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Quantum Numbers and Density Calculations

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0% found this document useful (0 votes)
7 views21 pages

Quantum Numbers and Density Calculations

The document contains a series of physics, chemistry, and mathematics questions along with answer keys. Each section includes multiple-choice questions covering various topics in the respective subjects. The answer keys for the physics section are provided at the end of the document.

Uploaded by

sm230130.m
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© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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10-08-2025

9610WPE801566250004 TM

PHYSICS

1) If the vectors and are perpendicular to each other, then the value of
x is:

(1) 2
(2) 3
(3) –2
(4) –3

2) If and , then the cosine of the angle θ between the two vectors is:

(1)

(2)

(3)

(4)

3) A particle is moving with displacement under the action of force . The


work done by the force in an arbitrary unit is:

(1) 8
(2) 10
(3) 12
(4) 16

4) If and are unit vectors along x, y and z axis respectively, then choose the wrong statement:

(1)
(2)
(3)
(4)

5) If and are unit vectors along x, y and z axis respectively, then choose the correct statement:

(1)
(2)
(3)
(4)

6) If the diagonals of a parallelogram are and then area of parallelogram is :

(1) 2 sq. units


(2) 3 sq. units
(3) 8 sq. units
(4) 16 sq. units

7) Find the scalar product of the vectors:


and

(1) 12
(2) 20
(3) 18
(4) 24

8) If two vectors and are such that then vectors

(1) act at an angle 60º


(2) act at an angle 30º
(3) are perpendicular to each other
(4) are parallel to each other

9) Which of the following is not a fundamental quantity?

(1) mass
(2) time
(3) temperature
(4) density

10) The density of a substance is 0.6g/cm3. It's value in SI unit is

(1) 6000kg/m3
(2) 600kg/m3
(3) 0.06kg/m3
(4) 6kg/m3

11) Convert an acceleration of 20m/s2 in km/h2

(1) 25.92×104km/h2
(2) 2.592km/h2
(3) 0.2592×103km/h2
(4) 25.92×106km/h2
12) The dimensional formula of force is

(1) [M1L1T1]
(2) [M1L1T–2]
0
(3) [M LT–2]
0
(4) [M1L T–2]

13) 1 kg m2s–2 = ................gcm2s–2

(1) 106
(2) 107
(3) 105
(4) 103

14) The dimensional formula of momentum is

(1) [MLT–1]
(2) [M2LT–1]
(3) [ML2T–2]
(4) [MLT]

15) The dimensional formula [ML2T–3] represent the quantity:

(1) Energy
(2) Force
(3) Power
(4) Momentum

16) The number of significant figure in 0.3012 kg is

(1) 4
(2) 2
(3) 1
(4) 3

17) Number 4.350 on rounding off becomes.

(1) 4.3
(2) 4.4
(3) 4.0
(4) 4.5

18) What is the percentage error in volume of a sphere, when error in measuring its radius is 3%?

(1) ± 3%
(2) ± 9%
(3) ± 27%
(4) ± 8%

19) If error in measuring diameter of a circle is 2% then the error in circumference of the circle
would be:

(1) ± 2%
(2) ± 4%
(3) ± 1%
(4) ± 6%

20) In a experiment four quantities a, b, c and d are measured with percentage error 2%, 3%, 1%

and 5% respectively for the quantity X = , then percentage error in X will be

(1) ± 15%
(2) ± 18%
(3) ± 13%
(4) ± 12%

CHEMISTRY

1)

Bohr's radius of H-atoms is 0.529 Å. What is the radius of second shell of He+?

(1) 0.529 Å
(2) 10.58 Å
(3) 1.058 Å
(4) 0.2645 Å

2) The velocity of electron in third excited state of Be3+ ion will be :-

(1)
(2.188 × 108) ms–1

(2)
(2.188 × 106) ms–1
(3) (2.188 × 106) Kms–1
(4) (2.188 × 103) Kms–1

3)

If an electron makes a transition from 6th orbit to ground state then calculate total number of lines
obtained

(1) 15
(2) 30
(3) 10
(4) 20

4) In spectral series of hydrogen. The series which does not come in infrared region is :-

(1) Pfund
(2) Brackett
(3) Paschen
(4) Lyman

5)

The circumference of the 4th Bohr orbit in H-atom is 5.32 nm. The de-Broglie wavelength of the
electron revolving in this orbit is
(circumference of circle = 2πr)

(1) 0.133 nm
(2) 13.3 nm
(3) 1.33 nm
(4) 133 nm

6) The de-Broglie wavelength associated with a particle of mass 10–6 kg with velocity of 10 ms–1 is :-
(h = 6.63×10–34 j-s)

(1) 6.63 × 10–22 m


(2) 6.63 × 10–29 m
(3) 6.63 × 10–31 m
(4) 6.63 × 10–34 m

7)

The uncertainty in the momentum of an electron is 1.0 × 10–5 kg m s–1 . The uncertainty in its
position will be: (h = 6.626 × 10–34 Js)

(1) 1.05 × 10–28 m


(2) 1.05 × 10–26 m
(3) 5.27 × 10–30 m
(4) 5.25 × 10–28 m

8) Which two orbitals are located along the axis, and not between the axis ?

(1)
(2)
(3)
(4)
9) The correct set of quantum number is :-

(1)
n = 3, ℓ = 2, m = 0,

(2)
n = 3, ℓ = 3, m = +1,

(3)
n = 2, ℓ = 0, m = 0,

(4)
n = 4, ℓ = 2, m = 3,

10) Which of following ions has the maximum number of unpaired d-electrons :-

(1) Zn2+
(2) Fe2+
(3) Ni3+
(4) Cu+

11) The orbital angular momentum of a p-electron is given as :-

(1)

(2)

(3)

(4)

12) The orbital diagram in which Aufbau principle is violated is

(1)

(2)

(3)

(4)

13) No. of all subshells having n + ℓ = 7 is:-

(1) 4
(2) 5
(3) 6
(4) 7
14) Which of the following configuration follows the Hund’s rule :-

(1)

(2)

(3)

(4)

15) A 0.66 Kg ball is moving with a speed of 100 m/s. The associated wavelength will be (h = 6.6 ×
10–34 Js)

(1) 6.6 × 10–34 m


(2) 1 × 10–35 m
(3) 1 × 1032 m
(4) 6.6 × 10–32 m

16) The electrons identified by quantum numbers n and ℓ :


(A) n = 4, ℓ = 1
(B) n = 4, ℓ = 0
(C) n = 3, ℓ = 2
(D) n = 3, ℓ = 1
Can be placed in order of increasing energy is:

(1) (D) < (B) < (C) < (A)


(2) (B) < (D) < (A) < (C)
(3) (A) < (C) < (B) < (D)
(4) (C) < (D) < (B) < (A)

17) Four quantum numbers for last electron of sodium (Na) atom :-

(1)
3, 0, 0, +

(2)
4, 0, 0, –

(3)
3, 1, 0, +

(4)
4, 1, 1, –

18) Values of n, , m and s for electron of 4s1 orbital will be respectively

(1)
(2)

(3)

(4)

19) Match the following:

Column-II
Column-I
(Number of
(Sub shell)
orbitals)

(a) s (i) 7

(b) p (ii) 5

(c) d (iii) 1

(d) f (iv) 3
(1) a–i; b–iv; c–iii; d–ii
(2) a–iii; b–iv; c–ii; d–i
(3) a–iii; b–iv; c–i; d–ii
(4) a–i; b–iii; c–iv; d–ii

20) Which of the following value of n, l and m represents the 7Py orbital?

(1) 7, 0, +1
(2) 7, 1, +2
(3) 7, 1, +1
(4) 7, 2, +1

MATHEMATICS

1) If both roots of the equation x2 – (m + 1)x + (m + 4) = 0 are less than zero, then m equals

(1) –7 < m < – 5


(2) –4 < m ≤ –3
(3) 2 < m < 5
(4) 3 ≤ m < 4

2) The real value of 'a' for which the quadratic equation 2x2 –(a2 + 8a – 1) x + a2 – 4a = 0 has one
root is greater than zero and the other is less than zero, is

(1) a > 5
(2) 0 < a < 4
(3) a > 0
(4) a > 7
3) Which term of the A.P. 3, 8, 13,18, ... is 78?

(1) 12th
(2) 13th
(3) 15th
(4) 16th

4) What is the common difference of an AP in which a18 – a14 = 32?

(1) 8
(2) –8
(3) –4
(4) 4

5) The next term of the sequence is (x ≠ 1)

(1) 1 +
(2) 1 –

(3)

(4)

6) The sum of all odd integers between 2 and 100 divisible by 3 is

(1) 17
(2) 867
(3) 876
(4) 786

7) If 7 times the 7th term of an A.P. is equal to 11 times its 11th term, 18th term is,

(1) 18
(2) 9
(3) 77
(4) 0

8) The 6th term of a G.P. is 32 and its 8th term is 128, then the common ratio of the G.P. is

(1) –1
(2) 2
(3) 4
(4) None of these

9) If first term of a G.P. is 20 and common ratio is 4. Find the 5th term.
(1) 10240
(2) 40960
(3) 5120
(4) 2560

10) Which term of GP 25, 125, 625, .... is 390625?

(1) 5
(2) 6
(3) 7
(4) 8

11) In a G.P., 5th term is 27 and 8th term is 729. Find its 11th term.

(1) 729
(2) 2187
(3) 6561
(4) 19683

12) Find the sum of the series 1 + + + ..... up to ∞ terms.

(1) 3

(2)

(3)

(4) 2

13) Find the sum of 3 + 32 + 33 + ..... + 38.

(1) 6561
(2) 6560
(3) 9840
(4) None of these

14) If three positive integers a, b, c are in G.P., then log a, log b, log c are in

(1) A.P.
(2) G.P.
(3) Both A.P. and G.P.
(4) None of these

15) If the first term is 125 and the common ratio is , what will be the 4th term of the G.P.?

(1) 8
(2) 12
(3) 6
(4) 10

16) Three numbers are in A.P. whose sum is 33 and product is 792, then the smallest number from
these numbers is

(1) 4
(2) 8
(3) 11
(4) 14

17) 32 + x, 41, 32–x are in A.P. then which is wrong :-

(1) x2 – 4 = 0
(2) x + 2 = 0
(3) x2 – 8 = 0
(4) x – 2 = 0

18) If the sum of n terms of an A.P. is 3n2 + 5n and tm = 164, then m =

(1) 26
(2) 27
(3) 28
(4) None of these

19) A man starts repaying a loan as first instalment of Rs.100. If he increases the instalment by Rs. 5
every month, what amount he will pay in the 30th instalment ?

(1) Rs 250
(2) Rs 240
(3) Rs 235
(4) Rs 245

20) The sums of n terms of two arithmatic series are in the ratio 2n + 3 : 6n + 5, then the ratio of
their 13th terms is

(1) 53 : 155
(2) 27 : 77
(3) 29 : 83
(4) 31 : 89
ANSWER KEYS

PHYSICS

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 3 3 1 4 3 1 2 4 4 2 1 2 2 1 3 1 2 2 1 2

CHEMISTRY

Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. 3 4 1 4 3 2 3 4 3 2 1 2 1 1 2 1 1 3 2 3

MATHEMATICS

Q. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 2 2 4 1 4 2 4 2 3 3 4 4 3 1 1 1 3 2 4 1
SOLUTIONS

PHYSICS

1)

=6–8–x=0
⇒ x = –2

2) Cosθ =

3) Work done =
=
=2+3+3=8

4)
As angle between them is 0º and sin0º = 0

5) is a correct statement

6) Area of parallelogram =

= (4) = 2 sq. units

7) = (2×3)+[–3×(–6)]+[2×(–2)]
= 6 + 18 – 4 = 20

8) If then and are parallel to each other.

9) Density is a derived quantity

10) × 106kg/m3 = 600kg/m3

11) = 25.92 × 104km/h2


12) Force = ma = [M] [LT–2] = [M1L1T–2]

13) 1kg = 1000×104 g

14) Momentum = mv = [M][LT–1] = [MLT–1]

15) [ML2T–3] = [MLT–2] [LT–1]


⇒ Force×Velocity = Power

16) 0.3012 kg has 4 SF

17) 4.350 is rounded off to 4.4

18) Volume of the sphere V = πr3


Percentage error in Volume = 3(3%) = ± 9%

19) Error in circumference = 1×2% = ± 2%

20) Percentage error in X = (3×2%) + (2×3%) + (1×1%)+(1×5%)


= ± 18%

CHEMISTRY

21)

radius = 0.529 × Å (n = 2, z = 2)

Å = 1.058Å

22)

V = 2.18 × 106 × m/s

V = 2.18 × 106 ×
= 2.18 × 106 m/s
= 2.18 × 103 km/s

23)
n1 = 1, n2 = 6

= 15

24) Lyman Series come under UV region.

25)

26) De-broglie wavelength [ Given m = 10–6 kg; v = 10 m/s]

λ = 6.63 ×10–29 m

27)

28)

29) n = 2, ℓ = 0, m = 0,

30) 30Zn2+ → [Ar] 3d10 ⇒ no unpaired electron


2+
26Fe → [Ar] 3d6 ⇒ 4 unpaired electron (maximum)
3+
28Ni → [Ar] 3d7 ⇒ 3 unpaired electron
Cu+ → [Ar] 3d10 ⇒ no unpaired electron
31)

For P-electron
ℓ=1

orbital angular momentum =

32) According to Aufbau principle electron will be filled in increasing order of energy of
orbitals.

33) n + ℓ = 7
n ℓ
7 0 ⇒7s
6 1 ⇒6p
5 2 ⇒5d
4 3 ⇒4f
3 4 ℓ can not be > n

34) According to Hund's rule, every orbital in a subshell is singly occupied with an electron
before any orbital is doubly occupied, and all electrons in the singly occupied orbitals have the
same spin. So configuration that follows Hund's rule.

35)
λ = 1 × 10–35 m

36)

Higher value of (n + ℓ) is representing higher energy of subshell.


Subshell for which have same value of (n + ℓ) higher the value of 'n', higher is the energy.
(A) n + ℓ = 4 + 1 = 5 = 4p
(B) n + ℓ = 4 + 0 = 4 = 4s
(C) n + ℓ = 3 + 2 = 5 = 3d
(D) n + ℓ = 3 + 1 = 4 = 3p
The energy order is - 3p < 4s < 3d < 4p

37) 11Na → 1s2 2s2 2p6 3s1


for last electron of sodium (Na) atom,
4 Quantum numbers are → n = 3
For s-orbital ℓ = 0
ms = +

38)

In 4s1 n = 4

m = 0.

s=

39) Number of orbitals =


s – sub shell has 1 orbital
p – sub shell has 3 orbital
d – sub shell has 5 orbital
f – sub shell has 7 orbital

40) n = 7, l = 1, m = +1 or –1

MATHEMATICS

41) Method (i)


x2 – (m + 1) x + (m + 4) = 0
Both roots are negative,
sum of roots < 0
⇒m+1<0
⇒ m < –1 ....(i)
and products of roots > 0 ⇒ m + 4 > 0
⇒ m > –4 ....(ii)
Also, D ≥ 0 ⇒ (m +1)2 –4(m + 4) ≥ 0
⇒ m2 + 2m + 1 – 4m – 16 ≥ 0
⇒ m2 – 2m – 15 ≥ 0
⇒ (m – 5) (m + 3) ≥ 0
⇒ m ∈ (–∞, – 3] ∪ [5, ∞] .....(iii)
Taking intersection of (i), (ii) and (iii)

⇒ m ∈ (–4, –3]
Method (ii)
Since leading coefficient is positive
(1) D ≥ 0
(2) af(d) > 0

(3)
Now solving
(1) D ≥ 0
⇒ (m +1)2 –4(m + 4) ≥ 0
⇒ m2 + 2m + 1 – 4m – 16 ≥ 0
⇒ m2 – 2m – 15 ≥ 0
⇒ (m – 5) (m + 3) ≥ 0
⇒ m ∈ (–∞, – 3] ∪ [5, ∞] .......(i)
(2) af(d) > 0 ⇒ f(0) > 0
⇒m+4>0
⇒ m > –4
m∈(–4, ∞) ....... (ii)

(3) ⇒
⇒m+1<0
⇒ m < –1
m∈ (–∞, –1) ......... (iii)
Taking intersection of (i), (ii) and (iii)

⇒ m ∈ (–4, –3]

42) 2x2 – (a2 + 8a –1)x + a2 – 4a = 0


f(0) < 0 ⇒ a2 – 4a < 0
⇒ a (a – 4) < 0 ⇒ a ∈ (0, 4)

43) a = 3, d = 5
an = 78
78 = a + (n – 1)d
78 = 3 + (n – 1)5
75 = (n – 1)5
⇒ n – 1 = 15
⇒ n = 16
∴ 16th term of the given A.P. is 78.

44) a18 – a14 = 32 ⇒ (a + 17d) – (a + 13d)= 32


⇒ 17d – 13d= 32 ⇒ 4d = 32
⇒d=8

45)

are terms of AP, d =

Next term =

46) Sn = 3 + 9 + 15 + .... + 99
⇒ 99 = 3 + (n – 1)6 ⇒ n = 17

⇒ Sn = [3 + 99] = (102)
⇒ Sn = 17 × 51 = 867

47) 7(a + 6d) = 11 (a + 10d)


⇒ 7a + 42d = 11a + 110 d
⇒ 4a + 68d = 0
⇒ 4(a + 17d) = 0
⇒ a18 = 0

48) ar5 = 32 and ar7 = 128

⇒ r2 = 4 ⇒ r = 2

49) a = 20, r = 4
⇒ T5 = ar4 = 20 × 44 = 5120

50) a = 25, r = 5
⇒ an = arn–1
⇒ 390625 = 25 × 5n–1
⇒ 15625 = 5n–1
⇒ 56 = 5n–1
⇒n=7

51) ⇒ ar4 = 27
and, ar7 = 729

⇒ r3 = 27 ⇒ r = 3

⇒ a(34) = 27 ⇒ a =

⇒ a11 = ar10 = × 310 = 39 = 19683

52) 1 + + + .....

S∞ = =2.

53) a = 3, r = 3

⇒ s8 = = 9840
54) b2 = ac
log a + log c = 2 log b


Hence, log a, log b and log c are in A.P.

55) a = 125, r =

a4 = ar3 = 125 × =8

56) Suppose that three numbers are a + d, a, a – d, therefore a + d + a + a – d = 33 ⇒ a = 11


a(a + d) (a – d) = 792
⇒ 11(121 – d2) = 792
⇒ d=7
Then required numbers are 4, 11, 18.
Hence smallest number is 4.

57)

2(41) = 32 + x + 32 – x
82 = 9.3x + 9.3–x
Let 3x = t

82 = 9t +
9t2 – 82t + 9 = 0
9t2 – 81t – t + 9 = 0
9t(t – 9) – 1(t – 9) = 0
t = 9 or t = 1/9

3x = 9

x=2 or x = –2

58) tm = Sm – Sm–1
∴ 164 = 3m2 + 5m – 3(m–1)2 – 5(m–1)
⇒ 164 = 3m2 + 5m –3(m2 + 1 – 2m) –5(m –1)
⇒ 164 = 3m2 + 5m – 3m2 –3 + 6m – 5m +5
164 = 6m + 2
∴ 6m = 162 or m = 27

59) 100, 105, 110, 115 .........


a = 100, d = 5
T30 = 100 + 29 × 5 = 245

60)
We have

Put n = 25 then

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