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Ore Mineralogy and Chemical Analysis Guide

The document discusses ore mineralogy and chemical analyses, emphasizing the importance of understanding mineral properties for efficient ore processing. It details methods for mineral identification, chemical composition analysis, and various screening and classification techniques for size separation of ore particles. Additionally, it outlines the principles and types of classifiers used in ore classification based on particle size and density.

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Larsen Lufungula
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0% found this document useful (0 votes)
12 views4 pages

Ore Mineralogy and Chemical Analysis Guide

The document discusses ore mineralogy and chemical analyses, emphasizing the importance of understanding mineral properties for efficient ore processing. It details methods for mineral identification, chemical composition analysis, and various screening and classification techniques for size separation of ore particles. Additionally, it outlines the principles and types of classifiers used in ore classification based on particle size and density.

Uploaded by

Larsen Lufungula
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

A.

ORE MINERALOGY AND CHEMICAL ANALYSES

1. Ore Mineralogy

Mineralogy is the study of minerals and their physical and structural properties. For efficient
processing of an ore, it is necessary to know the mineralogy of the ore thoroughly. Mineralogy
test is done with a microscope and it enables us to have the following information :
a. The nature of the mineral values and the associated gangue minerals
b. The texture of the ore which includes the following:
i. The size of the mineral grains
ii. The shape of the mineral grains (c) Mineral value dissemination in the gangue
iii. Association between the mineral value(s) and the gangue minerals
c. The potential difficulty that may be encountered in separating the mineral
d. value(s) from the gangue minerals
e. The production of possible or feasible concentrate grade
f. The analysis of the concentrate and tailings microscopically also enables
g. one to know how efficient the liberation and separation processes are The methods of
microscopy used are as follows.

2. Visual Inspection
Many minerals can be identified by inspecting them visually and performing some simple tests.
There are about 4000 known minerals, the basic category being the rock-forming minerals.
Rock-forming minerals are minerals that constitute the earth’s crust rocks and they include
quartz, mica, calcite and feldspar In the visual identification of rock-forming minerals, very
small grains or larger hand specimens that can easily be readily observed and manipulated can
be used. In identifying metallic and rock-forming minerals, the use of a field guide that contains
features such as image, color, crystal shape and lustre is important.

3. Ore Chemical Analyses

When a fresh ore is received in the laboratory, it is necessary to subject the ore to analysis to
determine its chemical composition and thus be able to properly identify it. There are four
important factors to be considered in the chemical analyses of ore minerals, namely:
✓ Specification of the elements to be determined in the ore
✓ The chemical nature of the elements, that is, atomic number and atomic mass
✓ The expected concentrations of the elements in either weight%, ppm, ppb
✓ or ppt
✓ Identification of the minerals or mineral phases with which the elements are associated
Aside from the mineralogical analysis, there are three categories of analysis, namely: wet
classical analysis, powder or wet spectroscopy and in-situ spectroscopy that can be used. In wet
classical analysis, the ore is dissolved in an acid or other corrosive solution and the resulting
solution is analyzed. In spectroscopy tests, an energy source is used to bombard an ore to
generate an electromagnetic signal that is then detected and analyzed.
The wet chemistry method may be gravimetric, volumetric or calorimetric. The gravimetric
method determines the chemical composition of a material using weight measurements, while
the volumetric methods use volume measurements. On the other hand, calorimetric methods
measure changes in state variables of a material in a calorimeter to derive heat transfer arising
from a change of state during physical changes, chemical reactions or phase transition. These
wet methods require relatively “pure” powder samples and this poses a problem in the
application of these methods.

The many techniques of spectroscopy depend on the following principles:


1. An ore sample, with its aggregate of minerals, is bombarded with a high kinetic
energy particle such as an electron to cause the electrons and/or neutrons in it to
become excited to higher energy levels in it.
2. The excited electrons/neutrons will afterwards relax to their ground lower energy
levels and release energy characteristic of each element.
3. Detectors are arranged to collect one of the following: a. Specific energies
characteristic of each element b. Specific wavelengths characteristic of each element
c. Specific frequencies characteristic of each element.

B. ORE SCREENING

Industrial screening uses screens which are flat metal surfaces with apertures or holes usually
of uniform dimension for particle size separations. Screening has to do with size separations
and can be categorized as industrial screening and industrial classification depending on the
size fractions involved.

Industrial screening or sizing refers to size separations of crushed ores with sizes in the range
of ≤300 mm to ≥40 µm and the separation efficiency rapidly decreases as the particle fineness
increases. Industrial classification refers to size separations at finer particle sizes. Between 250
and 40 µm sizes, size separations are preferably done with classifiers although there are screens
that can also efficiently do them.
There are three types of size control, that is, scalping, circuit sizing and product sizing. In
scalping, the undersize is not allowed to enter the next reduction stage; while in circuit sizing,
the oversize is prevented from entering the next reduction stage but it is returned to the previous
stage for re-crushing. In product sizing, the output from the crusher is subjected to screening to
produce products of different size ranges. Screening can be done dry or wet:

Dry: 300 mm down to ≥5 mm


Wet: <5 mm to ≥250 µm
But < 250 µm to ≥40 µm are preferably treated with industrial classifiers

Screening is the most common method of separating ore particles based on size. For industrial
screenings of ores, the following basic facts are important:
a. For pre-screening and sizing operations, screens with 20-degree inclination are used.
b. A decrease in this inclination will slow down the sliding motion across the flat surface
and thus increases screening efficiency but decreases screen capacity.
c. For particles coarser than 12 mm, screening ore dry is preferred, while for particles
finer than 12 mm, wet screening is done using water spraying at low pressure and
flowing with a velocity of 0.8–1.4 m3/t/h.

1. Main Purposes of Industrial Screening


The main purposes of industrial screening are:
- Sizing or classifying is done to separate particles based on size difference
with the usual aim of providing a unit process downstream with particles
in the size range suited for that unit operation. For example, froth flotation requires feeds that
are <300 µm in size, while gravity concentrations require ore feeds with sizes >300 µm.
- It is used for scalping
- It is used for grading
- It is used for media recovery
- It is used for dewatering, that is, removal of water from a wet sand slurry.
- It is used for de-sliming or de-dusting, that is, the removal of slime or dust, which are
fine materials from a wet or dry ore feed with particle sizes generally smaller than 0.5
mm.
- It is used for taking away trash such as weed fibres from a slurry stream.

2. Screen Types

There are shaking, reciprocating and vibrating screens. The vibrating screen is presently the
dominant screen type while the shaking and reciprocating screens are now obsolete. Vibrating
screens have a rectangular screen surface with feed and oversize discharge points at opposite
ends. They perform size separation from 300 mm in size to 40 µm. They have applications in
scalping, dewatering, wet screening and washing.

C. ORE CLASSIFICATION

Ore classification deals with size separation using wet classifiers at fine particle sizes below
250 µm where screening becomes in-efficient. It involves the separation of a mixture of
mineral particles in a slurry based on the terminal velocity each particle attains under the
action of gravity.

1. The Principles of Classification

When a particle is introduced into a viscous carrier fluid in a sorting column with an upward
velocity of V, it is going to begin a downward motion due to the gravitational force (Fg) with
its acceleration decreasing because of fluid resistance. The fluid’s resistance to the downward
motion consists of a viscous resistance due to the viscosity of the fluid (Fv) and a resistance
(Ft) due to the carrier fluid’s displacement by the particle and this may be laminar or turbulent
depending on the particle velocity. At a point, an equilibrium will be reached between Fg and
(Fv + Ft) and the particle will attain its terminal velocity and subsequently descend at a uniform
rate. The particle in question may be small or large and may be light or heavy depending on its
density, size and shape.1
The total resistance to the particle’s downward motion is given by
R= Fv + Ft

and by extension, the terminal velocity (Vt) that the particle will attain depends on its density,
size and shape.
If Vt < V a particle will float as an overflow
Vt > V the particle will sink as an underflow

The coming down or descent of a particle suspended in water is also called settling or dynamic
settling. A settling particle may experience a free or hindered settling depending on a number
of factors.
Classifiers carry out size control using the motion of particles that depend on size, shape and
specific gravity.

2. Types of Classifiers
There are two broad classes of classifiers
1. The horizontal current or mechanical classifiers
2. The vertical current or hydraulic classifiers

Common questions

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Gravimetric and volumetric methods for chemical ore analysis pose challenges, including the requirement for pure samples to obtain accurate results, which can be difficult to prepare and maintain. Gravimetric methods rely on precise weight measurements, and volumetric methods depend on accurate volume assessments, both of which can be affected by impurities and measurement errors. These challenges can be mitigated by ensuring thorough sample cleaning and preparation, using standardized procedures and equipment calibration, and incorporating checks like gravimetric standards and control samples to validate results .

In industrial screening, scalping involves preventing the undersize particles from advancing to the next reduction stage. Circuit sizing restricts oversize particles from proceeding to the next stage and reintroduces them for re-crushing. Product sizing involves screening the crusher's output to produce products of different size ranges, ensuring that specific size requirements are met for downstream processes .

Vibrating screens are considered more efficient because they provide consistent separation due to their rectangular surface and points for feed and discharge at opposite ends, unlike shaking and reciprocating screens. They are also adaptable to various screening applications, including scalping, dewatering, wet screening, and washing, from coarser sizes to finer sizes as low as 40 µm. This versatility makes them the dominant choice in industrial screening .

Terminal velocity is significant in ore classification because it determines whether a particle will settle or float in the sorting column. When the downward force of gravity and the upward buoyant force are in equilibrium, the particle reaches its terminal velocity. This velocity depends on the particle's density, size, and shape. Particles with terminal velocities greater than the fluid's velocity sink as an underflow, while those with lower terminal velocities float as an overflow. Classifiers use this principle to achieve efficient separation of particles in a slurry .

An in-depth understanding of ore mineralogy is essential for efficient ore processing because it provides detailed information about the mineral values and associated gangue minerals, the texture of the ore which includes the size and shape of mineral grains, and the dissemination of mineral values in the gangue. This knowledge is critical in anticipating potential difficulties in separating the mineral values from the gangue and in planning the production of feasible concentrate grades. Furthermore, microscopic analysis of concentrates and tailings can assess the efficiency of liberation and separation processes .

Wet spectroscopy offers the advantage of detecting and analyzing the electromagnetic signals generated when ores are bombarded with high-energy particles, enabling the identification of specific energies, wavelengths, or frequencies characteristic of each element. This technique can be more precise and quicker for certain types of ores. However, its limitation lies in the requirement for relatively pure samples. In contrast, wet classical analysis involves dissolving ores in solutions and conducting tests that may be less dependent on sample purity but can be more time-consuming and less precise .

The choice between dry and wet screening is influenced by particle size. For particles coarser than 12 mm, dry screening is preferred due to ease of handling and processing. For finer particles, specifically those smaller than 12 mm, wet screening becomes necessary as it involves low-pressure water spraying, which helps in efficiently separating the finer particles and reducing dust .

Size control is pivotal in ore processing and downstream operations because it determines the suitability of particle sizes for subsequent processing stages. Effective sizing ensures that particles fall within the optimal size range for specific operations, such as froth flotation and gravity concentration, which have distinct size requirements (<300 µm and >300 µm, respectively). Proper size control also impacts resource recovery rates, energy efficiency, and operational costs, highlighting its critical role in maximizing the efficiency and productivity of ore processing operations .

Visual inspection techniques aid in mineral identification by allowing the physical characteristics of minerals, such as color, crystal shape, and luster, to be observed. These methods often involve using a field guide to compare observed features with known characteristics of minerals. This approach is especially useful for identifying rock-forming minerals in both small grains and larger hand specimens .

Mechanical classifiers, or horizontal current classifiers, utilize a mechanical motion to propel particles through a horizontal fluid current for separation based on size, shape, and specific gravity. In contrast, hydraulic classifiers, or vertical current classifiers, use an upward fluid flow to suspend and separate particles. The choice between these classifiers depends on the particle size and specific gravity, as each type optimizes separation based on these parameters .

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