03-05-2025

6250NURINTNLMAIN0305 JM

PHYSICS

SECTION - A

1)

The approximate value of x where x = sin 2° cos 2°, is :-

(A)

(B) 2
(C) 1

(D)

2) The velocity of a particle is given by the equation . The value of acceleration of particle

at .

(A)

(B) 1
(C) 0
(D) ∞

3) If then what is the approximate value of y. Choose the appropriate option :

(A)

(B)

(C)

(D)

4) =

(A) 0
(B) 1

(C)
(D)

5) If speed of particle depends on angle , according to the

relation, then minimum possible speed of the particle will be -

(A) 5 m/s

(B)
m/s
(C) 2 m/s

(D)
m/s

6) A particle moves on an elliptical path with its position vector is given by .

The speed of the particle at t = 0 is:

(A) bω
(B) aω
(C)
(D)

7) The value of is

(A)

(B)

(C)

(D)

8) Which of the following graph has a positive, decreasing slope?

(A)

(B)
(C)

(D)

9)

The value of is :-

(A) 1
(B) 3
(C) 2
(D) 4

10) A certain mountain road is inclined 3° with respect to the horizontal. The change in height of the
car as a result of its traveling 3 km along the road is nearly :-

(A) 157 m
(B) 181 m
(C) 116 m
(D) 203 m

11) If where P is linear momentum, then find force at t = 1 sec.

(A) 1
(B)
(C)
(D) 0

12)

If secθ = then correct answer is:-

(A)
sinθ =
(B) θ = 37°
 tanθ =
(C)

(D) All are correct

13) Find upto

(A)

(B)

(C) 3
(D) 2

14)

(A) 2
(B) 3
(C) 5

(D)

15) The slope of graph as shown in figure at points 1, 2 and 3 is respectively then

(A)
(B)
(C)
(D)

16) The value of will be :-

(A)

(B)

(C)
(D)

17) The work done by a gas molecule in an isolated system is given by, , where x is
the displacement [L], k is the Boltzmann constant
[M1 L2 T–2 K –1] and T is the temperature [K], a and b are constants. Then the dimension of b will be :

(A) [M L2 T–2]
(B) [M L T–2]
(C) [M2 L T2]
0
(D) [M0 L T ]

18) Applying the principle of homogeneity of dimensions, determine which one is correct. Where T is
time period, G is gravitational constant [M–1 L3 T–2], M is mass, r is radius of orbit.

(A)

(B)

(C)

(D)

19) If surface tension (S), Moment of inertia (I) [ML2] and Planck's constant (h) [ML2 T–1], were to be
taken as the fundamental units, the dimensional formula for linear momentum would be :-

0
(A) S3/2I1/2h
0
(B) S1/2I1/2h
(C) S1/2I1/2h–1
(D) S1/2I3/2h–1

20) In a new system of units on mass, 5 kg is unit of mass, 5 m is unit of length and 1 sec. is unit of
time. Find the value of 5N force in new system.

(A)

(B)

(C)

(D)

SECTION - B

1) If vibration frequency of the star is given by this equation f = kRaρbGc where f is frequency, R is
radius of star, ρ is density of star, G is universal gravitational constant and K is a dimensionless
constant, then find the value of 4a + 2b + 4c.

2)

Sides of a rectangle are measured as 2.13 cm and 3.456 cm. Then number of significant figures in
calculation of area will be :

3)

The density of a solid metal sphere is determined by measuring its mass and its diameter. The

maximum error in the density of the sphere is . If the relative errors in measuring the mass
and the diameter are 6.0% and 1.5% respectively, the value of x is :

4) The resistance , where V = and I = . The percentage error in R is ' x

' % . The value of ' x ' to the nearest integer is

5) A student of TN batch forgot Newton's formula for speed of sound but the remember that there
were speed (v), pressure (p) and density (d) in the formula. He then start using dimensional analysis
to find the actual relation by assuming v ∝ pxdy. Find the value of x–y.

CHEMISTRY

SECTION - A

1) A compound contains 38.8% C, 16.0% H and 45.2% N by mass. The empirical formula of the
compound would be:

(A) CH3NH2
(B) CH3CN
(C) C2H5CN
(D) CH2(NH)2

2) A gas is found to have the formula (CH2)x. Its vapour density is 14. The value of x should be :-

(A) 1
(B) 3
(C) 2
(D) 4

3) Which of the following set of compounds follows the law of multiple proportions ?
(A) H2O, D2O
(B) SO2, H2S
(C) NaCl, NaBr
(D) PCl3, PCl5

4)

What volume of CO2 at STP will evolve when 1 g of CaCO3 reacts with excess of dil HCl?

(A) 224 ml
(B) 112 ml
(C) 56 ml
(D) 448 ml

5)

Which of the following has highest number of neutrons?

(A) 44 g of CO2
56
(B) 28 g 26Fe
(C) 80 g H2
(D) 100 g He

6)

A compound contains 3.2% of oxygen. The minimum molecular weight of the compound is

(A) 300
(B) 440
(C) 350
(D) 500

7)

The largest number of molecules are in

(A) 28 g of CO
(B) 46 g of C2H5OH
(C) 36 g of H2O
(D) 54 g of N2O5

8) A 6.90 M solution of KOH in water has 30% of KOH by weight. The density of solution is :

(A) 3.88 g/ml

(B) 13.88 g/ml
(C) 1.4 g/ml
(D) 1.288 g/ml

9) Equal masses of H2, O2 and methane have been taken in a container of volume V at temperature
27°C in identical conditions. The ratio of the volumes of gases H2 : O2 : methane would be

(A) 8 : 16 : 1
(B) 16 : 8 : 1
(C) 16 : 1 : 2
(D) 8 : 1 : 2

10) Which one of the followings has maximum number of atoms?

(A) 1 g of Ag(s) [Atomic mass of Ag = 108]

(B) 1 g of Mg(s) [Atomic mass of Mg = 24]
(C) 1 g of O2(g) [Atomic mass of O = 16]
(D) 1 g of Li(s) [Atomic mass of Li = 7]

11) 1 amu = ________ g

(A) 6.022 × 10–23

(B) 1.66 × 10–23
(C) 1.66 × 10–24
(D) 1.66 × 10–27

12) The total no. of proton, electrons and neutrons in 12 g of 6C12 is :-

(A) 1.084 × 1025

(B) 6.022 × 1023
(C) 6.022 × 1022
(D) 18

13) In the reaction,

4NH3(g) + 5O2(g) —→ 4NO(g) + 6H2O(g),
When 1 mole of ammonia and 1 mole of O2 are made to react to completion

(A) 1.0 mole of H2O is produced

(B) 1.0 mole of NO will be produced
(C) All the oxygen will be consumed
(D) All the ammonia will be consumed

14) If 3.01 × 1020 molecules are removed from 98 mg. of H2SO4, then the number of moles of H2SO4
left are :–

(A) 0.1 × 10–3

(B) 0.5 × 10–3
(C) 1.66 × 10–3
(D) 9.95 × 10–2

15) Nitrogen has two isotopes N14 and N15 and its average atomic mass is 14.0067. The percentage
abundance of lighter isotope of N is

(A) 99.33%
(B) 90.95%
(C) 98.67%
(D) 99.05%

16) No. of mole of H2SO4 present in 100 ml of 4M H2SO4 is_____.

(A) 0.2 mole

(B) 0.4 mole
(C) 0.5 mole
(D) 0.6 mole

17) 214.2 gm of an aqueous solution of sugar contains 34.2 gm of sugar. Molality(m) of solution
is_____.
(Molecular mass of sugar = 342)

(A) 0.22 m
(B) 0.55 m
(C) 0.88 m
(D) 1.2 m

18)

What is the mole fraction of the solute is 1.00 m aqueous solution ?

(A) 0.0354
(B) 0.0177
(C) 0.177
(D) 1.770

19) Density of a 2.05M solution of acetic acid in water is 1.02 g/ml. The molality of the solution is :

(A) 1.14 mol/kg

(B) 3.28 mol/kg
(C) 2.28 mol/kg
(D) 0.44 mol/kg

20) 1000 g aqueous solution of CaCO3 contains 10 g of calcium carbonate. Concentration of solution
is-

(A) 10 ppm
(B) 100 ppm
(C) 1000 ppm
(D) 10000 ppm

SECTION - B

1) 3M NaOH solution is to be prepared using 84 g NaOH, then the volume of solution in litre is ____
× 10–1

2) What is the number of atoms in 100 u of He.

3) 12 moles of each A and B are allowed to react as given : If 60 gm of D is

produced then calculate the atomic mass of D (in gm.)

4) In the following reaction, if 3 gm of H2 react with N2, what will be the mass of NH3 formed in
reaction ?

5) An organic compound CxHyNz has molecular mass 108 in this C, H and N atoms are present in 9 :
1 : 3.5 by mass. What is the sum of x + y + z ?

MATHS

SECTION - A

1) The number of solutions of log23.logx2 = log3x is :–

(A) 0
(B) 1
(C) 2
(D) 3

2) If and , then the value of xy is

(A) 27
(B) 81
(C) 243
(D) 216

3) Solution set of the inequality is a subset of

(A)
(B)
(C)
(D) (–1,1)

4) If then logca (wherever defined)

(A)

(B)

(C) k3
(D) k1/3

5) If and x3y2z = 1 holds, where x ≠ y ≠ z, then the absolute value of 'k' is

equal to

(A) 1
(B) 2
(C) 3
(D) 4

6) If N is the number of positive integers having characteristic 10, when the base of logarithm is 5,
then the number of digits in N will be
(log102 = 0.3010)

(A) 6
(B) 7
(C) 8
(D) 9

7) If the equations x2 – 4x + 3 = 0 & x2 – (3k – 2)x + (k + 1) = 0 have one root common, then k is
equal to -

(A) 1 or 2
(B) 2 or 3
(C) 2
(D) 1

8) Sum of all the solution(s) of equation is -

(A) a prime number

(B) an irrational number
(C) a rational number which is not integer
(D) a composite number
9)

If p > q > 0 are two real numbers, then the value of

is -

(A) independent of q
(B) independent of p
(C) independent of both p and q
(D) dependent on both p and q.

10) The number of positive integral solutions of x4 – y4 = 1572 is -

(A) 0
(B) 1
(C) 2
(D) 4

11) The value of is equal to

(A) 1
(B) 3
(C) 9
(D) 27

12) If

and , then is

(A) 2
(B) 4
(C) 6
(D) 8

13) Let , then the value of is -

(A)
(B)
(C)
(D)

14) Sum of value of x satisfying the equation

|3x + |x|| = 5 is -
(A) 0

(B)

(C)

(D)

15) The value of x satisfying the equation is

(A) positive
(B) negative
(C) neither positive nor negative
(D) irrational

16) The number of points (x, y) having integral coordinates satisfying x2 + y2 < 25 is -

(A) 69
(B) 80
(C) 81
(D) 77

17) Sum of the roots of the equation is

(A) 2
(B) 0
(C) –1
(D) 1

18) Let ƒ(x) = x9 + x7 + ax5 + bx, the remainder when ƒ(x) is divided by (x + 1) is –11 and remainder
when it is divided by (x2 – 1) is g(x), then g(1) is -

(A) 6
(B) 3
(C) –11
(D) 11

19) The equation has

(A) only one solution

(B) two solutions
(C) no solution
(D) more than two solutions

20) The number of real solutions of the equation |x|2 – 3|x| + 2 = 0 is

(A) 4
(B) 1
(C) 2
(D) 3

SECTION - B

1) If polynomial Ax3 + 4x2 + Bx + 5 leaves same remainder, when divided by x – 1 and x + 2

respectively then value of 3A + B is equal to -

2) If a,b,c ≠ 0 determine the value of given that

3) Consider equation |x – 2| + 2|x – 5| = 7 then sum of solutions is

4) The value of is equal to

5) Minimum value of S = 3x+y (3x–1 + 3y–1 – 1) + 1 is

where p and q are coprime natural numbers, then (p + q) is equal to
 ANSWER KEYS

PHYSICS

SECTION - A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C B C C A C C C A A D B B B A B C B D

SECTION - B

Q. 21 22 23 24 25
A. 3.00 3.00 1050.00 5.00 1.00

CHEMISTRY

SECTION - A

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C D A D D C D C D C A C B A B B B C D

SECTION - B

Q. 46 47 48 49 50
A. 7.00 25.00 30.00 17.00 16.00

MATHS

SECTION - A

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C C B D C C A A A A A C B C A A D C A

SECTION - B

Q. 71 72 73 74 75
A. 4.00 1.00 8.00 3.00 5.00
 SOLUTIONS

PHYSICS

1)

180° = π rad, 2° = rad

sin θ = θ, cos θ = 1 for small θ

2)

⇒a=0

3)

4)

5)

6)
9)
=1+1=2

10)

h=

11) p =

F= = = (1) + (t) =1+

13)

14)

15) Conceptual

17) → dimensionless

⇒ [α] = = = M–1T2
Now [W] = [α] [β]2

[β] = = M1L1T–2.

18) According to principle of homogeneity dimension of LHS should be equal to dimensions of

RHS so option (C) is correct.
(Dimension of G is )

19) p = k saIbhc
where k is dimensionless constant
MLT–1 = (MT–2)a(ML2)b(ML2T–1)c
a+b+c=1
2 b + 2c = 1
–2a – c = –1

a= b= c=0
1/2 1/2 0
s I h.

20)

5N force = (new system of unit)

21)

(T–1) = La(ML–3)b(M–1L3T–2)c
b = c = 1/2
a – 3b + 3c = 0
a=0

25)

by comparing power of M, L and T

x + y = 0, – x – 3y = 1, –2x = – 1

⇒x= ,
 y=–

CHEMISTRY

33) Weight of KOH in 1 litre solution = 6.9 × 56 = weight of solution

∴ weight of solution = = 1288g

∴ density of solution =

34)

According to Avogadro’s hypothesis, ratio of the volumes of gases will be equal to the ratio of
their no. of moles.

So, no. of moles =

So, the ratio is or 16 : 1 : 2.

35)

1 mole of substance = NA atoms

108g of Ag = NA atoms

24g of Mg = NA atoms
32g of O2 = NA molecules = 2 NA atoms

7g of Li = NA atoms
Therefore, 1g of Li(s), has maximum number of atoms.

37) total (P + e– + n) ⇒ 6 + 6 + 6
⇒ 18 mol
⇒ 18 × 6.023 × 1023
⇒ 1.084 × 1025

40) Average atomic mass

=
x = 99.33%
 45)

A. Question Explanation:

The question asks for the concentration of a calcium carbonate (CaCO₃) solution in parts per
million (ppm). We are given the mass of the solute (CaCO₃) and the mass of the solution.

B. Given Data:

A. Mass of CaCO₃ (solute) = 10 g

B. Mass of aqueous solution = 1000 g

C. Concept:

ppm = (mass of solute / mass of solution) × 10⁶

D. Mathematical Calculation:

A. Substitute the given values into the formula:

ppm = (10 g / 1000 g) × 10⁶

B. Simplify:

ppm = (0.01) × 10⁶

ppm = 10,000

E. Final Answer:

The concentration of the CaCO₃ solution is 10,000 ppm. This corresponds to option 4.

46)

MATHS

51)
 log23logx2 = log3x
logx3 = log3x

⇒ log3x = ±1 ⇒

52) Let log3x = a, log3y = b

2a + 3b = 21 ......(1)
3a + 2b = 4 ......(2)
a = –6, b = 11 ⇒ xy = 243

53)
⇒
⇒ x2 –1 >(0.2)0.04
⇒ x2 > (0.2)0.04 + 1

54) ...(1)

...(2)

...(3)

(1) × (2) × (3) ⇒

55) Let \(\frac{{{{\log }_2}x}}{2} = \frac{{{{\log }_2}y}}{3} = \frac{{{{\log

}_2}z}}{{3k}} = p\) x = 22p , y = 23p, z = 23pk
hence, x3y2z = 1
26p.26p.23pk =1 ⇒ 23p(k + 4) ⇒ P = 0 or k = – 4, hence |k| = 4

56) N = 511 – 510 = 510 × 4.

log10N = log10510 × 4 = 10log105 + log104
= (10)(1 – 0.3010) + 2 × (0.3010)
⇒ Characteristic of log10N is 7.

57)

x2 – 4x + 3 = 0 ...(1)
2
x – (3k – 2)x + (k + 1) = 0 ...(2)
subtracting (2) from (1)
(–6 + 3k)x + 2 – k = 0
(3x – 1) (k – 2) = 0

⇒ k = 2, (rejected)
if we put k = 2, we will get a root common.

58)

log2x = t
2t2 – t – 1 = 0, (2t + 1)(t – 1) = 0
t = 1 (only)
x=2

59)

Let

x2 = (p – q)x + pq
x2 – (p – q)x – pq = 0
(x – p)x + q(x – p) = 0
(x – p)(x + q) = 0

x=p x = –q (rejected)

60) x4 – y4 = 1572
x and y both are either odd or even
(x – y)(x + y)(x2 + y2) = 1572
LHS is divisible by 8
RHS is not divisible by 8
⇒ not possible.

61)

∴
∴ y=1

62)

63)
64) Case I : x>0

|4x| = 5 ⇒
Case II : x < 0

|3x – x| = 5 ⇒

sum =

65)
⇒ 4x + 9x = 2(6x)

⇒ ...(1)

⇒ Let
⇒ t2 – 2t + 1 = 0 from eq. (1)
⇒ t=1

⇒
⇒ x=0

66)
y ∈ (0, ±1, ±2, ±3, ±4)
x ∈ (0, ±1, ±2, ±3, ±4)
⇒ Number of points = 9 × 9 – the cases take (3, 4), (4, 3) ........ total 12 cases
= 81 – 12 = 69

67)

68) x9 + x7 + ax5 + bx = (x + 1) (x – 1) q(x) + q(x)

⇒ g(1) = a + b + 2.
it is given that ⇒ –11 = –1–1–a–b
a+b=9
∴ g(1) = 11

69) x – 3 > 0 & x – 3 ≠ 1

⇒x>3&x≠4 ...(1)
x2 + x + 1 = x2 + 3x

⇒ (Rejected)
Hence no solution

70) |x|2 – 3|x| + 2 = 0

Case – I
x>0
x2 – 3x + 2 = 0
(x – 2)(x – 1) = 0
x = 1, 2
Case – II
x<0
x2 + 3x + 2 = 0
(x + 2)(x + 1) = 0
x = –1, –2
Number of real solution = 4

71) Remainder when Ax3 + 4x2 + Bx + 5 is divided by x – 1 is

A × 13 + 4 × 12 + B × 1 + 5 = A + B + 9.
Remainder when Ax3 + 4x2 + Bx + 5 is divided by x + 2 is
A(–2)3 + 4(–2)2 + B(–2) + 5 = –8A – 2B + 21
Both remainders are equal
A + B + 9 = –8A – 2B + 21
⇒ 9A + 3B = 12 ⇒ 3A + B = 4

72)
ab + bc + ca = 0

73) |x – 2| + 2|x – 5| = 7
(i) x > 5 x – 2 + 2 (x – 5) = 7
3x = 19

(ii) 2 < x < 5 x – 2 – 2x + 10 = 7

x = 1 (rej)
(iii) x < 2 –x + 2 – 2x + 10 = 7
3x = 5

74) =0+3=3
75)

SMIN = when a = b = c i.e. x = y = 0