1

SOLUTION : Worksheet -1

Choose the correct alternatives :

1) Value of Henry’s constant KH
(a) increases with increase in temperature (b) decreases with increase in temperature
(c) remains constant with change of temperature. (d) first increases, then decreases
2) The value of Henry’s constant KH is
(a) greater for gases with higher solubility. (b) greater for gases with lower solubility.
(c) constant for all gases. (d) not related to the solubility of gases.
3) KH value for Ar(g), CO2 (g), HCHO (g) and CH4 (g) are 40.39, 1.67, 1.83×10–5 and 0.413 respectively. Arrange
these gases in the order of their increasing solubility.
(a) HCHO < CH4 < CO2 < Ar b) HCHO < CO2 < CH4 <Ar
(c) Ar < CO2 < CH4 < HCHO d)Ar < CH4 < CO2 < HCHO
4) Scuba divers may experience a condition called ______. To avoids this, the tanks used by scuba divers are filled
with air diluted with _____ .
(a) Migrains, Hydrogen (b) Cramps, Nitrogen (c) Nausea, Oxygen (d) Bends, Helium
5) The relation between solubility of gas in liquid at constant temperature and external pressure is stated by :
(a) Raoults Law (b) Vant Hoff factor (c) Henrys law (d) Charles Law
6) Raoult’s law becomes a special case of Henry’s law when
(a) KH < p1o (b) KH = p1o (c) KH > p1o (d) KH < p1o
7) If the liquid A and B from ideal solution, then
(a) ∆ Hmix = 0 (b) ∆ Gmix = 0 (c) ∆ Smix = 0 (d) ∆Vmix > 0
8) Which one of the following is not the characteristics of liquid mixture benzene & toluene?
(a) ∆ Hmix = 0 (b) ∆ Gmix = 0 (c) psolvent = xsolvent × posolvent (d) ∆ Vmix = 0
9) ∆ Hmix > 0 for which of the following mixtures will show a positive deviation from Raoult’s law?
(a) Phenol & aniline (b) Chloroform & acetone (c) HNO3 & water (d) Methanol & acetone
10) On mixing 10 mL of acetone with 50 mL of chloroform, the total volume of the solution will be :
(a) < 60 mL (b) > 60 mL (c) = 60 mL (d) = 100 mL
11) An azeotropic solution of two liquids has boiling point lower than either of them when it :
(a) is saturated (b) shows positive deviation from Raoults Law
(c) shows positive deviation from Raoults Law (d) is ideal solution
12) Which one of the following binary mixtures forms an azeotrope with minimum boiling point type?
(a) acetone-ethanol (b) H2O-HNO3 (c) benzene-toluene (d) n-hexane-n-heptane
13) The azeotropic mixture of water (b.p.100°C) and HCl (b.p.85°C) boils at 108.5°C. When this mixture is distilled it
is possible to obtain
(a) pure HCl (b) pure water (c) pure H2O and pure HCl (d) neither HCl nor H2O in their pure states
14) Chloroform and acetone are added to each other, Raoult’s law shows negative [Link] does this
suggest?
(a) Exothermic reaction (b) Endothermic reaction (c) Zero change in enthalpy (d) None of these
15) If two liquids A and B form minimum boiling azeotrope at some specific composition then
(a) A–B interactions are stronger than those between A–A or B–B.
(b) Vapour pressure of solution increases because more number of molecules of liquids A and B can escape from
the solution.
(c) Vapour pressure of solution decreases because less number of molecules of only one of the liquid escape from
the solution.
(d) A–B interactions are equal to than those between A–A or B–B.
16) Which of the following is not the colligative property?
(a) Depression of freezing point (b) Elevation of Boiling point
(c) Osmotic Pressure (d) Lowering Of vapour Pressure
17) If the molality of a solution is doubled the molal depression constant (Kf) will be
(a) Doubled (b) Halved (c) Unchanged (d) Tripled.
18) Vant Hoff factor for Na2SO4,10 H2O solution assuming complete ionisation is
(a) 1 (b) 3 (c) 13 (d) 10
19) Which of the following 0.1m aqueous solution will have lowest freezing point?
(a) Al2(SO4)3 (b) C6H12O6 (c) C12H22O11 (d) KI
20) 0.01M solution of each Urea , Common salt and Sodium Sulphate are taken, the ratio of depression in freezing
point of these solution is
(a) 1: 1 : 1 (b) 1:2:1 (c) 1:2:3 (d) 2:2:3

Krishnendu Barik @ KVS

 2

21) Which of the following aqueous solutions should have the highest boiling point?
(a) 1.0M NaOH (b) 1.0M NH4NO3 (c) 1.0 M Na2SO4 (d) 1.0M KNO3
22) The experimental molecular mass of a solute is less than the actual molecular mass: The probable value for Vant
Hoff factor : (a) i=1 (b) i=0 (c) i<1 (d) i>1
23) The Vant Hoff Factor of 0.1M Ba(NO3)2 solution is 2.74. The degree of dissociation is
(a) 91.3% (b) 87% (c) 100% (d) 74%
24) Equal masses of m gram of following substances were dissolved in equal amount of water. Which of these will have
highest boiling point:
(a) Urea (NH2CONH2) (b) Glucose (C6H12O6) (c) Sucrose (C12H22O11) (d) All have same boiling point
25) Blood cells retain their normal shape in solution which are
(a) hypotonic to blood (b) isotonic to blood (c) hypertonic to blood (d) equinormal to blood
26) As a result of osmosis, the volume of more concentrated solution
(a) gradually decreases (b) gradually increases (c) is not affected (d) suddenly increases
27) The osmotic pressure of equimolar solution of glucose, NaCl and BaCl2 are
(a) Glucose < NaCl < BaCl2 (b) Glucose < BaCl2 < NaCl
(c) NaCl < Glucose < BaCl2 (d) NaCl < Glucose > BaCl2
28) People taking a lots of salt develop a swelling or puffiness of their tissues. The disease is called
(a) Edema (b) Anoxia (c) Bends (d) None of the above
29) Phenol dimerises in benzene having Vant Hoff factor 0.54 association. Its degree of association is :
(A) 0·54 (B) 0·46 (C) 0·92 (D) 0·27
30) When 1 mole of benzene is mixed with 1 mole of toluene The vapour will contain: (Given : vapour of benzene =
12.8kPa and vapour pressure of toluene = 3.85 kPa).
a) equal amount of benzene and toluene as it forms an ideal solution
b) unequal amount of benzene and toluene as it forms a non ideal solution
c) higher percentage of benzene
d) higher percentage of toluene

Answer the following questions in the space given below:

Q. Nirmal collected 10 ml each of pure water and ocean water. He observed that one sample labelled “P” froze at
0oC while the other “Q” at -1.3oC. Nirmal forgot which of the two, “P” or “Q” was ocean water. Help him
identify which container contains ocean water, giving rationalization for your answer.

Q. A student of class XII prepared 0.05 M Na2CO3 , 0.05 M KI, 0.05M glucose and 0.05M K4[Fe(CN)6] solution in
250 ml volumetric flask to measure the boiling point of each solution. While conducting experiment the student
found that he forgot to label the volumetric flask and labelled it as A, B, C and D arbitrarily.
With the observed following data help the student to identify the solution and give proper reason for your answer
Solution Boiling point
A 104.3o C
B 101.5oC
C 107.5oC
D 103.4oC

Krishnendu Barik @ KVS

 3

SOLUTION : Worksheet -2

In the following questions a statement of assertion followed by a statement of reason is given. Choose
the correct answer out of the following choices.
a) Both assertion and reason are true, and reason is the correct explanation of the assertion.
b) Both assertion and reason are true but reason is not the correct explanation of assertion.
c) Assertion is true but reason is false
d) Assertion is false but reason is true.
1) Assertion : Molarity is considered to better for expressing the concentration as compared to molality.
Reason : Molarity is temperature dependent but molality is independent of temperature.
2) Assertion (A) :The solubility of gases increase with increase of pressure
Reason(R): Raoult’s law gives the relation between pressure and solubility of a gas in a solvent.
3) Assertion : Concentration of Oxygen in blood of people living in high altitude is low.
Reason : Low atmospheric at high altitude.
4) Assertion: Aquatic animals are more comfortable in hot water than cold water.
Reason : Different gases have different KH value at same temperature.
5) Assertion : The tanks used by scuba divers filled with air are diluted with Helium.
Reason: Helium is a noble gas.
6) Assertion : In an ideal solution, Δmix H is zero.
Reason : In an ideal solution, A - B interactions are lower than A-A and B-B interactions.
7) Assertion: The components of azeotropic mixture cannot be separated by fractional distillation
Reason : Both the liquid have same boiling temperature.
8) Assertion : Two liquids nitric acid and water form a maximum boiling azeotrope when mixed in the ratio of
68% and 32% respectively.
Reason :Azeotropes are binary mixtures having same component in liquid and vapour phase.
9) Assertion. Cooking time is reduced in pressure cooker.
Reason. Boiling point inside the pressure cooker is raised.
10) Assertion : Vapour pressure of pure solvent decreases if non volatile solute is added to the solvent at a given
temperature.
Reason : Non volatile solute decreases the escaping tendency of solvent molecules to vapour phase
11) Assertion (A) : Addition of ethylene glycol to water lowers its freezing point.
Reason (R) : Ethylene glycol is insoluble in water due to lack of its ability to form hydrogen bonds with
water molecules.
12) Assertion (A) : NaCl is used to clear snow on the roads.
Reason (R): NaCl depresses the freezing point of water
13) Assertion : Elevation of boiling point of equimolal solution of Urea and Glucose in a given solvent is same.
Reason : Elevation of boiling point is a colligative property.
14) Assertion : Blood cell shrinks if placed in hypotonic solution.
Reason : Blood cell looses solvent molecules.
15) Assertion : Osmosis does not take place in two isotonic solutions separated by semi-permeable membrane.
Reason : Isotonic solutions have same osmotic pressure.
Answer the following questions in the space given below:
Q. A 5% (m/V) aqueous solution of NaCl (formula mass 58.5) is separated with fresh water through a
semipermeable membrane at 300 K as shown in the diagram given below :
(a) Mention the name of process shown in above
diagram?
b) What is the minimum pressure that is to be applied
by the piston on the solution side for the process to
occur?

Krishnendu Barik @ KVS