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Solutions and Colligative Properties Quiz

The document contains a series of chemistry questions related to colligative properties, including calculations for freezing point depression and boiling point elevation, as well as theoretical questions about ideal solutions and deviations from Raoult's law. It also includes multiple-choice questions regarding Van't Hoff factors and azeotropic solutions. Additionally, there are applications of Henry's law and discussions on the limitations of fractional distillation.

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47 views2 pages

Solutions and Colligative Properties Quiz

The document contains a series of chemistry questions related to colligative properties, including calculations for freezing point depression and boiling point elevation, as well as theoretical questions about ideal solutions and deviations from Raoult's law. It also includes multiple-choice questions regarding Van't Hoff factors and azeotropic solutions. Additionally, there are applications of Henry's law and discussions on the limitations of fractional distillation.

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pritee.kumari8b
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

Date : 28th May

Q.1. (i) Van’t Hoff factor values for KCl and K2SO4 respectively are :

(A) 1 and 2 (B) 2 and 3 (C) 2 and 2 (D) 2 and 4

(ii) On mixing 20 mL of acetone with 30 mL of chloroform, the total volume of the


solution is:

(a) <50 mL (b) =50 mL (c) >50 mL (d) =10 mL

(iii) An azeotropic solution of two liquids has a boiling point lower than either of
the two when it:

(a) shows a positive deviation from Raoult's law.


(b) shows a negative deviation from Raoult's law.
(c) shows no deviation from Raoult's law.
(d) is saturated
(iv) .Which one of the following pairs will form an ideal solution?
(a) Chloroform and acetone

(c) 𝑛-hexane and 𝑛-heptane


(b) Ethanol and acetone

(d) Phenol and aniline


(v) Match the following:
(v) Which of the following is the best matched options?

(a) (i) - (B), (ii) - (A), (iii) - (D), (iv) - (C)

(b) (i) - (C), (ii) - (B), (iii) - (D), (iv) - (A)

(c) (i) - (B), (ii) - (A), (iii) - (D), (v) - (C)

(d) (i) - (B), (ii) - (D), (iii) - (A), (v) - (C)


Q.2. State Henry’s law and write its two applications.

Q.3. An antifreeze solution is prepared by dissolving 31 g of ethylene glycol


(Molar mass = 62 g mol–1) in 600 g of water. Calculate the freezing point of the
solution. (Kf for water = 1·86 K kg mol–1)

Q.4. Calculate elevation of the boiling point of the solution when 4 g of MgSO4
(molar mass = 120 g/mol) was dissolved in 100 g of water, assuming MgSO4
undergoes complete ionisation. (Kb for water = 0.52 K kg mol–1)

Q.5. answer the following questions :

(a) Pure ethanol cannot be prepared by fractional distillation of ethanol – water


mixture. Comment.
(b) Why does a mixture of chloroform and acetone show deviation from ideal
behaviour ?
(c) The vapour pressure of pure benzene at a certain temperature is 1.25 atm.
When 1.2 g of non-volatile, non-electrolyte solute is added to 60 g of benzene
(M = 78 g mol–1), the vapour pressure of the solution becomes 1.237 atm.
Calculate the molar mass of the non-volatile solute.
(d) The boiling point of benzene is 353.23 K. When 1.80 g of a non-volatile
solute was dissolved in 90 g of benzene, the boiling point is raised to 354.11
K. Calculate the molar mass of the solute. Kb for benzene is 2.53 K kg mol–1.

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