Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS BT Paper -1(Adv-2023-P1-Model) Date: 20-07-2025
Time: 09.00Am to 12.00Pm RPTA-02 Max. Marks: 180
20-07-2025_Sr.Super60_NUCLEUS-BT_Jee-Adv(2023-P1)_RPTA-02_Syllabus
PHYSICS : Thermal Physics: First law of thermodynamics and its applications (only for ideal gases);
Isothermal and adiabatic processes, bulk modulus of gases; Equivalence of heat and work;
Second law of thermodynamics, Reversible and irreversible processes, Carnot engine and its
efficiency (Deleted for MAINS);
Heat Transfer: Heat conduction in one dimension; Elementary concepts of convection and
radiation; Blackbody radiation: absorptive and emissive powers; Kirchhoff’s law; Wien’s
displacement law, Stefan’s law, Newton’s law of cooling (Deleted for MAINS);
CHEMISTRY : GOC: Inductive effect, Resonance and hyperconjugation; Keto-enol tautomerism;
Hydrogen bonding- definition and their effects on physical properties of alcohols and
carboxylic acids; Inductive and resonance effects on acidity and basicity of organic acids and
bases; Polarity and inductive effects in alkyl halides; Reactive intermediates produced
during homolytic and heterolytic bond cleavage; Formation, structure and stability of
carbocations, carbanions and free radicals
Alkanes: Preparation, properties and reactions of alkanes. Homologous series, physical
properties of alkanes(melting points, boiling points and density) and effect of branching on
them; Combustion and halogenations of alkanes(including allylic and benzylic
halogenation); Preparation of alkanes by Wurtz reaction and decarboxylation reaction,
Corey-House Reaction.
MATHEMATICS : LCD, Differentiation, Differentiability and successive differentiation.

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 20-07-2025_Sr.Super60_NUCLEUS-BT_Jee-Adv(2023P1)_RPTA-02_Q.P

JEE-ADVANCED-2023-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve [Link] Total
Section ! Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 1 – 3) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 4 – 7) +3 -1 4 12
Choice
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 8 – 13) +4 0 6 24
Type
Sec – IV(Q.N : 14 – 17) Matching Type +3 -1 4 12
Total 17 60

PHYSICS:
+Ve - Ve [Link] Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 18 – 20) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 21 – 24) +3 -1 4 12
Choice
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 25 – 30) +4 0 6 24
Type
Sec – IV(Q.N : 31 – 34) Matching Type +3 -1 4 12
Total 17 60

CHEMISTRY:
+Ve - Ve [Link] Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 35 – 37) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 38 – 41) +3 -1 4 12
Choice
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 42 – 47) +4 0 6 24
Type
Sec – IV(Q.N : 48 – 51) Matching Type +3 -1 4 12
Total 17 60

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MATHEMATICS Max Marks: 60

SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

  
 1  1  1
 x sin    sin   , x  0, x  , x  [0,1], r  1, 2,3,
  x 1
 x sin  r 
1. Let f ( x)   then, which of
  x
 1
 0, x  0, , r  1, 2,..
r
the following is/are correct?
A) f is continuous at x  0 B) f is differentiable at x  0
C) f is continuous on [0, 1] D) f is not differentiable at x  0
2. Which of the following is/are correct?
(Where [.] denotes Greatest Integer Function and {.} denotes fractional part function)
sin{x} sin[ x]
A) lim 1 B) lim 1
x0 { x} x 0 [ x ]

 sin 1{x} 
C) lim   1 D) lim cot 1 x   3
x 0
 { x }  x

x
3. Let x0 be a real number such that e 0  x0  0 . For a given real number  , define
3 xe x  3 x   e x   x
g  x  for all real numbers x. Then which one of the following

3 e 1 x

statement(s) is /are TRUE?
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x x
g  x  e 0 1 g  x  e 0
A) For   2, lim  B) For   2, lim 1
x x x  x0 3 x x x  x0
0 0
x x
g  x  e 0 g  x  e 0 2
C) For   3, lim 0 D)   3, lim 
x x x  x0 x x x  x0 3
0 0
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases

1  ( f ( x))3
4. Let f ( x)  cos x  cos 2 x  cos3 x.....cos10 x then lim 
x 0 tan 2 x
115 155 55 1155
A) B) C) D)
2 2 2 2
 x
 tan x , if    x  0  x  4, if    x  1
 

5. Let f ( x )  2, if x  0 and g  x  =  x 2  5 x  11, if 1  x  2
 ln(1  2 x)  x  3, if 2  x  
 , if 0  x   
 x
then, which of the following is correct?
A) lim g ( f ( x))  5 B) lim g ( f ( x))  7
x 0 x 0
C) lim g ( f ( x))  6 D) lim g ( f ( x))  1
x 0 x  0

 
6. If f ( x )  ln 1  x   tan x, x  0 and g ( x)  f ( x ) , then the value of 27 g   ln 2e 4 
2 1 1

 
Where g ( x ) denotes second derivative of g ( x ) , is
A) 4 B) 3 C) 2 D)1

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 x 2  Sgn  x    x ,0  x  2,
7. If f  x    where [.] and {.} denotes greatest integer
sin x  | x  3 |,2  x  4
function and fractional part functions respectively Sgm(k) denotes signum function of k,
then which of the following is incorrect?
A) f  x  is discontinuous at x  2
B) f  x  is differentiable at x  1
C) f  x  is continuous but not differentiable at x  1
D) f  x  is not differentiable at x  2
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

 
n
1  2  2r  1  then, the value of lim
n
8. If Sn   tan   cot  Sn1   cot  Sn  
r 1  
 4  r 2 r 2  2r  1 
  n n  2

is
9. A differentiable function f is satisfying the relation
1 2 f ( h)  1 2
f ( x  y )  f ( x)  f ( y )  2 xy ( x  y )  x, y  R and lim  , then integral
2 h0 6h 3
part of f (2) is
  x 2 
2  2    k , if x  1,2,3
2
  x  3 x  2 x  5 x  6 
5, if x  1

  
10. Let f ( x)    
 lim   
 , if x  2
 y 0 n
n  sec1  tan y  
   y  
   

10, if x  3
If f(x) is continuous at x = 2, then the value of k, is ________
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


 1
 ln 1 | x |  (b  2) | x  1|  a tan x  2, if  2  x  0

11. If f ( x )   b, if x  0
   x 
 ln  4   
 (c  2)sin 1  x  e 2 x  e   2    1
 , if 0  x  2
 x2

is derivable in (-2,2) (where {.}is denoted F.P.F). Then the value of 9a 2  b 2  c 2 is  

 13 (sin x) x    23 (sin x ) x      n3 (sin x ) x  
12. If L  lim lim 4  where [.] denotes Greatest
x 0

n  n 
3
Integer function, then the value of is
L
 1   1 
13. f :  ,3  R , defined by f ( x )   x 2  4  and g :  ,3  R , defined by
3  3 
g ( x) | x  2 | f ( x)  | 3x  5 | f ( x) . If 'a' is the number of points of discontinuity of f (x)
and ' b ' is the number of non-differentiable points of g(x). Then the value of a  b is
(Note:[.] is G.I.F)
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.

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14. Match the following
Column-I Column-II
A) log  2  x   x 2n sin x p) 0
If f  x   lim is discontinus at x = a, b then
n 1  x 2n
the value a  b is
B) cos 4 x  a cos 2 x  b q) 4
If f  x   lim is finite then the value of
x 0 4
x
a  2b is
C)  sin  Sgn  x    r) 1
lim    Where [.] denotes the greatest integer
x 0  Sgn  x  
function and Sgn  x  denotes signum function of x
D) The number of non differentiable points of f  x   loge | x | is s) 3
t) 2
A) A  t , B  t , C  s, D  t B) A  p, B  t , C  p, D  s
C) A  t , B  r , C  t , D  r D) A  p, B  q, C  r , D  s
15. Match the following
Column-I Column-II
A)  1 1  1 1  1 1  p) 5
lim  2 2  2 3  2 2  2 5  .... 2 2  2 2n 1  
n     
    
B) 1 q) 0
 tan x  x2
If lim    p then 3log e P 
x 0  x 
C) A function f is defined on [-3,3] as r) 1

f  x  
 
min | x |,2  x 2 , 2  x  2
where [.] denotes the
| x | , 2 | x | 3
greatest integer function. The number of points , where f is not
differentiable in (-3,3) is
D) bx 2  a, if x  1 s) 2
If f  x    and f   x  is continuous every
2
ax  bx  2 if x  1
where, then the value of a + b is____
t) 3
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A) A  q, B  r , C  p, D  t B) A  p, B  q, C  r , D  s
C) A  q, B  p, C  r , D  r D) A  q, B  r , C  t , D  p
  
  
16. Let f1 :   , f 2 :   ,   , f3 : 1, e  2    and f 4 :    be functions
 2
 2 2  
 
defined by
 2 
(i) f1( x)  sin  1  e x ,
 
 
 | sin x |
 if x  0
(ii) f 2 ( x)   tan 1 x , where the inverse trigonometric function tan 1 x assumes
 1 if x  0

  
values in   ,  ,
 2 2
(iii) f3 ( x )  sin  log e ( x  2)   where, for t ,[t ] denotes the greatest integer less than or

equal to t,
 2 1
 x sin   if x  0
(iv) f 4 ( x)   x .
 0 if x  0

LIST-I LIST – II
P) The function f1 is 1 NOT continuous at x  0
Q) The function f 2 is 2 continuous at x  0 and not differentiable at x  0
R) The function f3 is 3 differentiable at x  0 and its derivative is no
continuous at x  0
S) The function f 4 is 4 differentiable at x  0 and its derivative is
continuous at x  0
The correct option is
A) P  2;Q  3;R  1;S  4 B) P  2;Q  1;R  4;S  4
C) P  4;Q  2;R  1;S  3 D) P  2;Q  1;R  4;S  3
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17. Match the following
Column-I Column-II
A) 1 p) 2
 tan x  1cos x
If lim    e , then 3k 
k
x 0
 x 
B) The number of points where f ( x )  Sgn  x 2  3 x  2   [ x  2] i q) 3
discontinuous at x  [0,4] , where Sgn(x) denotes Signum
function of x and [.]Denotes greatest integer function, is
C) Let f (x) be a polynomial function with real coefficients and r) 4
1
 f ( x)  x
lim 1  3   e 2 then coefficient of x 4 in f (x) is
x 0
 x 
D) The number of points of discontinuity of f ( x)  [5  2cos x] , s) 5
  
where [.] denotes greatest integer function x   ,   is
 2 
t) 0
A) A  p, B  r , C  p, D  s B) A  p, B  q, C  p, D  t
C) A  r , B  r , C  p, D  t D) A  p, B  r , C  t , D  s

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PHYSICS Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

18. Two moles of an ideal monatomic gas are confined within a cylinder by a massless and
frictionless spring loaded piston of cross-sectional area 4  103 m 2 . Initially the spring is
in its relaxed state. Now the gas is heated by an electric heater, placed inside the cylinder,
for some time. During this time, the gas expands and does 50 J of work in moving the
piston through a distance 0.10 m. The temperature of the gas increases by 50 K.
( P0  1.0  105 Nm 2 )
A) Spring constant is 1000 N/m B) Spring constant is 2000 N/m
C) Heat supplied to the gas is 1245 J D) heat supplied to the gas is 1295 J
19. A rectangular box as shown in the figure has a partition which can slide without friction
along the length of the box. Initially each of the two chambers of the box has one mole of
 5
monatomic ideal gas     at a pressure P0 , volume V0 and temperature T0 . The
 3
chamber on the left is slowly heated by an electric heater.

The walls of the box and the partition are thermally insulated. The gas in the left chamber
expands, pushing the partition until the final pressure in both chambers
 243 
becomes   P0 .
 32 

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4
A) final volume of right chamber is V0
9
27
B) final temperature of right chamber is T0
8
C) final temperature of left chamber is 13T0
D) magnitude of work done by gas in the right chamber is (nearly)15.5 T0 Joules
20. Heat received by the Earth due to solar radiations is 1.35KWm 2 . It is also known that the
temperature of the Earth's crust (near surface layer) increases 1 C for every 30 m of
depth. The average thermal conductivity of the Earth's crust is K  0.75 J(msK) 1 and
radius of the Earth is R  6400 km . Assume that the Earth is a perfect black body (Take
58  7.6 ).
A) rate of heat loss by earth’s core due to conduction is 1.29  1013 watts
B) rate of heat received by earth from the sun is nearly 1.7  1014 watts
C) mean surface temperature of earth is nearly 30C
D) mean surface temperature of earth is nearly 27C
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
21. A gas consisting of monatomic molecules (having three degrees of freedom) was
expanded in a polytropic process so that the rate of collisions of the molecules against the
vessel's wall did not change. Calculate the molar heat capacity of the gas in the process.
3R
A) 2R B) 3R C) 4R D)
2
22. In the P-V diagram shown in figure ABC is a semicircle. The work done in the process
ABC is

 
A) zero B) atm-lit C)  atm- lit D) 4 atm- lit
2 2
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23. P-V diagram of n moles of an ideal gas is as shown in figure. Find the maximum
temperature between A and B.

9 PV 5 PV 9 PV 5 PV
A) 0 0
B) 0 0
C) 0 0
D) 0 0
2 nR 2 nR 4 nR 4 nR
24. The two ends of a uniform metallic rod are maintained at 100 C and 0 C as shown in the


figure. Assume that end of the rod at 100 C is at x  0 and the other end at 0 C is
at x  L . Plot the variation of temperature as x changes from 0 to L in steady state if rod is
not insulated and surroundings are at 00 C

T  0C  T  0C 
100 100

x x
0 L 0 L
A) B)
T  0C  T  0C 
100 100

x x
0 L 0 L
C) D)

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SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

25. For an ideal gas if the molar heat capacity varies as C  CV  3aT 2
2
 3aT 2 
 
 xR 
The equation of process is Ve    constant. Find x
26. A piston can freely move inside a horizontal cylinder closed from both ends. Initially, the
piston separates the inside space of the cylinder into two equal parts each of volume V0 , in
which an ideal gas is contained under the same pressure P0 and at the same temperature.
Work W has to be performed in order to increase volume of one part of the gas is  times
the other part through isothermal process by slowly moving the piston. If
 x 
W  P0V0 ln   ; find x
   12 
 
27. An ideal gas with the adiabatic exponent  goes through a cycle shown in Figure within
which the absolute temperature varies n fold in each process. (i.e T3  nT2  n 2T1 ) for
1
 = 1.5, n = 2, the efficiency of cyclic process is . Then x is
x

28. A metal ball of mass 1.0 kg is kept in a room at 15C . It is heated using a heater. The
heater supplies heat to the ball at a constant rate of 96W. The temperature of the ball rises
as shown in the graph. Assume that the rate of heat loss from the surface of the ball to the
surrounding is proportional to the temperature difference between the ball and the
surrounding. Calculate the rate of heat loss from the ball when it was at temperature of
20C in watts
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29. A solid cylinder and a sphere of same material are suspended in a room turn by turn, after
heating them to the same temperature. The cylinder and the sphere have same radius and
same surface area. The initial rate of cooling of sphere is n times the initial rate of cooling
of cylinder. Then 100 n is
30. Three carnot engines operate in series between a heat source at a temperature T1 and a
heat sink at temperature T4 , there are two other reservoirs at temperature T2 and T3 such
that T1  T2  T3  T4 . If the three engines are equally efficient, and
T1  512 K & T4  64 K then T2  T3  ____ K
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
31. A monoatamic ideal gas of 2 moles was found to be undergoing a thermodynamic poly-
tropic process whose volume coefficient is varying with temperature as shown. (take
25
R  J / mol / K )
3

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Column-I Column-II
A) work done by gas in joules for every 1 K rise in P) 0
temperature if tan   3
B) internal energy rise of the gas is joules for every Q) 25
1 K rise in temperature if tan   2
C) heat absorbed by the gas in joules for every 1 K R) 125
rise in temperature if tan   1 3
D) value of '  ' in degrees for which the internal S) 50
energy rise of the gas for every 1 K rise in
temperature is 25 J
A) A  P, B  Q, C  R, D  PS B) A  S , B  Q, C  R, D  PQRS
C) A  R, B  S , C  Q, D  PS D) A  R, B  Q, C  S , D  PQS
32. In Column-I some statements or expressions related to first law of thermodynamics are
given and in Column-II some processes are mentioned. Match the entries of column-I,
with the entries of column-II.
Column-I Column-II
A) dU  nCv dT is valid for P) Adiabatic process
B) Temperature of the system can change in Q) Isothermal process
C) Q  dU  W is valid for R) Polytropic process
D) The process in which heat exchange between S) Free expansion
system surrounding is zero
A) A  PQRS , B  PR , C  PQRS , D  PS
B) A  PQRS , B  PQR, C  PS , D  PQRS
C) A  PQRS , B  PQRS , C  PS , D  PQRS
D) A  PS , B  PR, C  PQRS , D  PQRS
33. A copper rod (initially at room temperature 20 C ) of non-uniform cross section is placed
between a steam chamber at 100 C and ice-water chamber at 0 C .

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Column-I Column-II
A)  dQ  p) maximum at section A
Initially, rate of heat flow   will be
 dt 
B)  dQ  q) maximum at section B
At steady state, rate of heat flow   will be
 dt 
C)  dT  r) minimum at section C
At steady state, temperature gradient  
 dx 
will be
D) At steady state, rate of change of temperature s) minimum at section B
 dT 
  at a certain point will be
 dt 
t) same for all sections
A) A  q, B  t , C  qr , D  t B) A  pq, B  qr , C  qr , D  t
C) A  pr , B  t , C  qr , D  t D) A  ps, B  qr , C  t , D  pq
34. Match the following.
Column-I Column-II
A) R p) Change in internal energy of an
1 
T f  Ti  Isothermal process
B) Zero q) Molar specific heat of an Adiabatic process
C) R T f  Ti  r) Internal energy of n mole of gas sample
D) PV s) Work done in an Isobaric process carried on
 1 one mole of gas.
t) Work done in an Isochoric process.
u) Work done in an Adiabatic process carried on
one mole of gas.
A) A  pu , B  qt , C  s, D  r B) A  tu , B  pq, C  s, D  r
C) A  r , B  pqt , C  r , D  ru D) A  u, B  pqt , C  s, D  r

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CHEMISTRY Max Marks: 60

SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

35. Which of the following options are correctly indicated?

A) 2, 2-dimesitylethanal > Cyclopentane-1, 3-dione (enol content Order)
B) cis-cinnamic acid > Trans-cinnamic acid > propiolic acid [Acidic strength]
C) Glycerol > ethylene glycol [boiling point]
N
N
N
> >
D) N N N [Basic strength]
36. Which of the following is/are stronger acids than Benzonic – acid
COOH

H 3C CH 3

A) B)
COOH COOH

HO OH H2N

C) D)

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37. Which of the following options are correctly indicated [% enol content in pure liquid
form]?
O O
O O O O O O
>
>
A) B)
O O O
O O O O
>
>
C) D) O
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
38. The rate constant of decarboxylation of A and B are K1 and K 2 respectively, then
O

H  C  O 1 Na 1 
Soda lime
K1

(A)

O
CH 3  C  O 1 Na 1 
Soda lime
K2

(B)
A) K1  K 2 B) K1  K 2 C) K1  K 2 D) None of these
39. Which of the following compounds having smallest heat of combustion

IV
I II III
A) I B) II C) III D) IV

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CH 3

Br
2  [ X ]  fractional
  [Y ]
h distillation

total number total number

of monobromo of fractions
40. products
Then find the value of [X-Y]?
A) 2 B) 3 C) 4 D) 5
41. Which of the following reaction is incorrect
 /hv  /hv
A) Azomethane  radical B) Diazomethane  radical
 /hv 
C) Ketene  carbene D) Trichloroacetate  carbene
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
42. X is the number of compounds which liberate CO2 with NaHCO3 , then X is_____
Picric acid, Acetic acid, phenol , squaric acid, benzene sulfonic acid, Ethyl alcohol, 2,4-
dinitro phenol, Methyl alcohol, P-methyl benzoic acid, cyclopentadiene, Trifluoro acetic
acid, formic acid, Ethyne .
43. How many of them may serve both as hydrogen bonding acceptors and donors?

A)
N
B) OH C) H 3C  C  O  C2 H 5 D) H – F
CH 3 O
O
CH 3
CH 3 C  OH
E) F) O G) H)

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NH 2 O

H 3C  C  N O
I) J) K) L)
Na
A (g)
NaH B (g)
O
NaNH 2 C (g)
Ph  C  OH
14 NaHCO3
D (g)
1 mole
CH 3 Li
44. E (g)
Sum of molar mass of gases (A + B + C + D + E ) is____
45. Among the nitrogen’s (labelled as 1,2,3,4 etc), The most basic nitrogen is

46. How many groups (attached with benzene ring) can show + M effect?

47. How many of the following are more basic than Aniline?
Benzyl amine, Pyrrole, Pyridine, Pyrrolidine, Ortho-toluidene, Para-toluidine, para-
anisidine, Acetanilide, Phthalimide
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SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
48. Match Column – I with Column II and select the correct answer using the codes given
below
Column – I (Stability) Column – II (Reason)
P) Only inductive effect

I)
Q) Only resonance

II)
R) Hyperconjugation and
resonance

III)
S) Hyperconjugation and
inductive

IV)
A) I - P; II – R; III – S; IV – Q B) I -R; II – P; III –S; IV – Q
C) I - P; II– S; III – Q; IV –R D) I -Q;II – S; III –R; IV – P

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49. Match the following of Column-I with Column-II
Column-I (Molecule) Column-II
(pKa of Conjugate acid)
P) 0.8

A)
Q) 5.33

B)
R) 10.65

C)
S) 10.95

D)
A) A – P, B – R, C – S, D – Q B) A – S, B – R, C – P, D – Q
C) A – P, B – Q, C – S, D – R D) A – R, B – S, C – Q, D – P
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50. Match the enteries in column-I with that in major column-II.
Column-I Column-II
(Reactants) (Reaction characteristics)
P) Carbon free radical as
A) Intermediate
Q) Reduction of substrate
B)
R) Carbanion as intermediate

C)
S) Oxidation of substrate

D)
A) A – S, B – P, C – Q, D – R B) A – S, B – P, C – R, D – Q
C) A – R, B – P, C – S, D – Q D) A – R, B – P, C – Q, D – S
51.
Column I (Reaction ) Column II (Major product)
Cl / hv P)

2
A)
Br / hv

2 Q)
B)
CH 3 2 CuLi
C) C2 H 5  Br 
 C2 H 5  O 2
Br

R)
D) C2 H 5COOK  Kolbe ' s
Electrolysis Br
S)
Cl
T)
A) A  T , B  R, C  P, D  Q B) A  T , B  S , C  P, D  Q
C) A  T , B  S , C  Q, D  P D) A  T , B  S , C  Q, D  Q

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