LIS IIS // ISIS J SUB: Cl I if CLASS - Xi ASSIGNMENT SOLUTION (a1 10) Given below are four options against each question. Choose the option which you consider the most appropriate as your answer. Qi Which of the solutions is an example of non- ideal solution? (a) n-hexane + — heptanes (b) benzene and toluene G er bromoethane + chloroethand (d) none of these ee Q2 Which of the following are the example of colligative properties? wR ° {a) relative lowering of vapour pressure (b) elevation of boiling point (c) depression of freezing point ASF all of these Q3 The number of moles of NaCl in § litres of of 2 M solution is: (a)1 (b) 3 Gf 10 (d) 27 SK Which of the solutions Is an example of non- ideal solution? (a) n-hexane + n—heptanes (b) benzene and toluene Jor oromoethane + chloroethane (d) none of these Qewhich of the following are the example of colligative properties? (a) relative lowering of vapour pressure (b) elevation At boiling point (c) depression of freezing point ABY all of thése ae Which has the highest freezing point 7 Y 1 M glucose (bo) 1 MNaCl © 1MCaCh (d) 1MAIFs QB A10 % solution of urea is isotonic with 20% solution of 'x’ al same temperature . Molecular weight of ‘x’ will be; 4) 120g mol" : (b) 60g mot" (c) 80g mor" (d) none of these.v Of Aeasurarent ot which collate Proper is prefered lr detomingiy, . ? ‘ mraas Mo, (a) relative lowering of vapour pressure fb} osmotic pressure ‘ {e) elevation of boiling point (8) depression of Ireezing Pring Q¥PColtigative properties depend upon : {a)_ no. of particles (b) nature of particle {oy both of these (d) none of these og Wt solute undergo association, what will be the possible values of §a¥ less than 1 (>) greater than 4 (c) equal to 1 (@) can't be predicteg ‘Short Answer type Questions ag Deline ideal solution. Give any two examples. QtDHow is vapour pressure of solvent affected when a non- Volatile solute ig add ed ty ue? Q4a Find the boiling point of a solution containing 0.50 g of glucose (CoH0, dissolved in.80.2 9 of water. [ Given Ky for water 180.52 K kg mor}. "0 ) Qh81.00 9 of a non- electrolyte solution dissolved in 50 9 of benzeng lowered thy } freezing point of benzene by 0.40 K. The freezing point depression Constant of benzeng hy Is 5.12 K kg mot. Find the molar mass of the solute. | Q43,Explain abnormal molar mass giving example of Potassium chloride and acetic acid. Long Aanswer type Questions OF (a) Explain why a solution of chloroform and acetone shows negative deviation | from Raoutt's law, 3 S B 2 3 a n 8 © 2 2 z g S 5 é 45 (a) Detine the following terms: 4 0) Azeotropes fii) Osmotic Pressure @) Calculate the mota rity of 9.89% ( Solution is 1,92 ML", (mors wt) Solution of H.80,, if the density of the + (Molar mass of sulphuric acid is 98 gmot!"). | ai — o1g 29 of benzoic acid (CeHsCt in Freezing point equal to 1.62 ones in 25 g of benzene sh \ it it Kh ressi shows s |. What is the percentage association of acid, if "een re of benzene is 4 See imer in solution? : Lao the help of a ne iagram describe reverse osmosis. H Ip of a neat diagram describe smo! low can water be aise with cess? Explain its im; portance in the cont text of gulf countri ies. purified by this prot apg Explain the positive and ni neat diagram. egative deviation fro m ideal behaviot ur with the hel; Ip of aPage No. Date ( Asdignmeinb) LAns)| ©) brownebhane + th lo¥nethone ~~ Anse a) All of these. : Ans3) eis VOR ers te a becouse wolarity (M) = Males / volume C2) ste Doles = Mal thy. Velie ———_ Moles = 9 = lo role ) ; METS M glucose | aligektos naan ea eh. 0 eles 2} Moze Pathicles 2 9 a Agotession oF Feeezing painh. —_+ | Glucose es hb. i So, i4 ‘ ave _highe. Feeering _ | Ans. D120 9 mos"! coal beca: using iscoric xelabr'oh &- laxity 2 Molecules Lei ht dowd be Sabre. | to - 20 _ So Be lox = 1200, i x = \log lopel |W) Psmobic [Link], ecow itis aq Me ac, even lok low concenbiobions “ \ bath of these. |hecanse no. of pevtreles onl vabwte of pavbick« | Poth aomabber 82 yt aie less than a. Ba Because > a Associabion duces humbex) oF paybiole 2 Nant HSS Fuctox Wil be less thay a ) | An’ teal 2 a Solution hake obeys Raoulk’s law _ exh All ae coher, In ideal sal” A= 2 i et tata BoB liad BY th ne se 2x > n=exane + bi Hephane Benzene +-Tolusne |_Ant Id) | When _s= nan=valabile isa a -Sduent the Ve post tess Lo the -Sclvenk “ deczease thi e S. Soles clecul 2ibi Jac ede ais Yumbex Jvenk molecules escanthe tke An 1) ee phase, =O bog Ma = $0. 2g = 0.0 w2kg pig = Ceti2Og = lh dileladigxg = 18og mot! | Kye OS2k Kg rol!Moles of 2 = Gn = .[Link] = 6.0 2 MM (go: — Mololiky, (rd = 20g > 0.0022 Ma Og 0. 09D 2 Now, BT, = Kpxm BT, = 0,92 4 0.0348 jist, = 0-01%% Sty =~ Te - Ti Te = bt + Ti Te = 0.014 + D2R1b — Cloo'e =/32 2.0K) (ape 233. 16G : 12). piceer [Link] = Bog 20.05 Kg QMp= a | bts = OOK Ke = GAD ke Kg mag! DTf = KE A Mit wy = Df = 10.038) mol Kgs! KE moe Lee bt GMa XAg= mx GMa Xp = O.0%Gl% 0.05 Tacg = 0.003405 mal |Xpes Gog. = MMB [Mea = Grp 2. 2A = 5 _ ae 2.003905 BEd gts A Ang 1D | Abnormal molox mass is observed whey there Z| ig associablon ot diesocishioh of Selim Iwolecules i» the Solubion, causing moles mass beeps. 6 gy Seotre; Sroalles then expected Sob 22 Vi) KCl Sissolves ike! k? en) ce” jon: decreases observed welax hmss (her mete pathicle cits Berea) ti) Acebi acid CCWs COU) dimerizes Chuo mdecules sfoin) in benzene increases Sbsexved molas_1mass ( ber Fewer paxhicles axe pyesenb) 1 Valabite Iigssi | png WW | Rerorsl ! \" a . a [Ae the deal ve presse of cach ComAchent bhe Le. | fox wm ponen’ A > Parent Pane Bey 2270 Fox Compenend “8 2~—+ fos PB x-2op rik Nespas pies youof pate Aand B. « |ocy and arp =~ wole Srochions of A cvd DBMola ia ni 2g" @ eee ee | Pina = ta Op ee J Dis is Dre expaessiin Gt dobal Vapmct Oxessure iy terms of male frachion oF corponenb 3B. _ | Dos ih Osta px mM ved ak xoom temp. — ho = Jes. cchadeuc efat Liki ail analtlnigeailtiy ase. by, —_ 93 a et (a FT | + |Even fr very dilde Sol”, OSwabic precawe Measuxenents_ $e aCeuxroke 2 = - |The chonge in OSmobic _pxessute isi\ lo¥g ven fa "eal . Cone”, Maing tb easy to detect __ No need Fox olebile Solvents, Sol” Jo nob qa eoSsily. Thus, psmobic pre | Molax Moss, especially Fox aa Like protein rod _polymexs. A sote_xelioble valves of lee le $___—wv ays 1D = || Date ligalise pagel ta ae calecedel ge | pun perbhy —[Link], be ostaciakion ox dissociaklan [Effect on colligative Properbies 2~ [fot dissociation 2? mune of pasbiles.. Iiereteesd) — Co! ca Ses. fx ex 3 KCL KY Cr fox associobion' =) numbex of payticles decseases —> cdiigative piopexhiy decxease Modified fosrmlas $2 - | pt = ix Kk ST, = 1% Kn x ™ ; [Ais siier RX TF (D)| Ks = 1.64 K Kg ok" [Link] = 1g >see [Link] = \bog = 0.1 Kg MMg = CalgOn = 2232 Iv@tidx3 = Wy rod" Xp = GM ~. Jole84 wod/ MoM ay 2 me = Zi = 0,0la4 4 = joie Lah Kg! Gira Ca) out aes Dig = Kix m Srp = 146x0, lo&t_ (Nt Aaa Kk 7 %ene DbYpis Thy Te; —~ ae = ie thy D = TEi Thi = O- 0.262 — nS toe ASsociabion. ‘akon J nlite molecules carbine bo _ Tl fos thiggey rclecules (diness,buirress ebe,) it So)” Fed Acti ‘acid assoclabesi sin’ berpehe Mp%e lows in Solbion. Forlex =) Sodium ehlox: CulaCL) dissoctakesAnkn Nat awd Ch) wakes. Ascociabion leads ba dectease” sn Colligakive: prone sticc, whi) i ot Aismciabion leads ba Increase.