20-08-2025

7102CJA20220125006 JM

PHYSICS

SECTION-I

1) In the figure shown, battery 1 has emf = 6 V and internal resistance = 1 Ω. Battery 2 has emf =
2V and internal resistance = 3 Ω. The wires have negligible resistance. What is the potential
difference across the terminals of battery 2 ?

(A) 4 V
(B) 1.5 V
(C) 5 V
(D) 0.5 V

2) In given circuit, the potential difference across the resistance of 400Ω, as measured by voltmeter

of resistance 400Ω, is :-

(A) 18 V
(B) 12 V
(C) 10 V
(D) 20 V

3) σ1 and σ2 are the electrical conductivities of Ge and Na respectively. If these substances are
heated, then

(A) Both σ1 and σ2 increase

(B) σ1 increases and σ2 decreases
(C) σ1 decreases and σ2 increases
(D) Both σ1 and σ2 decrease
4) In the circuit shown, what is the potential difference VPQ?

(A) + 3V
(B) + 2V
(C) – 2V
(D) none

5) In the network shown in the figure, choose the incorrect statement :-

(A) Potential difference between points H and B is 5V

(B) Potential difference between points D and B is 1V
(C) Potential difference between points D and E is 1V
(D) Potential difference between points D and G is 2V

6) In the circuit shown, the cell has emf = 10V and internal resistance = 1Ω :-

(A) The current through the 3Ω resistor is 2A

(B) The current through the 3Ω resistor is 0.5A
(C) The current through the 4Ω resistor is 0.5A
(D) The current through the 4Ω resistor is 0.25A

7) The bulbs A, B and C are connected as shown in figure. The bulbs B and C are identical. If the

bulb C is fused,

(A) both A and B will glow more brightly

(B) both A and B will glow less brightly
(C) A will glow less brightly and B will glow more brightly
(D) A will glow more brightly and B will glow less brightly.

8) A battery of e.m.f. 10 V is connected to resistance as shown in figure. The potential difference

VA–VB between the points A and B is

(A) –2V
(B) 2V
(C) 5V

(D)

9) In the circuit shown in figure reading of voltmeter is V1 when only K1 is closed, reading of
voltmeter is V2 when only K2 is closed and reading of voltmeter is V3 when both K1 and K2 are closed.

Then :-

(A) V3 > V2 > V1

(B) V2 > V1 > V3
(C) V3 > V1 > V2
(D) V1 > V2 > V3

10) A wire has a non-uniform cross-section as shown in figure. A steady current flows through it. The

drift speed of electrons at points P and Q is vP and vQ.

(A) vP = vQ
(B) vP < vQ
(C) vP > vQ
(D) Data insufficient

11) An unknown resistance R1 is connected in series with a resistance of 10 Ω. This combination is

connected to one gap of a metre bridge while a resistance R2 is connected in the other gap. The
balance point is at 50 cm. Now, when the 10 Ω resistance is removed the balance point shifts to 40
cm. The value of R1 is (in ohms) :–

(A) 20
(B) 10
(C) 60
(D) 40

12)

In shown system, each of the block is at rest. The value of θ is :

(A)

(B)

(C)

(D)

13) In the following circuit, the current through the resistor R (= 2Ω) is I Amperes. The value of I is
:-

(A) 1A
(B) 2A
(C) 3A
(D) 4A

14) A parabolic bowl with its bottom at origin has the shape y = x2/20. Here x and y are in meter.
The maximum height at which a small mass m can be placed on the bowl without slipping

(coefficient of static friction is 0.5) is

(A) 2.5 m
(B) 1.25 m
(C) 1.0 m
(D) 4.0 m

15) If acceleration of block B is a then acceleration of block A will be :-

(A)

(B)

(C) 2a
(D) 3a

16) For the given diagram for what maximum value of force both block will move together ?

(A) 150 N
(B) 200 N

(C)

(D) 80 N

17) One end of a massless rope, which passes over a massless and frictionless pulley P is tied to a
hook C while the other end is free. Maximum tension that the rope can bear is 360 N. With what
value of minimum safe acceleration (in ms–2) can a monkey of 60 kg move down on the rope :-

(A) 16
(B) 6
(C) 4
(D) 8

18) Starting from rest a body slides down a 45º inclined plane in twice the time it takes to slide
down the same distance in the absence of friction. The co-efficient of friction between the body and
the inclined plane is :
(A) 0.75
(B) 0.33
(C) 0.25
(D) 0.80

19) A horizontal force of 10 N is necessary to just hold a block stationary against a wall. The

coefficient of friction between block and wall is 0.2. The weight of block is:-

(A) 20 N
(B) 50 N
(C) 100 N
(D) 2 N

20) Two masses A and B of 10 kg and 5 kg respectively are connected with a string passing over a
frictionless pulley fixed at the corner of a table as shown. The coefficient of static friction of A with
table is 0.2. The minimum mass of C that may be placed on A to prevent it from moving is :

(A) 15 kg
(B) 10 kg
(C) 5 kg
(D) 12 kg

SECTION-II

1) A uniform rope of mass 2 kg, which can tolrate maximum tension 80 N at any point, If maximum

value of vertical force F which can be applied on 2 kg block is 14n then the value of n is :

2) A block of mass M = 4 kg is resting on a rough horizontal surface for which the coefficient of
friction is 0.5. When a force F = 40 N is applied as shown in figure, the acceleration of the block will
be (g = 10 m/s2)

3) A block of mass 5 kg lies on a horizontal surface in a truck. The coefficient of static friction
between the block and the surface is 0.4 if 10 N static friction acting on block what is the
acceleration of truck?

4) A block P is kept between two surfaces, are vertical and one inclined at an angle 60° with
horizontal, in equilibrium. Weight of the block is N. The normal force applied by vertical

surface on P in N is

5) In the given circuit as shown in figure the value of R(in Ω) for which current through 4Ω resistor is

zero.

CHEMISTRY

SECTION-I

1) Two glass bulbs A and B are connected by a very small tube having a stop cock. Bulb A has a
volume of 100 cm3 and contained the gas, while bulb B was empty. On opening the stop cock, the
pressure fell down to 40%. The volume of the bulb B must be :

(A) 75 cm3
(B) 125 cm3
(C) 150 cm3
(D) 250 cm3

2) In SO2, and the hybridizations at the central atom are respectively :

(A) sp2, sp2 and sp

(B) sp2, sp and sp
(C) sp2, sp2 and sp2
(D) sp, sp2 and sp

3)

How many bond angles are 90o in BrF5 molecule

(A) 0
(B) 4
(C) 8
(D) 12

4) According to Molecular orbital theory which of the following is correct

(A) LUMO level for C2 molecule is orbital

(B) In C2 molecules both the bonds are π bonds
(C) In ion there is one σ and two π bonds
(D) All the above are correct

5)

Correct statement is

(A) SH6 exists

(B) SCl6 does not exist while exist
(C) SF6 does not exist
(D) PI5 (Vapour) exists

6) The dipole moment of LiH is found to be 2.0 × 10–29 C m. If the interatomic distance in LiH is 1.6
Å, then the percent ionic character of Li-H bond is nearly

(A) 80%
(B) 60%
(C) 50%
(D) 40%

7) If 4g O2 effuse through a very narrow hole, How much H2 would have effused under identical
conditions.

(A) 16 g
(B) 1 g
(C) 0.25 g
(D) 64 g

8) The total kinetic energy of a sample of gas which contains N molecules at –123°C is Ek joules.
Another sample of gas at 27°C has total kinetic energy 2Ek joules. The number of molecules in the
second sample of gas is

(A) N/2
(B) 2N
(C) N
(D) N2

9) Points I, II and III in the following plot respectively correspond to :

(A) Vmp of N2 (300K); Vmp of H2(300K); Vmp of O2 (400K)

(B) Vmp of H2 (300K); Vmp of N2 (300K); Vmp of O2(400K)
(C) Vmp of O2 (400K); Vmp of N2(300K); Vmp of H2(300K)
(D) Vmp of N2 (300K); Vmp of O2 (400K); Vmp of H2 (300K)

10) Two closed bulbs of equal volume(V) containing an ideal gas initially at pressure pi and
temperature T1 are connected through a narrow tube of negligible volume as shown in the figure
below. The temperature of one of the bulbs is then raised to T2. The final pressure pf is :

(A)

(B)

(C)

(D)

11) Product which is not formed in above reaction

(A)

(B)

(C)

(D)

12) Product :-

(A)

(B)

(C)

(D)

13)

Arrange the following reaction in decreasing order of electrophilic addition reaction :

(A) P > Q > R

(B) Q > R > P
(C) R > Q > P
(D) P = Q = R

14)
Product (X) and (Y) respectively are :-

(A) 1-butene, trans-2-butene

(B) 1-butene, cis-2-butene
(C) cis-2-butene, 1-butene
(D) trans-2-butene, 1-butene

15) What would be the product formed when 1-bromo-3-chlorocyclobutane reacts with two
equivalents of metallic sodium in ether?

(A)

(B)

(C)

(D)

16)
What is the number of –OH group in the Major Product B ?

(A) 4
(B) 2
(C) 6
(D) 1

17)
The relationship between (A) & (B) is :

(A) Identical
(B) Enantiomer
(C) Diastereomer
(D) Position isomer

18) The major product P is

CH2=CH–CH3

(A)

(B)

(C)

(D)

19) Rate of decarboxylation of following carboxylic acid with sodalime will be in order

(A) r1 > r2 > r3

(B) r3 > r2 > r1
(C) r2 > r3 > r1
(D) r1 > r3 > r2

20) Product is -

(A)

(B)
(C)

(D)

SECTION-II

1) Number of possible monochloroderivative of given compound is (Excluding sterioisomers)?

2) The total number of chiral molecules formed from one molecule of P on complete ozonolysis (O3,

Zn/H2O) is ________.

3) Out of given seven species, how many specie(s) is/are hypervalent?

BF3, SF4, ClF3, CH4, SiCl4,

4) For SO3 number of lone pair (all outermost)= x, number of pπ - pπ bond = y, number of pπ - dπ

bond = z find .

5)

An air of length 14.4 cm column is trapped by a mercury column of length 15.2 cm as shown in
figure.

If the tube is now kept vertically with its open end up.
Find the length of air column in cm.

MATHS

SECTION-I
1) If the letters of the word ' AKALA' are arranged as in the dictionary then the word which appears
on the 8th position is

(A) AAKAL
(B) AKALA
(C) AKAAL
(D) AAKLA

2) A country has ten smart cities. The government decides to connect all these cities by road. How
many roads the government need to construct so that every city is connected to every other city ?

(A) 45
(B) 50
(C) 55
(D) 60

3) Number of ways to form a three membered committee out of 4 men and 3 women when women
are always in majority is :

(A) 10
(B) 11
(C) 12
(D) 13

4) The number of arrangements of the letters of the word 'ANALYTICAL' in which the two L's do not
appear adjacently is -

(A) 8!
(B) 6 × 8!

(C)

(D) 9!

5) is equal to-

(A)

(B)

(C)

(D)
6) is equal to

(A) 1/2
(B) 0
(C) 1
(D) None of these

7) The value of (where[·] denotes greatest integer function) is :

(A) 0
(B) –3
(C) 4
(D) does not exist

8) If = b (finite), then...

(A) a = 2, b = 0
a = 0, b =
(B)

a = 2, b =
(C)

(D) a = 0, b = 2

9) If then

(A) 0
(B) 2
(C) 3
(D) 4

10) If 4x + 3 |y| = 5y, then y as a function of x is:

(A) differentiable at x = 0
(B) continuous at x = 0

(C)
for all x
(D) None of these
11) If f is a periodic function, then

(A) f' and f" are also periodic

(B) f' is periodic but f" is not periodic
(C) f" is periodic but f' is not periodic
(D) None of these

12) If function f(x) is differentiable at x = a then

(A)
(B)
(C)
(D)

13) If where [x] denotes the greatest function, then

(A) Both and does not exist

(B) exist but does not exist
(C) exists but does not exist
(D) Both and exist

14) Which of the following statements is NOT true (where [.] denote the greatest integer function
and {.} denote fractional part function)

(A)
is continuous as well as differentiable at x = 0

(B)
is continuous as well as differentiable at x = 0

(C)
is continuous as well as differentiable at x = 0
(D) None of the above

15) Let function be differentiable and is continuous in with then

is equal to

(A) 7
(B) 14
(C) 28
(D) 56
16) Let then f(x) is discontinuous in at

(A) Two points

(B) Three points
(C) One point
(D) No point

17)

Maximum distance between parallel lines

(2λ + 1)x + (λ – 1)y + 3 = 0 and

(2λ + 1)x + (λ – 1)y + 2 = 0 is -

(A)

(B)

(C) 6

(D)

18) The line parallel to -axis and passing through the point of intersection of the lines
and , where (a, b) ≠ (0, 0) is :

(A) below x-axis at a distance 2/3 from it

(B) above x-axis at a distance 3/2 from it
(C) above x-axis at a distance 2/3 from it
(D) below x-axis at a distance 3/2 from it

19) The perpendicular bisector of the line segment joining P (1, 4) and Q (k, 3) has y–intercept –4.
Then a possible value of k is-

(A) 1
(B) 2
(C) –2
(D) –4

20) Let A (2,-1) and B (6,5) be two points. The foot of the perpendicular drawn from P(4,1) on AB
divides AB in the ratio
(A) 5 : 8
(B) 8 : 5
(C) 8 : 15
(D) –5 : 8

SECTION-II

1) Number of ways in which all letters of word "KOLAVERIDE" can be arranged so that vowels &
consonants are always alternate is (n!)2, then n is equal to

2) is

3) If is continuous at x = 0 then |a + b| is :

4) Let f(x) = min {|x 1|, |x + 1|, 1}. Find the number of points where it is not differentiable.

5) If the line segment joining P(1, 3) and Q(5, 7) subtends a right angle at R(x, y) and area of
then find the maximum number of such points R in the xy-plane
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D B B C D C B B C A C A B D C C A D A

SECTION-II

Q. 21 22 23 24 25
A. 8 6 2 60 1.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A A D B A B C D D C C C D D A C C A B

SECTION-II

Q. 46 47 48 49 50
A. 5 2 3 8 12

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A D B B A B C C B A D A C C D B D D A

SECTION-II

Q. 71 72 73 74 75
A. 5 0 1 5 4
 SOLUTIONS

PHYSICS

1)
V2 = ε + ir = 2 + 1 × 3 = 5V

2)

VAB =

3)

σ1 increases and σ2 decreases

4) Let VQ = 0
4 – i + 2 – 2i = 0
i = 2A
Now 4 – 2 × 1 = VP
VP = 2V
∴ VPQ = 2 – 0 = 2V
5)

VH – VD = 4V
VD – VB = 1V
VH – VB = 5v
VH – VD = 4V ....(i)
VH – VG = 6V ....(ii)
Equation (ii) – (i)
VD – VG = 2V

6)

Equivalent resistance Req = 10 Ω so current passing through battery and 3 Ω resistance is

i=
and current passing through 4 Ω is 0.25 A

7) ⇒
∵ i2 < i1
∴ intensity of bulb A↓
but voltage across B↑
∴ intensity of B↑

8) Req = 5Ω, Current and current in each branch = 1A

Potential difference between C and A,

 .......(i)
Potential difference between C and B,
......(ii)
On solving (i) and (ii)

Short Trick :

9)

V2 > V1 > V3

10) ∴V α
∴ VP > VQ

11) ....(1) ...(2)

12)
Tcosθ = 3g, Tsinθ = 4g
⇒ tanθ = 4/3 ⇒θ = tan–1 (4/3)

13)

i=
= 1A

14) y =

= tan θ = µ
 = 0.5 ∴ x = 5m

So height y =
y = 1.25 m

15)

T × aA = 3T × aB

aA = 3a

16) a = , fL = (0.4) (200) = 80 N

F – 80 = 20 a

F – 80 = 20

F = N

17) For downward motion of monkey

mg – T = ma
600 – 360 = 60 a
240 = 60a
a = 4 m/s2

18)
Let acceleration in Ist case is a1 and that in second case is a2

Now ..... (i)

Clearly ..... (ii)

and ...... (iii)

From (i), (ii) and (iii),
we get μ = 0.75.
19)

f = µN
N=F

f = 0.2 × 10
mg = f = 2 N

20) Apply Newton’s law for system along the string

mB g = μ(mA + mC) × g

⇒ mC = – mA = – 10 = 15 kg

21)
F – 70 = 7 × 6
F = 112 N

22) N = 40 – 40 sin 37 = 16 N

23)

Flim = μ mg
= 0.4 × 5 × 10
= 20 N
F = ma
10 = 5a
a = 2 m/s2

24)
 25)

i= 10 – i × 2 = 6

2= i=2
4+2R=6
R = 1Ω

CHEMISTRY

26)
P × 100 ml
0.4 P × (100 + V) ml

= 100 + V = = 250
⇒ V = 150 ml

27) SO2 sp2

NO2– sp2

sp

28) In BrF5 molecule there is one lone pair and 5 B-F bonds with octahedral geometry. Due to
lone pair repulsion no bond angle is 90o

29) M.O. for C2 =

30) → For 'A' as 'H' is less electronegative so can't cause d-orbital contraction of S.
→ For B' size of Te > S, so can accomodate six ' '
→ for 'C' size of 'F' is small so 'S' can accomodate 6 -F around it
→ For D, Due to steric crowding not exists.
31)

32)

w = 1g

33)

34)

N2 H2 O2

35)

Final total pressure in both bulb will be same.

Initial total mole and final total mole in both bulb remain conserved.
Initial total mol = final total mol
n1i + n2i = n1f + n2f

36)

Ans is (C)
Not Possible
37)
4α-H
Stability ↓, Reactivity ↑

38) Reactivity for EAR stability of carbocation.

39)

40) In Wurtz reaction, an ether solution of an alkyl halide gives an alkane when heated with
metallic sodium. Iodide > Bromide > Chloride.
Since, bromides are more reactive than chlorides in Wurtz reaction, therefore, Wurtz reaction
occurs on the side of Br atom.

41)

Ans. (4)

42) Explanation - Addition of Br2 on alkene

Concept - Electrophilic addition reaction of alkene including stereo chemistry.
Solution - It is an example of Anti addition reaction

Final Answer - Option (3) is correct

43)

44)

Rate of decarboxylation α stability of carbanion

45) Syn addition of hydrogen.

46) , , , ,

47)

48)

Hypervalent → SF4, ClF3, SO42–

Hypovalent → BF3
 49)
x=6
y=1
z=2

50)

From Boyle’s Law

P1 V1 = P2 V2
P 1 × A × 1 = P2 A × 2
where A = cross sectional area
76 × 14.4 = (76 + 15.2) × 2
2 = 12 cm.

MATHS

51) A, A, A, K, L
A, A _ _ _ = 3! = 6
AKA AL= 1
AKA LA= 1
_____
8
______

52) 10C2

53)

Case 1: 3 women + 0 men

Case 2: 2 women+ 1 men
Total = 12+1 =13

54)

Total number of arrangements

The number of arrangements in which two L's appear adjacently =

 Total number of arrangements

55)

56)

57)

= –3

58)

a = 21 L = 4/2 – 1/2
L = 3/2

59) ƒ'(x) = 3 ∀ x > 2

⇒ ƒ'(2+) = 3

60)
y ≥ 0 ⇒ y = 2x

y≤0⇒y=

61) Let T be period of ƒ(x)

⇒ ƒ(x + T) = ƒ(x)
⇒ ƒ'(x + T) = ƒ'(x)
⇒ ƒ"(x + T) = ƒ"(x)
⇒ ƒ'(x) & ƒ"(x) are periodic

62)
By L'H Rule

63) and

and

Both and does not exist.

64) Shown in the figures

(a)

(b)
(c)

65)

66) Clearly, f(x) is discontinuous in at no point.

67) Distance between parallel lines

68)

Ans. (D)
Pt. of intersection of line
ax + 2by + 3b = 0
bx – 2ay – 3a = 0

is

∴ Line parallel to x-axis & passes through pt of intersection is y = –

69)

Slope of PQ :
Slope of perpendicular bisector = (K – 1)
∴ Equation of perpendicular bisector -

⇒ y-axis intercept = – 4

K2 = 16 ⇒ K = 4, – 4

70)

71)

Vowels → A, O, E2, I
consonants → K, L, V, R, D

ways = 2 × 5! ×

72) 0 × sin(∞) = 0 × finite = 0

73) ƒ(0) = b
⇒
b = 1, a = –2
|a + b| = 1

74) From graph,

No. of non differentiable points = 5

75)

L1 & L2 are intersecting at (–1, –2)

Distance between (–1, –2) and (5, 1)
as exactly two lines