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Complex

The document consists of a series of questions and answers related to coordination chemistry, focusing on ligands, complex ions, and their properties. It covers topics such as coordination numbers, oxidation states, and IUPAC nomenclature for various coordination compounds. The questions are structured in a quiz format, likely for educational purposes, aimed at testing knowledge in the field of chemistry.

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5 views19 pages

Complex

The document consists of a series of questions and answers related to coordination chemistry, focusing on ligands, complex ions, and their properties. It covers topics such as coordination numbers, oxidation states, and IUPAC nomenclature for various coordination compounds. The questions are structured in a quiz format, likely for educational purposes, aimed at testing knowledge in the field of chemistry.

Uploaded by

sushilahiremath919
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF or read online on Scribd
= pa ary-Thinking —— ———*——————opjective-Questions= 2 10, Basic Terms ‘Which of the following igands is expected tobe bident (CBSE AIT 19381 @ & ©) Cor (© CHyNH, () CHyCeN ‘The anion of acetylacetone (acac) forms Co (acuc)s chelate ‘with CoM The rings of the chelate are (NET (Karnataka) 2013] (a) Five membered (b) Four membered (©). Six membered (a) Three membered In the compound lithium tetrahydroaluminate, the ligand is (AUMS 1957) @ ae @H (@) None of these Which one of the following forms with an excess of CN” (Cyanide) a complex having coordination number two TALIMS 2004; MP PET 2013] @ Gut tb) Ag? «NP () Fe* Which of the following is not considered as an organometallic compound TATIMS 200, MP PET 2011] (2) Cisplain (©) Ferrocene (©) Zeive’s salt (6). Grignard reagent ‘The ligands in an-cancer dg csplatin ae [ATIMS 2006] (@ aH,ct (6) Ny #0 © amo (®) noc ‘Which othe folowing is a common donor atom in ligands {BHU 2001 © Anenic (©) Nitrogen (©) Oxygen (4) Both () and fod Potassium ferocyanie sa TARMC 2000) (2), Norma ak (>) Mixed san {© Double st (@) Complen sak EDTA has coordination number TAFMC 2004 Mr PAT 2007; MP PET 211) @3 4 5 «6 In the complex ion [Co(WH),}". the NE7,molecules are Tinked to the central metal ion by [AFM 2010) (@) Tonic bonds (©) Covalent bonds (© Coordinate bonds __(d)_ Hydrogen bonds Number of ons preseat in K,lFe(CN)¢] (KCET 1990; Pb. CET 2000; MP POET 2 @ 2 ©) 10 3 « $ ‘Among the following which are bidentate ligands NO; i) NO; iy EDTA «wy Gor © sor (6) HANCH,CHNH, @ Wand Gy (©) @and (vi) ©) @and uM. 16. wv. 1». “The ligand N(CH,CH,NH,), is (kerala PMT 2011) (@) Tridentate (b) Pentadentate (©) Tetradeniate (@) Bidentate (©) Hexadeniate ‘Which one of the following isthe correct order of Field strength cof ligands in spectrochemical series (Kerala PMT 2012], @) P C,H; > NH, () NH, > N7 > Br > CHE (6) ON” > Gls > Br” > NH (Br > CN” > NH > Cyt Which one of the following shows maximum paramagnetic character [ATMS 1998] fa) (CrH,0),)" (b) (FetCN) I ©) (FACw (@) (Cutt, 0),)" ‘Which one of the following has an optical isomer IAIIMS 2008; ATERE 2010; MP PNET 2013] (a) [2n(en),F* (6) (Za(en)(NH), 1° (© [Cotem, (@) Co(H,0)4¢en)I* ‘The pair in which both species have same magaetic moment pin only valu) is TAIIMS 2061 fa) (CHO), [CoC () [Citth Os LetO™ (©) [MntH,O)a™, [CrH:0n* (@ [CoChy, [FeH,O)” The number of possible isomers of an octahedcal complex ICo{C0,)0NH)3T is {atts 2006) @! 2 © 3 @4 [Fe(N0;),Ct} and (Fe(-NO),C} shows [DCE 2008; ATIMS 2008) (2) Linkage isomerism (b)_ Geometrical isomerism (©) Optical isomerism (A). None ofthe above ‘Which ofthe following will not give a precipitate with AgNO; IMP PET 2003; AFMC 2006; 3 & K CET 2006] () [CONCH] (b) [Co(H,) Ch IC1 (©) (CoH) CHC, (€) (CoH IC, “The colour of CoCl, SNHy.H0 is {Kerala PMT 2002] (2) Orange yellow (b) Orange (©) Green (@) Violet (e) Pink Among the following complexes, which has a magnetic ‘moment of $9 BM Ni(CO),,[Fe(H,0)41",[Co(NH, 4) LMnBrP, zac) (Kerala PMT 2006) @) NCO), @) [Fe(H,0),7" (Coen? (@) [MnBe (©) (Z0WHs da” ‘854 Coordination Chemistry a. 2 ‘Which one ofthe following complexes isnot diamagnet (Kerala PMT 2006) () (FiCH,O)4I" (a) [Fe(CN) TE © (PHCN),)* (@) (Cont), © (WKCOn] Both geometrical and optical isomerism are exhibited by [Kerala PST 2008}, (@)_Dichlorobis (ethylenediamine) cobalt (ID ion (&)_Pentaammineehlorocobalt IIT (©) Triamminotrichlorocobalt (I) ion (@) Tetraamminedichlorocobalt (1) ion (©) Trioxalatochromate (Il) ion ‘The complex ion which has the highest magnetic moment among the following is (Kerala PET 2013] (@) (Cor, (©) (Cotntt I (©) (NKNH))" «Wenn © [FACN) I ‘Which one has the highest paramagnetism [AMU 2001) @) NCO, () LNKNH, IC, (© WNWNHS ]Ch (@) (Cu(NHs a1, ‘Which o the following species wil be diamagnetic TAMU CEng, 2009] fa) [Fe(EN), (b) [FeR, I (©) (CalC,0).7 (8) None ofthe above ‘What will be the theoretical value of magnetic moment (4) when CN" ligands join Fe™ ion o yield complex {GUICET 2007; DUMET 2008: AMU CEng) 2010] ( 238M () 3878M (© 592M 738M ICo(CN),1°. a complex ion of eobalt (ID, absorbs radiations in violet region of the visible ight. is aqueous solution, therefore, appears TAMU Med) 2013] (Pink (b) Orange (©) Blue (@) Yellow ‘Maximum value of paramagnetism is shown by TAMU Gags) 2012] @ Facn) &) (cKeM © [CCN (@) [SCO Which one of the following is expected to be « paramagnetic complex (MP PMT 1981, 2000) @) (NiUH,0,)" (©) (NICO) (©) (2uNH)P* (CoN)? ICo(NH,),Br]80, and [Co(NH,),S0,]Br are examples of DP PNET 1993, 94, 95; [MP PET 1993,91, 98; 3 & K CET 2012] which eype of isomerism (2) Linkage (b) Geometrical (©) onization (@) Optical ICo(NH,)4Cl,]NO; and (Co(NH,),CLNO;ICI are isomers [MP PMT 1993; MP PET 1995, 2001] (@) Geometrical (b) Optical (©) Linkage (@) lonization sh. Pick out from the following complex compounds. a poor and (ef) (RPET 1999) (@) Both are paramagnetic (©) Only (Fe(CN)4]™ is paramagnetic (©) Only [FeF,)* is paramagnetic (@) Both are diamagnetic Coordination Chemistry 885 3. 55. a. ITi(H,0),1° is paramagnetic im nature due 19 () One unpaired (©) Three unpaired (RPM 2002] (b) Two unpaired (@) Nownpaired & Magnetic moment of [Cu(NH,),"*ions (RPE 2005) (@ Lats 173 © 23 (a) 238 “The type of isomerism presen in sitropentammine chromium Al chose is {AIEEE 2002] (@) Optical (©) Linkage (©) loization (@)Polymerisation “The “spin-only” magnetic moment [in units of Bohr magneton, (a) Jof Ni™* ia aqueous solution would be (At. no. Ni= 28) AIRE 2006; KCET (Med) 2012] ( 283 () 490 0 @ 17 “The magnetic moment (spin only) of NICT Fis (AIEEE 201] @ 182M () S46BM (@ 2826M (@) 141s Which ofthe following has an optical isomer {ATEEE 2008] (@) (CoNH,),C (©) (Colen(NH),]* (© (CoHO)lemI* ——d)_(Cotem) (NH), 1" Which ofthe following pairs represents linkage isomers [AIEEE 2005] (2) (Cu(NH)gIIPeCIg} and (PHONE) CHC, ©) [PAP Ph ),(NCS).} and [PACP Ph, )(SCN)} (© (Co(NH,),80,150, and [CoNH,),504]NO, (©) (PICI(NH,)41Bry and [Pr BQ (NH )eICl ‘The magnetic moment of salt containing Za ion is IVITEEE 2008) @o ) 187 © 592 2 ‘The ion of least magnetic moment among the following is U&KCET 2009] @ 7 (Ne © Co* (a) Mn “The optically active co-ordination complex ion among. the following is U&KCET2009) (a) trans (Cofen), Ct)" (©) (CoN 4)" ‘The complex (CoF,]* is (a) Outer orbital and diamagnetic (b) Inner orbital and paramagnetic (©) Outer orbital and paramagnetic (4) Inner orbital and diamagnetic ‘Which is high spin complex (a) (CoF|* (©) [Fe(CN)}* For the given complex|CoCl,(em(VH)2]".the number of geometrical isomers, the number of optical isomers and total ‘umber of isomers of all type possible respectively are (DCE 209] (@ 2.2and$ (b) 2. 2and 3 © 20and2 (@) 0. 2and 2 (0) eis (ColenyN#H) Ch" (@) (FECHA U&KCET = (DCE 2006] 0) FFAKCM)IE (A) None of these or. na nm 2B. 4. ‘Which of he following can panicipate in linkage isomerism IKCET 2006), © [Link], km, oom (@) NO; ©) 40 ‘The magnetic moment of a transition metal ion is V5 BM. ‘Therefore the number of unpaired electrons present in iis, KCET20091 @ 4 ot © 2 @3 ‘The spin only magnetic moment of Mn ion is nearly (CET 2010) (@ 35M ) 6BM (© 43M @ 5BM Amongst {NCI} [MH,0),]"*.[N(PPh,) Ch INKCO),] and[Ni(CW),] "the paramagnetic species are (WB JEE2013) (2) (HAC INCH Og AMLPP) CE) (0) (WACO), INHER), CI, NCCE F™ (©) [MENA [NH O)9}* ANCL T™ (@) (WHPPH,) oC, LINCO) | ANKEN) AT “The spin-only magnetic moment of /CrF,J* (atomic number of Cris is [WB JEE 2016), @ 0 @) 19738M (©) 283 BM (@) 498M ‘What is the magnetic moment of K,LFeF,] (Odisha JEE 2004, 5; DUMET 2009} (a) $91 BM (®) 489BM (©) 387 BM (@) 692BM How many unpaired electons are present in the central metal fon of [CoCt, {0disha JEE 2005) @ 3 m4 © 5 @ 2 ‘The reaction (Fe(CNS)q])" + [FeF,]™ takes place with {Odisha Jee 2908), {@)_ Decrease in magnetic moment (©) Increase in magnetic moment (6) Deerease in co-ordination number (@) Increase in co-ordination number ‘Which ofthe following can exhibit geometical isomerism {Odisha JEE 2008) @) (Mabe (©) LPUNH,),CU (©) (PiCh PC Hs)al (8) [Fel #130), NO} Which ofthe following is diamagnetic in mature [DUMET 2010) (2) Co™ octahedral complex with weak fel ligands (©) Co™ octahedral complex with strong field ligands (©) Co in worahedral complex (@) Co™ in square planar complex Coordination isomerism is eaused by the interchange of ligands ‘between the TUPSEAT 2002} (@) cis and trans stueture () Complex cation and complex anion (©) er sphere and outer sphere (@)_Low oxidation and higher oxidation states Coordination Chemistry 857 x 10, 2, B. M 15, 16. m7 18, "The diamagnetic species is (AIMS 2008; CRSE PST (Pre) 2011; 'NEET (Karnataka) 2013) @ (NEN) &) (icl, (© (cock (a) (CORI Red precipitate is obtained when ethanol solution of dimethylglyoxime is added to ammoniacal Ni(IN). Which of the following statements is not true (CBSE PMT (Mains) 2012), (@)_ Red complex has a square planar geometry (b) Complex has symmetrical H-bonding (© Red complex has a tetrahedral geometry (@) Dimethylglyoxime functions as bidentate ligand on Hyc-can Simedylahorine= dy ~ou. Low spin complex of d®—cation in an octahedral field will ‘have the following energy {CBSE PMT (Main) 2012] =2, @ “Basse o to Ba,+2r @ Zaye 3°" so” (Aq = Crystal Field Spliting Energy in an octahedral field, P= Electron pairing energy) (Crystal Geld stabilization energy fr high spin ocuhedral complex is (CBSE PMY (Pre) 2010; NEET (Karnataka) 2013] (@) 064, (b) -184, (© 1645 +P @ -124, ‘Among the following complexes the one which shows Zero ‘rysil field stabilization energy (CFSE) is (CBSE PMT2014) (a) [Co(#,0)4]" (by [Co(H 0.1" (© (tn H,0),P" @ (FeUt,0),1" ‘The hybridization involved in complex [/Vi(CN), is (ALNo. 8) IAIPMIT(Cancted) 2015] (a) dsp? &) sp" fe) dsp? (d) dsp’ Jahn-Teller effect is not abserved in high spin complexes of [NEET (Phase-11) 2016) we wa od wd Which of the following isa acid ligand IKCET 1 @ NH, ) co or (@) Ethylene diamine ‘Among the following, the species having square planar geometry for central atom are @ XeF Gi) SF Ga (Nic ivy (Pac {ams 2006) (a) Gand Gv) (b) Gand Giy (© Giana Giiy @) Giiyand vy Which of the following compounds is coloured [ATIMS 2008), @ Tcl, (b) FeCl, © Coc, (@) Alot uese B. 2. ‘Which has square planar geometry [DCE 2001, 6; CPM 2010], (a) [PUNHS)2Cle] ©) [MCN (€)_ Both (a) and >) (@)_ None of these ‘Which of the following complexes are not correctly matched ‘withthe hybridization oftheir central metal ion () [NKCO),|5p" (i) IUCN), ap? il) (CoF)- a? =p? Gv) LFe(CN) Ppa? Select the correct answer using the codes given below (Kerala PET 2006] (a) @and Gi) () Gand Gity (©) Gijanddiv) @) Cid) and Gy ©) id, Gi and Gy The correct statement with respect to these complexes Ni(CO), and (NIKCN),T™ is (Kerala PET 20111 (2) "Nickel i in he same oxidation state in both (6) Both have ttrhedel geometry (©) Both have square planar geometry (@) Have square planar and tetrahedral geometry respectively (@)_ Have tetrahedral and square planar geometry respectively Hybridisation in (Co(NH,),}" is [ASU 2006; DUMET 2010] © 9 0) apa © dsp ©) spa? ‘What is (re) number (6) of unpaired electrons in the square planar [P1(C¥),F* ion (AMU (fed) 2009) (@ Ze0 ot © 4 @ 6 Which complex of Co? will have the weakest erystil eld spliting IDUMET 2010; AMU (Engg, 2010) (a) (CoKEN) (b) [Coch (© (Cotens]" (@) (Co(H,0)," ‘e-bonding isnot present in (MP PET 2003; AMU (Med) 2012] (@) Grigoard reageavTetamethy lead (©) Dibenzene chromium (©) Zeise's sal (@) Ferrocene ‘Which one ofthe following is wrongly matched [DMP PMT 1997; KCET 2002, 10) (2) (Cu(NH,),1* ~ square planar () [¥i(CO),]~ new ligand (©) [FACN),* =p? (@) (Colem,)* — follows EAN rule ‘Which ofthe following is not te for metal carbonyls IMP PET 19931 (@)_ The oxidation state ofthe metal in the cazboayls is 2er0 () ‘The secondary carbonyls are obtained from_photo- decomposition (©). Mela carbonyls are single bonded species (@) dx-= pr overlap is observed in metal carbonyls ‘The strongest ligand inthe following is IM PET 19951 @ or 0) Be © Ho @F 858 Coordination Chemistry 2. 31. 2 INWCN),F. (MB J and [FeF,P-. Geometry, hybridisation and magnetic moment ofthe ions respectively are TMP PET 200; Oda TEE. 2008) (@) “Tear, square planar, octahedra sp" dsp? sp'd? [Link] (b) Tetrahedral, square planar, octahedral: dsp? sp’.sp'd* 05.949 (©) Square planar, Tetrahedral, octahedral: dsp? sp’. d sp’ :59.490 (@) Square planar, Tetraeda, octahedra: dsp? sp? sp'd? 05949 Which complex compound obeys 18-electon rule IMPPET 200] (@) (CO)s1 (b) (Fe(H15),1 (© IWiCO),) (@) (MntH,0),)" ‘Which ofthe following molecules is not tetrahedral [MP PET 2011) (@) [Penh ©) (NKCO)} (©) (20NH))* @) (NICK ‘Which one ofthe following complexes is paramagnetic (ReMcr 1997) (a) (CoF,)” 0) (Co(H:0)] (©) (CoF HO) (@) Allof hese One mole of the complex compound Co(NH,),Cl, gives 3 ‘moles of ions on dissolution in water. One mole of the same complex reacts ith two moles of AgNO, solution to yield 1wo moles of AgCI(s) The structure ofthe complex is [AIEEE 2003) (©) ICoNH) ENC ——(P)- (Co(NH),C1,]. 2H; (©) [Co(NH,)4CHICINH, (A) (Co(NH,),CTCI,.NE Nickel (Z = 28) combines with a uninegative monodentate ligand X~ 10 form a paramagentic complex [NiX,]>. The ‘number of unpaired electrons (s) in the nickel and geometry of this complex ion are, respectively [ATEEE 2006] (2) One, tetrahedral (b) Two, tetrahedral (©) One, square planar (d)- Two, square planar ‘Which one ofthe following has a square planar geometry IAIEEE 2007] (@) (Coc. (b) (FeCl. (©) (NICK @) [PCA Which of the following facts about tho complex ICr(NH), IC, 8 wrong, [AIEEE 2011] 'sp" hybridization and is (2) The complex involves ‘octahedral in shape (b) The complex is paramagnetic (c)_ The comples is an outer orbital complex (2) The complex gives white precipitate with silver nitrate solution The number of unpaired electrons calculated in ICo4Nts)g)" and (CoF,)™ are (VTTEEE 2008) (@ 4ana4 () Oand2 (© 2and4 @) Oana a 2, In the complex [SF,|".sp'd hybridization is present. Geometry of the comple is Pb, PMT 2000] (@) Square pyramidal —_(D)_ Square bipyramidal (©) Tatrahedral (4) Square planae ‘Which of the following shell form an octahedral complex {ce 2001) a low spin) (©) a*ebigh spiny © a dow spin) (4) None of these Hybridization of Fe in KyFe(CN), is we 2002] (a) sp (>) dsp? 4) sp'd® @ dsp! ‘An octahedral complex is formed, when hybrid orbitals of the following type ate involved wce 2003} (a) sp" () dsp* © sa (spd ac | yo Seabees >I ee > @ cis ©) trans © mer (@) fac Ta which ofthe following complexion, the central metal ion is ina sate of p'f hybridization IRCET 206] ta) [cor (b) (CoWWH 6 ©) [Feeny, (@) [Cr Hy) QI Hybridization, shape and magnetic momen of K,(Co(CO,)s1 is {aisha SEE 2008) ©) d°sp?, oothedal, 49 BM. ©) sp'd?, ccthedral, 49 BM (©) dp, square planar, 49 BM. (@) tetrahedral, 4.9 BM “The crystal field stabilization energy (CFSE) i the highest for (DUMET 209] (Cor () (Coqwes),)* (©) (CONE dg)" @) (Coch? The magnitude of crystal field stabilization energy (CFSE of 8,) in tetrahedral complexes is considerably less than that in the octahedral field. Because (DUMET 2009], (a) There are only four ligands instead of six so the ligand Field is only 2/3 the size hence the A, is 23. (©) The direction of the orbitals does not coincide with the direction of the ligands, ‘This reduces the erystal field stabilization energy (A) by Further 2/3 (©) Both points (a) and (b) are correct (@)_ Both points (a) and (b) are wrong, In Fe(CO),, the FeeCOo bond results by the overlap between filled sp hybrid orbital of C—atom of CO molecule and vocant (DUMET 2010) @ asp © © ay? (8) dyy* hybrid orbital of Fe £860 Coordination Chemistry n. 2 ‘Which ofthe following complex ton has Yeast stability °. [GUICET 2014) (a) [CoKCn),)* (b) [CoH (©) [CotNHS)4]" (d) (CKCO),)" ‘Correct increasing order for the wavelengths of sbsorption in the visible region the complexes of Co” ig (NEET 2017], () [Cott O)g}"*. [Coens P*, [COANE II" 10, (©) (CoCH2O)4), [CoN]. [Coten)s]* (©) [CatNHtsdg I. LColemdg)*, [CoC 0),1" (@) (Coven) ,}*, (CotWH, 4] (Cot ,0).)" un. ‘Application of organometallics “The complex used asa anticancer agent is [AIMS 2003; CBSE PMT 2004, 14] or 2. Which one ofthe following coordination compounds is use (0 inhibit the growth of tumours Uerala PMT 2012] (@) trans -{CoANH)yCl4] (8) cis {PCI (NH)3] ©) cis-KPICBn]——) Mes, ‘Among the following, which i not the bonded organometallic compound {BSE POTr 2003; CPMtT 2010) @ (CHy)Sn 0) KUPICI In ~CHd (©) Fein? -CyHy)y () CHa Catto): Which ofthe following docs not have x metal carbon bond {ese PNET 2008) @) KIPHC HAIL) NHCO) © MOCHs (@) CytsMear Which of the fllowing is an organometallic compound TAINS 1997) ©) HOCH), @) TOC Dinethy!glyoxime gives a red precipitate with Mi, whichis used for is detection, To gt this precipitate readily the best pH i THC (© THOCOCH). range is TaTIMS 2008) @ (© (coeuy™ (@) [Co(H0),C1,) ‘The correct order forthe wavelength of absorption in the visible region is [aTIMs 2008) (a) [M(NOg)gI* Y 1 litre of mixuure X+ excess BaC, > Z [Number of moles of ¥ and Z are {HTT SEE 2003) (@ 001,001 () 0.02, 001 (© 001,002 (@) 002, 002 ‘The species having tetrahedal shape is Uurr 2006) (a) (Pact, Mb) (NHEM),) (©) PACH) @ [Nic ‘The spin magnetic moment of cobalt in the compound HelCHSCN As {rt 204 @ a by 4 © o The prot of oxidation of I with MnO in laine sium is (7 304 © 10; oh © 0 © 10; “The pair of the compounds in which both the metals are in the highest possible oxidation sate is [DTT Screening 2008) (2) FFACN Ig] ACOCN) 0) 610,01, Moog (9) Tid, Sno, (8) {Ce(C),]*. MnO, ‘Which pair of compounds is expected to show similar colour a aqueous medium (TT 2005} (2) FeCl, and CuCl, (©) VOC} and CuCl, (©) VOCI, and FeCl; (@) FeCl; and MnCl, Which kind of isomerism is exhibited by octahedral Co(NH, BrCl (ArT 2005) (2) Geometrical and ionization (by Geometrical and Optical (©) Optical and ionization (€)_ Geometrical only ”. 32. 5. 55. Ag? + NH, > [Ag(NH, IT :k, =3:5x107 [Ag(11,)]4 NET, > [Ag(NH oJ ko =1.7 x10" then the Formation constant of [Ag(NH)a]* is (ITT EE 2006) (a) 08x10 (©) 608x10° (©) 608x107 (@) None ofthese CuSO, decolourises on addition of KCN , the product is [a1 JE 2006) (@) (CuCN).P () Cie get reduced to form [Cu(CV),} © Cun); @ Cec ‘Among the following metal carbonyls, the C-O bond order is lowest in (arr 2007) (@) (MnCO)" @) [Fe(CO}s) (© [CACO] @ (MCOn The IUPAC name of [NiNH)JINICH] is [IIT JEE. 2008), (a) Tetrachloronicke (I) -tetrzamminenickel (11 () Tetraamminenickel (I) — tetrachloronickel (11) (©) Tetraamminenicke (I) tetrachloronickelate() (@)_Tetrachloronickel() ~ tetaamminenickelate (0) ‘Among the following , he coloured compound is [IFT SEE. 2008), @) cuct ©) KCUCND4} © Cu, (@ (CACHSCN) IBF, Among [Ni(CO),|-LNKCM),]”LNICI]” species, the hybridization states at the Ni atom are, respectively (UL JE 2008} © pap dg? dap pp! (©) sp’ dep? dsp? @) sp". dsp? sp” (At 00. of =28) ‘The spin only magnetic moment value (in Bob magneton units) of CrCO), is (0rT SEE 20091 @o ) 284 © 490 (@ 592 The comect structure of ethylenediaminetetnscetic acid EDTAVis [HT JEE 2010) HOC - CH, fH, COOH ay SS N- cH = CH=: © pooc- cH, 78-8 Noy. coon wooc coon ty DN CHC, NL ©) rooc 78 CHS coon HOOC-CH, cil, ~COOH © NCH; ~CH,~ © yooc-cn™ ‘e “H,-COOH “om i, Hooc-cH \ @ a bn cH et HEN C= on coon cH, Hooc’ ‘864 Coordination Chemistry The ionization isomer of [Cr(H,O),CUNO,)ICI is (IT sEE 2010) GO: LCRONLOSNCG: (BL MCHHRONCEING,) (©) [CH O),CKONONICL (A) [CHL#50),CL(NO,)IH0 The complex showing 2 spin-only magnetic moment of 2.82 Bais (HTT SEE 2010) @ NCO, @) bic (©) Ni(PP hy) 4d) (NEN), | Geometrical shapes ofthe complexes formed by the reaction of Ni with [Link]™ and H,0. respectively. are (Orr SEE 2011) (@) Octahedral, tetrahedral and square planar 46) Tetrbedral, square planar and octahedral ©) Square plata, tetrhedal and ectabedeal (8) Octabedral, square planar and tetera ‘Among the following complexes (K-P), Ks Fe(CN )g](K),[Co(NH 3)q]Cls (L), Nas{Coloxalate);} (Mt), [NH Og Cs (N).K4LPCN) (0) and {2n(H1,0)g](NO,).(P) the diamagnetic complexes are (arr SEE 2011) @) KLMN (b) K.M,O.P ©) LM0P @ LMAO [AS per TUPAC nomenclature, the name of the complex [Co(H,0),(NH,)>1Cl, is (1 JEE 2012) (a) Tetrsqudiasinecoba (I) chloride (©) ‘Tetranquadiamminecobalt (I) chloride (©) Diaminetetraaquacobalt (II) chloride (d)_Diamonineteiaaquacobalt II} chloride NiCI,(P(C;Hy)3(C,Hs))2 exhibits temperature dependent magnetic (paramagaetiidiamagnetic). The coordination geometries of Ni” in the paramagnetic and diamagaetic states ae respectively (unr see 2012] (@) Tetrahedra and tetrahedral (b) Square planar and square planar (6) Teerahedeal and square planar (d) Square plana and tetrahedral ‘Which ofthe following doesnot have optical isomer (EE (si) 2013] () (Cow) ,C4) ©) (Cotem, cl, (© (Coten),Ch}Ct @ (Colenyntty),Cta}Cl Consider the following complex ions, P,Q and R =LFeF,]", Q=1V(H.0)4]"" and R =1Fe(H,0)4)" The conect order of the complex ios, according to their spine only magnetic moment values Gn B.M,) is WEE (Advanced) 213) (@ RCr > Ru > Fe 0) V™> Rul > /CF" > Fe (©) CV > Ru > Pe (@) CP > Ru > Fe ov ‘The compounds that inhibits the growth of tumors is (UE (Main) 2019) 2) cis =[PAICIg(NH)s] (0) cit —[PHCI NH] ©) trams~[PHCI) ANH )a} (8) trans [PACH ANH, The calculated spin-only magactic moments (BM) of the anionic and cationic species of {Fe(H;O)gls and [Fe(CX),]. respectively, are EE (Main) 2019), (@) 49and0 () 2.84 and 5.92 ()0and4.9 (@) Oand5.92 866 Coordination Chemistry 100, “The degenerate orbitals of [Cr(H,0),]" are (SEE (Man) 2019] () dy and dy @ dyy and dy, ‘The one that will show optical activity is shane 1, 2-diamine) [JEE (tain) 2019] ve rs eet “The number of water molecules) not coordinated to copper ion directly in CuSO,5H,0, is (GEE (Main) 2019] @ 4 3 ©t @ 2 ‘The maximum possible demicities of « ligand given below towards a common transition and inner-transiton metal ion, respectively, are B00 Nyt boc \ coe” coe [HEE (stain) 2019) (@) 6ana8 () Sande (©) Sands (d) 6and6 “The species that can havea trans-isomer is (en=ethane-1, 2odiamine, ox oxalate) ©) Puemch) ©) [CremsonI? (©) [Zaten)Chy} (&) [t(em),Cy}* ‘Taree complenes, [eoCINH),F* 0, [Co(WH) HOY" (I) and cocnet,),)* a) absorb light in the visible region. The correct onder of the wavelength of light absorbed by them is (JEE (Main) 2019) (@ auy> o> ap (©) (b> ah>ah © a>@>an (a) am>an>@ ‘The INCORRECT statement is (@) The spin-only magnetic moments of [Fe(H.0) [CrtH4,0)6¥* are meaty similar (b) The spin-only magnetic moment of (Ni(NHs)4(20) 1" is283 BM (©) The gemstone, ruby, has Cr°*ions occupying. the octahedral sites of bey! (8) The colour of (CoCIUNH, gs violet a it absorbs the yellow tight [EE (stain) 2019) 103. 10s, 106, 107, The crystal field stabilization energy (CFSE) of Fe(H,0),]C and K.{NiCl,} respectively, are (EE (Mai) 2019), (@) -04dy and 08a, ) 049 and -1.24, (©) 24Ag and 128, ) 0.645 nd -084, ‘The complex ion that will lose its crystal field stabilization ‘enerey upon oxidation ofits metal to +3 stat is (Phen 2X5) = ignore pring energy) ‘4 EE (Maa) 2099) » (@) [Fetphen)s ©) (2aphem © (Wi¢phen 7 (8) [Co(phem By oxidation of Co™ into Co”. the CPSE value increases. Complete removal of both the axial ligands (along the c-axis) from an octahedral complex Jeads to Which of the following spliting pattems (lative orbital energies not on scale) (EE (Main) 2019] \ ies @ ,| do i tes dy ‘The coordination numbers of Co and Al in (Co(CI}en), ICI and. K4[AI(C30,)5}, respectively, are (en= ethane-t, 2-diamine) (SEE (Mai) 2019), (@ 3and3 () Gand 6 (© Sands (@) Sand3 Which ofthe following species is not stable (NEET 2019] (@ (Sif ©) (Geet) (©) (SMO), @ [SiC1.> “The manganate and permanganate ons ae tetahedal, due to INEET 2019) (a) The =bonding involves overlap of portals of oxygen with d~ orbitals of manganese (b) There isn bonding (©) The =bonding involves overlap of p—orbitls of oxygen with ~orbials of manganese (@) The bonding involves overlap of d—orbitls of oxygen with doris of manganese What isthe comet electonie configuration ofthe central stom in Kg{Fe(CN)q] based om crystal fd th am, oy @e we © ee w. a 2 2. 862 Coordination Chemistry How many unpaired electrons are preset in NE (ITE 198] @ 0 ) 2 @4 @ 8 ‘Sodium thiosuphate is used in photography because ofits (arr 1981 () Reducing behaviour (©) Oxidising behaviour (©) Complex forming behaviour (@)_ Reaction with ight In the metallurgy of iran, when limestone is added to the blast furnace, the calcium ion ends up ia (Orr 1982}, @ Shag (b) Gangue (©) Metallic ealeium (@) Calcium carbonate ‘Zinc-copper couple that can be used as a reducing agent is ‘obiained by (OTT 1984), (a). Mixing zine dost and copper gauze () Zine coated with copper (©) Copper coated with zine (2) Zine and copper wires welded together ‘Amongst the following, the lowest degree of paramagnetism ‘per mole ofthe compound at 268 K will be shown by (ET 1988) (@) MaS0,4H,0 () CuS0,5H,0 (©) FeS0,6H,0 (a) Nis0,6H,0 ‘Amongst Ni(CO),.[Ni(CN) } and NICIE™ rr ays (@)Ni(CO), and NICH ate diamagnetic and [NiCCN),}™ is paramagnetic (b) NICH and (Ni(CN)4)* are diamagnetic and NCO), is paramagnetic (©) Ni(CO), and [Ni(CN),]* are diamagnetic and NiCIy is paramagnetic (® Ni(CO) is diamagnetic and NICI?*and (NUCH), are paramagnetic “The compound which does no show paramagaetim is OTT IE 1992] (a) [Cu(NA )4}Cly () [Ag(NA) 210 © xo (@) NO, ‘Among. the following ions which one has the highest paranagnetism (HT SEE. 1993) (@) [CrH0)4)" (b) [FeCH;O)<1" © (Cutt,0," (8) (201,04 “The IUPAC name of (CoNE Cts is (@) Hexammine cobalt CD chloride (6) Hexammine cobalt (I) chloride (©) ‘riammine cobalt (ID treblorie (© None ofthese ‘The ype of magnetism exhibited by {Mat t1,0)41" ions UT SEE 1904) (2) Paramognetism (©) Diamagnetismn (©) Both) and.) (8) None of these Which pair gives Cts at room temperature tar 195) 9) HClege +KMnO, (0) NaCT+ SO sane (©) Nact Mads (8) NeCT+ HNO one a 2 ‘Which compound is formed when excess of KCN is aed 10 aqueous solution of copper sulphate tur 1996) (a) CHEN), ©) KylCuCN),) (©) KICMEN) 21 @) KylCutCW)} ‘Which compound does not dissolve ia hot, dilute 12NO, 07 1996 (a) Ags () Pos (©) Cus (a) cas {An aqueous solution of Fe50,,Al;(S0q), and chrome alum is heated with excess of Naj0; and filtered. The materials obtained oe (arr 1996) (a) Acolourless filtrate and a green residue (b) Ayellow filtrate and a green residue (€) A yellow fiteate and a brown residue (d) A green filtrate and a brown residue ‘Among the following, the compound that is both paramagnetic and coloured is. or 1997) (a) KxC,0, ©) (NH) (TIC, (©) CaSO, (@) KglCutCW) ‘Ammonium dichromate is used in some fueworks. The green coloured powder blown in the aris ‘arr 1997) (a) Cr0, ©) C0, © oF @) Cr010;) ‘Which of the following is an organometallic compound arr 1997) (2) Lithium methoxide (Lithium acetate (©) Lithimum dimethylamide (€) Methy ihium In the dichromate dianion, (a) 4Cr~0 bonds are equivalent () 6Cr—0 bonds are equivalent (6) All Cr-Obonds are equivalent (@) All Cr-Obonds are nonequivalent ‘The geometry of NCO), and NiCPPIy),C are (HT 1999) (2) Both square planar (b) Tetrahedral and square planar, respectively (@), Both terahedral (@). Square planar and tetrahedral, respectively ‘The complex ion which has no “electrons in the central metal rr 1999) atom is (rT 2001] (a) (Mao ©) [COONS gi (6) (FAC) (@) [crUHt,0),1" ‘Anhydrous feric chloride is prepared by rr 2002} (a), Heating hydrated ferric chloride ata igh temperature in a stream of ar (©) Heating metalic ion ina stream of dry chlorine gas {€) Reaction of metallic iron with hydrochloric acid (@)_ Reaction of metalic ion with ntsc acid ‘When MnO, is fused with KOH, a coloured compound is formed, the product and its colour is rr 2003) (2) KyMn0,, Purple green (@) KMnO,., Purple (6) Mn,0,, Brown (MnO, Block Coordination Chemistry 859 sh. Tn the complex fon (GWCNa™ the hybridization sate, Oxidation state and number of unpaired electrons of copper are respectively WB IEE 2016) (@) dsp 1,1 (0) $08 +1, 2e0 © wat @ dsp} 12,2010 “The shape of (Fe(CN I fon is (a) Hexagonal (©) Pyramidal (©) Octahedral @ Cetagonal Which ofthe fllowing statement is corect (2) [Cu(NH),}* is. acoouress ion (0) [ZnGH,0)4)* ions blue coloured (©) [Ni(CN),1* fom asa tewahedral shape (q) Nickel dimes] glyoxides is ed in colour Pick out he cont statement wi espet to [Ma(CH)) (NRE 2017 (@) Wis spd? hybridised and erahedral (©) ttis d?sp? hybridise and octahedral (©) Wis dip? hybridised and square planar (d) [tis sp’d? Ihybridised and octahedral Which one of he fling fos exis wasn and parmagevn el ine a tw) ror © cn} (e) Maoy- @) Mnoe Tae geommuy and magatc beavior of he complex [NKCO),) ate (NEET 2018) (Square paar geome and amagsec 0) Teva pomety and damage (© Square planar grorsty and puramegrtic (8) Teal geometry and prac ‘Complexes and complex stability In any fei salt, on adding potassium ferrocyanide, a prussian| blue colour is obiained, which is (CBSE PAT 1990: BIT 199 [BHU 2002; MP FOFT 2007; AFMC 2010 Or Ferric ions form Prussian blue coloured precipitate due to Pa PET 2015] © KFacw), (©) KF FCN) (0) [Link]), (©) FalFACN) gh ‘The sum of coordination number and oxidation number of the metal Min the complex [M(en)s(CyO,)ICI (where en is ethylenediamine} is IAIPMT (Canceled) 2015] @9 © 6 o7 @s ‘Cobalt (lf) chloride forms several octahedral complexes with ammonia. Which ofthe following will not give test for chloride jas with silver nitrate at 25°C (AIPM 2015] (a) CoC, ANH, () Cott, SNH, (©) CoC, 6nH, (@) Col, 3NH; Which ofthe following has longest C-O bonu length? (Free C= O bond length in COs 1.1284) INEET Phase) 2016] (a) NICO), (b) [Co(co),)° (©) [Fe(COn @ (MmCoyr ts 10. Mu 2 BB 4. 15. ‘AIF, is soluble in HF only in presence of KF. Irs due vo the formation of INEET (Phase 2016) (@) KAI ©) KAI HS] (©) KSLA @) aA; Complex salt can be made by the combination of [CoM (NH CHE with [RPMI 2000; Pb. CET 2001; AFMC 2003] @ Por © or (© 2cr (a 2K How many EDTA (thylenediaminetetracetic acid) molecules tate required to make an ectahedral complex with a Ca”*ion [AIEEE 2006; AFMC 2012] (a) Six ©) Taree (© One @) Two ‘A Solution containing 2.675 g of CoC, NA, (molar mas 267.5 mol") is passed through a cation exchanger. The Chloride ions obtained in soluion were treated with excess of AgNO, (0 give 4.78 g of AgCI (molar mass = 143.5 g mol”) ‘The formula ofthe complex is (At, mass of Ag =108 u) AIEEE 2010; Kerala PET 2011], (2) (CoCUNH,)s}C, ———(b) [COLNE ICy (©) (CoCIINHs)4IC1 (A) [CHCTACNFS)) ‘The most stable complex among the following is {MP PAT 2002) (@) KSANC00)5) (©) [Pelen)sICty © [Ag(WA)gICt (@)_K,INi(EDTA)] Silver sulphide dissolved in a solution of sodium eynamide to form the complex TAMU 1999] (@) NAAgCH)s1 (©) NaslAg(CMDa} (©) NaglAg(CW41 (8) NaglAgiC);} ‘The most stable complex among the following is TAMU (Med) 2010) @ (racy), ©) (FeCo),) © (NKCN)| @ (MKCN),)* ‘The most stable ion is (AIEEE 2002] (@) (FeOH),)* &) [FCI © (FAM), @) [FetHt,0),1" In the beown ring complex [Fe(H,0),(NO)|SO4, nitric oxide behaves as (WB JHE 20121 (@) Not (b) Neutral NO molecule © No (@ No™ Addition of excess potassium iodide solution 10 a solution of mercuric chloride gives the halide complex (WBJEE 2013), (a) Tetrahedral K,(Hal,] (6) ‘Trigonal KUHgh;) (©) Linear Hes! (@) Square planar K,LgCk,] Which of these statements about (Co(CA),)?~ i true [WB JE 2016] (@) [Co(CN),]"~ has four unpaired electrons and will bein a low-spin configuration (©) [Co(CN)_}"~ has four unpaired electrons and will be in a high-spin configuration (©) [Co(CN)g}"™ has no unpaited electrons and will be in a ‘high-spin configuration (@)(Co(CN)_}"~ has no unpaired electrons and will be in a low-spin configuration £856 Coordination Chemistry Which of the following complex will give white precipiate with Bact, (ag) UIPMER 19971 () (Co(NH,),5041NO, (0) {Cr(NH,),S0,1C7 (© [CANA CSO, —_ (A) Both and (0) In coordination compound [Coen CIs ICI which s fase (Werla CET 20051 (3) Show geometrical isomerism (b). Show opie isomerism (©) Show one isomerism (@) Acetabedal complex (©) Actinic complex ‘Which of the following complex does not show geometrical isomerism \ouscer 2071 (9 (COANH)«CIeI” OO) (FAN) (CDT © (cxon,!* () (Co(NH,)4(80,)51 Which of the following complex does not show optics! ikomerism (ouscer 214) (@ (Cr1C,0)5" tb) Cis] Pr( Br) (em), (©) (CHCTNMrsen}*——d) (CrEMIE SOT ‘Which would exhibit co-ordination som (©) (CAMHS )COLCNg] 0) [Coten) Cl} (@) (Crem sCh,)" (© (CANA) ,IC1, [Co(H,)4C1,]” exhibits (@) Geometric (© Bonding isomerism isomerism — (6) Optical isomerism (€) onisation isomerism Assertion Potassium ferrocyanide is diamagnetic whereas potassium fericyanide is paramagnetic Reason: Crystal field spliting in ferrocyanide ion is ‘greater than thal of ferricyanide fon, TAIIMS 2005] (2 If both assertion and reason are tue and the reason isthe correct explanation of the assertion. () If both assertion and reason are true but reason is not the comect explanation of the assertion. (© Tassertion is true but reason is false (@) Ifthe assertion and reason both ae false. (© Ifassertion i false but reason i true. Assertion: [CoNO3)s (NH) does not show optical Reason: Ithasaplane of symmetry. [ANIMS 2006] (@) If both assertion and reason are tue and the reason isthe comtect explanation of the asonion, () If both assetion and reason are true but reason is not the comect explanation of the asertion. (© assertion is true bat reason is false (@) Ifthe assertion and reason both are false (> Ifassertion i alse but reason is true. ‘The type of isomerism shown by the complex [CaCI (en);) is (NEET 2018) (©) Coordination isomerism (@) Linkage isomerism (2) Geometrical isomerism (© onization isomerism ‘86. Match the metal ions given in Column I withthe spin magnetic ‘moments ofthe ions given in Column Il and assign the correct ae {Neer 20 Taam Cama Al co* i | We aM. Bl a i | as eat CT] Fe ih | 3 Bw. De | it ew * [is om Ee re ee i om wi om oe Foo ‘Hybridisation and Geometry 1. AGCT precipitate dissolves in ammonia due to the formation of [ATIMS 1991; MP PET 1993; CBSE PMT 1998, MP PATT 19971 (@) [AgWNH) 3104 ©) (ASCH ICT (©) (Ag(NH) 10H (@) [AgvH,),1C1 2. Whit isthe shape of Fe(CO), tcRse Parr 2000), (@) Linear (©) Tetrahedsal (©) Square planar (@) ‘Teigonal bipyramidal 3. CW" isa strong fel ligand, This is due tothe fact hat [cBsE Parr 2004] (a) Heean accept electron from metal species () IL forms high spin complexes with metal species (6) Wearies negative charge (@) Wis a pseudobalide 4 Considering H,0 as a weak fold ligand, the number of "unpaired electrons in (Mn(F¥30)4]°* will be (At. 90. of Mn 25) IcBSE Part 2004) (@ Two () Four (© Tee (@) Five 5 Which one ofthe following i an incr orbital complex as well as diamagnetic in behaviour (Atomic number Zr Co=[Link]=28) (aN) © (crows (©) (CoN 6)” (@) NINH) 6 In which ofthe following coordination entities the magnitude Of (CFSE in octahedral field) willbe maximum [CBSE PMT 2008; AIEEE 2008) (@) (Cocen), ©) (CHKC.0)51" (© (CoHt,Or,1" (CoN) (Atomic no. Co= 27) 7. Name the typeof the structure of silicate ia which one oxyzen atom of {SiO,]* is shared {CBSE PO re) 201) (@) Tiweedimensional —_¢) Linear cain silicate ©) Shee silicate (@) Pyrosiicate {Which the following carbonyls wil have the strongest C-0 bond [CBSE POET (Mans) 2011) @ VCO, @) FCO), © Mucor; @) CHO,

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