Chemical Properties and Solutions Analysis
Uploaded by
pritee.kumari8bChemical Properties and Solutions Analysis
Uploaded by
pritee.kumari8bDate : 29th May
Q.1. Nitrogen gas is soluble in water. At temperature 293 K, the value of KH is
76.48 kbar . How would the solubility of nitrogen vary (increase, decrease or
remain the same) at a temperature above 293 K , if the value of KH rises to 88.8
kbar.
Q.2. Chloroform (b.p. 61.2oC) and acetone (b.p. 56oC ) are mixed to form an
azeotrope. The mole fraction of acetone in this mixture is 0.339. Predict whether
the boiling point of the azeotrope formed will be (i) 60oC (ii)64.5oC or (iii)54oC.
Defend your answer with reason.
Q.3. A soda bottle will go flat (loose its fizz) faster in Srinagar than in Delhi. Is
this statement correct? Why or why not?
Q.4. How does sugar help in increasing the shelf life of the product?
Q.5. a. An experiment was carried out in the laboratory, to study depression in
freezing point. 1M aqueous solution of Al(NO3)3and 1 M aqueous solution of
glucose were taken. From the given figure identify solution 1 and solution 2. Give
a plausible reason for your answer.
b. The osmotic pressure of a solution of cane sugar was found to be 2.46 atm at
300 K. If the solution was diluted five times, calculate the osmotic pressure at the
same temperature. How can the osmotic pressure of the given cane sugar solution
be decreased without changing its volume? Give a reason for your answer.
b. A solution of phenol was obtained by dissolving 2X 10-2 kg of phenol in 1 kg of
benzene. Experimentally it was found to be 73 % associated. Calculate the
depression in the freezing point recorded.
Q.7. a. Which of the two solutions : 1M aqueous solution of Al(NO3)3or 1M
aqueous solution of glucose will show a greater depression in freezing point? Give
a plausible reason for your answer. b. The osmotic pressure of a solution of cane
sugar was found to be 2.46 atm at 300 K. If the solution was diluted five times,
calculate the osmotic pressure at the same temperature. How can the osmotic
pressure of the given cane sugar solution be decreased without changing its
volume? Give a reason for your answer.