Weakly Test Marks: 50

Chapter Details
Chemistry
Unit XII Chapters: 2

ANSWER KEY

Chemistry

Q.1 D Q.2 A Q.3 B Q.4 B Q.5 B Q.6 A Q.7 A Q.8 B

Q.9 C Q.10 A Q.11 C Q.12 D Q.13 A Q.14 D Q.15 C Q.16 A

Q.17 B Q.18 A Q.19 D Q.20 B Q.21 C Q.22 A Q.23 D Q.24 C

Q.25 C Q.26 C Q.27 A Q.28 B Q.29 A Q.30 B Q.31 C Q.32 A

Q.33 D Q.34 B Q.35 A Q.36 A Q.37 B Q.38 B Q.39 C Q.40 C

Q.41 D Q.42 C Q.43 B Q.44 D Q.45 A Q.46 C Q.47 A Q.48 B

Q.49 A Q.50 D

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 SOLUTION

Chemistry
Q.1 Which of the following formula Correct option: (B)
CORRECTLY gives the value of ΔTb = Tb – = 84 – 75 = 9 ºC = 9 K
ebullioscopic constant?
Correct option: (D)

Q.2 Calculate the freezing point depression of = = 100 g

solvent when 20 gram of nonvolatile
mol–1
solute with molar mass 60 g mol–1 is
dissolved in 1180 gram solvent. Q.6 5 g sucrose (molar mass = 342) is
(Cryoscopic constant of solvent is 1.18 K dissolved in 100 g of solvent, decreases the
kg mol–1) freezing point by 2.15 K. What is
Correct option: (A) cryoscopic constant of solvent?
Correct option: (A)
=

=
Kf =
= 0.33 K
Q.3 Henry’s law is a relation between = = 14.7 K kg
_______.
Correct option: (B) mol–1
Q.7 A solution of nonvolatile solute is obtained
Q.4 Calculate osmotic pressure exerted by a by dissolving 30 g in 120 g solvent has
solution containing 0.822 g of solute in boiling point elevation 7.2 K. What is the
300 mL of water at 300 K. (Molar mass of molar mass of solute if molal elevation
solute = 340 g mol–1, R = 0.0821 L atm constant of solvent is 2.77 K kg mol­–1
­ ?
mol–1 K–1) Correct option: (A)
Correct option: (B) M2 =
π=
=
=
= 96.2 g mol–1

Q.8 The molal elevation constant is the ratio

= 0.2 atm of elevation in boiling point to _______.
Correct option: (B)
Q.5 Calculate the molar mass of solute when
50 gram solute is dissolved in 150 gram ΔTb = Kb × m
solvent that boils at 84 ºC. (Kb for solvent ∴ Kb =
is 2.7 K kg mol–1 and boiling point of
where m = Molality of solution
solvent is 75 ºC)
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Q.9 Calculate the molality of solution of ∴ =
nonvolatile solute if depression in freezing
point is 3.72 K and cryoscopic constant is
∴ =
1.86 K kg mol–1.
Correct option: (C)
Freezing point depression (ΔTf) = 3.72 K W2(glucose) = = 2.25 g

Cryoscopic constant (Kf) = 1.86 K kg mol-1

Q.13 What is the molal elevation constant if
Molality (m) = one gram mole of a nonvolatile solute is
dissolved in 1 kg of ethyl acetate? (ΔTb =
Q.10 The vapour pressure of solvent decreases xK)
by 10 mm Hg if mole fraction of non- Correct option: (A)
volatile solute is 0.2. Calculate vapour M2 =
pressure of solvent.
Correct option: (A)
∴ Kb =
Relative lowering of vapour pressure, = x2
Now, W2 = one gram mole = M2 g
∴ = 0.2 W1 = 1 kg = 1000 g

∴ Kb =
∴ = 50 mm of Hg
= x K kg mol–1
Q.11 Molal depression constant for a liquid is
Thinking Hatke
2.77 °C kg mol–[Link] Kelvin scale its One gram mole solute dissolved in 1 kg solvent =
value is _______. 1 molal solution
Correct option: (C) When concentration of solution is 1 molal,
Caution elevation in boiling point (∆Tb) is equal to molal
ΔTf = Kf × m elevation constant (Kb).
Kf = Therefore, Kb = x K kg mol–1

ΔTf is the difference between two temperatures Q.14 Calculate the molar mass of solute in a
solution prepared by dissolving 1 gram
and hence its value will be the same in °C or in K.
Therefore, the numerical value of Kf will remain in 0.3 dm3 solvent having osmotic
pressure 0.2 atm at 300 K.
the same whether it is expressed in °C kg mol–1 or
in K kg mol–1.
Correct option: (D)
Q.12 15 × 10–4 kg urea dissolved in 1 lit of
M2 =
H2O and it is isotonic with 500 mL aq.
glucose solution. What is the amount of
glucose present in solution? (At. mass: C =
= 12, H = 1, O = 16, N = 14).
Correct option: (D) = 410 g mol–1
Isotonic solutions have same osmotic pressure. Q.15 van’t Hoff factor for aqueous
Now, π = monofluoroacetic acid is _______.
Correct option: (C)

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Degree of dissociation (α) = Among the given options, Ferric chloride ( )

has the highest van't Hoff factor (i = 4) as it

n=2
dissociates into four ions ( and 3 ) in
α= ∴ α=i–1
solution. Therefore, a 0.1 M aqueous solution of
i=α+1 Ferric chloride will have the highest boiling point
due to its greater number of ions in solution
Q.16 Calculate osmotic pressure of 0.2 M
compared to the other options.
aqueous KCl solution at 0°C if van’t
Hoff factor for KCl is 1.83. [R = 0.082 Q.20 According to Raoult’s law, relative
lowering of vapour pressure for a
dm3 atm mol–1 K–1]
solution containing a non-volatile solute
Correct option: (A)
is equal to:
π = iMRT
Correct option: (B)
= 1.83 × 0.2 × 0.082 × 273
For a solution containing a non-volatile solute, relative
= 8.2 atm lowering of vapour pressure,
Q.17 Calculate the molar mass of nonvolatile
solute when of it is dissolved in = x2 = Mole fraction of solute

600 g water at 30 °C. [Relative lowering

of vapour pressure = 0.03] Q.21 van’t Hoff factor of centimolal solution
Correct option: (B) of K3[Fe(CN)6] is 3.333. Calculate the
= = percent dissociation of K3[Fe(CN)6].
Correct option: (C)
K3[Fe(CN)6] 3K+ + [Fe(CN)6]3–

∴ n=4
Degree of dissociation (α) =

Q.18 A solution of 5.6 g nonvolatile solute in = = 0.78

50 g solvent has elevation in boiling point
∴ Percent dissociation = 0.78 × 100 = 78%
1.75 K. What is the molar mass of solute
(Kb = 3 K kg mol–1)? Q.22 Calculate the Henry's law constant at 25
°C if solubility of gas in liquid is
Correct option: (A)
at 0.18 bar.
M2 =
Correct option: (A)

= = 192 g mol–1 KH = = = 0.1166 mol

Q.19 Identify the compound amongst the dm–3 bar–1

following of which 0.1 M aqueous Q.23 Which among the following salts
solution has highest boiling point. dissolves in water with the absorption of
Correct option: (D) heat?
The boiling point elevation of a solution is directly Correct option: (D)
proportional to the molality of the solute and the Dissolution of Na2SO4, CaCl2 and Li2SO4∙H2O in
van't Hoff factor (i). The van't Hoff factor water are exothermic processes while dissolution of
represents the number of ions a compound KCl in water is an endothermic process.
dissociates into when dissolved in a solvent.
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Q.24 Find the molality of solution if boiling
point increases by 1.75 K and molal
elevation constant of solvent is 5 K kg
mol–1.
Correct option: (C)
ΔTb = Kb × m

∴ m= = = 0.35 mol kg–1

Urea has higher solute concentration (0.1 M) than
sucrose (0.05 M).
Q.25 Which of the following salts of same
Thus, urea solution is hypertonic to sucrose.
concentration will have same value of
van’t Hoff factor as that of Q.29 What is vapour pressure of a solution
K4[Fe(CN)6]? containing 2.4 g urea in 10.8 g of water?
Correct option: (C) ( = 400 mm Hg, atomic mass of: C =
Assuming complete dissociation,
12, H = 1, O = 16, N = 14)
van’t Hoff factor (i) for K4[Fe(CN)6] = 5
Correct option: (A)
(A) MgSO4, i = 2 (B) Na2SO4, i = 3
(C) Al2(SO4)3, i = 5 (D) A(NO3)3, i = 4

Q.26 What is mole fraction of solute in the

∴
solution if vapour pressure of pure
solvent is 25.8 mm Hg and vapour
∴ 400 – P1 = 26.67
pressure of solution is 24.1 mm Hg at 30
∴ P1 = 400 – 26.67 = 373.33 mm Hg
°C?
Correct option: (C) Q.30 What is the unit of molality?
x2 = Correct option: (B)

∴ x2 = Q.31 Which of the following solutions on

complete dissociation exhibits maximum
elevation in boiling point?
Correct option: (C)
Q.27 Identify the CORRECT statement from Moles of particles in 1
Solution
the following: kg solution
Correct option: (A) (A) 0.1 m KCl 0.2
(B) 0.05 m NaCl 0.1
(C) 0.1 m BaCl2 0.3
Q.28 Which from the following statements is
(D) 0.1 m MgSO4 0.2
correct for aqueous solution of
0.1 m BaCl2 solution has maximum number of
urea and of sucrose?
particles in solution, so it exhibits maximum
[Molar mass of urea = 60 g mol–1 Molar elevation of boiling point.

mass of sucrose = 342 g mol–1] Q.32 38.4 g of unknown substance (molar

Correct option: (B) mass 384 g mol–1) and 116 g of acetone is
used to prepare a solution at 313 K. If
vapour pressure of pure acetone (molar

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 mass 58 g mol–1) is 0.842 atmosphere, Q.35 The van't Hoff factor (i) for a dilute
what is the vapour pressure of solution? aqueous solution of the strong electrolyte
Correct option: (A) barium hydroxide is _______.
Correct option: (A)
n2 = = 0.1 mol
On complete dissociation, barium hydroxide
Ba(OH)2 gives three ions. Hence, van’t Hoff factor
n1 = = 2 mol
(i) is 3.
Mole fraction of solvent (x1) Q.36 Which among the following values of
concentration has same values of ΔTb
= = 0.95
and Kb?
By Raoult’s law, the vapour pressure of the Correct option: (A)
solution is given by
P1 = = 0.842 atm × 0.95 = 0.7999 atm Q.37 What is molar mass of solute if 50 gram
of it in 150 gram solvent has boiling
Q.33 Which among the following solution has
point elevation of 5.54 K? (Kb = 2.77 K
minimum freezing point depression
assuming complete ionisation? kg mol–1)
Correct option: (D) Correct option: (B)
=
Total particles in solution = 0.2 mol
= 166.6 g mol–1

Total particles in solution = 0.4 mol Q.38 Calculate the molar mass of solute when
2 gram solute dissolved in 80 gram of the
solvent elevates the boiling point by 0.5
Total particles in solution = 0.3 mol
K. (molar elevation constant of solvent is
3.5 K kg mol–1)
Total particles in solution = 0.15 mole
Hence, 0.05 m CaCl2 solution has minimum moles and Correct option: (B)

particles. Hence, it shows minimum freezing point M2 = =

depression.

Q.34 Calculate the molar mass of solute when = 175 g mol–1

1.5 gram non-volatile solute dissolved in Q.39 What is the molality of solution of a
100 mL solvent having density 0.8 g mL– nonvolatile solute having boiling point
1 lowers its freezing point by 0.75 K. elevation 7.15 K and molal elevation
(Freezing point depression constant for constant 2.75 K kg mol–1?
solvent is 5 K kg mol–1) Correct option: (C)
Correct option: (B) ΔTb = Kb × m
Mass of solvent = density × volume ∴ m= = = 2.6 mol kg–1
= 0.8 g mL–1 × 100 mL = 80 g

M2 = Q.40 Which of the following solutions will not

show flow of solvent in either direction
when separated by semipermeable
=
membrane?
Correct option: (C)
= 125 g mol–1

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 and = 24 mm Hg, molar mass of urea = 60

g mol–1)
Correct option: (B)

Now, nurea = nsucrose

∴ πurea = πsucrose
Hence, if these solutions are separated by a ∴
semipermeable membrane, there is no flow of
solvent in either direction. ∴ P1 = 21.33 mm Hg ≈ 21.6 mm Hg

Q.41 The solution containing 18 g dm–3 Q.44 Calculate Henry’s law constant if
glucose (molar mass 180) in water and solubility of nitrogen gas in water at
another containing 6 g dm–3 of solute A 25°C is 6.85 × 10–4 mol dm–3.
in water boils at same temperature. [Partial pressure of nitrogen gas = 0.9
What is molar mass of A? bar]
Correct option: (D) Correct option: (D)
As boiling points of both the solutions are same, S = KH × P
they must have same molality. ∴ KH =
∴ mglucose = mA

= 7.6 × 10–4 mol dm–3 bar–1

Q.45 Find the molar mass of solute when 2
Considering weight of water is same in both gram dissolved in 60 gram benzene at
solutions, 30°C and relative lowering of vapour
∴ = 60 g mol–1 pressure is 0.06. (Molar mass of benzene
is 78 g mol–1)
Q.42 Calculate the partial pressure of oxygen
Correct option: (A)
if its solubility in water is 3.2 mg dm–3. Relative lowering of vapour pressure,
(KH = 2 × 10–3 mol dm–3 atm–1)
Correct option: (C)
Solubility = 3.2 mg dm–3 = 3.2 × 10−3 g dm–3
∴ 0.06 =
Solubility in mol dm–3

= ∴ M2 = = 43.3 g mol–1

S = KH P
Q.46 A solution of nonvolatile solute is
∴ P= = obtained by dissolving 15 g in 200 mL
water has depression in freezing point
0.75 K. Calculate the molar mass of
solute if cryoscopic constant of water is
1.86 K kg mol–1.
Q.43 What is vapour pressure of a solution
Correct option: (C)
containing 6 g urea in 16.2 g of water? (

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M2 = Thinking Hatke
Since solubility of a gas (S) in a liquid is equal to
KH, pressure of the gas over the solution is 1 bar.
=
Q.50 A 5% solution of cane sugar (molar mass
= 186 g mol–1 342) is isotonic with 1% solution of non-
electrolyte substance X, the molar mass
Q.47 Which of the following solutions shows
of substance X is:
positive deviation from Raoult’s law?
Correct option: (D)
Correct option: (A)
Solution of non-electrolyte is isotonic with solution of
cane sugar.
Q.48 What is the unit of cryoscopic constant? ∴ Molarity of cane sugar solution = Molarity of non-
Correct option: (B) electrolyte solution
Molarity of cane sugar solution

Q.49 Calculate the pressure of gas if the = M

solubility of gas in water at 25°C is 6.85
∴ Molar mass of non-electrolyte =
× 10–4 mol dm–3.
(Henry’s law constant is 6.85 × 10–4 mol
dm–3 bar–1)
Correct option: (A) =
Henry’s law: S = KHP
=
∴ P= =1

= 68.399 g mol–1
bar
= 68.4 g mol–1

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