(1001CJA101021240063) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

MAJOR TEST
(Academic Session : 2024 - 2025)
11-05-2025

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Full Syllabus
ANSWER KEY PAPER-1
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. B C B B
Q. 5 6 7
SECTION-I (ii)
A. A,B,C A,B B,C
Q. 8 9 10 11
SECTION-I (iii)
A. B D A D
Q. 1 2 3 4 5 6
SECTION-II
A. 6 5 5 0 4 2

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. C B D B
Q. 5 6 7
SECTION-I (ii)
A. A,B,C A,C A,B,D
Q. 8 9 10 11
SECTION-I (iii)
A. B C C C
Q. 1 2 3 4 5 6
SECTION-II
A. 40 25 0 7 9 4

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. D C C C
Q. 5 6 7
SECTION-I (ii)
A. A,D B,C,D A,B,C
Q. 8 9 10 11
SECTION-I (iii)
A. C B B A
Q. 1 2 3 4 5 6
SECTION-II
A. 2024 1 4 3 7 1

HINT – SHEET

1001CJA101021240063 HS-1/8
 Target : JEE(Main + Advanced) 2025/11-05-2025/Paper-1
PART-1 : PHYSICS PART-1 : PHYSICS
SECTION-I (i) SECTION-I (ii)

1. Ans ( B ) 5. Ans ( A,B,C )

L
t1 =
2v0 System can be modified as
after collision
m m
AMC × v1 × r = × 2u × ℓ
2 2

m v1 r = 2uℓ
t2 = π √
2k
after t > t2

L
t3 =
2v0
L m Energy
Total time = + π√
v0 2k
2. Ans ( C ) mu2 −
kq 2
=
1 m 2 kq 2
v −
2π
=ω×
1000 ℓ 2 2 1 r
500 3 × 108
6 × π × 108 kq 2 1 m 4u2 ℓ2 kq 2
6π mu2 − = × −
ω= = × 103 ℓ 2 2 r2 r
5 × 10 5 5
= 1.2π × 103 rad/ sec ℓ2 1 1
mu2 [1 − ] = kq 2 [ − ]
r2 ℓ r
4. Ans ( B ) r+ℓ 1
mu2 [ ] = kq 2 [ ]
r2 rℓ

kq 2
( rℓ + ℓ2 ) = ×r
mu2
kq 2
r − rℓ = ℓ2
mu2
Total heat absorbed by 1 mole of gas
ℓ2
Δ Q = Cv(2T0 – T0) + CP(4T0 – 2T0) r=
kq 2
−ℓ
5 7 19 mu2
=
2
RT0 + R × 2T0 =
2 2
RT0
6. Ans ( A,B )
Total change in temperature from state A to C is dθR dT
ΔS = ∫ ⇒ nCV
Δ T = 3T0 T T
Tg
∴ Molar heat capacity ⇒ nCV ln
Tℓ
19
ΔQ 2
RT0 19
= = = R ΔS = CV ln 2
ΔT 3T0 6
HS-2/8 1001CJA101021240063
 Leader Test Series/Joint Package Course/11-05-2025/Paper-1
PART-1 : PHYSICS PART-2 : CHEMISTRY
SECTION-I (iii) SECTION-I (i)

8. Ans ( B ) 1. Ans ( C )
−13.6 −13.6 Catalytic hydrogenation follows concerted and
E4 = eV E2 = eV
16 4
Birch reduction follows non-concerted mechanism
|E2 − E4 | = 2.55 eV

2πr η2 η3
T= ∝ ×η ∝
v z×z z2 P d / H2
−−−−−−−−−−−→
BaSO4 , Quinoline
η3
T∝
z2

PART-1 : PHYSICS Na/NH3

−−−−−→
SECTION-II

2. Ans ( 5 ) 2. Ans ( B )
Let potential drop per unit length in the Bond order decreases due to increase in number of
antibonding electrons.
potentiometer wire be ρ .
∴ Stability decreases
ρℓ1 = 5 and ∴ ρℓ2 = 3
3. Ans ( D )
∴

ℓ1 5
∴ = Oxidising ability of 'O3' is greater than that of H2O2
ℓ2 3
3. Ans ( 5 ) 4. Ans ( B )
T A2 ωk π * has gerade symmetry
P=
2 HOMO-LUMO energy gap decreases from
dT F2 to I2 due to decrease in electronic
Pin − Pout = ms
dt repulsion
T A2 ωk dT 'C2' contains 2 π bonds
= ms
4 dt
I.E for removal of electron from different
t = 500 sec orbitals : B.M.O > A.O > A.B. M.O

1001CJA101021240063 HS-3/8
 Target : JEE(Main + Advanced) 2025/11-05-2025/Paper-1
PART-2 : CHEMISTRY PART-2 : CHEMISTRY
SECTION-I (ii) SECTION-I (iii)

5. Ans ( A,B,C ) 9. Ans ( C )

(P) is ; (Q) is

(R) is ; (S) is

6. Ans ( A,C )
* "P" is +

H2 N − NH3 Cℓ−

* dsp2 hybridisation and square planar complex

* Geometrical isomers are 4 and meso compounds
are 2
7. Ans ( A,B,D )
rgas MCH4 16
=√ ⇒4= ⇒ Mgas = 4
rCH4 Mgas Mgas
4
Vm = = 0.02 m3 mol−1
200

= 20 lit mol – 1

2 × 20 = Z × 0.08 × 750

Z<1
P. M
d= < 0.2 kg m−3
RT

HS-4/8 1001CJA101021240063
 Leader Test Series/Joint Package Course/11-05-2025/Paper-1
10. Ans ( C ) 2. Ans ( 25 )
n2 h2 n-pentane (g) ⇌ isopentane (g)
(A) rn =
4π 2 mKZe2 (A) (B)
h2 ΔfG°1000 = ΔfG°B – ΔfG°A = 82.84 – 85.04
(r2 )Li2+ =
3π 2 mKe2 = –2.2 kcal mol–1
2πKZe2 Now, ΔrG° = – RT ln K°P
(B) Vn =
nh PB
or, –2.2 × 103 = – 2 × 1000 × ln
PA
Kπe2
(V4 )He+ = PB 3
h or, =
PA 1
Z2 As the equilibrium is independent from pressure
(C) En = − 13.6 × eV
n2 change, the ratio at 1.0 bar and 0.5 bar will remain
−13.6 × 9 same.
(E2 )Li2+ = eV
4 Hence, mole percent of n-pentane (A) = 25%.

(D) fn =
4π 2 mK 2 Z 2 e4
⇒ (f2 )Li3+ =
9π 2 mK 2 e4 3. Ans ( 0 )
n3 h3 2h3

11. Ans ( C )
Theory based.

PART-2 : CHEMISTRY
SECTION-II

1. Ans ( 40 )
100 ml solution contains 17.10 gm Al2(SO4)3 'X' is K2 Zn3 [ F e(CN)6 ]2

(= 107.1 gm) (= 0.05 mole) 4. Ans ( 7 )

(P) is CrO2 Cℓ2 ; (Q) is Toluene ; (R) is Benzaldehyde
∴ mass of water = 107.1 – 17.10 = 90.0 gm 5. Ans ( 9 )
Al2(SO4)3 ⇋ 2Al3+ + 3SO42 – [Link] of HC ℓ = 200
m. mol of NaOH = 100
0.05 (1 – α ) 0.05 × 2 α 0.05 × 3 α m. mol of NH4OH = 150
NH4OH + HC ℓ ⇌ NH4C ℓ + H2O
Effective moles of solute = 0.05 (1 + 4 α )
At eq : m. moles : ∼ 50 ∼ 100
Po −P 1.3 0.05 (1 + 4α)
NH4+ ]
Now, = X1 ⇒ = OH Kb
[

P 0 51.3 0.05 (1 + 4α) + 90 p =p + log

18 [NH4 OH]
∴ α = 0.4 ⇒ 40% dissociation. 100
= 4.70 + log( ) = 5.00
50
∴ pH = 9.00
6. Ans ( 4 )
(i), (ii), (iii), (vi)
1001CJA101021240063 HS-5/8
 Target : JEE(Main + Advanced) 2025/11-05-2025/Paper-1
PART-3 : MATHEMATICS 3. Ans ( C )
SECTION-I (i)

1. Ans ( D )
L : Passes through ( – 1, – 6)
b
Let slope m ( m= )
a
line : y = mx + m – 6 A (0, 16),
2 B (3,0), C (5, 8)
for tangent m − 6 = line will pass through the mid point of A & C
m
2 m1 12
m − 6m − 2 = 0 ⟨ ; mAB = = −24
m2 −1/2
1/m1 ∣ m∣
2m2 + 6m − 1 = 0 ⟨ ∣ ∣ = 3
1/m2 ∣
8∣
∴ ∑
a
= −3 4. Ans ( C )
b Observe that 1, 2, 3, 4 are roots of
2. Ans ( C ) n4 – wn3 – zn2 – yn – x = 0
3
f (x) = (x − 1) w = 10, z = – 35, y = 50, x = – 24
(i) Clearly, y = h (|x|) is non-derivable at exactly
PART-3 : MATHEMATICS
one point
SECTION-I (ii)

5. Ans ( A,D )
For x ∈ [k, k + 1] , x + 1 ⩾ k+1
k+1 1
Hence ⩽
x (x + 1) x
k +1
998
k+1
∴ ∑∫ dx
k=1
x (x + 1)
|A|=1 k
k +1
998
(ii) f(x) and f–1(x) meet on the line y = x at x = x0 ⩽ ∑∫
1
dx
x
where 2 < x0 < 3. k=1
k
999
{∵ f (2) = 1 and f (3) = 8} 1
=∫ dx = ln 999
x
1

Hence I < ln 999

Also, x ≤ k + 1
998 k+1
1
∴ I ⩾ ∑∫ dx
x+1
k=1
k
999

x = ∫ ln (x + 1) dx
∴ cos−1 (cos 2x0 ) + 4tan−1 (tan 0 )
2 1
x0
= (2π − 2x0 ) + 4 = 2π = ln 500 > 6
2
HS-6/8 1001CJA101021240063
 Leader Test Series/Joint Package Course/11-05-2025/Paper-1
6. Ans ( B,C,D ) 10. Ans ( B )
x1 = 3 sin x + 4 cos x
x2 = 12 cos y + 5 sin y
3 1 8 9 93 x3 = 15 sin z + 8 cos z
= + . . =
4 4 10 10 100 ⇒ x1 + x2 + x3 ⩽ 35
Exactly two working 3 4 5 15
P( ) ≠1 ⇒ sin x = , cos x = , tan y = , tan z =
X 5 5 12 8

X
9
. 8 + 10
10 10
9
. 2 3
.
10 4 19 11. Ans ( A )
P( ) = =
X2 9 20
10

7. Ans ( A,B,C ) (P)

1
f ′ (x) = 2x cos + 2x > 0 ∀x ∈ [1, ∞)
x
⇒ f is increasing 0
A=∫ ( 1 − ∣∣e|x| − 2∣∣) dx
′′ 1 1 1 − ln 3
f (x) = 2 cos + 2x (− sin (− )) + 2 − ln 2 0
x x x2 = ln 3 − ∫ ( e−x − 2) dx − ∫ ( 2 − e−x ) dx
1 2 1
= 2 cos + sin + 2 > 0 − ln 3 − ln 2
x x x 3
(B) lim f ′′ (x) = 4 = ln 3 + (2 − 3) + 2 (ln ) − 2 ln 2 − (1 − 2)
x→∞ 2
(C) f(2) + f(4) > f(3) 27
= ln( )
(D) LMVT for f '(t) in [x, x + 3] 16
2 1 2 1 2 1 1
as f ′′′ = + sin − sin + cos (− )
x2 x x2 x x x x2
2 1 (Q)
=− cos <0
x3 x
∴ f ′′ > 4
f ′ (x + 3) − f ′ (x) 1
f ′ (α) = >4 A=1+∫ 1 + ex − e−x ) dx
3 (
0
⇒ f ′ (x + 3) − f ′ (x) > 12 ∀x ∈ [1, ∞)
= 2 + (e − 1) + (e−1 − 1)

PART-3 : MATHEMATICS = e + e−1

SECTION-I (iii)

8. Ans ( C ) (R)
4
sin A = , AB = AC = 5√2
5 ln 2
So, point B (0, 10) or (10, 0) and point C (4, – 2) or A = 2∫ (2 − ex ) dx
0
(6, 12)
= 4 ln 2 – 2
Centroid (3, 13 ) . . . . . . . . . . .
3
Circumcentre (− 5 , 5 ) (S)
2 2
9. Ans ( B )
ˆ ˆi − ˆj + 2kˆ ) = 0 − ln 3
(P) ( (x − 3) ˆi + (y − 6) ˆj + (z − 2) k) . (
A=∫ ( e−x − 2) dx + ln 3
−2
(Q) 4 (x – 5) – 12 (y + 2) – 8(2 – 4) = 0
= e2 − 3 − 2 (2 − ln 3) + ln 3
x – 3y – 2z = 3 = e2 + 3 ln 3 − 7
1001CJA101021240063 HS-7/8
 Target : JEE(Main + Advanced) 2025/11-05-2025/Paper-1
PART-3 : MATHEMATICS 3. Ans ( 4 )
c = – (a + b)
SECTION-II
b2 + c2 + bc = b2 + (a + b)2 − b (a + b)
1. Ans ( 2024 )
∴

= a2 + b2 + ab
2 n 2
Since f (x) = ( 1 + x + x +. . . . . . . . . +x )
Similarly, c2 + a2 + ac = a2 + b2 + ab
f ′ (x) = 2 (1 + 2x+. . . . . . . . . . . +nxn−1 ) (1 + x + x2 +. . . . +xn )
Hence the given expression reduces to
C (r, n) = (r + 1) (r + 2) if 0 ⩽ r ⩽ n − 1, r ∈ Z
So,
2 (a2 + b2 + (a + b)2 )
{
C (r, n) = (r + 1) (2n − r) if n ⩽ r ⩽ 2n − 1, r ∈ Z
2 ( a2 + b 2 + c2 )
This can be easily checked with induction or =
a2 + b2 + ab a2 + b2 + ab
otherwise. =4
Particularly in our case pattern helps as well : 4. Ans ( 3 )
2025 2
f (x) = (1 + x+. . . . . . . +x )
⎡
a2 ab ac ⎤ ⎡ a2 ab ac ⎤
f ′ (x) = 2 (1 + x + x2 +. . . . . . . x2025 ) (1 + 2x + 3x2 +. . . . . . . . . +2025x2024 ) ⎢ ⎥⎢ ⎥
A2 = ⎢
⎢ ab b2 bc ⎥
⎥ ⎢ ab
⎢
b2 bc ⎥
⎥
⎢ ⎥⎢ ⎥
⇒ C(0, 2025) = 2.1 ⎣ 2 ⎦⎣ 2 ⎦
ac bc c ac bc c
C(1, 2025) = 2.3 a 2
ab ac ⎤
⎡

C ( 2, 2025) = 2( 1.3 + 1.2 + 1.1) = 3.4 ⎢ ⎥

=⎢
⎢ ab b2 bc ⎥
⎥
=A
. ⎢ ⎥

.
⎣
ac bc c2 ⎦

. ∴ A8 – 2A6 + A3 + I = I
an so on
Hence 3

2023
Hence ∑ b2ij = 3
1 1 1 1 i,j=1
∑ = + +. . . . . . . +
r=0
C (r, 2025)
1 1 1
1.2 2.3
1 1
2024.2025
5. Ans ( 7 )
= 1 − + − +. . . . . . . + − 1
2 2 3 2024 2025 f (x) = sin−1 (2x − 1) + cos−1 (2√x − x2 ) + tan−1 ( )
1 2024 1 + [x2 ]
=1− =
2025 2025 3 π π π 7π
2. Ans ( 1 ) f(
4
) = + + =
6 6 4 12
The logic works for any n. 6. Ans ( 1 )
14 ⎛ ⎞
Note that ∑ xj = ∑ yj = ( ) as every game is 1
1 + 4x − 4x3 − 1 x4 − 4x + 4
2 I=∫
⎜
⎜
√
−
√ ⎟
⎟ dx
⎜ ⎟
won and lost by some body. ⎜ 2x

2 ⎟
0 ⎝ ⎠
f(x)
Also xj + yj = 13
−x2 + √x4 − 4x + 4
Now ∑x
2
= ∑ (13 − yj )
2 f −1 (x) =
j 2
j j
2
= 13 . 14 − 2.13 ∑ yj + ∑ yj2 1 f (1 ) 0
−1 x2
j j ∫ f (x) dx+ ∫ f (x) dx+ ∫ dx
2
= ∑ yj2 0 f(0) 1
j
14.13 1 1
Since, ∑ yj = = 1f (1) − 0f (0) + (−1) = −
j
2 6 6

HS-8/8 1001CJA101021240063
(1001CJA101021240064) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Advanced)

MAJOR TEST
(Academic Session : 2024 - 2025)
11-05-2025

JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE

Test Type : Full Syllabus
ANSWER KEY PAPER-2
PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. D C A D
Q. 5 6 7
SECTION-I (ii)
A. A,C B A,B
Q. 1 2 3 4
SECTION-II (i)
A. 0.50 1.41 0.10 0.40
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 4 1 3 0 4 32

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. B C D C
Q. 5 6 7
SECTION-I (ii)
A. B,D A,C A,D
Q. 1 2 3 4
SECTION-II (i)
A. 10.40 4.00 36.00 11.70
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 4 6 2 4 8 12

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. B D B C
Q. 5 6 7
SECTION-I (ii)
A. A,B B,D A,C
Q. 1 2 3 4
SECTION-II (i)
A. 36.00 0.00 13.00 1.00
Q. 5 6 7 8 9 10
SECTION-II (ii)
A. 3 5 3 16 0 2

HINT – SHEET

1001CJA101021240064 HS-1/8
 Target : JEE(Main + Advanced) 2025/11-05-2025/Paper-2
PART-1 : PHYSICS PART-1 : PHYSICS
SECTION-I (i) SECTION-II (i)

1. Ans ( D ) 2. Ans ( 1.41 )

6 2
I= = = 0.4 Conserve angular momentum
15 3
q2 1 mR2 mR2 mR2
= × 2 × 0.16 ω0 + ω0 = ( + mR2 ) ω
2 × 2 × 10 −6 2 2 4 2
q 2 = 4 × 0.16 × 10−6
Conserve energy ω = ω0
q 2 = 0.64 × 10−6 2
2
1 mR2 2 1 mR2 2 1 R 1 3mR2 2 1 2
q = 0.8 × 10−3 × ω0 + ω0 = k ( ) + ω + mvr
2 2 2 4 2 2 2 2 2

PART-1 : PHYSICS ω0 R
Vr =
2
SECTION-I (ii) ω
Vt = 0 × R
5. Ans ( A,C ) 2
ω0 R √
At t → ∞ ∴ Vnet = 2
2
3. Ans ( 0.10 )
λf 5 × 10−7 × 20 × 10−2
β= = = 0.1 mm
d 1 × 10−3
4. Ans ( 0.40 )
8
i = = 1A
8 n 1 B1 = n 2 B2
q = 10 × 10
4000f 5000f
= 100 μ C n1 × = n2 ×
d d
∈0 A ∈0 A ∈0 A n1 5
C1 = = = ⇒ = or
t d d 2d d n2 4
d−t+ d− + +
k 3 3×2 3 6
6∈0 A
C1 = = 12μF ⇒ distance 0.4 mm
5d
6. Ans ( B ) PART-1 : PHYSICS
SECTION-II (ii)

6. Ans ( 1 )
Use angular momentum conservation and energy

conservation.
Q2 1 × R2
U1 = ⇒( ) ω = (1.5) × V × R . . . . . . . . (i)
8π∈0 (2R) 2
1 1 1 × R2 1
Q2 Q2 × 1.5 × (2)2 = × ( ) × ( ω2 ) + × 1.5 × V 2 ... (ii)
U2 = = (between the shells) 2 2 2 2
∈0 2R2 16π∈0 R
2 × 4π
R
2
Q Q2
U2 = =
2 × 4π∈0 2R 16π∈0 R
HS-2/8 1001CJA101021240064
 Leader Test Series/Joint Package Course/11-05-2025/Paper-2
7. Ans ( 3 ) PART-2 : CHEMISTRY
h
λ= SECTION-I (ii)
2meV
5. Ans ( B,D )
√

Dλ
β⇒
d
(P) is
109.2 × 10−2 6.63 × 10−34
⇒ ×
66.3 × 10−6 √
2 × 9.1 × 10−31 × 1.6 × 10−19 × 45.5

=3
(Q) is
PART-2 : CHEMISTRY
SECTION-I (i)
(R) is
1. Ans ( B )
Natural rubber is a linear Cis-1, 4-polyisoprene NaOH
−−−−→ CHBr3
and Empirical formula is C5H8 Br2 (Colourless solution)

Gutta-Percha rubber is formed via 1,4-addition

Vulcanized rubber contains sulphur cross links
at the reactive sites of double bonds
6. Ans ( A,C )
0
EAg 0
+ /Ag > E +
[ Ag(NH3 )2 ] /Ag,NH3

∴ AgNO3(aq) is a S.O.A than Tollen's reagent

2
0 0.06 [C6 H12 O7 ] [H + ]
EOX = EOX − log
2. Ans ( C ) 2 [C6 H12 O6 ]

if pH ↓ ⇒ [H + ] ↑
0
⇒ EOX ↓ but EOX remain same
7. Ans ( A,D )
H2 O2
Cr2 (SO4 )3 −−−−→ CrO2−
4
• Lysine is a basic and essential amino acid OH (yellow solution)

3. Ans ( D ) MnO2
H2 O2
−−−
+
H
→ Mn2+
Δ
(NH4 )2 Cr2 O7 −→ N2 ↑ + Cr2 O3 ↓ + H2 O H2 O2
(Orange) (green) P bO2 −−−→ P bO
4. Ans ( C ) H O
K2 Cr2 O7 + 2F eC2 O4 + 7H2 SO4 →
NH2OH −−2−→
2
HNO3

K2 SO4 + F e2 (SO4 )3 + 4CO2 + Cr2 (SO4 )3 + 7H2 O

1001CJA101021240064 HS-3/8
 Target : JEE(Main + Advanced) 2025/11-05-2025/Paper-2
PART-2 : CHEMISTRY 2. Ans ( 4.00 )
SECTION-II (i)

1. Ans ( 10.40 )

E is

1,3-dimethyl benzene
3. Ans ( 36.00 )
100% 80% Zn+NaOH
−−−→ (A) −−→ (C) SO2−
3 −−−−−−−→ H2 S
(0.5 mole) (0.4 mole) (P ) (Q)
Na2 [F e(CN )5 (NO)]
Na2 S −−−−−−−−−−−−→ Na4 [F e(CN)5 (NOS)]
(R)

50% 100% 50% E.A.N = 26 – 2 + 6 × 2 = 36

−−→ (P ) −−−→ (Q) −−→ (R)
(0.2 mole) (0.2 mole) (0.1 mole) 4. Ans ( 11.70 )
NaOH NaOH
H2 S −−−−→ NaHS −−−−→ Na2 S
(Q) (S) (T )
∴ mass of (R) = 0.1 × 104 = 10.4 g H2 S + Na2 S → 2NaHS

moles at t = 0 : 1 3 2
final [Link] moles : ∼0 ∼2 ∼4
[ S 2− ]
∴ pH = pKa2 + log
[HS − ]
2
= 12 + log( )
4
= 12 – 0.3 = 11.70
HS-4/8 1001CJA101021240064
 Leader Test Series/Joint Package Course/11-05-2025/Paper-2
PART-2 : CHEMISTRY 9. Ans ( 8 )
Except NO2 - acidic , Li2O - basic, C ℓ O2 - acidic
SECTION-II (ii)

5. Ans ( 4 ) 10. Ans ( 12 )

π = i. CST
0.015 ST = i (0.01) ST
⇒ i = 1.5
∴ α = 0.5

6. Ans ( 6 ) [ OH − ] = C. ∝= 5 × 10−3 M
pOH = 2.3
∴ pH = 11.7

PART-3 : MATHEMATICS
SECTION-I (i)

1. Ans ( B )
1 1 1 1
Let P (x) = ( x− )( x− ) (x − ) −
k−1 k k+1 k

= (x − αk ) (x − βk ) (x − γk )

⇒ −P (0) = αk βk γk and

−P (1) = (1 + αk ) (1 + βk ) (1 + γk )

7. Ans ( 2 ) Hence given expression

∞
100 × 2.3 k2 + 3k − 1 k
2.3 log(k) = 2.3 × 5.4 − + 2.5 × 2.3 log(T ) = ∑( . )
T k (k − 1) (k + 1) k2 − 1
k=2
230 ∞
k2 + 3k − 1
ln(k) = 2.3 × 5.4 − + 2.5 ln(T ) =∑
T 2 2
k=2 (k − 1) (k + 1)
d 230 2.5
(ln k) = + ∞ 1 1
⎛
3 3
⎞
dT T2 T =∑
⎛ 2
−
2 ⎞
+
4
−
4
k−1 k+1 2 2
230 + 2.5T k=2
⎝ ⎠ ⎝ (k − 1) (k + 1) ⎠
=
T2 1 1 3 1 1 27
= (1 + ) + ( + ) =

But d (ln k) = Ea 2 2 2 4 12 22 16
dT
Ea
RT
2. Ans ( D )
∴ = 230 + 2.5T 2025
R x
n
dx
f (n) = ∫ ( )
⇒ Ea = (230 + 2.5 × 300) R 2025 − x x
0
2025 n−1
= 980 × 2 = 1960 cal/mol 2025 − x dx
f (1 − n) = ∫ ( )
x x
8. Ans ( 4 ) 0
f (1 − n) = f (n) ⇒ f ′ (n) = −f ′ (1 − n)
[ P b(EDT A)−2 ]
exists in two forms (d & ℓ ) and 1
f′ ( ) = 0
Pt(NH3)2Cl2 have two stereoisomer 2
1001CJA101021240064 HS-5/8
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3. Ans ( B ) 6. Ans ( B,D )
sin2 x x sin(sin x) 1 (A) Let
L = lim [ − 1]
2
x→0 x2 sin x x4 x2
2025x 3
sin2 x sin4 x g (x) = e − ∫ ( (f (t)) sin t) dt ∀x ∈ (0, 1)
x 1
= lim [ {1 − + } − 1] >1 0
x→0 x4 sin x 6 120 
⩽ 1
sin2 x sin4 x x2 x4
( 1− + +. . . . . .) − (1 − + . . . .)
1 6 120 6 120
= lim
x2
So g(x) > 0 ∀ x ∈ (0, 1)
x→0 x4 1− +. . . . .
6

2 Hence No zeroes
1 x2 x2 x4 x6 x4
= lim [ − (1 − +. . . . .) + + − +. . . . .]
x→0 x4 6 6 120 6 120 f (x)
(B) Let g (x) = x2025 −
ex + sin(2025x) + 1
x4 1 1 f (0)
= lim [ +. . . . .] =
x→0 x4 18 18 Then g (0) = 0 − <0
2
4. Ans ( C ) Since f(0) > 0 while
→
→b + b . → → 3 f (1)
Since →a . c + c . →a = − g (1) = 1 − >0
2 e + 1 + sin(2025)
2 → → → f (1)
⇒ →
→a + →b + c ) = a2 + b2 + c2 + 2 (→a . →b + b . c + c . →a ) Since <1
(
e + 1 + sin 2025
So by I.V.P. Since g is continuous in (0, 1) and we
=0
at least one zero in (0, 1)
⇒ →a + →b + c = 0
→
π
4

→∣ (C) Let g (x) = f (x) + f (t) sin t dt

2→a + →b + c ∣ = ∣∣→a ∣∣ = 1 and so on.
∣ ∫
∣
∣ ∣
0
π
Since f (x) ∈ (0, 1) and f(t) sin t > 0 for t ∈ ( 0, )
PART-3 : MATHEMATICS 4

SECTION-I (ii) hence g > 0 ∀ x ∈ (0, 1). So, No Root

5. Ans ( A,B ) π
2
−x

2
(D) Let g (x) = x2025 − ∫ (f (t)) cos t dt
For ℓx + my + n = 0 to be tangent to
0
π
2
x2 y 2

E: + =1 2
g (0) = 0 − ∫ f(t) cos t dt < 0
a2 b2 
0 ⩾ 0
We have aℓ2 + bm2 = n2 . π
2
−1

g (1) = 1 − ∫ f(t)2 cos t dt > 0

Hence 4ℓ2 + m2 = 1 ⇒ ℓ = 0 , m = ± 1 (Integer Sol) 0

<1

So by I.V.P there exists at least one zero in (0, 1)

Similarly for ℓx + my + n = 0 to be normal to E we
a2 b2 ( a2 − b 2 )
have + =
ℓ2 m2 n2
4 1
⇒ + =9
ℓ 2 m2
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7. Ans ( A,C ) 3. Ans ( 13.00 )
1 − 1 Put z = a + ib we get
f (x) = g ( ) e x6
2
x5 ⇒ 8 + 2|z| < 50
g( 1
) ⇒ a2 + b2 < 21
x5
lim f (x) = lim Cases :
x→0 x→0 1
e x6 a = 1, b = 1, 2, 3, 4
g (t5 )
= lim =0 a = 2 , b = 1, 2, 3, 4
t→∞ et 6
a = 3, b = 1, 2, 3
f (x) − f (0)
f ′ (x) = lim a = 4, b = 1 , 2
x→0 x
1 − 1
1
So total (a, b) pairs are 13.
g( ) e x6 g( )
x5 x5 Hence | S ∩ T | = 13
= lim = lim
x
4. Ans ( 1.00 )
x→0 x→0 1
xe x6
tg (t5 )
= lim 6
=0 z 3 + 2 − 2i∣∣ + ∣∣z 3 ∣∣ = 2√2
∣
∣
t→∞ et
Let u = z3 ⇒ | u – ( – 2 + 2i) | + |u| = 2√2
i3π

⇒ f(x) is continuous and differentiable at x = 0 Hence u lies on line segment joining 0 and 8 e 4 √

By De-moivre's theorem z lies on the three line

iπ i11π 19π

PART-3 : MATHEMATICS
segment joining origin (0) to 2 e 4 , 2 e , 2ei
√ √ 12 √ 12

SECTION-II (i)

1. Ans ( 36.00 )
| I – AB| = | I – BA| ∀ A, B if both are square
matricy of same order.
Hence ||T|| = 6 × 6 = 36
(2) ||R|| = 0 since Tr (AB – BA) So | P ∩ T | = 1
= Tr (AB) – Tr (BA) = 0 but Tr (I) = 3 PART-3 : MATHEMATICS
R is an empty set SECTION-II (ii)

2. Ans ( 0.00 ) 5. Ans ( 3 )

| I – AB| = | I – BA| ∀ A, B if both are square Let C = F1F2
matricy of same order.
Hence ||T|| = 6 × 6 = 36
(2) ||R|| = 0 since Tr (AB – BA)
F1 F2
= Tr (AB) – Tr (BA) = 0 but Tr (I) = 3 e=
AF1 + AF2
R is an empty set 2C
=
C ( √3 + 1 )

= √3 − 1
1001CJA101021240064 HS-7/8
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6. Ans ( 5 ) 8. Ans ( 16 )
y
dx
+ 2x = y 2 ln y
Let T+/ – indicate the test result and B+/ – indicate
dy whether the person actually does or does not have
dx 2 virus. The probability that someone has the virus,
+ ( ) x = y ln y
dy y given that their test is positive, is equal to the
2
I. F = e ∫
y = y2 probability that a given person tests positive and
has it over the total probability of testing positive,
⇒ y 2 x = ∫ (y ln y) y 2 dy In statistical notation.
P (T + / B+ ) . P (B+ )
2
y 4 (ln y) y2 P (B+ /T + ) =
xy = − +c P (T + /B+ ) . P (B+ ) + P (T + /B− ) . P (B− )
4 16
(0.99) (0.01)
=
Curve passes through (− 1 , 1) ⇒ c = 0 (0.99) (0.01) + (1 − 0.99) . (1 − 0.01)
16
2 2
= 1/2
y ln y y
⇒x=
4
−
16 9. Ans ( 0 )
Suppose the equation of the circle is
⇒ 16x + y 2 = 4y 2 ln y 2 2
(x − h) + (y − k) = r2
a=1,b=4 Since it intersects with the graph f(x) = x2, the above
equation be rewritten as
7. Ans ( 3 ) 2
(x − h) + (x2 − k) = r2
2

P : √6x + √2y + z =
3 Note that the coefficient of x3 of above quartic
√
3
2 equation is 0.
3
P− 3 : −√6x + √2y + z = Let the x-coordinates of 4 intersection points be α 1,
2
√

3 α 2, α 3 and α 4 . Then α1 + α2 + α3 + α4 = 0. On the

Q2 : 2√2y − z = −
2 other hand, from g (x) = x4 + ax3 − 2x2 + bx + 1, the
−1
Q0 : z =
2 sum of roots is − a . So a = 0 and hence 2025 ab = 0.
1
We can blindly solve for vertex and find volume 10. Ans ( 2 )
but there is a nicer way below : We have
5 (sin x + 2 sin 2x sin x + cos 3x + sin 3x) = (1 + 2 sin 2x) (3 + cos 2x)
Notice that all planes are at 1/2 unit from origin ⇒ 5 (sin x + cos x − cos 3x + cos 3x + sin 3x) = (1 + 2 sin 2x) (3 + cos 2x)

⇒ 5 (cos x + 2 sin 2x cos x) = (1 + 2 sin 2x) (3 + cos 2x)

also angle between any two pairs is cos – 1 (1/3).
⇒ 5 cos x (1 + 2 sin 2x) = (1 + 2 sin 2x) (3 + cos 2x)
That is feel of regular tetrahedron. ∴ Either (1 + 2 sin 2x) = 0
−1
We need just two point of intersection which is ⇒ sin 2x = (Not possible)
2
3 −1 −1 3 −1 −1 or 5 cos x = 3 + cos 2x = 3 + 2cos2 x − 1
(√ , , ) and ( −√ , , )
⇒ 2cos2 x − 5 cos x + 2 = 0
2 √2 2 2 √2 2
1 1 √3 2 ⇒ 2cos2 x − 4 cos x − cos x + 2 = 0
Volume = 3 × A × h = 3 × 4 × (√6)2 × √6. √
3 ⇒ 2 cos x (cos x − 2) − (cos x − 2) = 0
1
⇒ cos x = 2 or cos x = (But cos x ≠ 2)
2
π 5π
∴ x = or
3 3
As x ∈ [0, 2 π ], so we have only 2 solutions.
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