.00 96.00

PART-C-MATHEMATICS
 SECTION-I(i)

Q. 33 34 35 36
A. C B D B

SECTION-I(ii)

Q. 37 38 39
A. A,B,C,D A,B,C,D A,B,C

SECTION-I(iii)

Q. 40 41 42
A. C B C

SECTION-II

Q. 43 44 45 46 47 48
A. 4.00 7.00 0.00 6.00 14.00 85.00
 SOLUTIONS

PART-A-PHYSICS

1)
Shifting the mirror by slab,

virtual mirror is at distance 30 cm from object

so image is formed at 30 cm from virtual mirror.
so from actual mirror, image is at 29 cm.

2)
Differentiating w.r.t. time t,

or
instantaneous velocity of the image

vi =
Now, the instantaneous acceleration of the image,

ai =

Now, m= –

And

= =
Thus instantaneous acceleration of the image
 0
ai = –2mu

|ai| = ,
Now take |m| = 1 for object at C.

3)
Snell's law At point A

From symmetry,
Snell's law at point B.

Total deviation = 60o

4)

θ = 30°

OC =
x=R–

5)

Object distance = +μ
focal length = f
From mirror formula

Here u < f
so v will be negative
Hence image formed will be real

m is positive hence image will be erect.

Ans (1) and (3)

6)
Using Snell's law at C.

By sine rule,
7)
θ = 60°
Symmetrically

Unsymetrically

When a ray incident on M1 at 60°, it falls on M2

8) (I)

u2 = +15

(II) v1 = +20
u2 = +15

(III) v1 = +20
u2 = +15

(IV)
u2 = –15

9)

= 9 m/s
10)

(A) VI = – 2m/s

(B)

If u = – 20 cm

V = – 20 cm

(C)

Vi = – m2V0 = – 18 m/s

(D)

Vi – Vm = – m2(V0 – Vm)
11) The velocity of object is directed towords focus of the
mirror, hence velocity of image must be parallel to the principal axis, i.e. along x-axis.

12)

Deviation
δ = (µ – 1) A
∴ Angular dispersion
dδ = dµA

=
dδ = 0.05°

13)

This combination should behave as concave mirror of focal length 8 cm so that position of
object coincides with centre of curvature.

Now,

⇒ fL = 80 cm

Here, nL = 3, nS = 2, R1 = –x, R2 = –20

x = 40 cm

14) r2 < θC ; A – r1 < θC

r1 > A – θC
⇒ sinr1 > sin(A – θC)

⇒ > sin (A – θC)

⇒ sini > μ (sinA cosθC – sinθC cosA)

⇒ sini >
or i > 30º .

15) Image formation due to convex lens ⇒ n= = 180 cm

This image will act like a virtual object for mirror and after reflection from mirror its image
(shown by I2) will be formed at 80 cm below optical axis of convex lens.

For concave lens, this image will be object at a

position of 15 cm below the lens.

For final image formed by concave lens. ⇒

Also, = (μ – 1) or = ⇒ R= ; R = 60 cm

16) The given ray cuts y – axis at (0,1) and x-axis at (3,0). Taking u = + 3cm, f = + 15cm, we
 get v = + 2.5 cm. So, the refracted ray passes through (0,1) and (2.5, 0). Its equation then
becomes y = – 0.4 x + 1.

PART-B-CHEMISTRY

17)

...(1)
...(2)
(1) and (2)

18)

(b) Ionic molar conductivity of H+ is very high and NH4OH is a weak electrolyte.

19) Number of atoms of X (at packing site, i.e., at corners and face-centres)

Number of atoms of
Number of atoms of
Along one body diagonal there will be two X atoms, one Y atom and two Z atoms are found and
are removed.

Number of atoms of X will be

Number of atoms of Y will be
Number of atoms of Z will be

∴ Simplest formula will be

20) % efficiency of a cell = × 100

84 = × 100

84 =
Ecell = 1.24 volt

21)

Determine the Anode and cathode

Since the concentration of Cl– are different the electrode with lower cl conqntration (0.01 M)
acts as Anode and the elcttrode with high cl– (0.1M) concentation acts as cathode,
Anode : 2Cl– (0.01M) → Cl2(g) + 2e–
Cathode : Cl2(g) + 2e– → 2Cl– (0.1M)
In figure anode is given at right side

(since both electrode are Cl2/Cl–)

Ecell = Eocell – (n = 2 (no. of electron transperent)

Ecell =
E = 0.059 V
The elctrodepotintial (oxidation) is negative for the anodic compartment, this statement is not
necessarily true because, oxiln potential is the negative of pendnpotentialy The SRP is positive
so at standard conditions the oxidn potential is negative since the cell is not at standard
condition, we can not tell for sure that the oxidn potential is negative
Hence option C) and (D) are correct

22) Schottky defect is only observed in ionic compound.

23)

(A) In BCC unit cell effective number of atoms or lattice points are

=2= + 1×1
(Corners) (Body centre)
(B) Packing fraction of FCC & HCP does not depend upon size atom.
(C) Due to high packing efficiency.
(D) For trigonal system (Rhombohedral)
a = b = c α = β = γ ≠ 90

24) P : 3,6; Q : 5; R : 4; S : 2, 5
25)

26)

(P) First increase then does not change much

(Q) First remain constant then increase
(R) First decrease then does not change much
(S) First decrease then increase

27)
∴ KSP = (2 × 10–5)2= 4 × 10–10

28)
The k is halved while the A is doubled.
Hence, R remains 100Ω

29)

30)
 ⇒ [Cu2+] = 0.1 M

31)

Actual vol. occupied by 1 atom of argon = × π = 36Å3

Since density =

Vol. occupied by per atom of Ar in Crystal = × 40 = 60Å3

% of vacant space = × 100 = 40%

32)

PART-C-MATHEMATICS

33)

⇒ ln f(x) = 2x + ln (1+x2)+c
as f(0) = 2 ⇒ ln 2 = c
⇒ f(x) = 2 (1+ x2) e2x

34) y = f(x) ⇒
f'(t) = z ⇒ f"(t) dt = dz
z = f'(3) = 1

z = f'(1) =

α = 36, β = –10
α + β = 36 – 10 = 26

35)

36)
x=3⇒y=0
∴ f'(3) g'(0) = 1
37)

and

38)

put tx = z

Here f' (1) = 0. Sign scheme of f' (x) :

f' (2) < 0

Also

39) (A) Let g(x) = f(x)–3 cos 3x

Now

Hence g(x) = 0 has a root in

(B) Let h(x) = f(x) – 3sin 3x +

Now
=0–2+2=0

Hence h(x) = 0 has a root in

(C)

(D)

40) (I) Expand the square

(II) + = 1 ⋅ g(1) – 0 ⋅ g(0)

+ = (e + 2) × 1 – 0 × 2

= (e + 2) – = (e + 2) – =e+2–e– =
(III) g(x) = ax + b

(IV) Area bounded = 0 × 4 × 4 –

41)

(I) For
⇒ f(f(X)) +f(1– f(x)) =1

.... (1)
 .... (2)

(II) Area

(III)

(IV) and f(f(x)) = x

42)

43)

We have
 ......(1)

∴ On equation (1) + equation (2), we get

Now

44)
45)

46)

47) r = 1, 2, 3, 4, .....

r = 1, 2, 3, 4, .....
Required area

×
48) The required region is shaded below :

x + y = 6 and cut at S(3,3) & P(0,6). cut at R(2, 4).

Required area = Area of curvilinear ΔOMRO + Area of trapezium MNSR – area of curvilinear

ΔONSO (area of square ONSG – area of sector OSGO)

∴ a = 9, b = 4 and c = 6