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JEE Main 2024: Amines Question Bank

The document is a question bank for JEE Main 2024 and 2025, focusing on the topic of amines. It contains multiple-choice questions, fill-in-the-blank questions, and matching exercises related to reactions, products, and properties of amines. The questions are categorized by shifts and dates, with some requiring calculations based on given data.
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0% found this document useful (0 votes)
20 views40 pages

JEE Main 2024: Amines Question Bank

The document is a question bank for JEE Main 2024 and 2025, focusing on the topic of amines. It contains multiple-choice questions, fill-in-the-blank questions, and matching exercises related to reactions, products, and properties of amines. The questions are categorized by shifts and dates, with some requiring calculations based on given data.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Amines JEE Main 2024 April Question Bank

Questions MathonGo

Q1 - 2024 (04 Apr Shift 1)

Xg of ethylamine is subjected to reaction with NaNO2 /HCl followed by water; evolved dinitrogen gas which
occupied 2.24 L volume at STP. X is ×10−1 g.

Q2 - 2024 (04 Apr Shift 2)

Find out the major product formed from the following reaction. [Me : −CH3 ]

(1)

(2)

(3)

(4)

Q3 - 2024 (04 Apr Shift 2)

#MathBoleTohMathonGo
[Link]
Amines JEE Main 2024 April Question Bank

Questions MathonGo

Phthalimide is made to undergo following sequence of reactions.

Total number of π bonds present in product 'P' is/are ______

Q4 - 2024 (04 Apr Shift 2)

From 6.55 g of aniline, the maximum amount of acetanilide that can be prepared will be ______ ×10−1 g.

Q5 - 2024 (05 Apr Shift 2)

Xg of ethanamine was subjected to reaction with NaNO2 /HCl followed by hydrolysis to liberate N2 and HCl.
The HCl generated was completely neutralised by 0.2 moles of NaOH. X is ______ g.

Q6 - 2024 (06 Apr Shift 1)

9.3 g of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of
orange dye produced (assume 100\% yield/conversion) is _______ g. (nearest integer)

Q7 - 2024 (06 Apr Shift 2)

Identify the product (A) in the following reaction.

#MathBoleTohMathonGo
[Link]
Amines JEE Main 2024 April Question Bank

Questions MathonGo

(1)

(2)

(3)

(4)

Q8 - 2024 (06 Apr Shift 2)

#MathBoleTohMathonGo
[Link]
Amines JEE Main 2024 April Question Bank

Questions MathonGo

The ratio of number of oxygen atoms to bromine atoms in the product Q is ______ ×10−1 .

Q9 - 2024 (06 Apr Shift 2)

An amine (X) is prepared by ammonolysis of benzyl chloride. On adding p-toluenesulphonyl chloride to it the
solution remains clear. Molar mass of the amine (X) formed is ______ gmol−1 .

(Given molar mass in gmol−1 C : 12, H : 1, O : 16, N : 14)

Q10 - 2024 (08 Apr Shift 1)

If 279 g of aniline is reacted with one equivalent of benzenediazonium chloride, the maximum amount of

aniline yellow formed will be _______ g. (nearest integer)

(consider complete conversion).

Q11 - 2024 (08 Apr Shift 1)

Number of amine compounds from the following giving solids which are soluble in NaOH upon reaction with

Hinsberg's reagent is _______

Q12 - 2024 (08 Apr Shift 2)

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Amines JEE Main 2024 April Question Bank

Questions MathonGo

Match List - I with List - II.

Choose the correct answer from the options given below :

(1) (A)-(IV), (B)-(II), (C)-(III), (D)-(I)

(2) (A)-(I), (B)-(IV), (C)-(II), (D)-(III)

(3) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)


(4) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)

Q13 - 2024 (08 Apr Shift 2)

Given below are two statements :

Statement (I) : All the following compounds react with p-toluenesulfonyl chloride.
C6 H5 NH2 (C6 H5 )2 NH (C6 H5 )3 N
Statement (II) : Their products in the above reaction are soluble is aqueous NaOH. In the light of the above

statements, choose the correct answer from the options given below

(1) Statement I is false but Statement II is true


(2) Statement I is true but Statement II is false

(3) Both Statement I and Statement II are true

(4) Both Statement I and Statement II are false

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Amines JEE Main 2024 April Question Bank

Questions MathonGo

Q14 - 2024 (09 Apr Shift 2)

Major product of the following reaction is

(1)

(2)

(3)

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[Link]
Amines JEE Main 2024 April Question Bank

Questions MathonGo

(4)

#MathBoleTohMathonGo
[Link]
Amines JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Q1 - 2024 (01 Feb Shift 2)

Number of compounds which give reaction with Hinsberg's reagent is _______.

Q2 - 2024 (29 Jan Shift 2)

Which of the following reaction is correct?



HNO2 C

(1) CH 3
CH2 CH2 NH2 −−−−−→ CH3 CH2 OH + N2 + HCl
H2 O

(2)

(3)
C2 H5 CONH2 + Br2 + NaOH
(4)
→ C2 H5 CH2 NH2 + Na2 CO3 + NaBr + H2 O

Q3 - 2024 (29 Jan Shift 2)

The product A formed in the following reaction is:

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Amines JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(1)

(2)

(3)

(4)

Q4 - 2024 (30 Jan Shift 1)

Following is a confirmatory test for aromatic primary amines. Identify reagent (A) and (B)

(1) A = HNO 3 /H2 SO4 ;

(2) A = NaNO 2

+ HCl, 0 − 5 C ;

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Amines JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

(3) A = NaNO 2

+ HCl, 0 − 5 C ;

(4) A = NaNO 2

+ HCl, 0 − 5 C ;

Q5 - 2024 (30 Jan Shift 2)

The products A and B formed in the following reaction scheme are respectively

(1)

(2)

(3)

(4)

Q6 - 2024 (31 Jan Shift 2)

Given below are two statements :


Statement I: Aniline reacts with con. H 2
SO4 followed by heating at 453 − 473 K gives p− aminobenzene

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Amines JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

sulphonic acid, which gives blood red colour in the 'Lassaigne's test'.
Statement II: In Friedel - Craft's alkylation and acylation reactions, aniline forms salt with the AlCl catalyst.
3

Due to this, nitrogen of aniline aquires a positive charge and acts as deactivating group.
In the light of the above statements, choose the correct answer from the options given below :

(1) Statement I is false but statement II is true

(2) Both statement I and statement II are false


(3) Statement I is true but statement II is false
(4) Both statement I and statement II are true

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Amines Chapter-wise Question Bank
JEE Main 2025 April MathonGo
Q1. The correct order of basic nature on aqueous solution for the bases NH 3
, H2 N − ​ ​

NH 2 , CH 3 CH 2 NH 2 , (CH 3 CH 2 ) 2 NH and (CH 3 CH 2 ) 3 N is :


​ ​ ​ ​ ​ ​ ​ ​ ​ ​

(1) NH 3 ​
< H 2 N − NH 2 < (CH 3 CH 2 ) 3 N < CH 3 CH 2 NH 2 < (CH 3 CH 2 ) 2 NH
​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

(2) NH 3 ​
< H 2 N − NH 2 < CH 3 CH 2 NH 2 < (CH 3 CH 2 ) 2 NH < (CH 3 CH 2 ) 3 N
​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

(3) H 2 ​
N − NH 2 < NH 3 < (CH 3 CH 2 ) 3 N < CH 3 CH 2 NH 2 < (CH 3 CH 2 ) 2 NH
​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

(4) NH 2 ​
− NH 2 < NH 3 < CH 3 CH 2 NH 2 < (CH 3 CH 2 ) 3 N < (CH 3 CH 2 ) 2 NH
​ ​ ​ ​ ​ ​ ​ ​ ​ ​ ​

Q2. Identify [A], [B], and [C], respectively in the following reaction sequence :

(1)

(2)

(3)
Amines Chapter-wise Question Bank
JEE Main 2025 April MathonGo

(4)

Q3. In the following reactions, which one is NOT correct?

(1)

(2)

(3)

(4)
Amines Chapter-wise Question Bank
JEE Main 2025 April MathonGo
Q4. The sequence from the following that would result in giving predominantly 3, 4, 5-Tribromoaniline is :

(1)

(2)

(3)

(4)

Q5. The major product (A) formed in the following reaction sequence is
Amines Chapter-wise Question Bank
JEE Main 2025 April MathonGo

(1)

(2)

(3)

(4)
Amines Chapter-wise Question Bank
JEE Main 2025 April MathonGo
Q6. The correct order of basicity for the following molecules is:

(1) P > Q > R

(2) R > P > Q

(3) Q > P > R

(4) R > Q > P

Q7. The descending order of basicity of following amines is:

Choose the correct answer from the options given below :

(1) B > E > D > A > C

(2) E > D > B > A > C

(3) E > D > A > B > C

(4) E > A > D > C > B

Q8. A −−−−−−→ B −−−−−−−−→ C


(i) NaOH (i) EtOH

+
(ii) H3 O (ii) H2 SO4 ,Δ

' A ' shows positive Lassaign's test for N and its molar mass is 121.
' B ' gives effervescence with aq. NaHCO . 3
Amines Chapter-wise Question Bank
JEE Main 2025 April MathonGo
'C' gives fruity smell.
Identify A, B and C from the following.

(1)

(2)

(3)

(4)

Q9. Which of the following amine (s) show (s) positive carbylamines test?

(A)
(B) (CH 3)
2
NH
Amines Chapter-wise Question Bank
JEE Main 2025 April MathonGo
(C) CH 3 NH2

(D) (CH 3)
3
N

(E)

(1) A and E Only

(2) C Only

(3) A and C Only

(4) B, C and D Only

Q10. When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid ( 273 K) and
acidified with acetic acid, the mass ( g) of 0.1 mole of product formed is :
(Given molar mass in gmol −1
H : 1, C : 12, N : 14 , O : 16, S : 32)

(1) 343

(2) 330

(3) 33

(4) 66
Biomolecules Chapter-wise Question Bank
JEE Main 2025 April MathonGo
Q1. Which of the following is the correct structure of L-fructose?

(1)

(2)
Biomolecules Chapter-wise Question Bank
JEE Main 2025 April MathonGo

(3)

(4)
Biomolecules Chapter-wise Question Bank
JEE Main 2025 April MathonGo
Q2. Given below are two statements:
−H2 O

Statement I : D-(+)-glucose +D − (+) fructose −−−→


Statement II : Invert sugar is formed during sucrose hydrolysis.
In the light of the above statements, choose the correct answer from the options given below -

(1) Both Statement I and Statement II are true.

(2) Statement I is false but Statement II are true.

(3) Statement I is true but Statement II is false.

(4) Both Statement I and Statement II are false.

Q3. Fat soluble vitamins are :


A. Vitamin B 1

B. Vitamin C
C. Vitamin E
D. Vitamin B 12

E. Vitamin K
Choose the correct answer from the options given below :

(1) C & D Only

(2) A & B Only

(3) B & C Only

(4) C & E Only

Q4. Given below are two statements :


Statement I : Wet cotton clothes made of cellulose based carbohydrate takes comparatively longer time to get
dried than wet nylon polymer based clothes.
Statement II : Intermolecular hydrogen bonding with water molecule is more in nylon-based clothes than in the
case of cotton clothes.
In the light of above statements, choose the Correct answer from the options given below

(1) Statement I is false but Statement II is true

(2) Statement I is true but Statement II is false

(3) Both Statement I and Statement II are true

(4) Both Statement I and Statement II are false

Q5. Identify the correct statement among the following:

(1) All naturally occurring amino acids except glycine contain one chiral centre.
Biomolecules Chapter-wise Question Bank
JEE Main 2025 April MathonGo
(2) All naturally occurring amino acids are optically active.

(3) Glutamic acid is the only amino acid that contains a-COOH group at the side chain.

(4) Amino acid, cysteine easily undergo dimerization due to the presence of free SH group.

Q6. A tetrapeptide " x " on complete hydrolysis produced glycine (Gly), alanine (Ala), valine (Val), leucine (Leu) in
equimolar proportion each. The number of tetrapeptides (sequences) possible involving each of these amino acids
is

(1) 16

(2) 32

(3) 8

(4) 24

Q7. Identify the pair of reactants that upon reaction, with elimination of HCl will give rise to the dipeptide Gly-Ala.

(1)

(2)

(3)

(4)

Q8. A dipeptide, " x " on complete hydrolysis gives " y " and " z ". " y " on treatment with aq. HNO produces lactic
2

acid. On the other hand " z " on heating gives the following cyclic molecule.
Biomolecules Chapter-wise Question Bank
JEE Main 2025 April MathonGo

Based on the information given, the dipeptide X is:

(1) valine-glycine

(2) alanine-glycine

(3) valine-leucine

(4) alanine-alanine

Q9. Given below are two statements :


Statement (I) : On hydrolysis, oligo peptides give rise to fewer number of α-amino acids while proteins give rise
to a large number of β-amino acids.
Statement (II) : Natural proteins are denatured by acids which convert the water soluble form of fibrous proteins
to their water insoluble form.
In the light of the above statements, choose the most appropriate answer from the options given below :

(1) Both statement I and statement II are correct

(2) Statement I is incorrect but Statement II is correct

(3) Both statement I and statement II are incorrect

(4) Statement I is correct but Statement II is incorrect

Q10. The total number of hydrogen bonds of a DNA-double Helix strand whose one strand has the following
sequence of bases is_______.
5

- G - G-C-A-A-A-T-C-G-G-C-T-A-3'
Biomolecules Chapter-wise Question Bank
JEE Main 2025 April MathonGo
Q11.

Choose the correct option for structures of A and B, respectively.

(1)

(2)

(3)

(4)
Biomolecules JEE Main 2024 April Question Bank

Questions MathonGo

Q1 - 2024 (04 Apr Shift 1)

Which of the following is the correct structure of L-Glucose?

(1)

(2)

(3)

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Biomolecules JEE Main 2024 April Question Bank

Questions MathonGo

(4)

Q2 - 2024 (04 Apr Shift 2)

Match List I with List II


List - I List - II
A. α - Glucose and α - Galactose I. Functional isomers
B. α - Glucose and β - Glucose II. Homologous
C. α - Glucose and α - Fructose III. Anomers
D. α - Glucose and α - Ribose IV. Epimers
Choose the correct answer from the options given below:

(1) A-IV, B-III, C-I, D-II

(2) A-III, B-IV, C-I, D-II


(3) A-IV, B-III, C-II, D-I

(4) A-III, B-IV, C-II, D-I

Q3 - 2024 (04 Apr Shift 2)

Vanillin compound obtained from vanilla beans, has total sum of oxygen atoms and π electrons is ______

Q4 - 2024 (05 Apr Shift 1)

Which of the following gives a positive test with ninhydrin?

(1) Starch

(2) Egg albumin


(3) Polyvinyl chloride

(4) Cellulose

#MathBoleTohMathonGo
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Biomolecules JEE Main 2024 April Question Bank

Questions MathonGo

Q5 - 2024 (05 Apr Shift 2)

Coagulation of egg, on heating is because of :

(1) The secondary structure of protein remains unchanged


(2) Denaturation of protein occurs

(3) Biological property of protein remains unchanged


(4) Breaking of the peptide linkage in the primary structure of protein occurs

Q6 - 2024 (06 Apr Shift 1)

DNA molecule contains 4 bases whose structure are shown below. One of the structures is not correct, identify

the incorrect base structure.

(1)

(2)

(3)

(4)

Q7 - 2024 (06 Apr Shift 2)

#MathBoleTohMathonGo
[Link]
Biomolecules JEE Main 2024 April Question Bank

Questions MathonGo

The incorrect statements regarding enzymes are :

(A) Enzymes are biocatalysts.


(B) Enzymes are non-specific and can catalyse different kinds of reactions.

(C) Most Enzymes are globular proteins.

(D) Enzyme - oxidase catalyses the hydrolysis of maltose into glucose.

Choose the correct answer from the option given below :

(1) (B), (C) and (D)

(2) (B) and (D)

(3) (A), (B) and (C)

(4) (B) and (C)

Q8 - 2024 (08 Apr Shift 1)

The incorrect statement regarding the given structure is

(1) can be oxidized to a dicarboxylic acid with Br2 water

(2) will coexist in equilibrium with 2 other cyclic structure

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Biomolecules JEE Main 2024 April Question Bank

Questions MathonGo

(3) despite the presence of - CHO does not give Schiff's test

(4) has 4 asymmetric carbon atom

Q9 - 2024 (08 Apr Shift 2)

The total number of carbon atoms present in tyrosine, an amino acid, is _______

Q10 - 2024 (09 Apr Shift 1)

Total number of essential amino acid among the given list of amino acids is _______

Arginine, Phenylalanine, Aspartic acid, Cysteine, Histidine, Valine, Proline

Q11 - 2024 (09 Apr Shift 2)

The incorrect statement about Glucose is :

(1) Glucose is soluble in water because of having aldehyde functional group

(2) Glucose remains in multiple isomeric form in its aqueous solution

(3) Glucose is one of the monomer unit in sucrose

(4) Glucose is an aldohexose

#MathBoleTohMathonGo
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Biomolecules JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Q1 - 2024 (01 Feb Shift 1)

If one strand of a DNA has the sequence ATGCTTCA, sequence of the bases in complementary strand is:

(1) CATTAGCT
(2) TACGAAGT
(3) GTACTTAC

(4) ATGCGACT

Q2 - 2024 (01 Feb Shift 2)

The number of tripeptides formed by three different amino acids using each amino acid once is _______.

Q3 - 2024 (27 Jan Shift 1)

Two nucleotides are joined together by a linkage known as :

(1) Phosphodiester linkage

(2) Glycosidic linkage


(3) Disulphide linkage

(4) Peptide linkage

Q4 - 2024 (27 Jan Shift 2)

Which structure of protein remains intact after coagulation of egg white on boiling?

(1) Primary
(2) Tertiary

(3) Secondary
(4) Quaternary

Q5 - 2024 (29 Jan Shift 1)

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Questions with Answer Keys MathonGo

Match List I with List II


LIST-I LIST-II

(Substances) (Element Present)

[Link] catalyst [Link]

[Link] Pigment II. Cobalt

[Link] catalyst [Link]

[Link] B B 12 [Link]

Choose the correct answer from the options given below:

(1) A-II, B-IV, C-I, D-III


(2) A-II, B-III, C-IV, D-I

(3) A-III, B-II, C-IV, D-I

(4) A-IV, B-III, C-I, D-II

Q6 - 2024 (29 Jan Shift 1)

Type of amino acids obtained by hydrolysis of proteins is :

(1) β

(2) α

(3) δ

(4) γ

Q7 - 2024 (29 Jan Shift 1)

Number of compounds among the following which contain sulphur as heteroatom is _______
Furan,Thiophene, Pyridine, Pyrrole, Cysteine, Tyrosine

Q8 - 2024 (29 Jan Shift 2)

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Biomolecules JEE Main 2024 January Question Bank

Questions with Answer Keys MathonGo

Match List I with List II

Choose the correct answer from the options given below :-

(1) A-II, B-I, C-III, D-IV

(2) A-IV, B-II, C-I, D-III

(3) A-I, B-III, C-IV, D-II


(4) A-II, B-III, C-I, D-IV

Q9 - 2024 (30 Jan Shift 1)

Sugar which does not give reddish brown precipitate with Fehling's reagent is:

(1) Sucrose

(2) Lactose

(3) Glucose
(4) Maltose

Q10 - 2024 (30 Jan Shift 2)

The total number of correct statements, regarding the nucleic acids is


A. RNA is regarded as the reserve of genetic information.
B. DNA molecule self-duplicates during cell division

C. DNA synthesizes proteins in the cell.


D. The message for the synthesis of particular proteins is present in DNA
E. Identical DNA strands are transferred to daughter cells.

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Questions with Answer Keys MathonGo

Q11 - 2024 (31 Jan Shift 1)

Match List I with List II


List - I List - II

A. Glucose /NaHCO3 /Δ I. Gluconic acid

B. Glucose /HNO3 II. No reaction

C. Glucose/HI/ Δ III. n-hexane

D. Glucose / Bromine water IV. Saccharic acid

Choose the correct answer from the options given below:

(1) A-IV, B-I, C-III, D-II


(2) A-II, B-IV, C-III, D-I
(3) A-III, B-II, C-I, D-IV

(4) A-I, B-IV, C-III, D-II

Q12 - 2024 (31 Jan Shift 2)

A compound (x) with molar mass 108 g mol −1


undergoes acetylation to give product with molar mass

192 g mol
−1
. The number of amino groups in the compound (x) is _______

Q13 - 2024 (31 Jan Shift 2)

From the vitamins A, B B 1, B6 , B12 , C, D, E and K, the number vitamins that can be stored in our body is

_______

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Amines Chapter-wise Question Bank
JEE Main 2025 January MathonGo

Q1. Given below are some nitrogen containing compounds

Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume _______ mg of
HCl. (Given molar mass in gmol −1
C : 12, H : 1, O : 16, Cl : 35.5 )

Q2. Identify correct statements : (A) Primary amines do not give diazonium salts when treated with NaNO in 2

acidic condition. (B) Aliphatic and aromatic primary amines on heating with CHCl and ethanolic KOH form
3

carbylamines. (C) Secondary and tertiary amines also give carbylamine test. (D) Benzenesulfonyl chloride is
known as Hinsberg's reagent. (E) Tertiary amines reacts with benzenesulfonyl chloride very easily. Choose the
correct answer from the options given below :
(1) (A) and (B) only (2) (D) and (E) only
(3) (B) and (D) only (4) (B) and (C) only

Q3.

For reaction
The correct order of set of reagents for the above conversion is :
(1) Br2 ∣ FeBr3, H2O(Δ), NaOH (2) H 2SO4, Ac2O, Br2, H2O(Δ), NaOH

(3) Ac 2O, Br2, H2O(Δ), NaOH (4) Ac 2O, H2SO4, Br2, NaOH

59
Amines Chapter-wise Question Bank
JEE Main 2025 January MathonGo

Q4.

Which among the following react with Hinsberg's reagent?


Choose the correct answer from the options given below:
(1) A, B and E Only (2) A, C and E Only
(3) C and D Only (4) B and D Only

Q5. Consider the following sequence of reactions to produce major product (A)

Molar mass of product (A) is gmol


−1
. (Given molar mass in gmol −1
of
C : 12, H : 1, O : 16, Br : 80, N : 14, P : 31 )

Q6. Consider the following sequence of reactions.

Total number of sp hybridised carbon atoms in the major product C formed is________
3

60
Amines Chapter-wise Question Bank
JEE Main 2025 January MathonGo

Q7. The products formed in the following reaction sequence are :

(1) (2)

, CH
3 − CHO , CH3 − COOH

(3) (4)

, CH
3 − CHO

Q8. Consider the following sequence of reactions :

Molar mass of the product formed (A) is _______ gmol . −1

61
Amines Chapter-wise Question Bank
JEE Main 2025 January MathonGo

Q9. Match the Compounds (List - I) with the appropriate Catalyst/Reagents (List - II) for their reduction into

corresponding amines.
Choose the correct answer from the options given below :
(1) (A)-(II), (B)-(I), (C)-(III), (D)-(IV) (2) (A)-(III), (B)-(II), (C)-(IV), (D)-(I)
(3) (A)-(II), (B)-(IV), (C)-(III), (D)-(I) (4) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

62
Biomolecules Chapter-wise Question Bank
JEE Main 2025 January MathonGo

Q1. List - I List - II

(Carbohydrate) (Linkage Source)

(A) Amylose (I) β − C1 − C4, plant


Match List - I with List - II. Choose the
(B) Cellulose (II) α − C1 − C4, animal

(C) Glycogen (III) α − C1 − C4, α − C1 − C6, plant

(D) Amylopectin (IV) α − C1 − C4, plant

correct answer from the options given below :


(1) (A)-(IV), (B)-(I), (C)-(III), (D)-(II) (2) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
(3) (A)-(II), (B)-(III), (C)-(I), (D)-(IV) (4) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)

Q2. Identify the essential amino acids from below : (A) Valine (B) Proline (C) Lysine (D) Threonine (E) Tyrosine
Choose the correct answer from the options given below :
(1) (A), (C) and (E) only (2) (A), (C) and (D) only
(3) (C), (D) and (E) only (4) (B), (C) and (E) only

Q3. Given below are two statements: Statement I : D-glucose pentaacetate reacts with 2, 4-dinitrophenylhydrazine
Statement II : Starch, on heating with concentrated sulfuric acid at 100 ∘
C and 2-3 atmosphere pressure produces
glucose. In the light of the above statements, choose the correct answer from the options given below
(1) Statement I is false but Statement II is true (2) Both Statement I and Statement II are false
(3) Both Statement I and Statement II are true (4) Statement I is true but Statement II is false

Q4.

Match List - I with List - II.


Choose the correct answer from the options given below :
(1) (A)-(IV), (B)-(II), (C)-(I), (D)-(III) (2) (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
(3) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) (4) (A)-(II), (B)-(IV), (C)-(III), (D)-(I)

Q5. Identify correct conversion during acidic hydrolysis from the following : (A) starch gives galactose. (B) cane
sugar gives equal amount of glucose and fructose. (C) milk sugar gives glucose and galactose. (D) amylopectin
gives glucose and fructose. (E) amylose gives only glucose. Choose the correct answer from the options given
below :
(1) (A), (B) and (C) only (2) (B), (C) and (E) only
(3) (C), (D) and (E) only (4) (B), (C) and (D) only

Q6. The carbohydrate "Ribose" present in DNA, is A. A pentose sugar B. present in pyranose from C. in "D"
configuration D. a reducing sugar, when free E. in ∝-anomeric form Choose the correct answer from the options
given below:
(1) A, D and E Only (2) A, C and D Only
(3) A, B and E Only (4) B, D and E Only

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Biomolecules Chapter-wise Question Bank
JEE Main 2025 January MathonGo

Q7.

Choose the correct answer from the options given below :


(1) (A)-(IV), (B)-(III), (C)-(II), (D)-(I) (2) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
(3) (A)-(III), (B)-(IV), (C)-(I), (D)-(II) (4) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)

Q8. Given below are two statements: Statement I: Fructose does not contain an aldehydic group but still reduces
Tollen's reagent Statement II: In the presence of base, fructose undergoes rearrangement to give glucose. In the
light of the above statements, choose the correct answer from the options given below
(1) Both Statement I and Statement II are true (2) Both Statement I and Statement II are false
(3) Statement I is true but Statement II is false (4) Statement I is true but Statement II is false

Q9. The α-Helix and β - Pleated sheet structures of protein are associated with its :

64
Biomolecules Chapter-wise Question Bank
JEE Main 2025 January MathonGo

(1) tertiary structure (2) quaternary structure


(3) secondary structure (4) primary structure

Q10. Which of the following acids is a vitamin?


(1) Adipic acid (2) Ascorbic acid
(3) Saccharic acid (4) Aspartic acid

Q11. Identify the number of structure/s from the following which can be correlated to D-glyceraldehyde.

(1) four (2) one


(3) two (4) three

65

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Aliphatic amines generally have higher basicity than aromatic amines due to the electron-donating nature of alkyl groups versus the electron-withdrawing effects in an aromatic system such as aniline. This difference affects their reactivity; aliphatic amines readily participate in reactions involving nucleophilic substitution, while aromatic amines are more involved in electrophilic aromatic substitution reactions. These properties guide their applications in synthesis, such as the preparation of dyes and pharmaceuticals .

Preparing acetanilide from aniline involves acetylation, where aniline is treated with acetic anhydride. This reaction replaces the hydrogen of the amine group with an acetyl group, forming acetanilide. The yield is dependent on the initial amount of aniline because an exact stoichiometric amount relative to acetic anhydride ensures complete reaction, minimizing waste and maximizing product formation .

The carbylamine test, which involves heating an amine with chloroform and alcoholic KOH, is specific for primary amines, yielding an isocyanide with a characteristic foul odor. Only primary amines test positive because secondary and tertiary amines do not form isocyanides under these conditions. It is a valuable diagnostic test for distinguishing primary amines from other amine types .

Amines' solubility in water decreases from primary to secondary to tertiary amines. Primary amines have the most hydrogen bonding capacity due to hydrogen atoms attached to the nitrogen, enhancing their solubility. Secondary and tertiary amines have reduced hydrogen bonding capacity as the number of hydrogens decreases. The nature of the substituents and overall molecular size also impact solubility .

The stability of diazonium salts is influenced by the aromatic ring's electron-withdrawing substituents, which stabilize the diazonium group by resonance. These salts are stabilized at low temperatures and are prone to decompose at higher temperatures, making them excellent intermediates for coupling reactions in azo compound synthesis. The ability to form stable intermediates opens pathways for many substitution and conversion reactions, extending their utility in synthetic chemistry .

Diazotisation of aniline involves converting the aniline group into a diazonium salt using sodium nitrite and HCl, followed by a coupling reaction with phenol. The diazonium salt reacts with phenol to produce an azo compound, which is an orange dye. Factors that influence a 100% yield include complete conversion of reactants, effective coupling reaction conditions, and purification of the azo compound .

Hinsberg's reagent, benzenesulfonyl chloride, is used to distinguish between primary, secondary, and tertiary amines. Primary amines react to form sulfonamide, which is soluble in alkali. Secondary amines form an insoluble sulfonamide, and tertiary amines do not react. Therefore, the solubility in alkali and the presence of precipitate help identify the type of amine .

Phthalimide is used in the Gabriel synthesis of amines, where it reacts with a base to form a phthalimide anion, which then undergoes nucleophilic substitution with an alkyl halide to form an N-alkylphthalimide. Hydrolysis of this intermediate yields a primary amine and phthalic acid. This method is preferred for preparing primary amines because it avoids over-alkylation and yields pure primary amines .

In electrophilic aromatic substitution (EAS) reactions involving aniline, the amino group is a strong activating, ortho/para-directing group. It increases the electron density on the aromatic ring, particularly at the ortho and para positions, favoring substitution at these sites. The major product positions can be influenced by reaction conditions, such as substituent effects and catalysts used, which direct the selectivity in synthetic pathways .

The synthesis of amines through ammonolysis of benzyl chloride involves the substitution of the chloride group by an amine group, resulting in the formation of a benzyl amine. The reaction with p-toluenesulphonyl chloride tests the presence of primary amines: a primary amine would form a precipitate. The solution remaining clear implies that the product is either a secondary or tertiary amine, as these do not form precipitates with p-toluenesulphonyl chloride .

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