02-02-2025

1201CJA101016240077 JA

PART-1 : PHYSICS

SECTION-I

1) Two springs of force constant K and 2K are connected to a mass M as shown. The frequency of

oscillation of the mass is :-

(A)

(B)

(C)

(D)

2) The phase difference between SHM, and at t = 0 sec.

(A) 150°
(B) 90°
(C) 120°
(D) 30°

3) A particle moves on the x-axis according to the equation x = A + Bsinωt. The motion is simple
harmonic with amplitude :-

(A) A
(B) B
(C) A + B
(D)

4) A particle is executing SHM with time period T starting from mean position time taken by it to

complete oscillations is:-

(A)

(B)
(C)

(D)

5) A small mass executes linear SHM about O with amplitude a and period T. Its displacement from

O at time after passing through O is:-

(A)

(B)

(C)

(D)

6) A system is shown in the figure the time period for small oscillations of the two block will be :-

(A)

(B)

(C)

(D)

7) A particle executing S.H.M. of amplitude 4 cm and T = 4 sec The time taken by it to move from
positive extreme position to half the amplitude is :–

(A) 1sec

(B)
sec

(C)
sec

(D)
sec

8) A particle moves on x-axis according to the equation x = x0 sin2ωt, the motion is simple harmonic
:-

(A) with amplitude x0

(B) with amplitude 2x0
(C) with time period (2π/ω)
(D) with time period (π/ω)

9) The potential energy of a particle of mass 'm' situated in a unidimensional potential field varies as
U(x) = U0 [1–cosax], where U0 and a are constants. The time period of small oscillations of the
particle about the mean position is :-

(A)

(B)

(C)

(D)

10) The potential energy of a particle executing SHM changes from maximum to minimum in 5 s.
Then the time period of SHM is :-

(A) 5 s
(B) 10 s
(C) 15 s
(D) 20 s

11) A homogeneous solid cylinder of length L (L < H/2). Cross-sectional area A/5 is immersed such
that it floats with its axis vertical at the liquid-liquid interface with length L/4 in the denser liquid as
shown in the fig. The lower density liquid is open to atmosphere having pressure P0. Then density of

solid is given by :-

(A)

(B)

(C) d

(D)

12) A vertical U-tube of uniform inner cross section contains mercury in both sides of its arms. A
glycerin (density = 1.3 g/cm3) column of length 10 cm is introduced into one of its arms. Oil of
density 0.8 gm/cm3 is poured into the other arm until the upper surfaces of the oil and glycerin are
in the same horizontal level. Find the length of the oil column, (Density of mercury = 13.6 g/cm3) :-
(A) 10.4 cm
(B) 8.2 cm
(C) 7.2 cm
(D) 9.6 cm

13) A cubical wooden block of side 10 cm floats at the interface between oil and water with its lower
face 2 cm below the interface. If the density of oil is 0.6 gcm–3, the mass of the block is

(A) 200 g
(B) 340 g
(C) 480 g
(D) 680 g

14) A closed vessel have a small hole in one face of vessel near the bottom as shown. The velocity of
water coming out from the given hole at given instant is :

(A) 5 m/s
(B) 2 m/s
(C) 3 m/s
(D)

15) A cord of negligible mass is wound round the rim of a fly wheel (disc) of mass 20 kg and radius
20 cm. A steady pull of 25 N is applied on the cord as shown in figure. Angular acceleration of the
wheel is :-

(A) 5 rad/s2
(B) 12.5 rad/sec2
(C) 25 rad/sec2
(D) 10 rad/s2

16) A small object of uniform density rolls up a rough curved surface with an initial velocity v while

doing pure rolling. It reaches upto a maximum height of w.r.t. the initial position. The object is

(A) Ring
(B) Solid sphere
(C) Hollow sphere
(D) Disc

17) A particle of mass m = 5 units is moving with a uniform speed in the XOY plane along
the line Y = X + 4. The magnitude of the angular momentum of the particle about the origin is :-

(A) zero
(B) 60 unit
(C) 7.5 unit
(D)

18) The angular speed of a star spinning about its axis increases as the star begins to contract to a
smaller radius due to internal forces. Which of the following quantities associated with the star
decreases as this occurs?

(A) Moment of inertia

(B) Angular momentum
(C) Rotational kinetic energy
(D) None of these

19) A slender uniform rod of mass M and length ℓ is pivoted at one end so that it can rotate in a
vertical plane (see figure). There is negligible friction at the pivot. The free end is held vertically
above the pivot and then released. The angular acceleration of the rod when it makes an angle θ
with the vertical is :

(A)

(B)

(C)

(D)

20) A hollow sphere of mass M and radius r slips on a rough horizontal plane. At some instant it has
translational velocity v0 and angular velocity about the centre v0/2r as shown in the figure. The

translational velocity after the sphere starts pure rolling

(A) 4v0/5 in forward direction

(B) 6v0/7 in backward direction
(C) 6v0/7 in forward direction
(D) 5v0/4 in backward direction

SECTION-II

1) A cubical block is floating in a liquid with half of its volume immersed in the liquid. When the
whole system accelerates upwards with acceleration of g/3, the fraction of volume immersed in the

liquid will be , find the value of N ?

2) Two soap bubbles of radii 3 cm and 4 cm are kept in touch with each other. The radius of
curvature of interface will be_____cm.

3) Water rises to a height of 20 mm in a capillary. If the radius of the capillary is made one third of
its previous value then what is the new value of the capillary rise? (in mm)

4) A simple pendulum has time period T1. The point of suspension is now moved upwards according
to the relation y = t2 + 2t + 1, where y is the vertical displacement. The time period now becomes T2.
The ratio is ; find x. (g = 10 m/s2)

5) Figure shows two holes in a tank containing liquid. The liquid coming out of holes strike ground at

same point. The height of liquid in tank is (in cm) :-

PART-2 : CHEMISTRY

SECTION-I

1) What is the correct order of inductive effect ?

–
(A) –O > –CH3 > –CMe3
– –
(B) –CO2 > –O > CHMe2
–
(C) –O > –CH2Me > –D > –H
(D) None

2) How many 1°, 2° and 3° H-atoms are present in (Toluene) respectively :

(A) 3, 0, 5
(B) 3, 5, 0
(C) 4, 3, 0
(D) 0, 5, 3
3) Decreasing order of stabilities of following carbocation is :

(A) IV > III > II > I

(B) I > II > III > IV
(C) II > IV > III > I
(D) I > III > IV > II

4) Arrange in the order of heat of hydrogenation

(i) CH3 – CH = CH2
(ii) CH3 – CH = CH – CH3

(iii)
(iv) CH2 = CH2

(A) (iv) > (i) > (ii) > (iii)

(B) (iv) > (iii) > (ii) > (i)
(C) (iii) > (ii) > (i) > (iv)
(D) (ii) > (i) > (iii) > (iv)

5)

Give the correct acidic order of hydrogen for following rounded.

(A) b > c > d > a

(B) c > b > a > d
(C) b > a > c > d
(D) c > b > d > a

6) Which order is correct for resonance energy?

(A)

(B)

(C)

(D)

7) The decreasing order of basicity of the following amines is:

(A) (I) > (III) > (IV) > (II)

(B) (I) > (III) > (II) > (IV)
(C) (III) > (II) > (I) > (IV)
(D) (II) > (III) > (IV) > (I)

8) Find out correct stability order in the following carbocation -

(I) (II)
(III) (IV)

(A) IV > I > III > II

(B) IV > III > I > II
(C) I > IV > III > II
(D) IV > III > IV > II

9) Consider the relative acidity of the following carboxylic acids.

Which one of the following gives the correct order of acidity?

(A) I > II > III > IV

(B) II > IV > III > I
(C) II > IV > I > III
(D) II > III > IV > I

10) The correct stability order of following resonating structures is

(I) CH2 = CH – CH = O

(II)

(III)

(A) II > III > I

(B) I > II > III
(C) I > III > II
(D) III > II > I
11) The increasing order of pKb values of the following compounds is -

(A) I < II < IV < III

(B) II < IV < III < I
(C) II < I < III < IV
(D) I < II < III < IV

12) Most stable carbocation is :-

(A)

(B)

(C)

(D)

13) Which species is not aromatic ?

(A)
(B)

(C)

(D)

14) Arrange the following carbocations in the order of stability :-

(a) (b)

(c) (d)

(e) (f)

(A) d > c > b > a > e > f

(B) c > d > f > b > e > a
(C) a > b > c > d > e > f
(D) d > c > f > b > a > e

15) The hybrid state of C-atoms which are attached to a single bond with each other in the following
structure are :
O=CH–C≡N

(A) sp2, sp3

(B) sp2,sp2
(C) sp3,sp3
(D) sp, sp2

16) The IUPAC name for the following compound is:

(A) 2, 5-dimethyl-5-carboxy-hex-3-enal
(B) 2, 5-dimethyl-6-carboxy-hex-3-enal
(C) 2, 5-dimethyl-6-oxo-hex-3-enoic acid
(D) 6-formyl-2-methyl-hex-3-enoic acid

17)
How many σ and π bonds are present in ?

(A) 9π, 17σ

(B) 3π, 21σ
(C) 9π, 15σ
(D) 6π, 18σ

18) IUPAC name of given compound are :

(A) 3-Hydroxypentanoic acid

(B) 4-Carboxy-3-hydroxybutane
(C) 4-Carboxybutan-3-ol
(D) 3-Hydroxypentanal

19) The IUPAC name of the following compound is

(A) 4-Bromo-3-cyanophenol
(B) 2-Bromo-5-hydroxybenzonitrile
(C) 2-Cyano-4-hydroxybromobenzene
(D) 6-Bromo-3-hydroxybenzene

20) has the IUPAC name :-

(A) 1 – Ethyl – 3, 3 – dimethyl cyclohexane

(B) 3 – Ethyl – 1, 3 – dimethyl cyclohexane
(C) 3 – Ethyl – 1, 1 – dimethyl cyclohexane
(D) 3, 3 – Dimethyl – 1 – ethyl cyclohexane

SECTION-II

1) Find total number of functional group in given compound.

2) Number of carbon atoms in the principal carbon chain of the given compound in the IUPAC name

will be

3) How many of the following are aromatic?

4) How many of the following will show resonance

5) Total number of pairs of resonating structure in which second is more stable than first.

(a)
(b)

(c)

(d)

(e)

(f)

(g)

PART-3 : MATHEMATICS

SECTION-I

1) The function is

(A) Even function

(B) Odd function
(C) Neither even nor odd
(D) Periodic function

2) The range of the function y = is

(A)

(B)

(C)

(D) None of these

3) If then x belongs to :

(A)

(B)
(C)

(D)

4) Which one of the following is an odd function :-

(A)

(B)

(C)

(D)

5) The inverse of the function y = 2x – 3 is

(A)

(B)

(C)

(D)

6) The graph of : y = |x–3| + |x + 1| is

(A)
(B)

(C)

(D)

7) The domain of the definition of the function f(x) = is:-

(A) (1, 2) ∪ (2, ∞)

(B) (–1, 0) ∪ (1, 2) ∪ (3, ∞)
(C) (–1, 0) ∪ (1, 2) ∪ (2, ∞)
(D) (–2, –1) ∪ (–1, 0) ∪ (2, ∞)

8) If f(x) + 2f = 3x, x ≠ 0, and

S = {x ∈ R : f(x) = f(–x)}; then S :

(A) contains more than two elements.

(B) is an empty set.
(C) contains exactly one element
(D) contains exactly two elements

9) Range of the function is

(A) [0, ∞)
(B) (1, ∞)
(C) (–∞, 0)
(D) (–∞, 1)

10) If f(x + 2a) = f(x – 2a), then f(x) is :

(A) A periodic function with period 4a

(B) A periodic function with period 2a
(C) A periodic function with indeterminate period
(D) A non periodic function

11) If f : R → R, f(x) = 2x + sin x, then f is :-

(A) One-one function and onto function

(B) One-one function but not onto function
(C) Onto function but not one-one function
(D) Neither one-one function nor onto function

12) If [x] & {x} represent G.I.F and fractional part function of x, then the value of is :

(A) x
(B) [x]
(C) {x}
(D) x + 2001

13) The term independent of x in is

(A)

(B)

(C)

(D)

0
14) The term with x in is:

(A)
(B)
(C)
(D)

15) The sum of series

equals

(A) 5050
(B) 5051
(C) 4950
(D) 5151
16) Let the solution set of the equation :

is [a, b). Then the value of a + b = ______

(where [.] and {.} denote greatest integer and fractional part function respectively).

(A) 7
(B) 3
(C) 4
(D) 8

17) If = then the value of k is:

(A) 1
(B) 2
(C) 4
(D) 5

18) is equal to

2n 2n
(A) 2 – Cn
2n–1 2n–1
(B) 2 – Cn–1

(C)

(D)

19) The value of is :

(A)

(B)

(C)

(D) None of these

20) If f(x) = x2 + bx + c and f(2 + t) = f(2 – t) for all real numbers t, then which of the following is
true?

(A) f(1)< f(2) < f(4)

(B) f(2)< f(1) < f(4)
(C) f(2)< f(4) < f(1)
(D) f(4)< f(2) < f(1)

SECTION-II

1) If –a2x + aby + acz = 0, abx – b2y + bcz = 0 and acx + bcy – c2z = 0 have non-trivial solutions,

then find the value of .

2) For positive numbers the numerical value of determinant

is ___

3)

Let Dk = . If , then n is equal to

4) Let n (A) = 4 & n (B) = 6 then the number of one-one functions from A to B is:

5) The number of integral terms in the expansion of is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D B D D C C D C D A D D A B D B A C A

SECTION-II

Q. 21 22 23 24 25
A. 2 12 60 6 10

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B A A A B C C D B D C B B D C C A B C

SECTION-II

Q. 46 47 48 49 50
A. 4 5 6 6 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C D D A D C D A A A C C B D A C A C B

SECTION-II

Q. 71 72 73 74 75
A. 0 8 6 360 33
 SOLUTIONS

PART-1 : PHYSICS

1)

Springs are in parallel combination

2)

ϕ1 – ϕ2 = (πt + 60°) – (πt + 30°) = 30°

3) (x –A) = Bsinωt
SHM of particle about x = A and its amplitude is B.

8) x = x0sin2 ωt

Frequency ω' = 2ω
⇒ 2π/T' = 2ω
⇒ T' = (π/ω)
Amplitude = x0/2

9)

0 0
F= = –U [0 + asin ax] = –U a sin ax
for small oscillation; sinax ≈ ax
⇒ F = –(U0a2x)

⇒T=

10)

P.E. is maximum at extreme position and minimum at mean position.

Time to go from extreme position to mean position is, t = ; where T is time period of SHM

5s=
⇒ T = 20 s.
11)

ρ= =

12) P0 + ρglyg(10) = ρ0 + ρoilgh + ρHgg(10–h)

(1.3) (10) = (0.8) (h) + (13.6) (10–h)
h 9.6 cm

13) 8(100)0.6 g + 2(100) 1g = mg

⇒ m = 680 g

14) .9P + ρgh = P +

0 0

⇒ v = 5 m/s

16) and ω = v/R (rolling)

⇒ ⇒ disc

17)

= 60 unit

18) Separation of mass from axis get decreases so MOI decreases

 19)
Taking torque about pivot τ = Ια

mgsinθ =α

⇒α= sinθ

20)
Angular momentum can be conserved about lowest point

0
mv r + = mv'r +

v' =

24)

25) R = 2
2H – 8 = 3H – 18
H = 10 cm

PART-2 : CHEMISTRY

26) From theory

27)
1°H = 3°, 2°H = 5, 3°H = 0.

28)

29) Heat of hydrogenation

31)

-
32) Localised lone pair having high e density is more basic

Basicity order: III > II > I > IV

34) Acidic strength ∝ + M, + I ∝

 38)

47)

48)

50) a, c, d, e

PART-3 : MATHEMATICS

52)

–1 ≤ sin3x ≤ 1
1 ≥ –sin3x ≥ –1
1 + 2 ≥ 2 – sin3x ≥ 2 – 1

Range

54) Only in option (4), the graph has a symmetry w.r.t. origin.
56) y = |x – 3| + |x + 1| =

58) f(x) + 2f(1/x) = 3x .... (1)

x→ ⇒ f(1/x) + 2f(x) = 3/x .... (2)

f(x) + 2 = 3x

⇒ 3f(x) = – 3x ⇒ f(x) = –x

For S f(x) = f(–x) ⇒ –x=0

⇒x=

61) f(x) = 2x + sin x

f′(x) = 2 + cos x > 0
f(x) is increasing function so one–one function.
as x → ∞, f(x) →∞
as x → –∞, f(x) → (–∞)
so Range ∈ (–∞, ∞)
so onto

62)

63)

general term Tr+1=

term independent of x
18 - 2r - r = 0
3r = 18
r=6
64)

3rd term

65)

67) Numerator =

Denominator =

The expression is equal to:

68)

=
= (2n) (2n) – 2nCn
= 22n – 2nCn

69) Required sum =

71) The equation –a2x + aby + acz = 0, abx – b2y + bcz = 0 and acx + bcy – c2z = 0 have a non-
trivial solution.

⇒ =0 ....(i)

⇒ =0

⇒ =0

72)
73)

74) No. of one one functions

75)

∴ is an integer if and are both non-negative integers

∴ Possible values of r are 0, 8, 16, 24,....,256
∴ No. of integral terms = 1+ 32 = 33