ATOMIC STRUCTURE

1. The explanation of behavior of electron is more precisely explained by:

(a) Rutherford (b) Bohr (c) Heisenberg (d) Schrodinger
3+
2. The total number of electrons in one Ti ion
(a) 19 (b) 21 (c) 22 (d) 18
3. Total number of orbitals in a shell having principal quantum number “n” is:
(a) 2n (b) n2 (c) 2n2 (d) (n + l)
4. The probability of finding electrons along axes is maximum in:
(a) dx2-y2 (b) dz2 (c) dxy (d) All have same
5. An element M has an atomic number 9 and atomic mass 19. Its ion will be presented by:
(a) M (b) M2+ (c) M (d) M2
6. Two electrons present in same orbital can be distinguished by:
(a) Principal quantum number (b) Spin quantum number
(c) Azimuthal quantum number (d) Magnetic quantum number
7. A nodal plane is a surface on which the probability of finding the electron is:
(a) Zero (b) More than 95% (c) 50% (d) Infinite
8. Total number of d-electrons in an atom of atomic number 24 is:
(a) 2 (b) 4 (c) 5 (d) 6
2 2 6 2 3
9. 1s , 2s , 2p , 3s , 3p is electronic configuration of
(a) P3- (b) S2- (c) Si1- (d) Ar
10. Total number of orbitals for a given subshell can be calculated with the expression:
(a) 2n2 (b) 2l + 1 (c) 2(2l + 1) (d) n2
11. An orbital can accommodate a maximum of:
(a) 2 electrons (b) 6 electrons (c) 10 electrons (d) 14 electrons
12. Positive rays are produced:
(a) By the ionization of the gas (b) By cooling of the gas
(c) By burning of the gas (d) From anode
13. Positive rays give flash on:
(a) AgCl plate (b) ZnO (c) ZnS (d) AgNO3
14. Orbitals of the same energy are called:
(a) Generate orbital (b) Degenerate orbital (c) Schiff’s effect (d) Hybrid orbitals
15. Quantum numbers are derived from:
(a) Schrodinger wave equation (b) de-Broglie’s equation
(c) Bragg’s equation (d) Planck’s equation
16. A gas with minimum charge to mass ratio, when cathode rays are passed through it:
(a) Hydrogen (b) Oxygen (c) Nitrogen (d) Chlorine
17. Total number of p-electrons in an atom of atomic number 18:
(a) 4 (b) 5 (c) 6 (d) 12
18. An element “M” has atomic number 17, its ion will be presented by:
(a) M (b) M2+ (c) M (d) M2
19. The maximum number of electrons in a sub-shell with l = 3 is:
(a) 6 (b) 10 (c) 14 (d) 18
20. In planer d-orbitals the maximum probability of finding electrons is at:
(a) 0 (b) 45 (c) 90 (d) 180
21. The particle among following which has the same number of electrons as an alpha particle?
(a) H (b) H2 (c) H+ (d) He
22. Which of the following orbital is possible?
(a) 1p (b) 2d (c) 3f (d) 4s
23. The particle among following which contains 20 neutrons, 19 protons and 18 electrons:
(a) K+ (b) K (c) Ar (d) Ca2+
24. Which of the following specie on losing an electron, have a half-filled set of p-orbitals?
(a) C (b) O (c) N (d) O+
25. How many electrons in calcium have l = 0?
(a) 6 (b) 8 (c) 10 (d) 12
26. Opposite spin of electrons in an orbital was conserved by:
(a) Pauli (b) Bohr (c) Heisenberg (d) Schrodinger
27. The letter s, p, d, f are used to represent which quantum number?
(a) Azimuthal (b) Spin (c) Principal (d) Magnetic
28. A numerical value that describes about the number of orientation in a sub-shell is:
(a) Principal quantum number (b) Azimuthal quantum number
(c) Spin quantum number (d) Magnetic quantum number
29. The set of orbitals having n + l = 5 are:
(a) 2p, 3d, 3s (b) 3s, 4p, 4d (c) 3p, 3d, 5s (d) 5s, 4p, 3d
30. The ionization energy of an atom is the difference between:
(a) E2 E1 (b) E∞ E1 (c) E1 E∞ (d) E∞ En
31. The values of quantum numbers for the valence electrons of an atom are given by n = 2, l = 1,
m = 0, +1, 1, s = + . The given atom is:
(a) Lithium (b) Berylium (c) Carbon (d) Boron
32. The lightest atom with half filled 3d orbital in the ground state is:
(a) Cr (b) Mn (c) Co (d) Cu
33. Which of the following ions contains an unpaired electron?
(a) Ca2+ (b) Cu2+ (c) K+ (d) Fe2+
34. The electronic configuration of an atom which is iso-electronic with H2S:
(a) 1s2, 2s2, 2p6, 3s2 (b) 1s2, 2s2, 2p6, 3s2, 3p2
(c) 1s2, 2s2, 2p6, 3s2, 3p4 (d) 1s2, 2s2, 2p6, 3s2, 3p6
35. The element which has no paired p-electrons in its ground state:
(a) Carbon (b) Oxygen (c) Neon (d) Silicon
36. The maximum number of electrons in a sub-shell is given by the expression:
(a) 4l + 2 (b) 4l 2 (c) 2l + 1 (d) 2n2
37. The ratio of e/m values of a proton and an α-particle is:
(a) 2 : 1 (b) 1 : 1 (c) 1 : 2 (d) 1 : 4
38. If the value of principal quantum number is 3, the maximum number of value of magnetic quantum
number:
(a) 1 (b) 4 (c) 5 (d) 9
39. Two electrons present in same orbital can be distinguished by:
(a) Principal quantum number (b) Spin quantum number
(c) Azimuthal quantum number (d) Magnetic quantum number