20-07-2025

2401CJA101029250016 JA

PHYSICS

SECTION - I

1) A particle of mass m, charge Q and kinetic energy T enters a transverse uniform magnetic field of
induction. After 3 seconds the kinetic energy of the particle will be:-

(A) T
(B) 4 T
(C) 3 T
(D) 2 T

2) In an RC circuit while charging, the graph of ln i versus time is as shown by the dotted line in the
diagram figure, where i is the current. When the value of the resistance is doubled, which of the

solid curve best represents the variation of ln i versus time

(A) P
(B) Q
(C) R
(D) S

3) A capacitor is being discharged by infinite ladder of resistors, starting from Q0 charge. Total heat

dissipated in horizontal resistors is

(A)

(B)
(C)

(D)

4) In this figure the resistance of the coil of galvanometer G is 2 Ω. The emf of the cell is 4 V. The

ratio of potential difference across C1 and C2 is:

(A) 1

(B)

(C)

(D)

5) A circuit is connected as shown in the figure with the switch S open. When the switch is closed,

the total amount of charge that flows from Y to X is :

(A) 0
(B) 54 μC
(C) 27 μC
(D) 81 μC

6) Circuit shown is in steady state, now when switch is closed, galvanometer shows no deflection,
then correct relation is :-

(A)

(B)

(C) R1R2 = C1C2

(D)

7) Two spherical conductors A and B of radii a and b (b > a) are placed concentrically in air. A is
given a charge +Q while B is earthed. Then the equivalent capacitance of the system is

(A)

(B)
(C)

(D)

8) In a meter bridge circuit as shown, when one more resistance of 100 Ω is connected is parallel

with unknown resistance x, then ratio become 2. If ℓ1 is balance length of the uniform wire AB,

then the value of x must be :

(A) 50 Ω
(B) 100 Ω
(C) 200 Ω
(D) 400 Ω

9) AB is 1 meter long uniform wire of 10 ohm resistance. The other data are as shown in the circuit
diagram. Calculate length AO of the wire, when the galvanometer shows no deflection :-

(A) 37.5 cm
(B) 20 cm
(C) 45 cm
(D) 80 cm

10) A potentiometer wire has length 10 m and resistance 10Ω. It is connected to a battery of EMF 11
volt and internal resistance 1 Ω, then the potential gradient in the wire is :-

(A) 10 V/m
(B) 1 V/m
(C) 0.1 V/m
(D) none

11) AB is a potentiometer wire of length 100 cm and its resistance is 10 ohm. It is connected in
series with a resistance R = 40 ohm and a battery of e.m.f. 2V and negligible internal resistance. If a
source of unknown e.m.f. E is balanced by 40 cm length of the potentiometer wire, the value of E is

:-

(A) 0.8V
(B) 1.6 V
(C) 0.08 V
(D) 0.16 V

12) Circuit shown in figure is a simple ohm – meter, in which G is a galvanometer, R0 is known
resistance and R is the resistance which is to be measured. If A and B are short circuited by a
resistancesless wire, galvanometer gives full scale deflection. Then to read the resistance R directly

from galvanometer, ohm – meter scale would look like:

(A)

(B)

(C)

(D)

13) Two blocks A & B each of mass m are connected by two massless springs and a constant force F
acts on block B and the given system is in equilibrium on smooth horizontal surface. Just after force
F0 is removed acceleration of blocks A and B are aA and aB respectively then:

(A) aA = 0, aB = 0

(B)
aA = , aB =

(C)
aA = 0, aB =
(D)
aA = , aB = 0

14) Weight is defined as:

(A) Force of attraction exerted by the earth

(B) Mass of a body
(C) Nature of a body
(D) None of these

15) Bock B of mass 100 kg rests on a rough surface of friction coefficient . A rope is tied to
block B as shown in figure. The maximum acceleration with which boy A of 25 kg can climbs on rope

without making block move is :

(A)

(B)

(C)

(D)

16) The upper half of an inclined plane with inclination ϕ is perfectly smooth, while the lower half is
rough. A body starting from rest at the top will again come to rest at the bottom, if the coefficient of
friction for the lower half is given by-

(A) 2 sin ϕ
(B) 2 cos ϕ
(C) 2 tan ϕ
(D) tan ϕ

17) A ball is dropped inside an elevator accelerating downwards at acceleration 2 m/s2. As seen from
the elevator acceleration of ball will be : (g = 10 m/s2)

(A) 8 m/s2 downwards

(B) 10 m/s2 downwards
(C) 8 m/s2 upwards
(D) 10 m/s2 upwards

18) Two particles 1 and 2 starts at the same time from initial position vector and with constant
velocities and as shown. Find a relation between and for both particles to collide.
(A)

(B)

(C)

(D)

19) An enemy plane is flying horizontally with a speed of 300 m.s-1at an altitude h. A soldier with an
anti-aircraft gun on the ground sights the enemy plane when it is directly overhead and fires a shell
with a muzzle speed of 600 m.s-1. At what angle with the vertical should the gun be fired so as to hit
the plane at the highest point of projected shell?

(A) 30o
(B) 45o
(C) 60o
(D) 75o

20) Rain is falling vertically with a speed of 4 ms-1. After sometime, wind starts blowing with a speed
of 3 m s-1 in the north to south direction. The angle , with the vertical , at which the man standing
on the ground should hold his umbrella in order to protect himself from the rain is given by

(A)
= tan-1 towards south

(B)
= tan-1 towards north

(C)
= cot-1 towards south

(D)
= cot-1 towards north

SECTION - II

1) Two infinite length wires carries currents 8A and 6A respectively and placed along X and Y- axis.
Magnetic field at a point P (0, 0, d) m will be . Find n.

2) A charged particle of mass m is moving with a speed u in a circle of radius r. If the magnetic field

induction at the centre is B, the charge on the particle is , then find N.

3) A current is flowing in a circular coil of radius R and the magnetic field at its center is B0. At

distance from the center on the axis of coil, the magnetic field is . Find N.

4) A direct current I flows along a lengthy straight wire. From the point O (figure) the current
spreads radially all over an infinite conducting plane perpendicular to the wire. The magnetic

induction at perpendicular distance r from the wire is given by , then value of k is ?

5) A battery is connected between two points A and B on the circumference of a uniform conducting
ring of radius r and resistance R as shown in Fig. One of the arc AB of the ring subtends angle θ at

the centre. Find the magnetic field at the centre O.

CHEMISTRY

SECTION - I

1) (i) Cis-2 - butene → trans - 2 - butene, ΔH1

(ii) Cis - 2- butene → 1 - butene, ΔH2
(iii) Enthalpy of combustion of 1-butene, ΔH = -649.8 kcal/mol
(iv) 9ΔH1 + 5 ΔH2 = 0
(v) Enthalpy of combustion of trans 2 - butene, ΔH = –647.0 kcal/mol.
The value of ΔH1 & ΔH2 in Kcal/mole are

(A) -1.0 , 1.8

(B) 1.8, –1.0
(C) –5, 9
(D) –2, 3.6

2) Hydrazine, a component of rocket fuel, undergoes combustion to yield N2 and H2O.

N2H4 (l) + O2 (g) —→ N2 (g) + 2H2O (l)
What is the enthalpy change of combustion of N2H4 (kJ/mole)
Given Reaction ΔH/kJ
2NH3 (g) + 3N2O (g) —→ 4N2 (g) + 3H2O (l) – 1011 kJ
N2O (g) + 3H2 (g) —→ N2H4 (l) + H2O (l) – 317 kJ
4NH3 (g) + O2 (g) —→ 2N2H4 (l) + 2H2O (l) – 286 kJ

H2 (g) + O2 (g) —→ H2O (l) – 285 kJ

(A) – 620.5
(B) – 622.75
(C) 1167.5
(D) + 622.75

3) The enthalpy change for the reaction,

CH3CHO (g) → CH4(g) + CO(g) at 300 K is – 17.0 kJ/mol
Calculate the temperature at which ΔrH for the reaction will be zero.
[Given : Cp,m (CH4,g ) = 38 J/K mol ; Cp,m (CO, g) = 31 J/K mol & Cp,m (CH3CHO,g) = 52 J/K mol]

(A) 1300°C
(B) 1027°C
(C) 700°C
(D) 754ºC

4) An ideal gas having is taken from A to B according to given diagram, calculate ΔH for

ideal gas in process A to B.

(A) 25.6 atm-L

(B) 48 atm-L
(C) 12 atm-L
(D) 19 atm-L

5) Calculate the magnitude of net work done in the following cycle for one mol of an ideal gas (in

Calorie), where in process BC, PT = constant. (R = 2cal/mol-K).

(A) 800 cal
(B) 200 cal
(C) 300 cal
(D) 400 cal

6)

Which of the following is CORRECT statement ?

(A) In adiabatic expansion of an ideal gas, temperature of system always decrease

(B) In isothermal expansion of an ideal gas, temperature of a gas always remains constant
In a reversible adiabatic compression of an ideal gas, change in internal energy of system is
(C)
zero
In an irreversible adiabatic compression of an ideal gas, change in internal energy of system is
(D)
zero

7) The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the

figure. Which of the following statement(s) is (are) correct ?

(A) T1 < T2
(B) T3 > T1
(C) Wisothermal > Wadiabatic
(D) ∆ Uisothermal > ∆ Uadiabatic

8)
Major product is :

(A)

(B)

(C)

(D)

9) When all cis isomers of C6H6Cl6 (1, 2, 3, 4, 5, 6-Hexachlorocyclohexane) is heated with alc. KOH,
The most probable product is :
(A)

(B)

(C)

(D)

10) Which of the following alkane is prepared in a good yield by Wurtz reaction ?

(A)

(B)

(C)

(D)
11)
(If 96% racemisation takes place)
Find out the correct statement about the reaction.

(A) Among the products 48% S and 48% R configuration containing molecules are present.
(B) Among the products 50% S and 50% R configuration containing molecules are present.
(C) Among the products 48% S and 52% R configuration containing molecules are present.
(D) Among the products 52% S and 48% R configuration containing molecules are present.

12) The final product 'Q' is

(A)

(B)

(C)

(D)

13) Find out the total number of allylic mono-bromo substituted products (including stereo) in the

given reaction : ​ Products.

(A) 5
(B) 9
(C) 10
(D) 11

14) During change of O2 to O2– ion, the electron adds on which one of the following orbitals ?
(A) σ* orbital
(B) σ orbital
(C) π* orbital
(D) π orbital

15) Correct order of covalent character of alkaline earth metal chloride is

(A) BeCl2 < MgCl2 < CaCl2 < SrCl2

(B) BeCl2 < CaCl2 < SrCl2 < MgCl2
(C) BeCl2 > MgCl2 > CaCl2 > SrCl2
(D) SrCl2 > BeCl2 > CaCl2 > MgCl2

16) The molecule/species having highest bond order

(A) O2
–
(B) O2
+
(C) O2
2–
(D) O2

17) In the following the correct bond order sequence is:

(A)
(B)
(C)
(D)

18) In O–2, O2 & O2–2 species total No. of antibonding electrons are respectively :-

(A) 7, 6, 8
(B) 1, 0, 2
(C) 6, 6, 6
(D) 8, 6, 8

19) Incorrectly matched among the following is

Column - I Column - II
(Species) (Bond order)
A O2+ 2.5
B N2– 2
C NO 2.5
D OF 2
(A) A
(B) B
(C) C
(D) D

20) 3c-2e bond is absent in :-

(A) Be2H4
(B) BH3
(C) Al2H6
(D) Al2(CH3)6

SECTION - II

1) For reaction XeF6 + H2O XeOF4 + 2HF ; K1 = 4

XeO4 + XeF6 XeOF4 + XeO3F2 ; K2 = 100
Find equilibrium constant of

2) How many reaction given amount the following give alkane as a major product?

(I) CH3 – CH2 – Br

(II)

(III)

(IV) CH3 – CH2 – Br

(V) CH3 – COONa

3)

Total number of reactions correctly match with their major products are ?

(1) (2)

(3) (4)
(5) (6)

4) Maximum number of atom(s) in I2Cl6 which is/are in the same plane is x, then the value of is.

5) Find the total number of chemical species in which mentioned bond length decreases due to back
bonding.
BF3 (B-F) B(OMe)3 (B-O)
PF3 (P-F) H3SiNCO (N-Si)
B3N3H6 (B-N) NO2– (N-O)
O3 (O-O)

MATHEMATICS

SECTION - I

1) Value of is
(where [.] is greatest integer function)

(A)

(B)

(C)

(D)

2)

(A)

(B)

(C) 1
(D)
3) If f(x) = max{2 – x, 2,1 + x}, then equals

(A) 15/2
(B) 21/2
(C) 23/2
(D) 17/2

4) The value of is equal to -

(A)

(B) 2

(C)

(D)

5) The value of the integral is equal to

(A) 2
(B) 3
(C) 4
(D) 5

6) The value of definite integral , equals

(A)

(B)

(C)

(D)

7) The value of the definite integral where { x } denotes the fractional

part function.
(A) 0
(B) 6
(C) 9
(D) can't be determined

8) If g (x) is the inverse of f (x) and f (x) has domain x ∈ [1, 5], where f (1) = 2 and f (5) = 10 then

the values of equals -

(A) 48
(B) 64
(C) 71
(D) 52

9) The value of the definite integral equals

(A)

(B)

(C)

(D)

10)

(A) π2

(B)

(C)

(D)

11)

(A)

(B)
(C)

(D)

12)

If, . Where , then ƒ(0) + 10K is equal to

(A) 0
(B) 10
(C) 20
(D) 21

13)

(A)

(B)

(C)

(D)

14) is equal to (where C denotes constant of integration)

(A)

(B)

(C)

(D)

15) is equal to (Where C is integrating constant)

(A)
(B)

(C)
(D) None of these

16) If then

(A) 9
(B) 12
(C) 15
(D) 21

17) Equation of a circle which passes through (3, 6) and touches the axes is

(A) x2 + y2 + 6x + 6y + 3 = 0
(B) x2 + y2 – 6x – 6y – 9 = 0
(C) x2 + y2 – 6x – 6y + 9 = 0
(D) None of these

2 2
18) If the circle x + y = 4 and
x2 + y2 + 6x + λy + λ = 0
intersect orthogonally, then λ is

(A) 4
(B) –4
(C) 6
(D) –6

19) The distance from the centre of the circle x2 + y2 = 2x to the straight line passing through the
points of intersection of the two circles x2 + y2 + 5x – 8y + 1 = 0 and x2 + y2 – 3x + 7y – 25 = 0 is :-

(A)

(B) 2
(C) 3
(D) 1

20) An equilateral triangle SAB is inscribed in the parabola having its focus at 'S'. If chord
AB lies towards the left of S, then side length of this triangle is:

(A)

(B)

(C)

(D)

SECTION - II
1) Through the vertex O of parabola y2 = 4x, chords OP and OQ are drawn at right angles to one
another, where P and Q are point on the parabola. If the locus of middle point of PQ is y2 = 2(x – ℓ),
then value of ℓ is

2) Let a circle is passing through the point of intersection of circles x2 + y2 – 8x – 2y + 7 = 0 and x2 +

y2 – 4x + 10y + 8 = 0. Its centre lies on y-axis & having the radius R then is

3) If where C is integration constant,

then equals

4) If (where m & n are coprime natural numbers), then value of (m – n) is

5) The value of is
 ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B C B C A A B A B D A C A B C A B A B

SECTION - II

Q. 21 22 23 24 25
A. 5.00 4.00 3.00 2.00 0.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A B C A B D A B D C C B C C C C A D B

SECTION - II

Q. 46 47 48 49 50
A. 5.00 4.00 4.00 4.00 5.00

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C B A C D B A D B D C C D B C C A B B

SECTION - II

Q. 71 72 73 74 75
A. 4.00 0.50 6.18 or 6.19 5.00 3.20
 SOLUTIONS

PHYSICS

1)

If charged particle enters perpendicular to the uniform magnetic field, then it represents
uniform circular motion and in uniform circular motion kinetic energy remains constant.

2)

Ans. (B)
B is the correct answer

3) Total power in horizontal resistors at any time

Total power in vertical resistors

4)

At steady state, current in the circuit is

Voltage across C1 is

Voltage across C2 is

5) When steady state is reached, the current I coming from the battery is 9 = I(3 + 6)
⇒ I=1A

∴ Potential difference across 3Ω resistance = 3V and potential difference across 6Ω

resistance = 6V
∴ p.d across 3 μF capacitor = 3V
and p.d across 6 μF capacitor = 6 V
∴ Charge on 3 μF capacitor Q1 = 3 × 2 = 9 μC
∴ Charge on 6 μF capacitor Q2 = 6 × 6 = 36 μC
∴ Charge (–Q1) is shifted from the positive plate of 6 μF capacitor.
The remaining charge on the positive plate of 6 μF capacitor is shifted through the switch.
∴ Charge passing the switch = 36 – 9 = 27 μC

6) ....(i)

....(ii)

7)

Ans. (A)
A is the correct answer

8)
100 + x = 2x
x = 100Ω

9)

Ans. (A)
A is the correct answer

10)

Ans. (B)
B is the correct answer

11)

Ans. (D)
D is the correct answer

12)

Suppose emf of the battery connected in the circuit is equal to E. Then the current at R = 0

will be equal to when R increases, current through the circuit decreases.

If R = Ro, then net resistance of the circuit will become equal to 2R.

Hence, current through the circuit will become

To reduce the current to Io/4, the net resistance of the circuit is to be increased to 4 times of
its original value Ro. Hence, R = 3Ro. Similarly, to reduce the current to Io/8, the resistance R
must be equal to 7Ro and to reduce the current to zero, R must be very large. Hence, (A) is
correct.

13) (Fnet)A = 0
(Fnet)B = F = maB

14)

Ans. (A)
A is the correct answer

15)

16)

Ans. (C)
C is the correct answer

17)
=
= ↓ 8 m/s2

18) must be along

So,

19)

20) w is wind
 21)

Ans. (5.00)
(5.00) is the correct answer

22)

Ans. (4.00)
(4.00) is the correct answer

23)

Ans. (3.00)
(3.00) is the correct answer

24) Refer notes

25)

Magnetic field at the centre of an arc is given by,

Magnetic field due to a smaller arc,

Magnetic field due to larger arc,

Resultant magnetic field,

...(1)
Two arcs form a parallel combination of resistors.
Thus I1R1 = I2R2,
where R1 and R2 are resistances of respective segments.
As the wire is uniform,

Thus, , ...(2)
On substituting I2 in equation (1), we get

=0
Hence the field is independent of θ.

CHEMISTRY
26) ΔH1 ...(1)

ΔH2 ...(2)

+ 6O2 → 4CO2 + 4H2O ΔH4 ...(4)

(3) + (2) – (1) = (4)
–649.8 + ΔH2 – ΔH1 = – 647.0
ΔH2 – ΔH1 = 2.8
9ΔH1 + 5ΔH2 = 0
Solve for ΔH1 & ΔH2

27) (1) × (2) – (3) (1) × 2 ...(3)

2N2H4(l) + 2H2O(l) → 4NH3 + O2
4NH3 + 6N2O → 8N2 + 6 H2O

...(5)

8N2H4 + 6H2O → 18H2 + O2 + 4H2 + 8N2 ...(7)

18H2 + 9O2 → 18H2O(l)
__________________________________

__________________________________

28) ΔCp = Cp(CO) + CP(CH4) – CP(CH3CHO)

= 31 + 38 – 52
= 69 – 52 = 17
ΔH2 – ΔH1 = ΔCP × (T2 – T1)
ΔH2 = 0 ΔH1 = – 17.0
T1 = 300
ΔCP = 17
find T2 = ?

29)

Ans. (C)
C is the correct answer

30) wtotal=wAB + wBC + wCA

wAB = 0 (isochoric)

wBC = (Polytropic PV1/2= constant)

 = –2400 Cal
wCA = –nRΔT (isobaric)
= –1 × 2 × –800 = 1600 Cal
wtotal=0 – 2400 + 1600 = –800 Cal

31)

Ans. (A)
A is the correct answer

32)

Ans. (D)
D is the correct answer

33)

Ans. (A)
A is the correct answer

34)

Ans. (B)
B is the correct answer

35)

Although 3° radical is more stable, 3° radical do not combine or dimerise readily. Therefore
less hindered radical is suitable for Wurtz reaction.

36)

SN1 reaction Retention and inversion both.

Inverted Pdt slightly greater than retention Pdt.
So, answer will be 'C'

37)

Ans. (C)
C is the correct answer

38)
Ans. (B)
B is the correct answer

39)
As π* molecular orbitals are half filled so, one extra electron can be added to π* molecular
orbital

40) BeCl2 > MgCl2 > CaCl2 > SrCl2 →

Size of cation ↑, Polarisation ↓, Covalent character ↓.

41) O2 → 2
O2– → 1.5
O2+ → 2.5
O22– → 1

42) O2 (16 electrons)

Bond order of
Bond order of
Bond order of
Bond order of

43) O2 = 1s2(σ) 1 s 2(σ*) 2 s 2(σ) 1 s 2(σ*)

Total no. of e–s in ABM O in O2 = 6

in
in

44) OF bond order is 1.5

45) 3c–2e bond is absent in BH3

46)
 47)

Ans. (4.00)
(4.00) is the correct answer

48)

Ans. (4.00)
(4.00) is the correct answer

49) I2Cl6 is a planar molecule and all atoms are in same plane so total atoms in same plane = 8.

50) BF3 (B-F)

PF3 (P-F)
H3SiNCO (N-Si)
B3N3H6 (B-N)
B(OMe)3 (B-O)
For back bonding donor have minimum one lone pair and acceptor have vacant p or d-orbital.

MATHEMATICS

51)

52)

use
⇒ ⇒I=1

53)

54)

55)
Put x = –t
Put tan x = t

Put

56) Put 2x = tanq

57) ∵ {x} and sin2πx both have period equals to 1.

∴ I = (37 – 19)

= 18

58) ∵

∴
59) .....(1)
Using King

.....(2)
(1) + (2)

60) ....(1)
Using King's

....(2)
Adding (1) & (2)

....(3)
Using King's

Also ....(4)
Adding (3) & (4)
61)

62) = f(x) + K log|x| + C and f(π/4) = 1

= tan x + 2log |x| + C

f(x) = tanx, K = 2 (by comparing)
Now, f(0) + 10K = tan0 + 10 ⋅ 2 = 0 + 20 = 20

63)

use integration by parts

(Where c is an integral function)

64)

put

65)

66)
67)

Ans. (C)
C is the correct answer

68)

69) Centre (1, 0)

line : s1 – s2 = 0
8x – 15y + 26 = 0

Distance from centre

70) Let

We have

Clearly is rejected.

Thus,

Hence,
71)

⇒ t1t2 = –4

& k = t1 + t2
⇒ 2h = (t1 + t2)2 – 2t1t2
⇒ 2h = k2 + 8 ⇒ y2 = 2(x – 4)
∵

72) (x2 + y2 – 8x – 2y + 7) + λ(x2 + y2 – 4x + 10y + 8) = 0 x2(1 + λ) + y2(1 + λ) + 2x(–4 – 2λ) +

2y(5λ – 1) + (7 + 8λ) = 0
–4 – 2λ = 0 ⇒ λ = –2
x2 + y2 + 22y + 9 = 0

73)
put tanx = t

a1 = 1/4 b1 = 1/4
a2 = 9/4 b2 = 9/8
a3 = 17/4 b3 = 17/4

a1 + a2 + a3 + b1 + b2 + b3 =

74)
75)