30-07-2025
7102CJA20220125004 PF
PHYSICS
Category-I
1) If the velocity of the particle is given by V= 3t2 + 4t (in m/s) where t is the time taken, what is the
displacement of the particle till the time its acceleration becomes 10 m/s2.
(1) 1m
(2) 2m
(3) 3 m
(4) 6 m
2) Angle made by electric field due to short dipole at equatorial position with its dipole moment will
be:-
(1) 0°
(2) 90°
(3) 120°
(4) 180°
3)
A man is crossing a river flowing with velocity of 5 ms-1. He reaches a point directly across the river
at a distance of 60 m in 5 sec. His velocity in still water should be.
(1) 12 ms-1
(2) 13 ms-1
(3) 5 ms-1
(4) 10 ms-1
4) A relation is given below , here λ is wavelength and T is temperature than dimensional
formula of b is :-
0 0
(1) [M L1T K–1]
0 0
(2) [M L1T–1K ]
0 0
(3) [M L1T K1]
0 0
(4) [M L1T1K ]
5) The co-ordinates of a moving particle at any time t are given by x = αt3 and y = βt3. The speed of
the particle at time t is given by :-
(1)
(2)
(3)
(4)
6) A small circular ring has a uniform charge distribution. On a far-off axial point distance x from the
centre of the ring, the electric field is proportional to :-
(1) x–1
(2) x–3/2
(3) x–2
(4) x5/4
7) A quantity x is related with other quantities y & z as x = Ay + B tan (Cz) where A, B & C are
constants out of following which has not same dimensions.
(1) x, B
(2) C, z–1
(3) y, B/A
(4) x, A
8) If y = x – x2 is equation of trajectory then time of flight is (g is acceleration of objects)
(1)
(2)
(3) g
(4)
9) The unit of force and length are doubled, the unit of energy will be :-
(1)
times
(2)
times
(3) 2 times
(4) 4 times
10) The velocity υ (in cms–1) of a particle is given in terms of time t (in sec.) by the relation υ = at +
; the dimensions of a, b and c are :
(1) a = L2, b = T, c = LT2
(2) a = TL2, b = LT, c = L
(3) a= LT–2, b = L, c = T
(4) a = L, b = LT, c = T2
11) The dependence of electric potential V on the distance r from the centre of a charged spherical
shell is shown by :
(1)
(2)
(3)
(4)
12) In a new system of units, the unit of force is 100N, unit of length is 10m and unit of time is 100 s,
Unit of mass in this system can be expressed as
(1) 105 kg
(2) 106 kg
(3) 102 kg
(4) 103 kg
13) A water molecule as shown is in a region of uniform electric field V/m. This molecule
experiences:
(1) A counterclockwise torque.
(2) A clockwise torque.
(3) A net force to the right.
(4) A net force to the left.
14) The displacement-time graph of two moving objects A and B are shown in the figure given below.
Which of the following is incorrect ?
(1) B is moving with constant velocity
(2) A is moving with increasing speed
(3) B is moving with non-zero constant acceleration
(4) Acceleration of A may be constant
15) A sphere of radius R carries charge density proportional to the square of the distance from the
center: ρ = Ar2, where A is a positive constant. At a distance of R/2 from the center, the magnitude
of the electric field is :-
(1) A/4πε0
3
(2) AR /40ε0
3
(3) AR /24ε0
3
(4) AR /5ε0
16) Equation of a projectile is y = – 10x2 its angle of projection is :-
(1) 15°
(2) 30°
(3) 60°
(4) Can not be found
17) A ball is hit by a batsman at an angle of 37° as shown in figure. The man standing at P should
run at what minimum velocity so that he catches the ball before it strikes the ground. Assume that
height of man is negligible in comparison to maximum height of projectile :-
(1) 3 m/s
(2) 5 m/s
(3) 9 m/s
(4) 12 m/s
18) A body is projected vertically upwards. The time corresponding to height h while ascending and
while descending are t1 and t2 respectively. then the velocity of projection is : (g is acceleration due
to gravity) :-
(1)
(2)
(3)
(4)
19)
The ratios of the distances covered by a freely falling particle, starting from rest, in the first, second,
third ....... nth second of its motion :
(1) 1 : 2 : 3 : ............ : n
(2) 1 : 3 : 5 : ............. : (2n – 1)
(3) 12 : 22 : 32 : ................ : n2
(4) 12 : 32 : 52 : ............. : (2n – 1)2
20) The initial velocity of a particle moving along x-axis is u (at t = 0 and x = 0) and its acceleration
a is given by a = kx. Which of the following equation is correct between its velocity (v) and position
(x) ?
(1) v2 – u2 = 2kx
(2) v2 = u2 + 2kx2
(3) v2 = u2 + kx2
(4) v2 + u2 = 2kx
21) If the electric potential of the inner metal sphere is 10 Volt & that of the outer shell is 5 volt,
then the potential at the centre will be :-
(1) 10 volt
(2) 5 volt
(3) 15 volt
(4) 0
22) Two electric dipoles of moment P and 64 P are placed in opposite direction on a line at a
distance of 25 cm. The electric field will be zero at point between the dipoles whose distance from
the dipole of moment P is
(1) 5 cm
(2)
cm
(3) 10 cm
(4)
cm
23) The velocity V of waves produced in water depends on their wavelength λ, the density of water
ρ, and acceleration due to gravity g. The square of velocity is proportional to :-
(1) λ–1g–1ρ–1
(2) λg
(3) λρg
(4) λ2g–2ρ–1
24) A body moves with a velocity x = 2t3 – 3t2 along x-axis. Where x is in meter and t is in
second. The initial velocity of the body is :
(1) Zero
(2) 6
(3) 4
(4) Independent
25) A car travels A to B at 40 km/hr and returns at 60 km/hr its average speed is :-
(1) 50 km/hr
(2) 48 km/hr
(3) 60 km/hr
(4) 42 km/hr
26) Rain is falling vertically down at 3km/hr and a person holding a hollow tube is standing as
shown. If he runs at 4km/hr forwards at what angle with vertical he should tilt the tube so that rain
water entering tube do not wet the tube from inside:-
(1) 30°
(2) 53°
(3) 37°
(4) 60°
27) A Projectile is projected at an angle α (>45°) with an initial velocity u. The time t at which its
horizontal component will equal the vertical component in magnitude :
(1)
(2)
(3)
(4)
28) A scooter going due east at 10 m s–1 turns right through an angle of 90°. If the speed of the
scooter remains unchanged in taking this turn, the change in the velocity of the scooter is :
(1) 20.0 m s–1 in south-western Common direction
(2) zero
(3) 10.0 m s–1 in south-east direction
(4) 14.14 ms–1 in south-western direction Common
29) A stone is projected from the ground with a velocity of 25 m/s. 2 sec. later, it just clears wall 5 m.
high. Then angle of projection of the stone is:
[Neglect air resistance, Assume g = 10 m/sec2]
(1) 30°
(2) 60°
(3) 45°
(4) 53°
30) A ring of radius R has a linear charge density λ = λ0 cos θ, along its circumference. Total charge
on the ring is :-
(1) λ0πR
(2) zero
(3) –λ0pR
(4) 2λ0πR
Category-II
1) If force in a physical event is given by F = where r is radius and t is time then dimension of
a and b are :-
(1) M2L3T–2, T
(2) ML3T–2, T–1
(3) MLT–2, T–1
0
(4) ML3T–2, T
2) A stone is projected from point P on the inclined plane with velocity v0 = 10 m/s directed
perpendicular to the plane. The time taken by the stone to strike the horizontal ground S is (Given
PO = ℓ = 10 meter)
(1) 1.5 sec
(2) 1.4 sec
(3) 2 sec
(4) 2.3 sec
3) Four charges are placed at the circumference of the dial of a clock as shown in figure. If the
clock has only hour hand, then the resultant force on a positive charge q0 placed at the centre,
points in the direction which shows the time as :–
(1) 1:30
(2) 7:30
(3) 4:30
(4) 10:30
4) A river is flowing with a speed of 1 m/s. A swimmer wants to go to point C starting from A. He
swims with a speed of 5 m/s, at an angle θ w.r.t. river flow. If AB = BC = 1000 m. Then the value of θ
is :-
(1) 30°
(2) 37°
(3) 45°
(4) 53°
5) The electric potential at a point (x, y, z) is given by:
V = –x2y – xz3 + 4
The electric field at that point is :-
(1) = (2xy – z3) + xy2 + 3z2x
(2) = (2xy + z3) + x2 + 3xz2
(3) = 2xy + (x2 + y2) + (3xz + y2)
(4) = z3 + xyz + z2
Category-III
1) In a situation, a board is moving with a constant velocity v with respect to earth, while a man A
and man B are running with a velocity 2v with respect to earth and both men are running from the
opposite ends of the board at the same time, as shown. Length of the board is L. If they meet after
time T, then
Value of T is
(1)
Value of T is
(2)
(3) Displacement of man B with respect to board in time T is 3L/4
(4) Displacement of man A with respect to board in time T is L/4
2) Two non-conducting spheres of radii R1 and R2 and carrying uniform volume charge densities +ρ
and –ρ, respectively, are placed such that they partially overlap, as shown in the figure. At all points
in the overlapping region :-
(1) the electrostatic field is zero
(2) the electrostatic potential is constant
(3) the electrostatic field is constant in magnitude
(4) the electrostatic field has same direction
3) The motion of a body is given by the equation where v is speed in m/s and t in
second. If body was at rest at t = 0
(1) The terminal speed is 2.0 m/s
(2) The speed varies with the time as v = 2(1 – e–3t) m/s
(3) The speed is 0.1 m/s when the acceleration is half the initial value
(4) The magnitude of the initial acceleration is 6.0 m/s2
4) Two large thin conducting plates with small gap in between are placed in a uniform electric field
E (perpendicular to the plates). Area of each plate is A and charges +Q and –Q are given to these
plates as shown in the figure. If points R,S and T as shown in the figure are three points in space,
then the
(1) field at point R is E
(2) field at point S is E
(3)
field at point T is
(4)
field at point S is
5) If T is the total time of flight, h is the maximum height and R is the range for horizontal motion,
the x and y co-ordinates of projectile motion and time t are related as
(1)
(2)
(3)
(4)
CHEMISTRY
Category-I
1) In which of the following process energy is not absorbed :
(1) Na → Na+
(2) Mg → Mg+2
(3) O → O+
(4) None of these
2)
List-I (Element) List-II (ΔHIE1 in kJ / mol)
(P) N (1) +800
(Q) O (2) +900
(R) Be (3) +1300
(S) B (4) +1400
(1) P → 2;Q → 3;R → 1;S → 4
(2) P → 1;Q → 2;R → 3;S → 4
(3) P → 4;Q → 3;R → 2;S → 1
(4) P → 1;Q → 4;R → 2;S → 3
3) Identify correct order according to their mentioned properties.
(1) Mn+2 > Mn+4 > Mn+6 (Ionisation potential)
(2) Li > B > Be (2nd Ionisation potential)
(3) B > Aℓ > Ga > Tl (atomic size)
(4) F > Cℓ > Br > I (electron affinity)
4) Correct order in the following is :–
(1) Na2O > MgO > Al2O3 > SiO2 (acidic nature)
(2) LiH < BeH2 < BH3 < CH4 (basic strength)
(3) (hydrated size)
(4) KF(s) < BeF2(s) < BeO(s) (lattice energy)
5) The pair in which both species have same hybridisation and same molecular shape both :
(1) CH4 , H2O
(2) PCl5 , SF4
(3) XeF4 , ICl2¯
+
(4) PCl4 , SiF4
6) In which of the following molecule central atom uses it's maximum number of orbitals for bonding
:
(1) CH4
(2) XeO4
(3) SO3
(4) Both (2) and (3)
7) Which of the following compound is planar and non-polar
(1) ClF3
–
(2) ICl4
+
(3) I3
(4) OCN–
8) The correct order of increasing s-caracter (in precentage) in the hybrid orbitals of following
molecule/ion is :-
(I) (II) XeF4 (III)
(IV) NCl3 (V) BeCl2
(1) II < III < IV < I < V
(2) II < IV < III < V < I
(3) III < II < I < V < IV
(4) II < IV < III < I < V
9) Which of the following chemical species does not have co-ordinate bond.
(1) NOF3
(2) O3
(3) CO
(4)
10) The formal charge of each O in O3 is.
(1) 0, +2, –2
(2) 0, +1, –1
(3) 0, 0, 0
(4) –1, +2, –1
11) Molecule showing exception to lewis octet rule is
H2O,
(1)
(2) CO2, IF
(3) BCl3, XeF4
(4) PCl3, KCl
12) If x is internuclear axis, then type of bond formed between dxz and pz orbital is
(1) π-bond
(2) σ-bond
(3) δ-bond
(4) no bond formed
13) Order of bond strength in following overlappings.
(I) 2s – 2p (σ type)
(II) 2p – 2p (σ type)
(III) 2pπ – 3dπ
(IV) 3pπ – 3dπ
(1) (I) > (II) > (III) > (IV)
(2) (IV) > (III) > (II) > (I)
(3) (II) > (I) > (III) > (IV)
(4) (II) > (I) > (IV) > (III)
14) If total structural isomer of molecular formula C4H9Cl is (X) and total 3 member ring structure of
molecular formula C5H10 is (Y), then (X + Y) has value :
(1) 4
(2) 6
(3) 7
(4) 8
15) Which of following compound has keto content more than enol content :
(1)
(2)
(3)
(4)
16) Correct order of rate of enol formation is :
(I) (II) (III)
(1) I > II > III
(2) II > I > III
(3) II > III > I
(4) III > II > I
17) Identify total number of possible acyclic ether for molecular formula C5H10O [Excluding Stereo
Isomers].
(1) 4
(2) 13
(3) 5
(4) 6
18) Given compound show which type of isomerism?
(1) Chain isomerism
(2) Positional isomerism
(3) Metamerism
(4) Functional group isomerism
19) How many amines are possible with the molecular formula C4H11N (structural isomers only) :-
(1) 6
(2) 7
(3) 8
(4) 9
20) Which has maximum stable enol form
(1)
(2)
(3)
(4)
21) Which of following compound cann’t show GI ?
(1)
(2) H – N = N – H
(3)
(4)
22) Identify compound which shows geometrical isomerism ?
(1)
(2)
(3)
(4)
23) Which one of the following exhibits geometrical isomerism?
(1) 1, 2-dibromopropene
(2) 2, 3-dimethylbut-2-ene
(3) 2, 3-dibromobut-2-ene
(4) 2-methylbut-2-ene
24) In the following structure, the double bonds are marked as I II, III and IV
Geometrical isomerism is not possible at site (s) :
(1) I
(2) III
(3) I and III
(4) I and IV
25) Which one of the following is capable of showing geometrical isomerism.
(1)
(2)
(3)
(4)
26) Which of the following compound can show geometrical isomerism:
(1) CH2=CH–Cl
(2) CH3–CH=CBr2
(3)
(4)
27) Minimum carbon atoms are required in hydrocarbon to show geometrical isomerism.
(1) 2
(2) 3
(3) 4
(4) 6
28) How many benzene derivatives are possible for C6H3 FCl Br
(1) 5
(2) 12
(3) 10
(4) 11
29) In which of the following species presence of double bond does not affect idealised bond angle :-
(I) POCl3 (II) XeO3F2 (III) XeO2F4 (IV) XeO4
(1) II , III, IV
(2) I , II only
(3) III , IV only
(4) I , II , III
30) CORRECT order of number of planes present in molecule which contain maximum number of
atoms of corresponding molecule :
(1) IF7 > SF6 > PCl5
(2) PCl5 > SF6 > IF7
(3) SF6 > IF7 > PCl5
(4) PCl5 > IF7 > SF6
Category-II
1) Choose the incorrect option for bond strength.
(1) 2pπ – 2pπ > 2pπ – 3pπ
(2) 2pπ – 3pπ > 2pπ – 3dπ
(3) 1s – 2p > 2s – 2 p
(4) 2s – 2p > 3s – 3p
2) Pair of molecules or ions which are isostructural (similar molecular structure) is :
–
(1) CO2, I3
+
(2) PCl4 , PCl5
(3) XeO4, XeO3
+ –
(4) NO2 , NO2
3) The increasing order of atomic radii of the following group 13 elements is
(1) Al < Ga < In < Tl
(2) Ga < Al < In < Tl
(3) Al < In < Ga < Tl
(4) Al < Ga < Tl < In
4) Which is incorrect order?
(1) H2O < H2S < H2Se < H2Te (acidic nature)
(2) H2O < H2S < H2Se < H2Te (basic nature)
(3) HF < HCl < HBr < HI (acidic nature)
(4) HF > HCl > HBr > HI (basic nature)
5) The correct sequence of the electron affinity of C, N, O and F is:
(1) C > N < O < F
(2) O > N > C > F
(3) C < N > O < F
(4) C > N > O > F
Category-III
1) Which of the following orders of atomic / Ionic radius is/are correct ?
(1) B < Ga < Aℓ
(2) Sc > Cu < Zn
(3) C < O < N
(4) Al+3 < Al+2 < Al+1
2) In halogens, which of the following properties increase from iodine to fluroine
(1) Ionisation energy
(2) Electronegativity
(3) Bond length
(4) Electron affinity
3) Which of the following are correct ?
(1) IE2(Mg) < IE2(Na)
(2) EA (N) < EA (P)
(3) Atomic size Mg+2 > Atomic size (Li+)
(4) IP of Na < Mg < Al
4) Which of the following can show tautomerism ?
(1)
(2)
(3) CH3–CHO
(4)
5) Which of the following is the correct relationship ?
(1) I and II are functional isomers
(2) II and IV are metamers
(3) I and IV are position isomers
(4) I and III are constitutional isomer
ANSWER KEYS
PHYSICS
Category-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 3 4 2 3 4 3 4 2 4 3 3 1 1 3 2 2 2 4 2 3
Q. 21 22 23 24 25 26 27 28 29 30
A. 1 1 2 1 2 2 3 4 1 2
Category-II
Q. 31 32 33 34 35
A. 2 3 2 4 2
Category-III
Q. 36 37 38 39 40
A. 1,3,4 3,4 1,2,4 1,4 1,2
CHEMISTRY
Category-I
Q. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 4 3 2 4 4 2 2 1 4 2 3 1 3 3 3 3 2 3 3 4
Q. 61 62 63 64 65 66 67 68 69 70
A. 3 1 3 1 3 3 3 3 1 2
Category-II
Q. 71 72 73 74 75
A. 2 1 2 2 1
Category-III
Q. 76 77 78 79 80
A. 1,2,4 1,2 1,2 1,3,4 1,2,4
SOLUTIONS
PHYSICS
1)
t = 1 sec
2) Angle between is 180°
3)
4) so b = λT
= [L] [K]
0 0
b = [M L1T K1]
5) Vx = 3 ∝ t2 ; Vy = 3β t2
6)
Ans, (x–2)
7) [x] = [Ay] = [B]
0 0 0
[CZ] = [M L T ]
8) y = x tanθ –
y=x.1–
∴ tan θ = 1 θ = 45°
=1
u= =
T=
9) Energy ∝ (Force) (Length)
10)
[at] = [v]
[t] = [c]
11) r < R, V =
r > R, V =
12) Here, force (F) = [MLT–2] = 100 N ...(i)
Length (L) = [L] = 10 m ...(ii)
Time (t) = [T] = 100 s ...(iii)
Substituting values of L and T from Equations. (ii) and (iii) in Equation. (i), we get
M × 10 × (100)–2 = 100
or
or M = 100 × 1000 kg.
M = 105 kg
13)
14) Slope = = velocity
15)
16)
companing with
θ = 30°
17)
Ans. (5 m/s)
18)
19)
The particle covers a distance sn in the nth second
sn = u +
Here u = 0
sn =
s1 : s2 : s3 : .......... : sn
=
= 1 : 3 : 5 : .......... : (2n – 1)
20)
a=v
21)
Ans. (10 volt)
22)
Suppose neutral point N lies at a distance x from dipole of moment p or at a distance x2 from
dipole of 64 p.
At N |E. F. due to dipole |= |E. F. due to dipole ‚|
⇒ ⇒ x = 5 cm.
23) [λg] = LLT–2 = L2T–2 = [V2]
24)
On differentiating with respect to time the velocity v will be
= V = 6t2 – 6t
t=0;V=0
25)
26)
tan θ = θ = 53°
27) vx = u cos α
vy = u sin α – gt
|vx| = |vy|
u cos α = u sin α – gt
t=
28)
29)
S = ut + at2 (in y-direction)
5 = (u sin θ) 2 – × 10 × 2 × 2
20 + 5 = 50 sin θ
sin θ = =
∴ θ = 30°
30)
31) [a] = [Fr2] = [MLT–2] [L2] = ML3T–2,
[b] = = T–1
32)
0
–10 sin 53° = (v sin 37°) t – gt2
– 8 = 6t – 5t2
5t2 – 6t – 8 = 0
33) Fnet is in midway of 6 & 9 O' clock
∴ time = 7.30
34) According to situation θ > 45° OR 5 sinθ = 5 cosθ + 1
⇒ 25 sin2θ = 25 cos2θ + 1 + 10 cosθ
⇒ 50 cos2θ + 10 cosθ – 24 = 0
35)
36)
At the plane VAB = 4V
37)
Electric field at point
P= =
= constant in both magnitude and direction at every point of overlap region.
Also, E is non zero so potential is not same at all points.
38)
n6 – n(6 – 3v) = 3t
v = 2(1 – e–3t)
at t = ∞, v = 2 m/s
initial acceleration, a = 6
a=3
6 – 3v = 3
39)
40)
so
CHEMISTRY
43) (A) Ionization energy ∝ Change on cation
∴ IP of
(B) Very high IE
(C) At. Size of B < Ga < Cl < In < T
(D) E.A. of Cl > F > Br > I
44)
q1=1 q1=2 q1=2
q2=1 q2=1 q2=2
q1.q2=1 q1.q2=2 q1.q2=4
q1.q2 LE
LE order ⇒ KF < BeF2 < BeO
45) PCl4⊕ → sp3 hybridisation , tetrahedral shape
SiF4 → sp3 hybridisation , tetrahedral shape
46) XeO4 → sp3 hybridisation having four dπ – Pπ bonds So xenon uses it's 8 orbitals (One 'S' +
3'P' + 4'd' orbitals) for bonding.
47) (1) (Planar & Polar) (2) (Planar & non polar)
(3) (4)
48) sp2 % s = 33.33%
sp3d2 % s = 16.66%
sp3d % s = 20%
sp3 %s = 25%
sp %s = 50%
49)
50)
Hence formal charge is 0, +1, –1
51)
BCl3 → Hypo valent
XeF4 → Hyper valent
52)
53)
Theoretical
54) D. U = O
(1) C - C - C - C -
(2)
(3)
(4)
C5H10 D.U = 1
Total = 7
55) enol > keto
enol > keto
keto > enol
56)
57)
C5H10O (acyclic ether)
DOU = 1
58) Due to change in group of polyvalent functional group Metamers.
59) (Concept : Monovalent radical of saturated hydrocabron)
CH3- : 1, C2H5- : 1, C3H7- : 2, C4H9- : 4, C5H11- : 8 C4H11N ;
p-amine : C4H9 – NH2 : 4
t-amine : :1
Total amine : 4 + 3 + 1 = 8
60)
Since (phend) is aromatic compound, so it will be maximum stable.
61)
Cycloalkane having members less than 8 are not able to show G.I.
62)
63)
1. similar group No. g.I
2. similar group - No. g.I
3. show g.I
4. No g.I
64)
For G.I. in alkenes,
a ≠ b and c ≠ d
then above alkene arilll show G.I.
65)
66)
67)
CH3 - CH = CH - CH3 (4 - C - atom required)
68)
69)
(I)
(II)
Symmetrical structure so net repulsion equal zero.
(III)
Symmetrical structure so net repulsion equal zero.
(IV) Equivalent hybridization
Double bond will not affect structure in case of II, III, IV
Option (A) is correct.
70)
IF7 sp3d3
6 atom in one plane
No. of such planes 1
SF6
5 atom in one plane
No. of such planes 3
PCl5
4 atom in one plane
No. of such planes 4
Option (B) is correct
IF7 < SF6 < PCl5
71)
For same value of n π bond strength order
dπ - dπ > dπ - pπ > pπ - pπ
72)
A. Question Explanation: The question asks us to identify a pair of molecules or ions that are
isostructural, meaning they have the same or very similar shapes.
B. Given Data: We are given four pairs of molecules/ions and need to determine their
structures.
C. Concept: VSEPR (Valence Shell Electron Pair Repulsion) theory
D. Solution:
A. CO₂, I₃⁻: CO₂ has a linear structure (O=C=O). I₃⁻ also has a linear structure (I-I-I) due to
the central iodine having 3 lone pairs and 2 bond pairs. This pair is isostructural.
B. PCl₄⁺, PCl₅: PCl₄⁺ has a tetrahedral shape. PCl₅ has a trigonal bipyramidal shape. Not
isostructural.
C. XeO₄, XeO₃: XeO₄ has a tetrahedral shape. XeO₃ has a pyramidal shape. Not
isostructural.
D. NO₂⁺, NO₂⁻: NO₂⁺ is linear. NO₂⁻ is bent or angular. Not isostructural
E. Final Answer:
The pair of molecules/ions that are isostructural is CO₂ and I₃⁻ (option 1).
73) Correct order of atomic radii for 13th group elements:
Ga < Al < In < Tl
In general top to bottom in a group, 'n' increases so atomic radius increases.
Ga < Al (d contraction or Scandide contraction).
74) Down the group, acidic strength of hydra acids increases.
75) E.A. of N < C < O < F
76) C > N > O
77)
78)
r ⇒ Li+ > Mg+2
IE ⇒ Na < Mg > Al
79)
80) (i) I is 1° Amine and II is 2° amine so functional isomers.
(ii) Both are metamers as different group around 2° amine.
(iii) I, IV are functional isomer
(iv) I & III has difference in chain length.