PT3 REVISION WORKSHEET
1. How does sprinkling of salt help in clearing the snow-covered roads in hilly areas? Explain the
phenomenon involved in the process.
[Link] is Van’t Hoff factor (i) for a compound undergoing tertramerization in an organic solvent?
3. Arrange the following in the increasing order of freezing point 0.1M Al2(SO4)3, 0.1M KCl, 0.1M
Glucose, 0.1M K2SO4
4. The molar mass of Sodium Chloride determined by elevation of boiling point method is found to
be abnormal. Why?
5. What is the elevation of boiling point of a solution of 13.44g of CuCl2 in 1kg of water?
[Link] solutions of NaCl and BaCl2 are prepared in water. Freezing pint of NaCl is found to be -
20C. What freezing point do you expect for BaCl2 solution?
[Link] mole fraction of Ethyl alcohol in its solution with Methyl alcohol is 0.80. The vapour pressure
of pure Ethyl alcohol at this temperature is 40mm of Mercury. What is its vapour pressure in the
solution if the solution is ideal?
[Link] do a solution of Phenol and Aniline exhibit negative deviation from ideal behaviour?
[Link] pure Ethyl alcohol cannot be obtained from rectified spirit even by fractional distillation?
[Link] two liquids A & B are mixed the volume of the resulting solution is found to be slightly
greater than sum of the volumes of A & B. Identify the type of deviation exhibited by the solution.
[Link] 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K.
Calculate the formula of sulphur (Sx). (Kf for CS2 = 3.83 K kg mol-1, Atomic mass of Sulphur = 32 g
mol-1)
12. Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells
in a solution containing (i) 1.2% sodium chloride solution? (ii) 0.4% sodium chloride solution?
(iii)Define ideal solution?
13)Calculate the freezing point of solution when 1.9 g of MgCl2 (M = 95 g mol-1) was dissolved in 50
g of water, assuming MgCl2 undergoes complete ionization.
14. Out of 1 M glucose and 2 M glucose, which one has a higher boiling point and why?
[Link] happens when the external pressure applied becomes more than the osmotic pressure of
solution?
15. 18 g of glucose, C6H12O6 (Molar mass – 180 g mol-1) is dissolved in 1 kg of water in a sauce pan.
At what temperature will this solution boil? (Kb for water = 0.52 K kg mol 1, boiling point of pure
water = 373.15 K)
[Link] the following phenomena with the help of Henry’s law. • (i) Painful condition known as
bends. • (ii) Feeling of weakness and discomfort in breathing at high altitude. • (b) Why soda water
bottle kept at room temperature fizzes on opening?
[Link] the mass of compound (molar mass = 256 g mol-1) to be dissolved in 75 g of benzene to
lower its freezing point by 0.48 K (Kf = 5.12 K kg mol-1). (Delhi 2014)
18. Why is the mass determined by measuring a colligative property in case of some solutes is
abnormal? Discuss it with the help of the Van’t Hoff factor.
19.A solution is prepared by dissolving 10 g of non-volatile solute in 200 g of water. It has a vapour
pressure of 31.84 mm Hg at 308 K. Calculate the molar mass of the solute. (Vapour pressure of pure
water at 308 K = 32 mm Hg) (All India 2015)
[Link] mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation
from Raoult’s law is shown by the resulting solution? What change in temperature would you
observe after mixing liquids X and Y?
[Link] aqueous solution of sodium chloride freezes below 273 K. Explain the lowering in freezing
points of water with the help of a suitable diagram.
1. How will the rate of the reaction be affected when (a) Surface area of the reactant is reduced, (b)
Catalyst is added in a reversible reaction, and (c) Temperature of the reaction is increased ?
2.F or a reaction 2H2O2------------→2H2O+O2 the proposed mechanism is as given below:
(i) H2O2 +I- --------→H2O +IO-(slow) (ii) H2O2+IO- ---------→H2O +I- +O2(fast)
(A)Write rate law for the reaction (B)Write the overall order of reaction (c) Out of steps(1) and
(2),which one is the rate determining step?
3. The decomposition of NH3 on platinum surface is zero order [Link] rate constant (k)is 4 x 10-3
Ms-1,how long will it take to reduce the initial concentration of NH3 from 0.1 M to 0.064 M?
4.A reaction is of first order in reactant A and of second order in reactant B. How is the rate ofthis
reaction affected when (i) the concentration of B alone is increased to three times (ii) the
concentrations of A as well as B are doubled?.
5. The rate constant for a first order reaction is 60 s-1. How much time will it take to reduce the initial
concentration of the reactant to its l/10th value?
6. For a decomposition reaction the values of rate constant k at two different temperatures are given
below : k1 = 2.15 × 10-8 L mol-1 s-1 at 650 K k2 = 2.39 × 10-7 L mol-1 s-1 at 700 K Calculate the
value of activation energy for this reaction.
7. Rate constant k for a first order reaction has been found to be 2.54 × 10-3 sec-1. Calculate its 3/4th
life,
8. The thermal decomposition of HCO2H is a first order reaction with a rate constant of 2.4 × 103 s-1
at a certain temperature. Calculate how long will it take for three-fourths of initial quantity of HCO2H
to decompose. (log 0.25 = -0.6021)
9. The rate constant for a reaction of zero order in A is 0.0030 mol L-1 s-1. How long will it take for
the initial concentration of A to fall from 0.10 M to 0.075 M?
10. Define the following : (i) Order of a reaction (ii) Activation energy of a reaction
11. For a reaction R → P, half-life (t1/2) is observed to be independent of the initial concentration of
reactants. What is the order of reaction?
12.. Define rate constant (K) Write the unit of rate constant for a zero order reaction.
13. Express the rate of the following reaction in terms of the formation of ammonia : N2(g) + 3H2(g)
→ 2NH3(g)
14. The rate constant for the first order decomposition of a certain reaction is described by the
equation logk (s-1) = 14.34 – 1.25 x 104 K / T i) What is the pre-exponential factor and energy of
activation for this reaction? ii) At what temperature will its half-life period be 256min?