15-06-2025

1721CJA101029250010 JM

PHYSICS

SECTION-I

1) Find the Flux entering the cone

(A)

(B)

(C)
(D) Zero

2) Four point charges are placed in a straight line with magnitude and separation as shown in the
diagram. What should be the value of such that charge is in equilibrium?

(A)
(B)
(C)
(D)

3) Find the charge on an iron particle of mass 2.24 mg, if 0.02% of electrons are removed from it

(A) -0.01996 C
(B) 0.01996 C
(C) 0.02 C
(D) 2.0 C

4) Five balls numbered 1 to 5 are suspended using separate threads, Pairs (1,2), (2,4),(4,1) shows
electrostatics attraction, while pairs (2,3) and (4,5) show repulsion therefore ball 1 must be
(A) Positively charge
(B) Negative charge
(C) Neutral or made of metal
(D) Made of metal

5) In a regular polygon of n sides, each corner is at a distance r from the centre. Identical charges
are placed at (n - 1) corners. At the centre, the intensity is E and the potential is V. The ratio V/E has
magnitude.

(A) r n
(B) r(n-1)

(C)

(D)

6) A solid sphere having radius R and Uniform charge density has a cavity of radius R/2 as shown

in figure. Find the ratio of magnitude of electric field at point A and B i.e., .

(A)

(B)

(C)

(D)

7) Mark the correct options-

(A) Gauss’s Law is valid only for symmetrical charge distributions

(B) Gauss’s Law is valid only for charges placed in vacuum
The electric field calculated by Gauss’s Law is the field due to the charges enclosed by the
(C)
surface
The flux of the electric field through a closed surface due to all the charges is equal to the flux
(D)
due to the charges enclosed by the surface
8) A bead of mass m is fitted on a rod and can move on it without friction. Initially the bead is at the
middle of the rod and the rod moves translationally in a horizontal plane with an acceleration in a
direction forming an with the rod. The acceleration of bead with respect to rod is

(A)
(B)
(C)
(D)

9) Three concentric conducing spherical shells have radius r, 2r and 3r and and are final
charges respectively. Innermost and outermost shells are already earthed as shown in figure.
Choose the wrong statement.

(A)

(B)

(C)

(D)

10) A rod of length L and mass M is acted on by two unequal force F1 and as shown in the
following figure. The tension in the rod at a distance y from the end A is given by
(A)

(B)

(C)

(D)

11) In the given arrangement, n number of equal masses are connected by strings of negligible
masses. The tension in the string connected to nth mass is-

(A)

(B)

(C) mg
(D) mng

12) A mass m1 placed on top of a trolley of mass m3, is connected to another mass m2 by means of a
string passing over a smooth pulley as shown is figure. The friction between surfaces is negligible.
For m1 and m2 not to move with respect to trolley, the horizontal force F to be applied on trolley is

(A)
(B)

(C)

(D)

13) In the equilibrium scenario depicted, the cords can withstand a maximum tension of 100 N.
determine the maximum value of W (in Newtons) that they can support in this configuration
(A) 20 N
(B) 25 N
(C) 30 N
(D) 35 N

14) A body A weighing W1 descends down on an inclined plane D, which makes an angle with the
horizontal, and pulls a load B that weight W2 by means of a weightless and inextensible thread
passing over a small light pulley C, as shown in figure. Find the horizontal component of the force
with which the inclined plane D applied on the floor corner E.
(Take neglect friction)

(A)

(B)

(C)

(D)

15) Two concentric conducting spherical shells with radii a1 and a2 (a2 > a1)are charged to potentials
V1 and V2 respectively. Determine the charge on the inner shell.

(A)

(B)

(C)

(D)
16) A block can slide on a smooth inclined plane of inclination kept on the floor of a lift. When the
lift is descending with a retardation a. the acceleration of the block relative to incline is-

(A)
(B)
(C)
(D)

17) Which of the following is a volt?

(A) Erg per cm

(B) Joule per coulomb
(C) Erg per ampere
(D) Newton/(coulomb x m2)

18) A charge Q is placed at the centre of a circle of radius R. The work done in moving a charge q
from A to B so as to complete a semicircle is-

(A)

(B)

(C) Zero

(D)

19) The electric field strength in a region is given by . Determine the net charge inside a
sphere of radius ‘a’ with its center at the origin.

(A)
(B)
(C)
(D)

20) Two similar point charges q1 and q2 are positioned at a distance r apart in air. If a dielectric slab
of thickness t and dielectric constant k is inserted between the charges, determine the Coulomb
force of repulsion.
(A)

(B)

(C)

(D)

SECTION-II

1) A hollow metal sphere of radius 5 cm is charged such that the potential on its surface is 10 V. The
potential at a distance of 2 cm from the center of the sphere is

2) An inclined plane makes an angle 30o with the horizontal. A groove OA = 5m cut in the plane
makes an angle 30o with OX. A short smooth body is free to slide down the influence of gravity. The
time (in sec) taken by the body to reach from A to O is (g = 10 ms-2)

3) In the system of pulleys shown what should be the value of m1 such that 100 gm remains at rest
w.r.t. ground (in gm) is

4) In the arrangement shown, the pulleys and the strings are ideal. The acceleration of block B is

. Find ?
5) In the system shown block A is of mass 4.0 kg and blocks B and C are equal mass each of 3 kg.
Find the acceleration in m/s2 of block C, if the system is set free. (g = 10 m/s2)

CHEMISTRY

SECTION-I

1) Products;
Products of this reaction are :-
(A)

(B)

(C)

(D)

2) Which will form gem dihalide on reaction with PCl5 ?

(A) CH3–CH2–OH

(B)

(C)

(D) CH3–O–CH3

3)

Which of the following reaction is example of free radical Halogenation reaction.

(A)
(B)

(C)

(D)

4) Which of the following does not give alkane with R—Mg—X.

(A) Ph—OH
(B) CH3–O–CH3
(C) CH3COOH
(D) HCl

5) End product of the following sequence of reaction is

(A)
Yellow ppt. of CHI3,

(B)
Yellow ppt. of CHI3,

(C)
Yellow ppt. of CHI3,
(D)
Yellow ppt. of CHI3,

6)

(A)

(B)

(C)

(D) No reaction will occur

7) In the following reaction the most probable product will be:

(A)
(B)

(C)

(D)

8) In the given reaction :

(X) and (Y) are :

(A)
CH2 OH and HO CH2 O

(B)
CH3 O and HO CH2 O

(C)
CH2 OH and CH3 OH

(D)
CH2 OH and O

9) Identify (A) in the following reaction sequence :

(A)

(B)

(C)

(D)

10) The major product in the following reaction is

(A)

(B)

(C)
(D)

11) X is :

(A)

(B)

(C)

(D)

12) Which of the following will not give haloform with NaOX ?

(A)

(B)

(C)

(D)

13) Uavg speed of O2 at π × 10 bar pressure in a 8 m3 container containing 2 moles is

(A) m/sec
(B) m/sec
3
(C) 10 m/sec
(D) m/sec

14) The total kinetic energy of a sample of gas which contains N molecules at –123°C is Ek Joules.
Another sample of gas at 27°C has total kinetic energy 2Ek Joules. The number of molecules in the
second sample of gas is

(A) N/2
(B) 2N
(C) N
(D) N2

15) 500 mL of methane (CH4) effuses through a small hole in 48 sec. How much time will be taken by
same volume of helium to effuse out of the same orifice ?

(A) 192 sec

(B) 24 sec
(C) 12 sec
(D) 96 sec

16) Two glass bulbs A and B are connected by a very small tube having a stop cock. Bulb A has a
volume of 100 cm3 and contained the gas, while bulb B was empty. On opening the stop cock, the
pressure fell down to 40%. The volume of the bulb B must be :

(A) 75 cm3
(B) 125 cm3
(C) 150 cm3
(D) 250 cm3

17) Pressure of 1 g of an ideal gas A at 27°C is found to be 2 bar. When 2 g of another ideal gas B is
introduced in the same flask at same temperature the pressure becomes 3 bar. What is the
relationship between their molecular masses?

(A) 2MB = MA
(B) MB = MA
(C) MB = 4MA
(D) MB = 2MA

18) In a glass tube of uniform cross-section, HCl gas is sent from one end and a mixture of NH3, He
and Ar gases are sent from another end at the same time, the white fumes of NH4Cl will appear first

(A) At the middle of the tube

(B) At the NH3 end
(C) Closer to NH3 end
(D) Closer to HCl end

19) The figure shows the effect of pressure on the compressibility factor Z of a gas. The incorrect
conclusion is :

(A) The curve PU and RS can be explain by PVm = RT + Pb

(B) The curve PT can be explained by PVm = RT

(C)
The curve PQ can be explained by
(D) PQ shows that the gas is less compressible than ideal gas.

20) For a real gas following plot is given in high pressure range. Value of (b/RT) is :

(A) 10–3 atm–1

(B) 2 × 10–3 atm–1
(C) 5 × 10–4 atm–1
(D) 10–4 atm–1

SECTION-II

1)
The ratio x/y on completion of the above reaction is _________.

2) Total number of reactions correctly match with their major products are ?

(1)
(2)

(3)

(4)
(5) CH3CH2OH CH3CH2Cl + HCl + POCl3

3) Using the van der Waal's gas equation, calculate the pressure (in atm) exerted by 10.0 mol
NH3 gas in a 10.0 L vessel at 27°C.
(Given : a = 4.2 [Link]/mol2, b = 0.037 L/mol.)
(Answer to the nearest integer)

4) Assuming gaseous molecule to be spherical in shape with its critical volume 8.1 L. Calculate
empty space (in litre) in one mole of the gas at 1 bar and 273 K.

5) Calculate the mass (in gram) of hydrogen gas present in the 10 litre container at 240 K and 300K.
Given : Molar volume of hydrogen molecule is 0.025 L/mole, R = 0.08 L-atm/mole-K

MATHS

SECTION-I

1) Let the values of 'a' for which the roots of the equation (x - a)(x - a - 1) = 0 lie between the roots of

the equation (x + a) (x + a2 - 2) = 0 be , then the value of q - p is

(A) 1
(B) 2
(C) 3
(D) 4

2) If the quadratic equation where a,b,c are distinct reals,

has imaginary roots then:

(A)
(B)
(C)
(D) None of these

3) If p & q are distinct reals, then

\
is satisfied by:-

(A) No value of 'x'

(B) exactly one value of 'x'
(C) exactly two values of 'x'
(D) infinite values of 'x'

4) Number of integral values of a for which the equation (a + 2)x2 +2(a + 1) x + a = 0 will have
integer roots is/are-

(A) 3
(B) 2
(C) 5
(D) 4

5) If , then is

(A) Less than sin 2

(B) Greater than sin 2
(C) Equal to sin 2
(D) Is equal to 1

6) Let be the roots of the equation , then the number of points of discontinuity of
the function

on are

(A) 2
(B) 10
(C) 5
(D) 12

7) If α > β > γ > 0, then the expression

 is equal to:

(A)

(B) 3π
(C) 0
(D) π

8) Let f(x) = , 0 < x < 1. Then :

(A) (1 – x)2 f'(x) – 2(f(x))2 = 0

(B) (1 + x)2 f'(x) + 2(f(x))2 = 0
(C) (1 – x)2 f'(x) + 2(f(x))2 = 0
(D) (1 + x)2 f'(x) – 2(f(x))2 = 0

9) The number of real values in the domain of the function

is

(A) 0
(B) 1
(C) 2
(D) None

10) If is equal to L then the remainder when L is divided

by 15 is :

(A) 13
(B) 14
(C) 9
(D) 1

11) is equal to

(A)

(B)

(C)

(D)
12) The value of is

(A) –1
(B) 1
(C) 2
(D) e

13) If , then f(x) is :

(A) Differentiable at x = 0
(B) Not differentiable at x = 0
(C) Differentiable & Continuous ∀ x ∈ R
(D) None of these

14) Let ƒ(x) is continuous function which satisfies and ƒ(x) > 0 ∀ x ∈ R, then

is equal to :-

(A) 0
(B) 1
(C) 2
(D) –1

15) Consider the function , then

(A)

(B)
(C) g(x) is continuous for all x except at x = 0
(D) g(x) is differentiable for all x except at x = 0

16) If x = 2 + t3, y = 3t2, then the value of n for which is constant is

(A) 1
(B) 2
(C) 3
(D) 4
17) Let Then is equal to

(A)

(B)

(C)

(D)

18) If tangent at point P on curve y2 = x3 meets the curve again at point Q, then
(where O is origin)

(A) 1
(B) 2
(C) –2
(D) –3

19) Equation of normal to the curve at

(1, 3) is :-
(where [.] denotes greatest integer function)

(A) 2x + 3y = 11
(B) 8x – 3y = –1
(C) 11x + 10y = 41
(D) 13x + 6y = 3

20)

If the slope of tangent to the curve y = ax2 – bx at x = 1 is equal to 3 where a ∈ [5, 10], then number
of possible integral value of b is -

(A) 9
(B) 10
(C) 11
(D) 12

SECTION-II

1) Number of integer value of x satisfying

is
2) The least integral positive value of 'a' for which the equation
has no real solutions is ______.

3) If a particle starts moving from (0, 0) and rate of change of its abscissa is 8 cm/s on the curve
, then rate of change of area of triangle formed by co-ordinate axes & tangent at a point
reached after 2 sec of start is

4) is equal to

5) Let is a continuous function ∀ x ∈ R and a, b,

c are non negative integers then the value of a + b + c is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C B C B C D D D A A C D C D A B C D D

SECTION-II

Q. 21 22 23 24 25
A. 10 2 160 7 2

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C D B C A B C D D D D D C B C C D D A

SECTION-II

Q. 46 47 48 49 50
A. 2 3 21 20 100

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A D C A C D C C D A B B C C D B C C C

SECTION-II

Q. 71 72 73 74 75
A. 0 2 12 1 7
 SOLUTIONS

PHYSICS

1)

2)

3) 0.01996 C

4) Neutral of made of metal

5) r(n-1)

6) Ans.

7) The flux of the electric field through a closed surface due to all the charges is equal to the
flux due to the charges enclosed by the surface

8)

9)

10)

11)

12)

13) Ans. 35 N

14)
 15)

16)

17) Joule per coulomb

18) Zero

19)

20)

21) 10

22) 2

23) 160

24) 7

25) 2

CHEMISTRY

26)

27)

∴ CH3–CH2–OH CH3–CH2–Cl
 Gem dihalide
CH3–O–CH3 2CH3–Cl

28)

Sunlight / hν is responsible for formation of F. R.

29) Hint : Except Cl—NH2 all have active hydrogen, but Cl—NH2 when reacts with
R—Mg—X the product is R—NH2.

30) Intermediate is
Which loses CO2 on heating (β–keto acid)

31) reaction
(Pg - 132, Q - 1, BB - 1) unit - 8

32)
Unit - 8. Page no. 160. Q. 10

33)
34)

35)
(i) Grignard prefer to give nucleophilic addition on polar π-bond and form anion intermediate.

(ii) In next step anion give intramolecular nucleophilic substitution reaction & form 5
membered ring.

36)

37)
will not give haloform with NaOX test as it does not have keto methyl group
38) Uavg. = m/sec.

39)

40)

41)
P × 100 ml
0.4 P × (100 + V) ml

100 + V = = 250
V = 150 ml

42) 2 × V = × × RT and 3 × V =

∴ .

43) Rate of diffusion of NH3 will be faster than HCl.

44)

Correct option is (D)

PQ curve snows maximum value of a hence it is more compressible than
PT

45) ∵ Z = 1 + P
 46)
∴ x = 2 mole

47)

1,4,5

48)

Use van der Waal's equation to obtain pressure.

49) At 1 bar and 273 K Vm = 22.7 L

Empty space = Vm – b
VC = 3b

b= = 2.7
Empty space = 22.7 – 2.7 = 20 L

50) P(V – nb) = nRT

240 × (10 – n × 4 × 0.025) = n × 0.08 × 300
(10 – n × 4 × 0.025) = 0.1n
10 = 0.2n
n = 50
mass (in gram) of hydrogen gas = 50 × 2 = 100.

MATHS
51)

52)

Let

and D < 0

53)

It is an identity so infinite values of x are possible.

54) For integral roots

D = (2(a+1))2 - 4a(a + 2)
=4a2+8a+4-4a2-8a

For to be integer possible values of are 0, -1, -3 and -4

If a = -2 then x = -1
total number of integer values of x = 5
55)

56)

Points of discont. of

points

57)

⇒π

58) (0 < x < 1)

f(x) =

Now f '(x) =

∴ f '(x) (1 – x)2 = –
∴ (1 – x)2 f'(x) + 2(f(x))2 = 0

59)

and

and
 and
and
domain is

60)
⇒

L = (2023)2024

⇒ Remainder is 1 .

61) =

62)
0
From : 0

63) LHD =

RHD =
64)

.... (1)

Let, , then equation (1) becomes

⇒ L2 – L – 2 = 0
⇒ (L – 2) (L + 1) = 0
⇒ L = 2, –1 ( ∵ ƒ(x) > 0)

Ans

65)

and

66)

∴
Which is independent of t for n = 4.
67)

68) Let P(t12, t13) and Q(t22, t23)

y2 = x3

Slope of PQ =

On solving

69)

∴ curve is = y2 – 3x

∴ Slope of normal =
Equation of normal is

⇒ 10y – 30 = –11x + 11
⇒ 11x + 10y = 41 Ans.

70) y = ax2 – bx
minimum value of b = (2 × 5 – 3) = 7
maximum value of b = (2 × 10 –3) = 17
∴ No. of integral values of b = (17 + 1) –7 = 11
Option (C) is correct

71) |x| = t

72)

For no real value of x, either D < 0 for above equation or both negative roots

i.e.

or and and

or ; Least integral positive value of a is 2.

73) Let point be

Area of ΔOAB = [Link]

Slope of tangent at
Equation of tangent

OA = –a, OB =

Area
= 12

74)

Using L'H rule.

= eo = 1

75) f(1–1) = ƒ(1) = ƒ(1+)

⇒ 6a – b – 10c = 3 ...(1)
f(2–) = ƒ(2) = ƒ(2+)
⇒ 5a + 7b + 5c = 37 ...(2)
Solving (1) & (2)
⇒ 16a + 13b = 77 only at a = 4, b = 1, c = 2
⇒a+b+c=7