03-08-2025

7501CJA101021250068 JA

PHYSICS

SECTION-I

1) A cyclic process ABCD is shown in the P–V diagram. (BC and DA are isothermal)

Which of the following curves represents the same process?

(A)

(B)

(C)

(D)

2) In a potentiometer wire experiment the emf of a battery in the primary circuit is 20V and its
internal resistance is 5Ω. There is a resistance box in series with the battery and the potentiometer
wire, whose resistance can be varied from 120Ω to 170Ω. Resistance of the potentiometer wire is
75Ω. The following potential differences can be measured using this potentiometer.

(A) 5V
(B) 6V
(C) 7V
(D) 8V

3) In the circuit shown in figure, reading of ammeter will :-

(A) increase if S1 is closed

(B) decrease if S1 is closed
(C) increase if S2 is closed
(D) decrease if S2 is closed

4) As shown in circuit

(A) The potential at P is –15V

(B) The potential at Q is –2V
(C) The potential at R is zero
(D) The potential at S is zero

5) In the network shown, points A, B and C are potentials of 70 V, zero and 10 V respectively which

one is incorrect

(A) Point D is at a potential of 40 V

(B) The currents in the sections AD, DB, DC are in the ratio 3: 2: 1
(C) The currents in the sections AD, DB, DC are in the ratio 1: 2: 3
(D) The network draws a total power of 200 W.

6) In the circuit shown below, the key is pressed at time t = 0. Which of the following statement(s)
is(are) true?

(A) The voltmeter displays –5V as soon as the key is pressed, and displays +5V after a long time.
(B) The voltmeter will display 0 V at time t = ln 2 seconds.
(C) The current in the ammeter becomes 1/e of the initial value after 1 second.
(D) The current in the ammeter becomes zero after a long time.

SECTION-II

1) 20 gm ice at -10 °C is mixed with m gm steam at 100 °C. The minimum value of m so that finally

all ice and steam converts into water is . Find the value of x: (Use sice=0.5cal/gm°C,swater = 1
cal/gm°C,L (melting) = 80 cal/gm and L (vaporization)=540 cal/gm)

2) Determine the current x (in A) in the 4Ω resistance of the circuit shown in figure. The

represents constant current carrying source of 6A.

3) Find charge supplied by the cell after the switch is closed (in µC)
4) The amount of heat generated in the circuit shown in figure after the switch S is shifted from

position 1 to position 2, is . Then find value of 'n' given that C0 = C.

5)

In the shown figure, potential at A point is 12V and point B is earthed. The potential at the point P
in volt is

6) Calculate the potential difference across the capacitor in the circuit (in Volts).

SECTION-III
1) 3J of heat is given to a gas at constant pressure of 200 N/m2. If its volume increases by 10 litres
during the process find the change in the internal energy of the gas (in J)

2) The adiabatic container shown in figure has two chambers, separated by a partition, of volumes V1
= 2.0 litre and V2 = 3.0 litre. The chambers contain μ1 = 4.0 and μ2 = 5.0 moles of a gas at pressures
p1 = 1.00 atm and p2 = 2.00 atm. The pressure after the partition is removed and the mixture attains

equilibrium is P atm, then the value of , Find N

3) A perfect voltmeter is connected between C & D gives reading 140 V. When we replace it with an
ideal ammeter, its reading is 21 A. Now, we connect a resistor r between C & D. If the current I (in

A) is flowing through this r between C & D. Find the value of .

4) There are six plates of equal area A and separation between the plates is d (d << A) are arranged

as shown in figure. The equivalent capacitance between points 2 and 5, is . Then find the value

of α.

5) Three identical air capacitors having plate separation 3 mm each are connected as shown. They
are charged by applying a potential difference V and then the source voltage is removed. When a 3
mm thick slab is introduced between all the plates, the distance between the plates is increased by
2.4 mm to maintain same potential difference. Find dielectric constant of the slab.

6) At time t = 0, a battery of 10 V is connected across points A and B in the given circuit. If the
capacitors have no charge initially, at what time (in seconds) does the voltage across them become

4V ? [Take ln5 = 1.6, ln3 = 1.1]

CHEMISTRY

SECTION-I

1) Which of the following are correct according to their properties mentioned

(A) Cr2O3 PbO ZnO, BeO, Al2O3 → All are amphoteric oxide
(B) AgI > AgBr > AgCl → Colour Intensity
(C) Be(OH)2 < Mg(OH)2 < Ba(OH)2 → Solubility order
(D) PbCl4 < PbCl2 → Stability

2) An amount of 4 moles of an ideal monoatomic gas expands adiabatically and reversibly by which
its temperature decreases from 47°C to 17°C. Which of the following is/are true?

(A) q = 0
(B) ΔH = 0
(C) ΔH = –600 cal
(D) ΔU = –360 cal

3)

0.5 mole each of two ideal gases and B(Cv.m. = 3R) are taken in a container and
expanded reversibly and adiabatically, during this process temperature of gaseous mixture
decreased from 350 K to 250 K. Then for the process :

(A) ΔU = –100 R
(B) ΔU = –275 R
(C) ΔH = –375 R
(D) ΔH = –300 R

4) Which of the following is/are state function?

(A) Enthalpy
(B) Internal energy
(C) Temperature
(D) Pressure
5) Correct statement about monochlorinated products of above reaction :

(A) Total 10 monochlorinated products are formed

(B) 6 resolvable products are formed
(C) 4 enantiomeric pair are obtained
(D) 7 fractions are obtained after fractional distillation of product mixture

6) The reaction among following which are correctly match with their Major product

(A)

(B)

(C)

(D)

SECTION-II

1)

How many pair are correct for covalent character order

(AlCl3 > MgCl2), (BeCl2 > LiCl), (PbCl4 > PbCl2), (HgS > ZnS), (CdCl2 > CaCl2)

2) What is the total number of intensive properties in the given list ?

(a) Internal energy (b) Pressure

(c) Molar entropy (d) Volume
(e) Density (f) Boiling point
(g) Molality

3) A gas expands against a variable pressure given by P = bar. During expansion from volume of
1 litre to 10 litre, the gas undergoes a change in internal energy of 400 J. Heat absorbed by the gas
during expansion (in kJ)
(consider volume in litre and take 1bar-lit = 100J)
4) When 1 mole of H2O2(g) decomposes to form H2O(g) and O2(g), 103 kJ/mole of energy is released.
Given the bond energies below.

what is the bond energy (in kJ/mole) of O–O single bond in H2O2.

5)

(I) product

(II) product
find the sum of product's (X + Y) including stereo isomers?

6) How many compounds gives positive haloform test ?

SECTION-III

1) Compounds which are more covalent in nature than BeCl2.

AlCl3 , MgCl2 , LiCl , CCl4 , BeBr2 , BeF2 , BeI2 , BCl3 , AlF3

2)

Calculate change in internal energy (in kJ) when 4 kJ of work is done on the system and 1 kJ of heat
is given out by the system.

3) Find magnitude of difference in standard Gibb's energy of formation of H2O(g) & H2O(l) for the
given reaction at 300K in kJ/mol if Vapour pressure of H2O at 300 K is 30 torr.
[Use : 1 bar = 75 cm Hg] [log5 = 0.7, R = 8.314 J/[Link]]
[Give your answer as nearest integer]

4) If heat of reaction for the given acid-base reaction :

HA + NaOH → NaA + H2O; ΔH = – 4.7 kcal
The heat of dissociation of HA (in kcal) ______ .
ΔHN = –13.7 kcal/mole

5)
If the percentage yield of step 1 is 60%, step 2 is 40% and step 3 is 80%, then report the mass of
C(ing) obtained if we start with 21 g of X. (Round off your answer to nearest integer)

6) Number of optically active isomers formed by the given reaction is(are):

MATHEMATICS

SECTION-I

1) The equation ax2 – 6xy + y2 + bx + cy + d = 0 represents pair of lines whose slopes are m and m2,
if angle between the lines is θ, then (a > 0)

(A)

(B)

(C)

(D)

2) One of the diameter of the circle circumscribing the rectangle ABCD is x – 3y + 1 = 0. If two
vertices of rectangle are the points A (–2, 5) and B (6, 5) respectively, then which of the following
hold(s) good?

(A) Area of rectangle ABCD is 64 square units.

(B) Centre of circle is (2, 1)
(C) The other two vertices of the rectangle are (–2, –3) and (6, –3)
(D) Equation of sides are x = -2, y = -3, x = 5 and y = 6.

3) Let if derivative of f(x) with respect to

g(x) at x = 1 exists and is equal to k, then
(A)
(B)

(C)

(D)

4)

Which of the following are true?

(A)

(B)
(C)
(D)

5) If f(x) = Then,

(A) f(1+) + f(1–) = 0

(B) f(1+) + f(1–) + f(1) = 3/2
(C) f(–1+) + f(–1–) = –1
(D) f(1+) + f(–1–) = 0

6)

If 3x + 3y = 3x+y , then has the value equal to :

(A)

(B)

(C) 1 – 3y

(D)

SECTION-II

1) For ℓ, m, n , p and q are the value of ℓ and m respectively such that equation ℓ(13 + 11n) +
m(19 + 17n) - 4 (8 + 7n) = 0 is satisfied then (p + q) equals

2) Three circles of radius 11,11 and 50 units are touching each other externally and a fourth circle of
radius r is placed such that it touches all 3 circles externally then r is equal to :
3) The sum of all possible value of x satisfying
(where [.] denotes the greatest integer function and {.} denotes fractional part) is S. Then the value
of 2S is

4) If the tangent of the curve at a point and the normal to the parabola at the

point (1, 2) intersect at the same point on the x-axis, then the value of is

5) If f(x) = , then least integral value of α for which f(x) has minima at x
=1, is

6)

If f(2016) = , f(x) = f(2x) ∀ x ∈ R and f(x) is a continuous function for all x ∈ R, and a =

and b is number of points of g(x) = max{tanx, cotx} in x ∈ (–π,π) where it is

non-differentiable, then is equal to

SECTION-III

1) If x = cos(tan–1((secθ + 1) cotθ)), y = sin(cot–1((secθ – 1) cotθ)) where , then

is equal to

2)

Let P be any point of the line x – y + 3 = 0 and A be a fixed point (3, 4). If the family of lines given by
the equation (3 sec θ + 5 cosec θ) x + (7 sec θ – 3 cosec θ) y + 11 (sec θ – cosec θ) = 0 are
concurrent at a point B for all permissible values of θ and maximum value of |PA – PB| =
then find the value of n.

3) Consider the circle x2 + y2 – 8x – 4y – 5 = 0. Then find minimum value of x2 + y2 + 2x + 20y + 40

4) Let f(x) = |sinx||(x – 1)||(x – π)||(x – 2π)| (where ) and g(x) = ℓn(x – 1) + |x – 2| +
|x + 3| (where x > 1). Let number of points where f(x) and g(x) are non differentiable are
respectively λ1, λ2, then λ1 + λ2 is
5) Let f(x) be a non-constant thrice differential function defined on (–∞, ∞) such that

and f′(0) = = f′(2) = f′(3) = = 0 then the minimum number of

2
zeroes of h(x) = (f′′(x)) + f′(x) f′′′(x) in the interval [0, 9] is k then (k – 11) is equal to

6) For any real number b, let f(b) denotes the maximum of . If

the minimum value of f(b) is p/q, where p, q are coprime them p + q is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6
A. A,B A,B,C A,C B,C,D C A,B,C,D

SECTION-II

Q. 7 8 9 10 11 12
A. 4.00 4.05 to 4.15 16.80 3 4.00 3.09 to 3.10

SECTION-III

Q. 13 14 15 16 17 18
A. 1 8 3 1 5 2

CHEMISTRY

SECTION-I

Q. 19 20 21 22 23 24
A. A,B,C,D A,C,D B,C A,B,C,D A,B,D A,B,C,D

SECTION-II

Q. 25 26 27 28 29 30
A. 5.00 5.00 5.00 146.00 4.00 4.00

SECTION-III

Q. 31 32 33 34 35 36
A. 5 3 8 9 6 4

MATHEMATICS

SECTION-I

Q. 37 38 39 40 41 42
A. B,D A,B,C A,B,C,D A,B,C,D B,C,D A,B,C,D

SECTION-II

Q. 43 44 45 46 47 48
A. 2.00 2.38 19.00 0.4 2.00 1.75
 SECTION-III

Q. 49 50 51 52 53 54
A. 1 5 3 3 9 7
 SOLUTIONS

PHYSICS

1)

A → B constant pressure B→C T = constant

C → D constant Volume D→A T = constant
∴ clearly, option A and B are constant

2) If resistance of resistance box is 170W current in

wire AB is
Case I

VAB =
So max. 6V or less than 6V can be measured
Case II
if R = 120

VAB = 0.1 × 75 = 7.5

so 7V can be measured.

3)

increase if S1 is closed
increase if S2 is closed

4)

The potential at Q is –2V

The potential at R is zero
The potential at S is zero

5)

The currents in the sections AD, DB, DC are in the ratio 1: 2: 3

6) (A) At t = 0, capacitor acts as short-circuit

At t → ∞, capacitor acts as open circuit and no current flows through voltmeter.

=
(C) τ = 1 sec.
So, by i = i0e–t/τ current at t = 1 sec. is = i0/e
(D) After long time no current flows since both capacitor and voltmeter does not allow.

7)

the value of x is 4

8)

4.05-4.15

The represents constant current carrying source of 6A.

9)

charge supplied by the cell after the switch is closed in 16.80 µC

10)

value of 'n' given that C0 = C is 3

11)

The potential at the point P in volt is 4

12)

The correct answer is 3.09-3.10

13) ΔQ = 3 J
W = P Δ V = (200 N/m2) (10 × 10–3m3)
=2 J
ΔU = ΔQ – W
= 1 J.

14)

The correct answer is 8

15)

With a perfect voltmeter C & D is open circuit, current from cell.

Potential differnet between C & D =

0
(V ) =

140 = 420

with an ideal ammeter, C and D is zero resistance, total current from cell

Current through ammeter between C & D

= I2

r = 5Ω, R = 10 Ω
Finally, we get
 Now, using KVL & KCL, we can determine the current through r between C & D = 12 A

16)

The correct answer is 1

17)

The correct answer is 5

18)

The correct answer is 2

CHEMISTRY

19)

(A) They react with both acid & base

(B) AgI > AgBr > AgCl → Deep yellow > Pale yellow > White
(C) Down the group solubility for group-II hydroxides
(D) Down the group stability of lower oxidation state increases.

20)

q = 0, ,
ΔU = nCvΔT = –360 cal
ΔH = nCpΔT = –600 cal

21)

= – 275 R
 = – 375 R

22)

Conceptual.

23)
(Chiral compound)
2 Stereo isomers

ABD are correct option

24) (A)
(B)

(C)

(D)

25)

All are correct

26)

The correct answer is 5.00

27)

Heat absorbed by the gas during expansion 5 kJ

28)

H2O2(g) → H2O(g) + O2(g) = –103 kJ

–103 = [2 × (BE)O–H + (BE)O–O] – [2 × (BE)O–H + × (BE)O=O]

–103 = (BE)O–O + × (BE)O=O

–103 + × 498 = (BE)O–O

(BE)O–O = 146 kJ/mole
29) (I)

(II)

Total total (4) products

30)

Positive haloform test is given by CH3 – CH2 – OH,

31)

AlCl3 , CCl4 , BeBr2 , BeI2 , BCl3

32)

ΔU = q + W
ΔU = (–1) + 4
= 3 kJ

33)

H2O(l) ⇌ H2O(g)
ΔrG° =
= – RTlnK

= –RTln = –2.303 ×
= +8 kJ (nearest integer)

34)

The heat of dissociation of HA is 9 kcal

 35)

The correct answer is 6

36)

MATHEMATICS

37)

m + m2 = 6 m3 = a
(m + m2)3 = 216
m3 + m6 + 3m3 (m + m2) = 216
a + a2 + 18a = 216
a2 + 19a – 216 = 0
(a + 27) (a – 8) = 0
a=8 (∵ a > 0)

38) Area of rectangle = (8)(8) = 64 sq. units

Let D(x, y)

∴ and
∴
39)

If it is differentiable
then 1+ a = 2+b ⇒ a – b = 1
& 3 + b = 1 ⇒ b = –2
a = –1
(B) a + b = –3

(C)

(D)

40)

41)

∴ f(1+) = f(–1–) = 0
f(1–) = 1, f(–1+) = –1
f(1) = 1/2

42) =
43) (13l + 19m - 32) + n (11l + 17m - 28) = 0
Let (13x + 19y - 32) + n (11x + 17y - 28) = 0
Equation is family of line passes through (1,1)
p+q=2

44) (r + 11)2 = (10 − r)2 + 112

42r = 100

45)

46)

47)

3 tan–1 α – 5 ≥ – 2
tan–1α ≥ 1 ⇒ α ≥ tan 1
∴ least integral value of α is 2

48)

f(2x) = f(x) =

if

=0=a
and g(x) is non-differentiable
So, b = 7

49)

⇒ ⇒

50)

(3x + 7y + 11) sec θ + (5x – 3y – 11) cosec θ = 0 passes through intersection of 3x + 7y + 11 =

0 and 5x – 3y – 11 = 0∀ permissible values of θ given by (1, –2)
|PA – PB| ≤ AB

|PA – PB|max = AB =

51) r =
r=5
centre C(4, 2)
= 13
(PA) = AC – r

(x +1)2 + (y + 10)2 = 64
x2 + 2x + 1 + y2 + 100 + 20y = 64
x2 + y2 + 2x + 20y + 40 = 3
52) ƒ(x) is not differentiable at x = 1, and g(x) is non differentiable at x = 2. Total number of
points are three.

53)

f(x) = f(8- x)
f '(x) = -f '(8 - x)

f '(2) = –f '(6) = 0
f '(3) = –f '(5) = 0

= –f'

f '(0) = –f '(8); h(x) =

Clearly : h(x) has minimum 18 zeroes

54)
sin x = t

increasing

if
min of