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Melting Point and Thermal Physics Insights

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3 views3 pages

Melting Point and Thermal Physics Insights

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anonymouslmaoo69
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Cambridge International AS and A level Physics

4 a They pass through the ionosphere with little reflection and iii thermal vibrations of the atoms of the material; electrical
can carry large amounts of information. interference (for example, wire acts as aerial); induced
b To prevent the satellite’s high power transmitted signal emf caused by change in magnetic field
swamping reception of the very low power signal received ⎛ signal power ⎞
iv 10 lg ⎜
from Earth. ⎝ noise power ⎟⎠
c Space wave to satellite, sky wave reflected from ionosphere, v increases as the signal reduces and the noise remains,
surface wave travels direct. approximately, constant
d Ionospheric reflection varies as layers of ions vary in height b i 1.52 mW
and density according to the time of day.
ii 27 dB
5 Optic fibres have a wide bandwidth and large transmission iii 4.5 km
capacity. Signal power losses are relatively small and allow longer c i less attenuation with fibre optic cable; longer distance
distances between regenerator amplifiers. The diameter, weight before signal attenuated to minimum acceptable signal;
and cost of fibre optic cables are much less than those of metal also, noise may be lower on an optic fibre
cables. Optic fibres have negligible ‘cross-talk’ and do not pick
ii larger bandwidth; larger transmission capacity; smaller
up electromagnetic interference.
diameter, weight and cost; negligible ‘cross-talk’; less
electromagnetic interference/noise
Exercise 20.4 Attenuation
1 a 2.0
Chapter 21:
b 15.8

2 a 190 or −190 dB
Thermal physics
b Logarithm provides a smaller number or attenuation in series
is added when using logarithms.
Exercise 21.1 Kinetic model and internal energy
1 a most closely together: solid
3 20 dB farthest apart: gas
4 3.0 × 10 −14 W b They vibrate with greater amplitude; their velocity is greater
34
5 a 6.0 × 10 −2 mW or 6.0 × 10 −5 W as they oscillate through the midpoint of their oscillation.
b 49.6 km c attractive
d Potential energy increases as particles are pulled apart;
6 a 4.6 × 10 −4 W energy is being added to the material.
b 7.3 × 10 −3 W e greater separation: greater potential energy
7 a 240 dB greater speed: greater kinetic energy

b six 2 a greater amplitude of oscillation


b greater separation
Exam-style questions c The potential and kinetic energies of the atoms have
increased.
1 a Amplitude of carrier wave varies in synchrony with the
displacement of the information signal. 3 a B
b i spectrum A as only the carrier wave is present b More molecules in B have sufficient kinetic energy to escape
ii spectrum C as the carrier and one signal in the two from the surface of the water.
sidebands is present c Evaporation means that the molecules with the highest
iii spectrum B as the carrier and two sidebands are present; kinetic energies escape, so the average kinetic energy of the
music has a number of different frequencies and thus molecules remaining in the liquid decreases.
different lines in the sidebands d More molecules escape initially from B (see answer to b), so
c i 200 kHz the average kinetic energy of the molecules remaining in the
liquid decreases more quickly.
ii 3.0 kHz
iii 12 kHz 4 a average speed of the particles increases
d disadvantages: more noise; more interference; less b total kinetic energy increases
bandwidth; lower quality c temperature of the gas increases
advantages: longer range; fewer repeaters or transmitters d a force is doing work
needed; less complex electronics; cheaper
e 2.4 J
2 a i the gradual loss of power along a wire
ii thermal energy lost in the wire
Answers

f work done = area under the force–distance graph e Non-linear: graph of voltage against temperature is not a
straight line.
area = work done
Calibration: setting of a scale of measurement by testing
known values and recording the response (for example
finding fixed temperatures such as melting and boiling
points of water).
Force

4 a absolute zero, 0 K and −273.15 °C


b Water can exist in solid, liquid and gas forms at this
temperature.
c 273.16 K and 0.01 °C
Distance moved
Exercise 21.3 Energy change calculations:
5 a ΔU = change in internal energy s.h.c. and s.l.h.
q = energy supplied by heating
1 a c = specific heat capacity in J kg−1 K−1
w = energy supplied by an external force doing work; all
E = energy supplied in J
in joules (J).
m = mass in kg
b Δ U = 700 kJ Δθ = increase in temperature in K (or °C)
c w = 12 J b 1260 J
q = −4.0 J
c 8 °C
Δ U = 8.0 J
6 a from B to A 2 a energy lost by the steel = mcΔθ = 5 × 450 × (200 – X)
b Energy is being transferred continually both from A to B and b energy gained by the water = 50 × 4200 × (X – 20)
from B to A, but more is moving from B to A. c 5 × 450 × (200 – X) = 50 × 4200 × (X – 20)
c A and C, because they are at the same temperature. d 450 000 – 2250X = 210 000 X – 4200 000; X = 21.90 °C
d A and C, because the net transfer of energy between them will e Heat the material. Drop it into water. Measure the final
temperature. 35
be zero.
e All three temperatures will be the same. Need to measure: initial temperature of the material and of
the water, final temperature of water + material, and the mass
of the material and of the water.
Exercise 21.2 Thermometers and temperature
Need to know: the specific heat capacity of water.
scales
3 a temperature increase = 13 °C in 200 s.
1 a i 273 K
b energy supplied = 12 000 J
ii 373 K
c specific heat of copper = 12 000 / (2.00 × 13) = 462 J kg −1 K−1
iii 800 K
d The graph curves at higher temperatures; energy is being lost
iv 77 K to the surroundings so the block’s temperature rises more
b i −273 °C slowly.
ii −73 °C e The true value is likely to be lower; the heater has had to
iii 77 °C supply extra energy because of the energy that escapes into
the surroundings.
iv 727 °C
c 400 K = 127 °C so is greater than 125 °C 4 a L = specific latent heat in J kg −1
d 20 K E = energy supplied in J
m = mass in kg
2 a 25 °C
b specific = per unit mass (i.e. per kg); fusion = melting (change
b 3000 Ω
of state from solid to liquid)
c The thermistor has greater sensitivity (is more sensitive) close
c 3300 J
to 0 °C because its resistance decreases by a greater amount
for each degree rise in temperature than at 100 °C. 5 a six
3 a thermocouple thermometer b Number reduces as material becomes a liquid; reduces to
zero as it becomes a gas.
b thermocouple thermometer
c Less energy is required to make the atoms separate a little,
c thermistor
as in the change from solid to liquid, than to make the atoms
d Smaller amount of energy needed to change voltage; fewer separate completely as in the change from liquid to gas.
particles to be affected.
Cambridge International AS and A level Physics

Exam-style questions 4 a Volume increases.


b
1 a 185 °C
b Total kinetic energy is constant.
c Potential energy is increasing.
d Internal energy is increasing.
e Rate at which energy is supplied

Volume
f The metals should be solids for the full range of normal room
temperatures, so as to remain solid in use. They should both melt
at relatively low temperatures, to minimise the amount of energy
required to make them liquid. They should have significantly
lower melting points than the metal used to make the wires, so
the liquid solder does not melt the wires. They should be good
electrical conductors (although all metals are).
0
2 a specific latent heat of vaporisation: the energy required per 0 Temperature / K
kilogram to change a liquid to a gas without any change in
temperature c It will condense before it reaches 0 K, so its volume will
b 12 500 J suddenly decrease rapidly.
d 0.064 m3
c L = 12 500 × 10 −3 = 2.9 × 106 J kg−1
4 31
5 a constant = nR
d For example: energy conducts downwards into balance;
unit = J K−1
energy radiates from beaker; energy lost by convection
currents rising from sides of beaker. b 46.67 J K−1
e Estimated value for L is an over-estimate; less than 12 500 J would c 4.91 × 105 Pa
be required to evaporate 4.31 g, so value of L would be smaller.
d 421 K = 148 °C

36
Chapter 22: Exercise 22.2 The kinetic model of a gas
Ideal gases 1 a The molecules of the air are too small to be seen in visible
light.
Exercise 22.1 Ideal gases b particles of smoke, reflecting light into the microscope
1 a p = pressure (Pa) c The molecules of the air are colliding with the smoke
V = volume (m3) particles, repeatedly changing their momentum.
n = number of moles (mol) d The speed of the smoke particles is much less than the speed
R = universal molar gas constant (8.31 J mol−1 K−1) of the molecules of the air. The smoke particles have much
T = thermodynamic temperature (K). greater mass, since the KEs of the two types of particle are
similar, the air molecules must be moving much faster.
b Boyle’s law relates p and V; n, R and T are constant (mass is
constant since n is constant). 2 a The total volume of the particles is much less than the total
c n; mass = n × molar mass. volume of the box.
b The particles of a gas attract one another, but this is only
2 a 0.015 mol significant when they are very close together. They do not
b 4.0 g influence each other between collisions.
c 2820 mol c They move with constant velocity (constant speed in a
straight line).
3 a 3200 × 103 Pa
d The collisions between particles are elastic; the total kinetic
b energy of the particles is constant.

3 a 500 kg m s −1
1000 kg m s −1
Pressure

b
c time interval = 0.004 s
frequency = 250 Hz
d 250 000 N
e 250 000 Pa
0
0 Volume f the same (250 000 Pa)

c 3.2 mol g one-third; 83 300 Pa

Common questions

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During a phase transition, the temperature of a substance remains constant because the energy supplied is used to change the structure of the substance, specifically breaking intermolecular forces, rather than increasing the kinetic energy of its molecules. In the case of melting, for instance, energy is absorbed to overcome solid-state bonding without raising temperature .

The efficiency of converting thermal energy into kinetic energy in engines is determined by factors like the nature of the working substance (e.g., specific heat capacity), the temperature difference across the engine, and the energy losses due to friction, heat, and incomplete combustion. Thermodynamic principles, such as the Carnot cycle, dictate that maximizing temperature difference and minimizing irreversibilities like heat leakage and friction enhance efficiency. Engine design, material choice, and operational conditions further impact conversion efficiency by altering these variables .

In the kinetic molecular theory, potential energy becomes significant during close encounters between gas molecules. As gases expand, molecules are pulled apart, increasing potential energy with separation. Conversely, during contraction or compression, molecules draw closer, potentially decreasing potential energy as attractive forces become significant, influencing state changes or returns from gaseous expansion .

Elastic collisions are significant in maintaining the kinetic energy of gas molecules as they ensure that the total kinetic energy is conserved during particle interactions. This conservation underlies the assumption of ideal gas behavior, where particles interact without any net loss of energy, supporting the kinetic theory's depiction of constant temperature and internal energy in isolated systems .

Thermocouple thermometers offer several advantages compared to traditional mercury or alcohol thermometers. They are more sensitive to temperature changes, provide rapid response times due to the small amount of material being heated, and can measure a wide range of temperatures, including very low or high extremes. Additionally, they allow for precise electronic readouts and can be integrated into automated systems for continuous monitoring, making them versatile in scientific and industrial applications .

In communication systems using metal wires, noise may arise from thermal vibrations of the wire’s atoms, electrical interference as the wire acts like an aerial, and induced EMF from changing magnetic fields. These factors contribute to decreased signal-to-noise ratios as they interfere with signal integrity, especially when the signal diminishes but the noise remains relatively constant .

Higher amplitude vibrational motion in solids is associated with greater energy content because it implies that molecules are moving with greater velocity and separating more significantly from equilibrium positions. This increased kinetic and potential energy within the solid's atomic or molecular lattice reflects higher thermal energy content on a microscopic level .

Amplitude modulation (AM) offers advantages like longer range transmission, which reduces the need for repeaters or complex electronics, and cost benefits. However, it has disadvantages including increased noise and interference, lower quality due to a narrower bandwidth, and susceptibility to atmospheric and RF disturbances. These factors make AM suitable in scenarios where cost and range are prioritized over fidelity and noise immunity .

Evaporation leads to a decrease in the average kinetic energy of a liquid because the molecules with the highest kinetic energy escape first. This reduces the average kinetic energy of the remaining molecules in the liquid, leading to a lower temperature, which can be seen as a cooling effect on the liquid .

Fiber optic cables provide higher signal quality and transmission efficiency because they have less attenuation, allowing signals to travel longer distances before requiring amplification. They offer larger bandwidth, enabling more data transmission. Fiber optic cables also have smaller diameters, are lighter and cheaper, and do not suffer from electromagnetic interference or 'cross-talk', unlike metal wires .

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