Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS BT Paper -2(Adv-2024-P2-Model) Date: 10-08-2025
Time: 02.00Pm to 05.00Pm CTA-04 Max. Marks: 180
10-08-2025_Sr.Super60_NUCLEUS-BT_Jee-Adv(2024-P2)_CTA-04_Syllabus
PHYSICS : Thermal physics, Heat Transfer, SHM, Waves & Sound, Fluid statics &
Dynamics
CHEMISTRY : Nomenclature, Isomerism, GOC, Alkanes, Alkene & Alkyne, Benzene,
Alkyl Halides & Aryl Halides, Alcohols, Phenols , Ethers
MATHEMATICS : Functions and Inverse Trigonometric Function, LCD and Differentiation,
AOD, Total Differential Calculus , Indefinite Integration

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 10-08-2025_Sr.Super60_NUCLEUS-BT_Jee-Adv(2024-P2)_CTA-04_Q.P

JEE-ADVANCED-2024-P2-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve [Link] Total
Section Question Type ^
Marks Marks Qs marks
Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 5 – 7) +4 -2 3 12
with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 8 – 13) +4 0 6 24
Answer Type
Sec – IV(Q.N : 14 – 17) Paragraph with NUMERICAL VALUE 3 0 4 12
Total 17 60

PHYSICS:
+Ve - Ve [Link] Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 18 – 21) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 22 – 24) +4 -2 3 12
with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 25 – 30) +4 0 6 24
Answer Type
Sec – IV(Q.N : 31 – 34) Paragraph with NUMERICAL VALUE 3 0 4 12
Total 17 60

CHEMISTRY:
+Ve - Ve [Link] Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 35 – 38) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 39 – 41) +4 -2 3 12
with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 42 – 47) +4 0 6 24
Answer Type
Sec – IV(Q.N : 48 – 51) Paragraph with NUMERICAL VALUE 3 0 4 12
Total 17 60

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MATHEMATICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
7n  
r 6  6r 5  5r 4  4r 3  3r 2  2r  1
1. The value of lim    for k R, n N, is
n  r 1 7 n7  6n 6  5n5  4n 4  3n3  2n 2  7 n  k 

A) 67 B) 65 C) 57 D) 75
2. Let f  x  and g  x  be two differentiable function in R and f  2   8, g  2   0, f  4  10
and g  4   8 then which of the following is correct ?
A) g '  x   4 f '  x  x   2,4 B) 3g '  x   4 f '  x  for at least one x   2,4 
C) g  x   f  x  x   2,4  D) g '  x   4 f '  x  for at least one x   2,4 
3. The function f  x   y defined by x  2t  t , y  t 2  t t ; t  R is
A) Continuous and differentiable in  1,1
B) Continuous but not differentiable in  1,1
C) Differentiable but not continuous in  1,1
D) Neither continuous nor differentiable in  1,1
4. f  x   ax 2  bx  c; a, b, c R  0 . If f 1  2  f  3 and if a  N , the largest possible

c
real value of is " " , then which of the following options is incorrect ?
a
1 1 1 5
A) 1     ...... infinite terms  
 2 3 4
B) f '  2   0

C) f  2   

D)  ,   3,  2 are in G.P
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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

5. Suppose f is a real valued differentiable function defined on 1,  with f 1  1.

x2  1
Suppose f   x   ,  x 1 , then which of the following is/are correct?
x   f  x 
4 2

A) Minimum value of f  x  in 1,  is 1

B) Maximum value of f  x  in 1,  is 1


C) f  x   1  , x  1
2 2

D) f  x   1 , x  1
2 2
7
 x  1 4 dx  g x & g 1  0 . Then which of the following option(s) is/are
6. If  15
   
 x  2 4
incorrect?
A) Largest set of values of “x” for which g  x  is defined is R  2

B) Largest set of value of “x” for which g  x  is defined is R  [2, 1)

4
C) Range of y  g  x  is [0, )   
11 
3
D) g  t  
t   2
11
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 2 1
 x sin 2 , x  0
7. Let f  x   x , then which of the following is/are correct?
0 , x0

A) f  x  is not differentiable at x = 0
B) f  x  is differentiable at x = 0, but f '  x  is unbounded near x = 0
C) f  x  is continuous but not differentiable at x = 0
D) f  x  is differentiable and f '  x  is bounded in a neighborhood of 0
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

3e x  5sin x  10cos x
8. Let I  
x
e  4sin x  3cos x

dx  mx  n ln e x  4sin x  3cos x  C , where C is 
constant of integration and m, nN , then the value of m 2  n 2 is _____  
9. Let M be the greatest and m be the smallest value of sin 1 x  cos 1 x , then the value
4
M 
of   is
m
10. If there exists a straight line which intersects the curve
y  x 4  2 x3  cx2  9 x  4  c  R  at four distinct points and the range of c is (a,b), then
100b is …..
11. Let g : R4 be a function given by
g  x   x3  f '  t   2   x 2 f ''  t   4 x  f  0   6   4, x, t  R and h  x  is defined as
x
  f  t   2 dt , 0  x  6

h  x   0 number of integers in the range of h  x  equals
 2
 x  6   20, 6  x  12

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1
12. Let f  x   , [.] is the greatest integer function, then the number of integral
6   x 2  2
 
values of x in domain of f  x  is

x       2L
13. Let L  lim  1 sin  2 x 2  x  2  .sin    where x  N , then   is
x   2   4 4x   L 
equal to ______
SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases
PARAGRAPH-I
sin 4 x  sin 2 x  1  x 1   x 1 
Let f  x   and g  x   tan 1    tan 1  
sin 2 x  sin x  1  x2  x2
14. If f   x   a sin 2 x  b sin x  c x  R, then the value of b  c  a is
1 1
15. Sum of all the solution of equation g  x   tan 1  tan 1 is
2 3
PARAGRAPH-II
 x 2  4 x  5  x 2  4 x  5 ; x  1

If f  x    1
10tan x  5  10; x   , 1
 x 2
16. lim f  x   1 and the number of points at which f  x  is not differentiable is 2 then
x 1
1  2 

17. g  x   max f  t  ;   t  x, then lim g  x  

x 5

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PHYSICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
18. A body of mass one unit with specific heat 2 unit at temperature Th is brought into
thermal equilibrium by contact with an identical body which was initially at a lower
temperature Tl . No heat is lost to the surroundings and the temperatures are in Kelvin.
The change in entropy of the system is, assume very slow heat transfer and whole body at
same temperature thought out any instant
  T  T 2   T  T 2 
A) ln  h l  B) ln  h l 
 4TlTh   4TlTh 
   
2
T   T  T 2 
C) ln  h  D) ln  h l 
 Tl   4TlTh 
 
19. The pressure of one mole of an ideal gas varies according to the equation

p = p0 - 4aV 2 where p 0 and a are positive constants. The maximum temperature attained
by the gas during the process is
1 1 1 1
3 p0  p0  2 p  p 2 p  p 2 2 p0  p0  2
A)   B) 0  0  C) 0  0  D)  
2 R  3a  R  3a  3R  3a  3R  3a 
20. Two particles are in SHM in a straight line about same equilibrium position. Amplitude A
and time period T of both the particles are equal. At time t = 0, one particle is at
A
displacement y1   A and the other at y2   and they are approaching towards each
2
other. The time after which they cross- each other first time will be
T T 5T T
A) B) C) D)
3 4 6 6

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21. A massless rod rigidly fixed at O. a string carrying a mass m= 4k at one end is attached to
point A on the rod so that OA =a. at another point B  OB  b  2 a  of the rod, a
horizontal spring of force constant k is attached as shown. Find the period of small
vertical oscillations of mass m around its equilibrium position.

A)  B) 2 C)  / 2 D)  / 4
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.
22. A source approaching with speed u towards the open end of a stationary pipe of length L,
is emitting a sound of frequency f s . The farther end of the pipe is closed. The speed of
sound in air is v and f 0 is the fundamental frequency of the pipe. For which of the
following combination(s) of u and f s , will be sound reaching the pipe lead to resonance?
A) u  0.8v and f s  f 0 B) u  0.6v and f s  2 f 0
C) u  0.75v and f s  1.25 f0 D) u  0.5v and f s  1.5 f 0

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23. As shown in the figure, the radius of the pulley is R, its moment of inertia relative to the
rotation axis is I, the mass of the body is 2m, and the spring constant is K. the mass of the
thread and the spring is negligible, the thread does not slide over the pulley, and there is
no friction in the axis of the pulley, then (  is angular displacement from equilibrium)

1 K
A) The frequency of oscillation 
2 I / R 2  2m

KR 2
B) Angular acceleration =
I  2mR 2

I  mR 2
C) The time period of oscillation  2
KR 2

2m  I / R 2
D) The angular frequency 
K

24. A syringe is filled with water. Its volume is v0  40cm3 and cross section of its interior is
A  8cm 2 . The syringe is held vertically such that its nozzle is at the top, and its piston is
pushed up with constant speed. Mass of the piston is M= 50 g and the water is ejected at
a speed of u0  2m / s . Cross section of the stream of water at the nozzle is a  2mm 2 .
Neglect friction, take the density of water to be   103 kg / m3 , g  10m / s 2 . Choose the
correct options.
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A) The speed of the piston is 0.4 cm/s
B) The force required to push the piston decreases as the piston moves up
C) Total work done in emptying the syringe is nearly 0.125 J
D) Total work done in emptying the syringe is nearly 0.115 J
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..
25. In the figure shown, an observer O1 floats (static) on water surface with ears in air while
another observer O2 is moving upwards with constant velocity V1  V / 5 in water the
source moves down with constant velocity V2  V / 5 and emits sound of frequency f.
the velocity of sound in air is V and that in water is 4V. For this situation the wavelength
16V
of the sound received by O2 is . Find x
xf

26. An equi- molar mixture of a mono atomic and diatomic gas is subjected to continuous
1 1
expansion such that dQ  dU  dw . The equation of the process in terms of the
3 2
variable P & V is PV 11/ x = constant. Then value of x is ____

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27. A liquid of density  is filled in a cylindrical vessel whose base radius is R. A wooden
cylinder of height h, base radius R/2 and density  / 2 is floating in the liquid. Minimum
work to be done by external agent in completely immersing the cylinder into liquid is
n R 2  gh 2
. Find the value of n.
128

28. An ideal monoatomic gas is confined by a spring loaded massless piston of cross-section
8  10 3 m 2 . Initially the gas is at 300K and occupies a volume of 2.4  10 3 m 3 and the
spring is in its relaxed state. The gas is heated by an electric heater until piston moves out
without friction by 0.1 m. Force constant of the spring is 8000 N/m, atmospheric
pressure 1  105 N / m2 , the cylinder and piston are thermally insulated, the piston and
spring are massless and there is no friction between the piston and cylinder. Neglect the
heat lost through the wire of the heater. The heat capacity of the heater is neglected.

Find the ratio of heat supplied by the heater to the work done by the gas.
29. A string of length l fixed at one end and free at another end is vibrating in 5th harmonic
Maximum displacement of particle is A. Amplitude of oscillation of a particle at distance
l 2A
from free end is find the value of  .
10 
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30. A certain amount of mono atomic gas undergoes a process for which U   V , where U is
U
internal energy and V is volume of gas. It is found that the ration for the process is
Q
1
. What is the value of  .
7
SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases
PARAGRAPH-I
The Bernoulli effect can have important consequences for the design of buildings. For
example, wind can blow around a skyscraper at remarkably high speed, creating low
pressure. The higher atmospheric pressure in the still air inside the buildings can cause
windows to pop out. As originally constructed, the building popped windowpanes that
fell from many stories to the sidewalk below.

31. Suppose a horizontal wind blows with a speed of 11.2 m/s outside a large pane of plate
glass with dimensions 4.00m  1.50m . Assume the density of the air to be constant at
1.20kg / m3 . The air inside the building is at atmospheric pressure. What is the total force
exerted by air (in N) on the windowpane?

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32. If second Skyscraper is built near by, the air speed can be increased when wind passes
through the narrow separation between the building due to which force on the window
pane having dimensions 4m  1.5m becomes 1810 Newton outward. Find the velocity of
the wind (in m/s) near the window pane after the construction of second building. Air

density is 1.20 kg / m3 .
PARAGRAPH-II
A non –conducting piston of mass m and area S 0 divides a non- conducting, closed
cylinder as shown in figure. Piston having mass m is connected with top wall of cylinder
by a spring of force constant k. Top part is evacuated and bottom part contains an ideal
gas at pressure P0 in equilibrium position. Adiabatic constant  and in equilibrium
PS
length of each part is l. (neglect friction). [Assume 0 0 =10 and   1.4 ]
ml

k
33. Angular frequency for small oscillation of piston is  n . find the value of n
m
34. If the spring is removed and old piston is replaced with a conduction piston. Which
slowly moves down isothermally, reducing the gas column’s length from l to a new
equilibrium position such that the gas pressure becomes P1  1.3P0 .
PS
The angular frequency for a small isothermal oscillation will be, Use 0 0 =10
ml

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CHEMISTRY Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
35. In which reaction the major product is not correctly given ?

Br
t  Bu O  K 



A)
Br EtOH




B)
Cl

H O
2 



C)
Br
Na


OH
D)
36.
Z Z
OH 


Br OH

For the above reaction to be fastest the group ‘Z’ should be:
A) – H B) – Cl C) – COOR D) – SR

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37.
X

Y



X
Most suitable ‘X’ and ‘Y’ for the given conversion are ____ respectively
A) OH,NaNH 2 B) Br,Na C) Cl , AlCl3 D) OH , Al2O3
38.
OH

H
 Product  major 

 H 2O

Energy profile diagram of the above reaction is :

Free
Energy
B

A C
D
Reaction Co-ordinate

Which statement is correct about the given reaction?

A) ‘A’ has one atom with incomplete octet.
B) ‘D’ on ozonalysis gives a mixture of an aldehyde and a ketone
C) Formation of ‘A’ from reactant involves ‘C-O’ cleavage.
D) Atomicities of ‘B’ and ‘C’ are same but that of ‘D’ is one unit less than that of ‘B’or
‘C’
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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

39. Which of the following have lesser heat of hydrogenation (magnitude) than 1–hexene?

A) B)

C) D)
40. In which of the following cases the conversion occurs through formation of any cyclic
intermediates or transition state?

3 i) O
 Products
ii ) H 2O / Zn

A)
i ) Hg  OAC 
2  Products

ii ) NaBH 4
B)
Br

NaCN

 Products
DMSO

C) Ph

2 6 i) B H

 products
ii ) H 2O2 / OH
D)

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41. Which statements are correct about the following given conversion ?
O Me O Me
H
H
moist
 
Ag 2O
O Br O OH
A) The product is incorrectly shown in stereo specific aspect
B) The reaction follows addition and elimination consecutive steps
C) The reaction involves intramolecular nucleophilic substitution  SN 2 
D) The reaction involves attack of OH  in SN 2 path.
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

2 CaOCl
CH 3CH 2OH  X  Y
  liquid  salt
42.
aq KOH
X  Z  W
 aq   organic 
AgNO
3  ppt
Z 
aq
Electrolysis
W  aKOH  bCO2  cA 
What is the mass of ‘A’ obtained in grams in the above sequence starting with one mole
of ethanol?
(assume 100% yield in all reactions)
43.
Me

Cl
EtOK

 P (major )
EtOH


EtOH

Q  major 

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Number of transition states formed towards formation of ‘P’ and ‘Q’ are ‘x’ and ‘y’
respectively.
Number of allylic hydrogen atoms in ‘P’ and ‘Q’ are ‘z’ and ‘w’ respectively.
What is (x+y+z+w) ?
44.

Cl Cl

Cl Me
Cl
Cl
Cl
When the above substance is treated with excess of AgNO3 in proper polarizing medium
(dielectric constant close to H 2O ) 10 x% percent of the total chlorine content of reactant
is precipitated as AgCl. What is x ?
45. A compound A  C2 H 4O2  with O17 isotope participitates in the following sequence of
reactions .
C H MgCl  leq 
2 5 i ) CH MgCl  leq 
3
A  B  C
H 2O  organic  ii ) H 2O  organic 
i ) C6 H 5MgCl
Na ii ) H 2O

No reaction
D  E
 organic   organic 
What is the difference in the molecular weights of ‘D’ and ‘E’ ?
46.
O

LAH A(major)
Ph
H

NaBH 4

B(major)
What is the difference in molecular weights of ‘A’ and ‘B’ ?
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47.
OH

2 i ) I / KOH


 A X 
ii ) H 3O

2 SOCl
A  B C 
Pyridine

3 AlCl
B   D  HCl
 D.O.U  9 
3 i ) CH MgCl 3
2 4  F  H SO i) O
D 
 E  G
ii ) H 2O  ii ) H 2O / Zn

How many statements are correct about the above sequence?

a) ‘A’ can liberate H 2 with sodium.
b) Degree of unsaturation of ‘D’ is 6.
c) ‘E’ on heating with Cu/350oC gives a ketone
d) ‘G’ gives ‘+ve’ iodoform test
e) The total scheme involves electrophilic addition, nucleophilic addition at some stage.
f) The sequence involves momentary loss of aromaticity.
SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases

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PARAGRAPH-I
O

 i ) Cl2 / 
ii ) Ca  OH 
 X  salt  A 
A) 2

NH 2
o
i ) NaNO2 / HCl (05 C )
 ii ) H 2O
Y  salt  ( B)
( gas )
B)
i ) KOH
C) X  Y 

Z
ii ) H 3O
48. In the reaction labeled as ‘C’ the molecule ‘X’ suffers nearly ‘m’ % mass loss to form
an intermediate. What is ‘m’?(atomic weights of C=12,H=1,O=16,Cl=35.5, N=14)
49. The salt ‘A’ is acidified and heated with excess NaOH/CaO to liberate a reducing gas.
What is the molecular weight of that gas?
PARAGRAPH-II

N
Base
 A + B
Optically
active

alk KMnO
4  C  H LAH
B   D  E.
cold major
50. How many structural isomers are possible with the formula of E?
51. How many asymmetric sp3 atoms are present in the molecule ‘A’ ?

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