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Tire Pressure Changes with Temperature

The document contains a tutorial with various questions related to thermodynamics, including classifications of systems, temperature changes, thermal equilibrium, and the Joule-Thomson effect. It also includes practical problems involving gas laws, pressure calculations, and temperature conversions. The tutorial aims to enhance understanding of heat transfer, gas behavior, and thermodynamic principles.

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0% found this document useful (0 votes)
13 views2 pages

Tire Pressure Changes with Temperature

The document contains a tutorial with various questions related to thermodynamics, including classifications of systems, temperature changes, thermal equilibrium, and the Joule-Thomson effect. It also includes practical problems involving gas laws, pressure calculations, and temperature conversions. The tutorial aims to enhance understanding of heat transfer, gas behavior, and thermodynamic principles.

Uploaded by

moiwelya
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Tutorial no.

1. Classify the following systems as open, closed, or isolated:


a) A mass of gas in a container with rigid, impermeable, diathermal wall,
b) A mass of gas in a container with rigid, impermeable, adiabatic wall,
c) A sugar solution enclosed by a membrane permermeable only to water that is immersed
in a large container of water.
2. Give an example of a process in which no heat is transferred to or from the system but the
temperature of the system changes.
3. If you heat the air inside a rigid, sealed container until its Kelvin temperature doubles, the air
pressure in the container will also double. Is the same thing true if you double the Celsius
temperature of the air in the container? Explain.
4. A newspaper article about the weather states that “the temperature of a body measures
how much heat the body contains.” Is this description correct? Why or why not?
5. To raise the temperature of an object, must add heat to it? If you add heat to an object, must
you raise its temperature? Explain.
6. If system A is in thermal equilibrium with system B, but B is not in thermal equilibrium with
system C, what can you say about the temperatures of A, B, and C?
7. Is it possible for two objects to be in thermal equilibrium if they are not in contact with each
other? Explain.
8. A piece of copper is dropped into a beaker of water. If the water’s temperature increases,
what happens to the temperature of the copper? Under what conditions are the water and
copper in thermal equilibrium?
9. Two identical cylinders at the same temperature each contain the same kind of gas and the
same number of moles of gas. If the volume of cylinder A is three times greater than the
volume of cylinder B, what can you say about the relative pressures in the cylinders?
10. There is a temperature whose numerical value is the same on both the Celsius and
Fahrenheit scales. What is this temperature?
11. Why does the air pressure in a car tyre increase during driving?
12. State and explain Joule- Thomson Effect.
13. How can you show that Joule-Thomson effect is isenthalpic?
14. What is the Joule-Thomson Effect? Why does it cause a cooling effect?
15. Why is the Joule-Thomson coefficient of an ideal gas, zero?
16. The mass of a hot-air balloon and its cargo (not including the air inside) is 200 kg. The air
outside is at 10.0°C and 101 kPa. The volume of the balloon is 400 m3. To what temperature
must the air in the balloon be heated before the balloon will lift off? (Air density at 10.0°C is
1.25 kg/m3.)
17. An automobile tire is inflated with air originally at 10.0°C and normal atmospheric pressure.
During the process, the air is compressed to 28.0% of its original volume and its temperature
is increased to 40.0°C. (a) What is the tire pressure? (b) After the car is driven at high speed,
the tire air temperature rises to 85.0°C and the interior volume of the tire increases by
2.00%. What is the new tire pressure (absolute) in pascals?
18. The pressure gauge on a tank registers the gauge pressure, which is the difference between
the interior and exterior pressures. When the tank is full of oxygen (O 2), it contains 12.0 kg of
the gas at a gauge pressure of 40.0 atm. Determine the mass of oxygen that has been
withdrawn from the tank when the pressure reading is 25.0 atm. Assume that the
temperature of the tank remains constant
19. Two beakers of water, A and B initially are at the same temperature. The temperature of
the water in beaker A is increased 10 F, and the temperature of the water in beaker B is
increased 10 K. After these temperature changes, which beaker of water has the higher
temperature? Explain.
20. You put a bottle of soft drink in a refrigerator and leave it until its temperature has dropped
10.0 K. What is its temperature change in (a) F and (c) C?
21. (a) Calculate the one temperature at which Fahrenheit and Celsius thermometers agree
with each other. (b) Calculate the one temperature at which Fahrenheit and Kelvin
thermometer agree with each other.
22. A gas thermometer registers an absolute pressure corresponding to 325 mm of mercury
when in contact with water at the triple point. What pressure does it read when in contact
with water at the normal boiling point?
23. The pressure of a gas at the triple point of water is 1.35 atm. If its volume remains
unchanged, what will its pressure be at the temperature at which CO2 solidifies?
24. A constant-Volume Gas Thermometer. An experimenter using a gas thermometer found the
pressure at the triple point of water (0.01C) to be 4.80  104 Pa and the pressure at the
normal boiling point (100 C) to be 6.50  104 Pa. (a) Assuming that the pressure varies
linearly with temperature, use these two data points to find the Celsius temperature at
which the gas pressure would be zero (that is, find the Celsius temperature of absolute zero).
(b) Does the gas in this thermometer obey Constant-Volume Gas Thermometer Precisely? If
that equation were precisely obeyed and the pressure at 100 C were 6.50  104 Pa, what
pressure would the experimenter have measured at 0.01C?

Common questions

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Thermal equilibrium between a piece of copper and water is reached when the heat lost by the copper equals the heat gained by the water, resulting in no net heat flow. This occurs when both substances reach the same final temperature. The specific heat capacities and masses of both substances will dictate the equilibrium point .

When heat is added to an object, it typically causes an increase in temperature due to the increase in kinetic energy of particles. However, if the heat is used for a phase change, such as melting or boiling, the temperature does not increase. An example is the melting of ice into water where heat is absorbed to change the phase from solid to liquid, yet the temperature remains at 0°C .

The pressure inside a car tire increases after driving due to increased air temperature from friction between the tire and the road, and heat generated by constant flexing of the tire. According to the Ideal Gas Law, with an increase in temperature and constant volume, the pressure must increase .

The system is a closed system. Since the walls are both rigid and impermeable, no matter can enter or leave the system. Additionally, the adiabatic condition implies that no heat is exchanged with the surroundings. However, because the container can interact with the external environment only through work done on or by the system, it is not isolated .

The Joule-Thomson coefficient of an ideal gas is zero because an ideal gas does not experience any change in temperature during free expansion when no external work is done and no heat is exchanged. This implies that the internal energy of a gas is solely dependent on temperature, and in perfect conditions, its internal energy remains constant during both isenthalpic expansion and compression .

When the Kelvin temperature of a gas in a rigid, sealed container doubles, the pressure also doubles according to the pressure-temperature relationship (P1/T1 = P2/T2). However, doubling the Celsius temperature does not equate the same ratio as Kelvin; thus, the change will not double the pressure because the scale starts at a different zero point .

The unique temperature where both Fahrenheit and Celsius are numerically the same is -40°. This can be calculated by setting the conversion formula, C = (F - 32) × 5/9, equal to F and solving: F = C. Solving gives C = -40, as substituting this value into either scale yields -40 .

A 10 K increase corresponds to a 10°C increase, while a 10°F increase is approximately a 5.56°C increase due to the conversion formula (1°C = 1.8°F). Therefore, the beaker subjected to a 10 K increase will have a higher final temperature, because 10°C is greater than 5.56°C .

According to the Ideal Gas Law (PV=nRT), if one cylinder (A) has three times the volume of another (B), cylinder A will have one-third the pressure of cylinder B if the temperature and amount of gas remain constant. This is due to the inverse relationship between pressure and volume .

Yes, it is possible for two objects to be in thermal equilibrium without direct contact, as long as they can exchange heat through radiation or another medium. Thermal equilibrium means that the temperature is uniform across objects, not necessarily requiring contact. For example, an object in thermal equilibrium with its surroundings through air convection .

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