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Dipolar Forms

Dipolar compounds are Electrically neutral molecules carrying a positive and a negative charge in one of their major canonical descriptions. 1,2Dipolar compounds have the opposite charges on adjacent atoms. The term 1,3-dipolar compounds is used for those in which a significant canonical resonance form can be represented by a separation of charge over three atoms.

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5 views1 page

Dipolar Forms

Dipolar compounds are Electrically neutral molecules carrying a positive and a negative charge in one of their major canonical descriptions. 1,2Dipolar compounds have the opposite charges on adjacent atoms. The term 1,3-dipolar compounds is used for those in which a significant canonical resonance form can be represented by a separation of charge over three atoms.

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Siddarth Singh
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© Attribution Non-Commercial (BY-NC)
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doi:10.1351/goldbook.

D01753

dipolar compounds
Electrically neutral molecules carrying a positive and a negative charge in one of their major canonical descriptions. In most dipolar compounds the charges are delocalized; however the term is also applied to species where this is not the case. 1,2Dipolar compounds have the opposite charges on adjacent atoms. The term 1,3-dipolar compounds is used for those in which a significant canonical resonance form can be represented by a separation of charge over three atoms (in connection with 1,3-dipolar cycloadditions). Subclasses of 1,3-dipolar compounds include: 1. Allyl type X=Y+Z XY+=Z X+YZ X=YZ+ (X, Z = C, N, or O; Y = N or O) See: azo imides, azomethine imides, azomethine ylides, azoxy compounds, carbonyl imides, carbonyl oxides, carbonyl ylides, nitrones, nitro compounds 2. Propargyl type XN+Z X=N+=Z X=NZ+ XN=Z (X = C or O, Z = C, N, or O) See: nitrile imides, nitrile oxides, nitrile ylides, nitrilium betaines, azides, diazo compounds 3. Carbene type X:C=Z X+=CZ (X = C or N; Z = C, N, or O) See: acyl carbenes, imidoyl carbenes, vinyl carbenes See: betaines Source: PAC, 1995, 67, 1307 (Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)) on page 1333

IUPAC Compendium of Chemical Terminology

Copyright 2010 IUPAC

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