DAILY PRACTICE PROBLEMS
TARGET : JEE(MAIN + ADVANCED)
PERIODIC TABLE & PROPERTIES
TOPIC : DEVELOPMENT OF PERIODIC TABLE & MODERN PERIODIC TABLE
Elements with atomic number 47 belongs to-
(A) 4th period & XII group (B) 4th period & XI group
(C) 5th period & XII group (D) 5th period & XI group
Which of the following pairs has both members from the same group of periodic table -
(A) Mg, Ba (B) Mg, Na (C) Mg, Cu (D) Mg, CI
Who presented the law of octave -
(A) Dobereiner (B) Newland (C) Lother meyer (D) Mendeleeff
Without looking at the periodic table select the elements of Ill A group of the periodic table.
(Atomic no. are given) -
(A)3, 11,19, 37 (B) 5,13, 21,39 (C)7,15,31,49 (D) 5, 13,37, 49
The law of triads was given by -
(A) Mendeleeff (B) Newlands (C) Lother meyer (D) Dobereiner
Alkaline earth metals belong to which group -
(A) 1A (B) IIA (C) A (D) IVA
Inert gases belong to which group -
(A) VIA (B) zero group (C) IlIA group (D) None
Calcium is a member of -
(A) alkali metal (B) alkaline earth metal
(C) p-block (D) d-block
Atomic number 25 element is belong to which block -
(A) s-block (B) p-block (C) d-block (D) All of them
10. The long form of periodic table has
(A) Eight horizontal rows and seven vertical columns
(B) Seven horizontal rows and eighteen vertical columns
(C) Seven horizontal rows and seven vertical columns
(D) Eight horizontal rows and eight vertical columns
1. If an atom has electronic configuration
1s? 252 2p° 352 3p° 3d° 4s?, it will be placed in
(A) Il A group (B) Il A group (C) V B group (D) VI A group
12. An element has electronic configuration 1s? 2s? 2p°® 3s? 3p*. Predict their period, group and
block
(A) Period = 3, block = p , group = 16 (B) Period = 5™ block = s, group = 1
(C) Period = 3, block = p , group = 10 (D) Period = 4™ block = d , group = 12
13. Which configuration represents a noble gas
(A) 1% 25° 2p° 35 3p° 3d" 4s? (B) 1s® 252 2p° 35 3p°
(C) 1% 25% 2p° 3p° (D) 1s* 2% 2p° 3s°
14. In the periodic table, the element with atomic number 16 will be placed in the group
(A)ILA (B)IVA (C)VA (D) VIA
15. Which of the following pairs has both members from the same group of the periodic table
(A)Mg,Ba (B) Mg,Na (C) [Link] (D)Mg,K
16. Which one of the following belongs to representative group of elements in the periodic table
(A) Iron (B) Argon (C) Chromium (D) Aluminium
17. The heaviest atom amongst the following is
(A)Zn (B)Cl (C) Ar (D) Ca
18. Dobernier Triads is :
(A)Na, K, Rb (B) Mg, S, As (C)Cl, Br, | (D)P, S, As
19. The element with atomic number 35 will be placed in
(A) Noble gas family (B) Alkali family
(C) Alkaline earth family (D) Halogen family
20. The element having the electronic configuration 1s? 2s? 2p°, 3s” 3p’ is
(A) A transition element (B) A representative element
(C) An inert gas (D) An inner-transition element
21. Element with outer electronic configuration ns?np® are
(A) Alkaline earth metals (B) Transition elements
(C) Chalcogens (D) Noble gases
22. Elements in which 4f orbitals are progressively filled are called as
(A) Transition elements (B) Lanthanides
(C) Acitinides (D) Inert gases
23. Atomic number of 15, 33, 51 represents the following family :
(A) carbon family (B) nitrogen family
(C) oxygen family (D) None
24. What is the position of the element in the Modern periodic table satisfying the electronic
configuration
(n—1)d'ns*forn=4:
(A) 3rd period and 3rd group (B) 4th period and 4th group
(C) 3rd period and 2nd group (D) 4th period and 3rd group
25. Which of the following are d-block elements but not transition elements ?
(A)Zn, Mn Fe (B) Zn, Cd, Hg (€)Y, La Sc (D) Au,Pd,Pt
DAILY PRACTICE PROBLEMS
TARGET : JEE(MAIN + ADVANCED)
PERIODIC TABLE & PROPERTIES NO. 02
TOPIC : ATOMIC SIZE, Z.«
A givgarmolecule Br,, whose total distance between two nuclei is 3.2 A. What will be the co-
valeht radius of Br atom ?
A)1.6A (B)6.4A (C)2.4A (D)4.9A
Which of the following atom has smallest size
(A) He (B)F (C)H (D) None of these
Which of the following atom has largest size
(A) Cs (B) Fr (C) Kr (D) Xe
Which of the alkali metals is smallest in size ?
(A) Rb (B) K (C) Na (D) Li
Which of the following ions has the smallest radius ?
(A) Be* (B) Li (C) 0* D)F~
Which of the following has largest radius ?
(A) Mg (B) Na’ (©) o* (D) F~
Elements of which group form anions most readily ?
(A) Oxygen family (B) Nitrogen group (C) Halogens (D) Alkali metals
The correct order of increasing atomic radius of the following elements is -
(A)S<O<Se<C (B)O<C<S<Se (C)O<S<Se<C (D)C<0O<S<Se
The correct order of increasing radii of the elements Si, Al, Na and P is-
(A) Si, Al P, Na (B) P. Si, Al, Na (C) Al, Si, P, Na (D) Al, P, Si, Na
10. The correct decreasing order of size of a isoelectronic series is -
(A)Se?>Br > Kr>Rb* > Sr? (B)S? >CI” >K'>Ar>Ca*
(C)N?®>0?>Ne>F >Ca™ (D) F> Ne > Na* > AI** > Mg*?
1. Match list | with list Il and select the correct answer using the codes given below -
List | List Il
lon Radius (in pm)
(a) L iy 216
(o) Na* iy 195
() Br (iiy 60
(@) I (iv) 95
iv iii jii
12. Lanthanide contraction is related with -
(A) Sharp decreasing in atomic size in lanthanide series
(B) Slow or gradual decreases in atomic size in lanthanide series
( C) Constancy in atomic size
(D) All the above
13. Which of the following ions is smallest in size -
(A)CI™ (B) Na* (C) Mg** (D) s*
14. The screening effect of d-electrons is -
(A) Much less than s-electrons (B) Much more than s-electrons
(C) Equal to s-electrons (D) Equal to p-electrons
15. Which one of the following is the smallest in size ?
(A) N> (8) 0% (C)F~ (D) Na*
16. Moving from right to left in a periodic table, the atomic size is-
(A) Increased (B) Decreased
(C) Remains constant (D) None of these
17. Which one is the correct order of the size of the iodine species.
A > >0 B) 1> >0 ©)r>r=>i o)yr=1>r
18. Which is smallest in size i
(A) 0> (B) C* (C)F~ (D) N*
19. Which one of the following is the biggest ion
(A) AI® (B) Ba* (C) Mg*? (D) Na”
20. The correct order of radii is
(A)N <Be <B (B) F-<0* < N* (C)Na<Li<K (D) Fe*" < Fe”'< Fe*
21. Radius of the isoelectronic species
(A) Increases with the increase of nuclear charge.
(B) Decreases with the increase of nuclear charge.
(C) Is the same for all
(D) First increases and then decreases
22. When a neutral atom is converted into cation, there is
(A) Decrease in the atomic number (B) An increase in the atomic number
(C) A decrease in size (D) An increase in size
23. Order for Zait
(A)Na">Mg*>072 >F (B)Na’ > Mg>
>F >0
(C)Mg* >Na' > 07> F (D) Mg** > Na* >F~ >0
24. In modem periodic table, the element with atomic number Z = 118 will be :
(A) Uuo; Ununoctium; alkaline earth metal (B) Uno; Unniloctium; transition metal
(C) Uno; Unniloctium; alkali metal (D) Uuo; Ununoctium; noble gas
25. Among following species which of them have maximum Z..
(A)Sn (B) Sn** ©)In (D) In*
TARGET : JEE(MAIN + ADVANCED)
PERIODIC TABLE & PROPERTIES
TOPIC : IONISATION ENERGY
The dominant factor in determining the IE of the elements on moving down the group is its -
(A) Atomic radius (B) Effective nuclear charge
(C) Positive charge of the ion produced (D) All of the above
M(g) > M(g)+e~ AH=100eV
M(g) > M*'(g) + 26~ AH =250 eV
AH is the energy required for ionisation. Which of the above statement is incorrect ?
(A) IE, of M(g) is 100 eV (B) IE; of M+(g) is 150 eV
(C) IE of M(g) is 250 eV (D) IE; of M(g) is 150 eV
Value of |E of Na (Z =11) would be -
(A) Greater than the IE of Ne
(B) Below the IE of Ne but above the IE of oxygen
(C) Lesser than the IE of Li
(D) Between the IE of N and O.
In which of the following element has highest value of 1. P. ?
(A)Ti B) Zr (C) Hf (D) None of these
In C, N, O, F which of the following order is correct forI. P. : —
(A)F>0>C>N B)O>F>N>C (C)F>N>0>C (D)N>F>0>C
In which of the following have higher difference in the value of lind and llird I.P. —
(A) 1s% 257 2p° 3s% 3p’ (B) 1s2 2s% 2p° 3s*
(C) 1s2 252 2p6 3s1 (D) 1s? 2s? 2p° 3s? 3p*
Which of the following has highest ionisation energy ?
(A) [Ne] 3% 3p’ (B) [Ne] 3s% 3p° (C) [Ne] 3s? 3p? (D) [Ar] 4s? 3d"0 4p®
The energy required to remove an electron of an isolated gaseous atom from its ground state
is called
(A) Potential energy (B) lonization energy
(C) Electrode potential (D) Activation energy
In the long form of periodic table, the element having lowest ionisation potentials are present
in:
(A) | group (B) IV group (C) VIl group (D) Zero group
10. Which of the following elements will have the lowest first ionisation energy ?
(A) Mg (B) Rb (C)Li (D) Ca
1. The ionization energy of nitrogen is more than that of oxygen because :
(A) Of the extra stability of half-filled p-orbitals in nitrogen
(B) Of the smaller size of nitrogen
(C) The former contains less number of electrons
(D) The formeris less electronegative
12, Which of the following has highest ionization energy -
(A) Argon (B) Barium (C) Calcium (D) Oxygen
13. Decreasing order of IP is -
(A) Na, Mg, Al (B) Al, Mg, Na (C) Mg, Al, Na (D) Al, Na, Mg
14. Element X, Y and Z have atomic numbers 19, 37 and 55 respectively. Which of the following
statements is true -
(A) Their ionisation potential would increase with the increasing atomic number
(B) 'Y’ would have an ionisation potential in between those of ‘X' and ‘2’
(C) ‘Z" would have the highest ionisation potential
(D) “Y" would have the highest ionisation potential
15. The first ionization energy of Al is smaller than that of Mg because -
(A) Atomic size of Al is more than that of Mg
B ) The electronic configuration of Mg is more stable than that of Al
(C) Atomic size of Alis less than that of Mg
(D) None of these
16. Amongst the following elements (whose electronic configuration are given below), the one
having the highest ionization energy is-
(A) [Ne] 3s? 3p’ (B) [Ne] 3s° 3p°
(C) [Ne] 3s° 3p° (D) [Ar] 3d"° 4s% 4p®
17. The incorrect statement among the following is -
(A) the first ionisation potential of Al is less than the first ionisation potential of Mg
(B) the second ionisation potential of Mg is greater than the second ionisation potential of Na
(C) the first ionisation potential of Na is less than the first ionisation potential of Mg
(D) the third ionisation potential of Mg is greater than the third ionisation potential of Al
18. The ionization potential order for which set is correct :
(A)Li>K>Cs (B)B>K=>Li (C)Cs>Li>B (D)Cs <Li<K
19. The five successive ionisation energies for an atom X are 800, 2425, 3660, 25025 and 32800
KJ/mole respectively. what are the number of valence electrons in and atom X.
(A1 B2 (OK] (D)4
20. The first ionisation potentials (eV) of Be and B respectively are
(A)8.29eV,9.32 eV (B)9.32eV,9.32 eV
(C)8.29eV, 829 eV (D)9.32eV,8.29 eV
TARGET : JEE(MAIN + ADVANCED)
PERIODIC TABLE & PROPERTIES
TOPIC : ELECTRON GAIN ENTHALPY
Which is the correct order of electron affinity-
(A) Li > Be > Na > Mg (B) Li > Na > Be > Mg
(C) Li < Be = Na <Mg (D) Li > Na> Mg = Be
Which of the following element has the highest value of electron affinity -
(A) Carbon (B) Oxygen (C) Fluorine (D) Neon
Which of the following element has the lowest value of electron affinity -
(A) Fluorine (B) Chlorine (C) Bromine (D) lodine
The process requiring the absorption of energy is :
A)F->F (B)Cl—>CI (C)0 — 0" (D)H—>H"
Arrange S, O and Se in ascending order of electron affinity
(A)Se<S<O (B)Se<0O<S$S (C)S<0O<Se (D)S<Se<O
Which of the following elements has the maximum electron affinity ?
(A)F (B)Cl (C) Br (D)1
There are 10 neutrons in the nucleus of the element ZM19. It belongs to -
(A) f - block (B) s - block (C) d - block (D) None of these
The correct order of electron affinity for the different families is -
(A) Halogen > carbon > nitrogen > oxygen
(B) Halogen > oxygen > nitrogen > carbon
(C) Halogen > nitrogen > carbon > oxygen
(D) Halogen > oxygen > carbon > nitrogen
Highest electron-affinity is associated with the configuration -
(A) 257, 2p° (B) 2s%, 2p? (C) 25 2p* (D) 2s2, 2p"
10. a )M (g)— M(g)
b) M(g) —> M"(g)
) M"(g) —> M(g)
d) M"%(g) —> M™(g)
Minimum and maximum energy will be absorbed by the processes -
(Aya.d (B)b, c (C)c,d D) a,b
1. Which will have the maximum value of electron affinity Ox, Oy and Oz—
[x,y and z respectively are 0,-1and -2]
(A) Ox (B) Oy (C) Oz (D) All have equal
12. In which case the energy released is the minimum in the process of attachement of electron -
(A)B——> B~ (B)C—>C~ (C)N—> N~ DOo—>0"
13. Fluorine has low electron affinity than chlorine because of-
(A) Smaller radius of fluorine, high density
(B) Smaller radius of chlorine, high density
(C) Bigger radius of fluorine, less density
(D) Smaller radius of chlorine, less density
14. Which of the following represents the correct order of increasing electron gain enthalpy with
negative sign for the elements O, S, F and CI ?
(A)O<S<F<Cl (B)F<S<O<Cl (C)S<0<CI<F (D)CI<F<0<$S
15. Electron affinity depends on :
(A) Atomic size only (B) Nuclear charge only
(C) Atomic number only (D) Atomic size and nuclear charge both
DAILY PRACTICE PROBLEMS
TARGET : JEE(MAIN + ADVANCED)
PERIODIC TABLE & PROPERTIES
TOPIC : ELECTRONEGITIVITY
1. The element with least electronegative nature is-
(A) Cu (B)Cs (©)cr (D)Ba
2. Element of which of the following atomic numbers has lowest electronegativity ?
(A)37 (B) 55 (C) 87 (D) 105
3. What will be the electropositive character when we move from left to right in a period -
(A) Increases (B) Decreases
{C) No change (D) First increases then decreases
4. Which will be the correct order of electronegativity -
(A)I<Br<F<Cl (B)F>CI>Br>1 (C)I>Br>F>Cl (D)F<Cl<Br<lI
5. Which is not the correct order of electronegativity -
(A)CI>S>P>Si (B)Si>Al>Mg>Na (C)F>CI>Br>| (D) None
of these
6. Match list | with list Il and select the correct answer using the codes given below -
List1 1 (electronic
(element) configuration)
@) Gallium 1. 15% 2% 2p° 35% 3p° 45° 3d"
\ (b) Vanadium 2. 1s” 25% 2p° 35 3p° 457 30"
' |l zine 3. 15" 257 2p° 35" 3p° 45” 34" 4p'
* | Scandium |4, 15 25? 2p° 3% 3p° 457 3d°
Codes:
@ ® © (@ @ ® @© @@
(A) 2 1 3 4 (B) 3 4 1 2
©) 3 4 2 1 (D) 1 2 4 3
7. The first ionization potential of Na, Mg, Al and Si are in the order-
(A)Na<Mg>Al<Si (B) Na > Mg > Al > Si
(C)Na <Mg < Al>Si (D) Na > Mg > Al < Si
The increasing order of electronegativity in the following elements-
(A)C, N, Si,P (B)N, Si, C, P (C)Si,P,C.N (D)P,Si,N, C
Which element has the highest electronegativity :
(A)F (B) He (C) Ne (D) Na
10. Which of the following relation is correct if EN value is on Mulliken scale and IP & EA are in
ev:
(A)2I.P.—EA.-EN.=0 (B)2I.P.—EA +EN.=0
(C)2EN.-IP.-EA.=0 (D)EN.-IP.-EA.=0
1. The most polar bond is :
(A)O-F (B) N—-CI (C)N-F (D) N-N
12. The tendency of atom in a compound to attract a pair of bonded electrons towards itself is
known as :
(A) Electron affinity (B) Electronegativity (C) lonisation energy (D) Valence
13. The electronegativity of H and Cl are 2.1 and 3.0 respectively. The correct statement about
the nature of HCl is:
(A) 17% ionic (B) 83% ionic (C) 50% ionic (D) 100% ionic
14. Among the following oxides, the least acidic is :
(A)P4Os (B) P4O1o (C) AssOs (D) As4O10
15. Which of the following statement is incorrect ?
(A) Oxide of aluminium (Al,Os), and arsenic (As,Os) are amphoteric.
(B) Oxide of chlorine (Cl,O;) is less acidic than oxide of nitrogen (N,Os).
(C) Oxide of carbon (CO) is more acidic than oxide of silica (SiO2).
(D) The correct increasing order of basic character of various oxides is H,O < CuO < MgO <
CaO.
ANSWER KEY
DPP-1
DPP-3
(©) ©)
B) B) (A) 10.
1. 14. (B) 15.
16. 19. ©) 20.
DPP-4
® ©) D) (C)
D) D)
1. 12, (©) 13.
DPP-5
(©) (A)
1.