Quantum Mechanics: Wave Function Normalization Problems
Problem 1: Exponential Wave Function
A particle has a wave function:
ψ(x) = Ae−a∣x∣ , −∞ < x < ∞
where a >0.
(a) Find the normalization constant A .
Solution: We require:
∞
∫ ∣ψ(x)∣2 dx = 1
−∞
∣ψ(x)∣2 = A2 e−2a∣x∣
Since the function is even:
∞
A2 ⋅ 2 ∫ e−2ax dx = 1
0
∞
1 −2ax 1 A2
= 2A2 [− e ] = 2A2 ⋅ = =1
2a 0 2a a
A= a
Problem 2: Sine Wave Function in 1D Box
2πx
ψ(x) = A sin ( ), 0≤x≤L
L
(a) Find A .
(b) Find the probability the particle is between 0 and L/2 .
Solution: (a)
L
∫ ∣ψ(x)∣2 dx = 1
0
L
2πx
A2 ∫ sin2 ( ) dx = 1
0 L
1
L 2
= A2 =1⇒A=
2 L
(b)
L/2
2πx
P = A2 ∫ sin2 ( ) dx
0 L
2 L
= ⋅ = 0.5
L 4
Problem 3: Complex Exponential Wave Function
ψ(x) = Aeikx , 0≤x≤L
(a) Find A .
(b) Find the probability the particle is between L/4 and 3L/4 .
Solution: (a)
∣ψ∣2 = ∣A∣2
1 iϕ
∣A∣2 L = 1 ⇒ A = e
L
where ϕ is arbitrary.
(b)
P = ∣A∣2 (3L/4 − L/4) = ∣A∣2 L/2 = 0.5
Problem 4: Gaussian Wave Function
2
ψ(x) = Ae−ax , −∞ < x < ∞
(a) Find A .
(b) Find probability particle is in [−1, 1] if a =1.
Solution: (a)
1/4
2a
=1⇒A=( )
π
A2
2a π
2
(b)
1
P = A2 ∫
2
e−2x dx
−1
(Numerical integration gives P ≈ 0.76 )
Problem 5: Superposition of Sine Functions
2πx
ψ(x) = A (sin ),
πx
+ sin 0≤x≤L
L L
(a) Find A .
Solution:
2
2πx
∣ψ∣2 = A2 (sin )
πx
+ sin
L L
= A2 (∫ dx)
L
πx 2πx
sin2 + sin2
0 L L
1
= A2 L ⇒ A =
L