27-07-2025

1701CJA101029250031 JA

PART-1 : PHYSICS

SECTION-I

1) A practically very small source (S) of light is kept in front of a plane mirror. But due to imperfect
manufacturing, there is a small spherical bulge (radius of curvature 80 mm). The situation is as
shown in the figure. You can assume that principal axis of bulge is perpendicular to the plane mirror.

Find the separation between the images formed.

(A) 10.025 mm
(B) 20.025 mm
(C) 40.025 mm
(D) 80.025 mm

2) Two thin symmetrical lenses of different nature (one converging and other diverging) have equal
radii of curvature R = 20 cm. The lenses are put close together and immersed in water. The
converging focal length of the system is 24 cm. Find the difference between refractive indices of the

two lenses. (refractive index for water = )

(A)

(B)

(C)

(D)

3) A prism of angle A and refractive index 2 is surrounded by medium of refractive index . A ray is
incident on side PQ at an angle of incidence i (0 ≤ i ≤ 90°) as shown. The refracted ray is then
incident on side PR of prism. The minimum angle A of prism for which ray incident on side PQ does
not emerge out of prism from side PR (for any value of i) is

(A) 30°
(B) 45°
(C) 60°
(D) 120°

4) A point charge is placed at the centre of cube then find how much flux pass through shaded
region ABCD?

(A)

(B)

(C)

(D)

5) A thin glass rod is bent into a semicircle of radius r. A charge +Q is uniformly distributed along
the upper half and a charge –Q is uniformly distributed along the lower half, as shown in figure. The

electric field E at P, the centre of the semicircle, is

(A)
(B)

(C)

(D)

6) Three charged particles are placed on a straight line as shown in the figure. q1 and q2 are fixed
but q3 can move. Under the action of the forces from q1 and q2 , q3 is in equilibrium. What is the

relation between q1 and q2 ?

(A) q1 = –9q2

(B)

(C)

(D)

7) Planet A has mass M and radius R. Planet B has half the mass and half the radius of Planet A. If

the escape velocities from the Planets A and B are νA and νB, respectively, then . The value of
n is :

(A) 4
(B) 1
(C) 2
(D) 3

8) A solid sphere of radius R gravitationally attracts a particle placed at 3R form its centre with a

force F1. Now a spherical cavity of radius is made in the sphere

(as shown in figure) and the force becomes F2. The value of F1 : F2 is :

(A) 25 : 36
(B) 36 : 25
(C) 50 : 41
(D) 41 : 50

9)

A wire has resistance of 24 Ω is bent in the following shape. The effective resistance between A and
B is-
(A) 24 Ω
(B) 10 Ω

(C)

(D) None of these

10) In the circuit shown, the potential difference VA – VB is :

(A) –2 V
(B) 2 V
(C) 5 V

(D)

11) What is the electron drift speed at the 3 mm diameter end (the left end) of the wire in figure.

(A) 0.055 × 10–4 m/s

(B) 4.5 × 10–4 m/s
(C) 0.055 × 10–3 m/s
(D) 4.5 × 10–3 m/s

12) What will be equivalent resistance between A and B?

(A) 6 Ω
(B) 7 Ω
(C) 8 Ω
(D) 10 Ω

13) Figure shows 3 identical bulbs with switch S closed. The brightness of bulb 1 is B1, bulb 2 is B2
and net brightness of system is BT. If switch is now opened, the brightness of :-

(A) B1 remains same, B2 increases and BT increases.

(B) B1 remains same, B2 decreases & BT decreases
(C) B1 decreases, B2 increases & BT decreases
(D) B1 decreases, B2 increases & BT increases

14) A 120 V toaster has a resistance of 12Ω. What must be the minimum rating of the fuse in the
electric circuit to which the toaster is connected ?

(A) 5 A
(B) 10 A
(C) 15 A
(D) 20 A

15) Figure shows the capacitors in steady state, with S open. When S is closed :-

(A) Both batteries supply energy & heat is lost.

(B) Both batteries supply energy to increase the energy of both the capacitors separately
(C) One battery supplies & other absorbs energy and no heat loss takes place.
(D) One battery supplies energy, other absorbs and heat is lost in the process.

16) The circuit shown above shows a steady state with S open. When S is closed :-
(A) No charge/current passes through S.
(B) A steady current of 30 A flows through S.
(C) 90µC of charge flows from B to A.
(D) 120 µC of charge flows from A to B.

17) Identical metal plates are located in air at equal distances d from one another. The area of each
plate is equal to A. If plates are interconnected as shown in figure, then the capacitance of system

between points P and Q is :-

(A)

(B)

(C)

(D) None of these

18) Initially capacitor is uncharged and at t = 0 switch is closed. The value of i after a very long time

is :-

(A) 6A
(B) 5A
(C) 7A
(D) 4A
19) The charge flown through the cell on closing the key k is equal to

(A)

(B) CV

(C)
CV

(D)
CV

20) For the arrangement of identical capacitors shown, what is the equivalent capacitance?

(A)

(B)

(C)

(D)

SECTION-II

1) Find time constant of circuit shown in figure in microseconds.

2) A uniform rod of mass 12 kg and length 4 m is hung from two string of equal length from a ceiling
as shown in fig. Determine the tension T1 (in N) in the string. (take g = 10 m/s2)
3) Two identical rods each of mass M and length L are kept according to figure. If the moment of

inertia of rods about an axis passing through O and perpendicular to the plane of rods is , then
find value of (A + B).

[A and B are least integer value]

4) A uniform rod of mass m is hinged as shown and is released from a horizontal position. The

angular velocity of the rod as it passes the vertical position is given by . Find the value of x.

5) A disc of mass 4kg and radius 6 metre is free to rotate in horizontal plane about a vertical fixed
axis passing through its centre. There is a smooth groove along the diameter of the disc and two
small balls of mass 2kg each are placed in it on either side of the centre of the disc as shown in
figure. The disc is given initial angular velocity ω0 = 12 rad/sec and released. Find the angular speed

of disc (in radian/sec) when the balls reach the ends to disc.

PART-2 : CHEMISTRY

SECTION-I

1) For a tribasic acid, H3A, Kal = 2 × 10-5, Ka2 = 5 × 10-9 and Ka3 = 4 × 10-12.
The value of at equilibrium in an aqueous solution originally having 0.2 M – H3A is

(A) 5 × 10–17
(B) 5 × 10–9
(C) 1 × 10–17
(D) 2 × 10–22

2) Two solid compounds X and Y dissociates at a certain temperature as follows :

X(s) A(g) + 2B(g) ; Kp1 = 9 × 10–3atm3
Y(s) 2B(g) + C(g) ; Kp2 = 4.5 × 10–3atm3
The total pressure of gases over a mixture of X and Y is -

(A) 4.5 atm

(B) 0.45 atm
(C) 0.6 atm
(D) 6 atm

3) The gas A2 in the left flask allowed to react with gas B2 present in right
flask as A2(g) + B2(g) ⇌ 2AB(g); Kc = 4 at 27°C. What is the concentration of AB when equilibrium is
established?

(A) 1.33 M
(B) 2.66 M
(C) 0.66 M
(D) 0.33 M

4) ΔSTotal = –40 kJ/mol-K

ΔHSystem = 2000 kJ/mol
T = 400 K
Find out value of ΔSSystem.

(A) –35 kJ/mol-K

(B) –10 kJ/mol-K
(C) –40 kJ/mol-K
(D) –5 kJ/mol-K

5) Calculate ΔrG(in kJ/mol) for given reaction at 300 K

N2(g) + O2(g) ⇌ 2NO(g)
the partial pressure of N2, O2 & NO are 10–4 bar, 10–2 bar and 10–5 bar respectively when mixed
together at 300 K.
Given : 2.303 RT = 5750 J/mol
At 300 K standard enthalpy of formation of NO(g) = 90.5 kJ mol–1,
Standard molar entropy data at 300 K :
S°(N2, g) = 190 J K–1 mol–1
S°(NO, g) = 210 J K–1 mol–1
S°(O2,g) = 205 J K–1 mol–1 ?

(A) 160.5 kJ/mol

(B) 173.5 kJ/mol
(C) 196.5 kJ/mol
(D) 179.25 kJ/mol

6)

Calculate the standard molar enthalpy of formation of Al(BH4)3(g). Given

[Al(BH4)3(ℓ)] = 30 kJ/mol
[Al(BH4)3(ℓ)] = – 4135 KJ/mol
[Al2O3(s)] = – 1668 kJ/mol
[H2O(ℓ)] = – 286 kJ/mol
(B2O3(s)] = – 1266 kJ/mol :-

(A) – 314 kJ/mol

(B) – 344 kJ/mol
(C) – 284 kJ/mol
(D) None of these

7) The bond enthalpies of C–C, C=C and C ≡ C bonds are 348, 610 and 835 kJ/mol, respectively, at
298 K and 1 bar. The enthalpy of polymerization per mole of 2-Butyne at 298 K and 1 bar, as shown
below, is

(A) –123 kJ
(B) –132 kJ
(C) –139 kJ
(D) –37 kJ

8) When salt 'A' reacts with acidified K2Cr2O7 it gives orange red gas 'B' which is passed to NaOH
solution and gives yellow soluble compound 'C'. Yellow ppt 'D' is obtained on adding lead acetate
solution to 'C' . 'A' gives brick red colour in flame test. A, B, C and D are respectively.

(A) CaSO4, CrO2Cl2, Na2Cr2O7, PbCr2O7

(B) BaCl2, CrO2Cl2, Na2CrO4, PbCrO4
(C) CaCl2, CrO2Cl2, Na2CrO4, PbCrO4
(D) BaSO4, CrO2Cl2, CaCrO4, PbCrO4

9)
Reagent, 1-naphthylamine and sulphanilic acid in acetic acid is used for the detection of

(A) N2O
–
(B) NO3
(C) NO
–
(D) NO2

10) A white sodium salt dissolves readily in water to give a solution which is neutral to litmus. When
silver nitrate solution is added to the aforementioned solution, a white precipitate is obtained which
does not dissolve in dil. nitric acid. The anion is :

(A) S2–
2–
(B) SO4
2–
(C) CO3
(D) Cl–

11) Statement-1 : NO3– ion can not be detected by brown ring test in presence of NO2– ion.
Statement-2 : Both NO2– and NO3– ions evolve brown NO2 gas with conc. H2SO4 acid.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

12) Select the correct matching for given silicates?

(A) Neso-silicate (Ortho silicate) – Mg3(OH)4[Si2O5]

(B) Soro-silicate (Pyro silicate) – Zn4(OH)2[Si2O7].H2O
(C) Pyroxene – Al2(OH)2[(Si2O5)2]
(D) Amphiboles – BaTi[Si3O9]

13) Given below are two statements: one is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : Boron is unable to form .
Reason (R) : Size of B is very small.
In the light of the above statements, choose the correct answer from the options given below

(A) Both (A) and (R) are true and (R) is the correct explanation of (A).
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A).
(C) (A) is true but (R) is false.
(D) (A) is false but (R) is true.

14) Which of the following statement is correct ?

(A) CoCl3.6NH3 > PtCl4.6NH3 ; higher electrical conductivity in aqueous solution

(B) CoBr.NO2.5NH3 shows ionisation isomerism as well as linkage isomerism
(C) The correct IUPAC name of [Ni(dmg)2] is dimethylglyoximatenickelate(II)
(D) Mohr's salt not give test of Fe2+ ion

15) Which of following reaction(s) produce Saytzeff product as a major product :

(A)

(B)

(C)

(D)

16) The major product P is

CH2=CH–CH3

(A)

(B)

(C)

(D)

17) Which is the correct match for the following reactions.

(P) CH3–Br + NaI + Acetone → CH3–I (1) Swart’s reaction

Finkelstein
(Q) CH3–CH2–Br + AgF + H2O → CH3–CH2–F (2)
reaction

Williamson
(R) CH3–CH2–OH + SOCl2 → CH3–CH2–Cl (3)
synthesis

(S) Ph–OH + NaOH + CH3–Br → Ph–OCH3 (4) Darzen reaction

(A) P → 2 ; Q → 4 ; R → 1 ; S → 3
(B) P → 3 ; Q → 2 ; R → 4 ; S → 1
(C) P → 2 ; Q → 1 ; R → 4 ; S → 3
(D) P → 4 ; Q → 1 ; R → 3 ; S → 2

18) Which of following is correct order of stability

(A) >
(Resonating structure stability)

(B)
(Resonating structure stability)

(C)
(Ion stability)

(D)
(Resonating structure stability)

19) For the reaction sequence given below, the correct statement(s) is(are)

(In the options, X is any atom other than carbon and hydrogen, and it is different in P, Q and R)

(A) C–X bond length in P, Q and R follows the order : Q > R > P.
(B) C–X bond enthalpy in P, Q and R follows the order : R > P > Q.
(C) Relative reactivity toward SN2 reaction in P, Q and R follows the order : P > R > Q.
pKa value of the conjugate acids of the leaving groups in P, Q and R follows the order : R > Q >
(D)
P.

20) Consider the depicted hydrogen (H) in the hydrocarbons given below. The most acidic hydrogen
(H) is

(A)

(B)
(C)

(D)

SECTION-II

1) An otto cycle is an idealized thermodynamic cycle that describe the functioning of a typical spart
ignition piston.
Assuming working substance to be ideal monoatomic gas 3 – 4 and 1 – 2 are reversible adiabatic.

If T1 = 300 K; = 8;

If value of is x then calculate value of |3x|.

W412 = work done during process 4 → 1 → 2

W234 = work done during process 2 → 3 → 4

2)
Number of correct statements in the above flow diagram ?
(i) Gas 'B' is SO2
(ii) The molecular formula of 'D' is Fe(SCN)3
(iii) The green colour compound of (E) contains three unpaired electrons on the metal ion.
(iv) The white turbidity of 'C' is elemental sulphur
(v) Charge of anion of salt 'A' is –2
(vi) On hydrolysis of gas 'B' dibasic acid is produced
(vii) Aq. solution of 'A' gives white ppt. with excess of AgNO3 .

3) How many of the following terms is/are associated to the purification of iron.
(i) Puddling process (ii) Thomas slag (iii) Cupellation
(iv) Bessemerisation (v) Amalgamation

4) Number of chlorine atoms present in product ?

5) Number of bromo derivatives obtained on treating ethane with excess of Br2, in diffused sunlight
is…

PART-3 : MATHEMATICS

SECTION-I

0
1) If 2ƒ(x2) + 3ƒ = x2 – 1 ∀ x ∈ R then ƒ(x2) is :-

(A)

(B)

(C)

(D)

2) A sheet of area 40m2 is used to make an open tank with square base then edge length of base
such that volume of this tank is maximum, is -

(A)

(B) 2
(C)
(D)

3) Let . If ; , where ℓ, m and n

are non-zero finite, then the value of p + q + r is
[Note : {y} denotes fraction part function]

(A) –1
(B) 2
(C) 3
(D) 1

4) Consider ƒ(x) = cosπx + 10x+3x2+x3 , x∈[–2,3], then the absolute minimum value of ƒ(x) is-

(A) 0
(B) 3–2π
(C) –2
(D) –15

5) Consider all rectangles lying in the region

and having one side on the x-axis. The area of the rectangle which has the maximum perimeter
among all such rectangles, is

(A)

(B) π

(C)

(D)

6) Let then
Assertion A : f(x) is continuous at x = 0.

Reason R : .

(A) Both A and R are correct and R is the correct explanation of A

(B) Both A and R are correct but R is NOT the correct explanation of A
(C) A is correct but R is not correct
(D) A is not correct but R is correct

7) The equation of normal to the curve y = x3 – 2x2 + 4 at the point x = 2 is-

(A) x + 4y = 0
(B) 4x – y = 0
(C) x + 4y = 18
(D) 4x – y = 18

8) If ..., then the value of at x = is :-

(A) 2

(B)

(C) 1

(D)

9) If f(x) is continuous and differentiable over [–2, 5] and –4 ≤ f '(x) ≤ 3 for all x in (–2, 5), then the
greatest possible value of f(5) – f(–2) is -

(A) 7
(B) 9
(C) 15
(D) 21

10) If f(x) = x3 + x then least integral value of x for which f (f (x)) – f (4 – 2x) > 0 is

(A) 1
(B) 2
(C) 3
(D) 4

11) If f(x) = cosx cos2x cos3x cos4x cos5x, then value of is -

(A)

(B)

(C)

(D)

12) The function has :

(A) only one maxima

(B) only one minima
(C) no maxima and minima
(D) many maxima and minima

13) Let f(x) satisfy the requirements of Lagrange’s mean value theorem in [0, 2]. If f(0) = 0 and f'(x)
≤ for all x in [0, 2], then :

(A) |f(x)| ≤ 2
(B) f(x) ≤ 1
(C) f(x) = 2x
(D) f(x) = 3 for at least one x in [0, 2].

14) If the point P(h, h3 + 1), is situated at a least distance from the circle (x – 4)2 + (y – 1)2 = 1
then 3h5 + h is equal to

(A) 2
(B) 3
(C) 4
(D) –4

15) The number of integral values of k for which the equation , has exactly two solutions is
-

(A) 5
(B) 6
(C) 7
(D) 9

16) The minimum value of is equal to

(A)

(B)

(C)

(D)

17) The circle lying in the first quadrant whose centre lies on the curve y = 2x2 – 27 is tangent to 4x
– 3y = 0 and the y-axis then the radius of the circle is

(A)

(B) 9
(C) 5

(D)

18) If ax + by = 10 is the chord of minimum length of the circle (x – 10)2 + (y – 20)2 = 729 and the
chord passes through (5,15), then the value of (4a + 2b) is

(A) 2
(B) 3
(C) 4
(D) 5

19) The number of integral values of 'c' for which the circle x2 + y2 – 4x – 6y + c = 0 does not touch
or intersect the coordinate axes and point (2, 2) lies inside the circle is

(A) 2
(B) 3
(C) 4
(D) 5

20) If the radical axis of the circles x2 + y2 – 1 = 0 and x2 + y2 – 2x – 2y + 1 = 0 forms the triangle of

area A with co-ordinate axes, then the value of is -

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-II

1) Number of positive integers x satisfying the equation ,

is :

2) then find the value of . where k1, k2, k3 are

integers

3) If , where C denotes constant of integration, then value of (k1 + k2) is

(where k1, k2 ∈ N)

4) If the function f(x) = x2 + 4x + 6 satisfies LMVT at x = 6 on the closed interval [0, k] then the
value of (k – 3) is

5) Let d be the minimum distance of y3 = x2 from point measured in first quadrant, then 9d2 –
4 is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C D D A C A C B B A C C B D C B A A B

SECTION-II

Q. 21 22 23 24 25
A. 12 40 17 3 4

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A B C A A C A C D D A B B B B C C B B B

SECTION-II

Q. 46 47 48 49 50
A. 4 7 3 3 9

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A A D C A C C D B C B B C C B D B A B

SECTION-II

Q. 71 72 73 74 75
A. 1 4 20 9 9
 SOLUTIONS

PART-1 : PHYSICS

1) ⇒ v = +40 mm

⇒ separation between the two images formed =

2)

Lenses are of opposite nature, so,

in water,

focal length of the system is

So,

3) For no ray to emerge out of side PR

A > 2C ⇒ sin > sinC ⇒ sin >

or A > 120°

4)
5)

EP due to circular arc is given by

where α = angle formed by end points of arc at point P.
Here, for both arc α = 90°
Here, by symmetry, we can say magnitude of electric field due to both arc will be same say E.

Horizontal component will cancel each other.

Vertical downward component

Now,

6) -For q3 in equilibrium net force = 0

7) (Escape velocity)

∴ Correct answer (1)

8) Let initial mass of sphere is m'. Hence mass of removed portion will be m'/8

F1 = m.E. =

F2 =

9)

10)
VA – VB = –1 × 1 + 3 × 1 = 2 volt

11) I = neAvd

vd ∝ ∝

vd left = = 0.055 m/s

12)

Refer notes.

13)
finally

Since current through B1 decrease, it becomes drive, B2 increase, it becomes bright & current
through battery decreases,
∴ total brightness decreases.

14)

15)
Hence work done by one battery will be + and other will be – & since
(work by battery 1) + (work by battery) + ΔU ¹ 0

16)

Charge initially
Charge finally

for this charge arrangement to happen, 90μC charge has to flow upwards.

17)
C(y – V) + C(y – x) + Cy = 0
3y – x = V
C(x – 0) + C(x – y) + C(x – V) = 0
3x – y = V

⇒ 8x = 4V ⇒ x = ,y=

⇒ ΔQ =

18) At t = ∞

19)
20)
1 & 2 parallel and in series with 3 and combination is parallel with 4.

21)
Req. = 4Ω, τeq = 12

22)
Total mass of complete length = 12kg. for length

Therefore, for , mass is 3kg. And for , mass is 9kg

A/Q T1 + T2 = mg (translational equilibrium)
T1 + T2 = 120 ____ (1)
About (A) τA = 0 (rotational equilibrium)

↓ + T2 ×
Let say A.C.W = +ve
 And, T1 + T2 = 120
⇒ T1 = 120 - 80 = 40

23)

A + B = 5 + 12 = 17

24)

25)

Since τnet external = 0

is conserved

∴ Li = Lf

PART-2 : CHEMISTRY
26)

Now,

27) Question Explanation:

Find total pressure above two simultaneous equilibrium.

Concept:
This question is based on simultaneous equilibrium.

Solution:

∴ P1 = 2P2
∵ 4.5 × 10–3 = P2(4P2 + 2P2)2 =

∴ and P1 = 0.1
PT = P1 + 2P1 + 2P2 + P2 = 3(P1 + P2)
= 3(0.1 + 0.05) = 3 × 0.15 = 0.45 atm

Final Answer:
The correct option is (2)

28)

⇒ mole

[AB(g)] =

29) ΔG = ΔH – TΔS
–TΔSTotal = ΔH – TΔSsys.
ΔSsys. = –35 kJ/mol-K

30) ΔrG = ΔrGº + RT ln Qp

ΔrGº = ΔrHº – T . ΔrSº ⇒ 2 × 90.5 –

ΔrG = 173.5 + log

ΔrG = 150.5 kJ/mol

31)

Al(BH4)3(ℓ) + O2(g) —→ + +

ΔHrxn =
–

– 4135 = – 1668 – 1266 – 6 × 286

–
= – 314 kJ/mol
= – 314 + 30 = – 284 kJ/mol

32) BE of reactant

BE of Product

ΔH =

33)

34)

For detection of NO2–, the following test is used.

NO2– + CH3COOH → HNO2 + CH3COO–
35)

Refer notes.

36)

Refer notes.

37)

Refer notes.

38) Assertion (A): True

Reason (R): True but not correct explanation.
Correct explanation: Expansion of octet not possible for ‘B’.

39)

Refer notes.

40) (A) gives hoffmann's product due to poor leaving group

(B) gives Saytzeff due to normal E2 reaction
(C) gives Hoffmann product due to bulkier size base
(D) gives Hoffmann product due to Hoffmann elimination reaction

41)

42) (P) CH3–Br + NaI + Acetone → CH3–I ⇒ Finkelstein reaction

(Q) CH3–CH2–Br + AgF + H2O → CH3–CH2–F ⇒ Swart’s reaction
(R) CH3–CH2–OH + SOCl2 → CH3–CH2–Cl ⇒ Darzen reaction
(S) Ph–OH + NaOH + CH3–Br → Ph–OCH3 ⇒ Williamson synthesis
43) (A) R.S. having complete octet of each atom is more stable
(C) Anion is stablised by –R or vacant 3d orbital of Cl.

44)

Refer notes.

45)

46)

T2 = 300 (8)2/3 = 1200 K

, T3 = 1600 K

3|X| = 4

47)

Refer notes.

48) Purification of ion iron is/are associated to the (puddling process, thomas slag,
Bessemerisation)

49)

Explain Question :
Asking about the number of Cl-atoms in final product of E2 elimination reaction of
benzenehexachloride (BHC) with NaNH2.

Concept :
Dehydrohalogenation by E2 mechanism.
 E2 reaction is anti elimination reaction (Leaving group & β-H eliminate from anti/trans
positions).

Solution :
3-Alternate Cl atoms with anti β-H eliminate in this molecule. Hence three alternate π bonds
are formed in 6-membered ring to get aromatic product.

In this reaction eliminate the circled H & Cl atoms from trans positions.
3 Chlorine atoms are present in the final product.
Final Answer : (3)

50) CH3 – CH3 + Br2 (Excess)

Monobromo

Dibromo

Tribromo

Tretrabromo

Pentabromo

Hexabromo

PART-3 : MATHEMATICS

51)

2f(x2) + = x2 – 1 ....(i)

replace x by

....(ii)
solving (i) and (ii)
52) Let length of base be x and height be y
v = x2y
x2 + 4xy = 40

53) By given conditions ƒ(x) is

54) ƒ'(x) = –πsinπx + 10 + 6x + 3x2

ƒ'(x) = (3x2 + 6x + 6) + (4 – πsinπx)
+ve +ve
ƒmin(–2) = cos2π – 20 + 3 × 4 – 8
= 13 – 28 = –15

55)
Perimeter = 2(2α + 2 cos 2α)
P = 4(α + cos 2α)

= 4(1 – 2 sin 2α) = 0

sin2α =

= –4 cos2α

for maximum α =
Area = (2α) (2 cos 2α)
Ans. (C)

56) Reason R :

Assertion A :

= f(0) {using reason R}

57) At x = 2, y = 8 – 8 + 4 = 4

y – 4 = 4(x – 2)

58)

⇒y=1+x

59) Apply LMVT

f'(x) = for some x in (–2, 5)

Now, –4 ≤ ≤3
–28 ≤ f(5) – f(–2) ≤ 21
∴ Greatest possible value of f(5) – f(–2) is 21.

60) f(x) = x3 + x

⇒ x>1
Least integral value of x is 2.

61)
62)
and

Since
∴ f has a local minima at x = 0.
There is no other critical point and exists for all

63) Given (x) ≤ ⇒

⇒ h(x) = f(x) – is a deceasing function.

Now h(0) = 0 and h(x) is decreasing

⇒ f(x) – ≤0

⇒ f(x) ≤
⇒ f(x) ≤ 1 since x ∈ {0, 2}

64) y = x3 + 1

– (h – 4) = 3h5

65)
ex(x – 3) = k
Let ƒ(x) = ex(x – 3)
ƒ'(x) = ex(x – 2)
k ∈ (–e2, 0)

66)

Consider two curves:

Minimum distance occurs along common normal

⇒ Normal at P must pass through (0, 0)

67)

5r = 6r2 – 4r – 81
(from position of point)

r = –3(rejected) or =

68) It is chord with a given middle point i.e.

x + y = 20

69)
So, 2 values of (c)

70) x + y – 1 = 0 (R.A)

71)

⇒ =1

⇒ =1–
⇒ x (x + 1) + 10 = 10 (x + 1) – x
⇒ x2 + x + 10 = 10x + 10 – x
⇒ x2 – 8x = 0 ⇒ x = 0, 8.

72)
Hence (D) is the correct answer.

73)

k1 + k2 = 20

74)

⇒ 16 = k + 4 ⇒ k = 12

75) h > 0 ;
Slope of normal at P = MPQ