13-07-2025

1103CMD303021250070 MS

PHYSICS

1) A steel ball of radius 6mm has a terminal speed of 12 cms–1 in a viscous liquid. What will be the
terminal speed of a steel ball of radius 3 mm in the same liquid?

(A) 4 cms–1
(B) 9 cms–1
(C) 6 cms–1
(D) 3 cms–1

2) The pressure inside a soap bubble A is 1.01 atmosphere and that in a soap bubble B is 1.02
atmosphere. The ratio of volume of bubble A to that of B is [Surrounding pressure = 1 atmosphere]

(A) 101 : 102

(B) 102 : 101
(C) 8 : 1
(D) 2 : 1

3) A closed pipe containing a liquid showed a pressure P1 by gauge. When the value was opened,
pressure was reduced to P2. The speed of water flowing out of the pipe is (ρ = density of water)

(A)

(B)

(C)

(D)

4) A completely filled water tank of height 'h' has a hole at the bottom. The total pressure of the
bottom is 4H and atmospheric pressure is H. The velocity of water flowing out of the hole is
(ρ = density of water)

(A)

(B)
(C)

(D)

5) Two metal spheres are falling through a liquid of density 2.5 × 103 kg/m3 with the same uniform
speed. The density of material of first sphere and second sphere is 11.5 × 103 kg/m3 and 8.5 × 103
kg/m3 respectively. The ratio of the radius of first sphere to that of second sphere is

(A)

(B)

(C)

(D)

6) Water is flowing in a conical tube as shown in figure. Velocity of water at area 'A2' is 60 cm/s. The
value of 'A1' and 'A2' is 10 cm2 and 5 cm2 respectively. The pressure difference at both the cross-
section is

(A) 230 N/m2

(B) 200 N/m2
(C) 135 N/m2
(D) 105 N/m2

7) Liquid drops are falling slowly one by one from vertical glass tube. The relation between the
weight of a drop ‘w’, the surface tension ‘T’ and the radius ‘r’ of the bore of the tube is (Angle of
contact is zero)

(A)
(B)

(C)

(D)

8) A ball rises to surface at a constant velocity in liquid whose density is 4 times greater than that of
the material of the ball. The ratio of the force of friction acting on the rising ball and its weight is

(A) 3 : 1
(B) 4 : 1
(C) 1 : 3
(D) 1 : 4

9) Three liquids have same surface tension and densities Q1, Q2 and Q3 (Q1> Q2 > Q3). in three
identical capillaries rise of liquid is same. The corresponding angles of contact are
related as

(A)
(B)
(C)
(D)

10) The height of liquid column raised in a capillary tube of certain radius when dipped in liquid ‘A’
vertically is 5 cm. 1f the tube is dipped in a similar manner in another liquid ‘B’ of surface tension
and density double the values of liquid ‘A’, the height of liquid column raised in liquid ‘B’ would be
(Assume angle of contact same)

(A) 0.20 m
(B) 0.5 m
(C) 0.05 m
(D) 0.10 m

11) The excess pressure inside a spherical drop of water A is four times that of another drop B. Then
the ratio of mass of drop A to that of drop B is

(A) 1 : 4
(B) 1 : 8
(C) 1 : 16
(D) 1 : 64

12) A capillary tube stands with its lower end dipped into liquid for which the angle of contact is 90°.
The liquid will

(A) neither rise nor fall.

(B) get depressed only.
(C) rise only.
(D) rise upto the top of the tube.

13) If the work done in blowing a soap bubble of volume 'V' is 'W', then the work done in blowing a
soap bubble of volume '2V' will be

(A) W
(B) 2W
(C)
(D)
14) A fixed mass of gas at constant pressure occupies a volume ‘V’. The gas undergoes a rise in
temperature so that the r.m.s. velocity of the molecules is doubled. The new volume will be

(A)

(B)

(C) 2 V
(D) 4 V

15) The r.m.s. velocity of gas molecules kept at temperature 27°C in a vessel is 61 m/s. Molecular

weight of gas is nearly [R = ]

(A) 2
(B) 4
(C) 28
(D) 32

16) O2 gas is filled up in a cylinder. If pressure is increased 2 times, temperature becomes four
times. Then how much times their density will be –

(A) 2
(B) 4

(C)

(D)

17) The total kinetic energy of 1 mole of N2 at 27° C will be approximately (R = 2 cal/mol/°C):–

(A) 1500 J
(B) 1500 calories
(C) 1500 kilo calories
(D) 1500 erg

18) Absolute zero temperature is one at which :

(A) all liquids convert into solid

(B) all gases convert to solid
(C) all matter is in solid state
(D) the K.E. of a molecules becomes zero

19) For a gas having 'X' degrees of freedom, ' ' is (g = ratio of specific heats )
(A)

(B)

(C)

(D)

20) For polyatomic gases, the ratio of molar specific heat at constant pressure to constant volume is
(f = degrees of freedom)

(A)

(B)

(C)

(D)

21) The average translational kinetic energy of nitrogen (molar mass 28) molecules at a particular
temperature is 0.042 eV. The translational kinetic energy of oxygen molecules (molar mass 32) in eV
at double the temperature is

(A) 0.021
(B) 0.048
(C) 0.056
(D) 0.084

22) The temperature at which r.m.s. velocity of hydrogen molecules is 4.5 times that of an oxygen
molecule at is (Molecular weight of hydrogen and oxygen molecules are 2 and 32 respectively)

(A)
(B)
(C)
(D)

23) The ratio of the specific heats , in terms of degrees of freedom (n) is

(A)

(B)

(C)

(D)
24) Four point charges each +q is placed on the circumference of a circle of diameter 2d in such a
way that they form a square. The potential at the centre is proportional to

(A)

(B)

(C)

(D)

25) The electric potential at the centre of two concentric half rings of radii R1 and R2, having same
linear charge density ‘ ’ is ( = permittivity of free space)

(A)

(B)

(C)

(D)

26) A regular hexagon of side 10 cm has a charge l C at each of its vertices. The potential at the

centre of hexagon is

(A) 1.8 × 105 volt

(B) 3.6 × 105 volt
(C) 5.4 × 105 volt
(D) 7.2 × 105 volt

27) Four electric charges +q, +q, –q and –q are placed in order at the corners of a square of side 2L.
The electric potential at point midway between the two positive charges is

(A)

(B)
(C)

(D)

28) If a unit charge is taken from one point to another point over an equipotential surface, then

(A) work is done on the charge.

(B) work is done by the charge.
(C) work done on the charge is constantly increasing.
(D) work done to move a charge is zero.

29) Two point charges q1 = 6 mC and q2 = 4 μC are kept at points A and B in air where AB = 10 cm.
What is the increase in potential energy of the system when q2 is moved towards q1 by 2 cm ?

(A) 0.27 J
(B) 0.54 J
(C) 0.81 J
(D) 54 J

30) Charge on a parallel plate capacitor of capacity C is Q. the electric field intensity between its
two plates separated by a distance of t is

(A)

(B)

(C)

(D)

31) Two capacitors C1 = and C2 = are connected in series across d.c. source of 100V. The
ratio of the potential across C2 to C1 is

(A) 2 : 3
(B) 3 : 2
(C) 5 : 6
(D) 6 : 5

32) Four identical capacitors are connected in series with a battery of emf 10V. The point X is
earthed. Than the potential of point A is-

(A) 10 V
(B) 7.5 V
(C) - 7.5 V
(D) 0 V

33) Four capacitors and a battery are connected as shown. the potential drop across

the capacitor is 6V, then choose incorrect option.

(A) Potential difference across the 3 capacitor is 10V

(B) charge on the 3 capacitor is 42

(C) e.m.f. of the battery is 30V

(D) potential difference across the 12 capacitor is 10V.

34) Capacitance of an air filled parallel plate capacitor is 10 μF. If two dielectric medium are filled
by deviding it in two equal parts as shown in figure then equivalent capacitance will be

(A) 30 μF
(B) 15 μF
(C) 5 μF
(D) 10 μF

35) Four capacitors are connected as shown in the figure. Their capacitance are indicated in the
figure. The effective capacitance between points x and y is (in µF)
(A)

(B)

(C)

(D) 2

36) In a parallel plate capacitor with air between the plates, the distance 'd' between the plates is
changed and the space is filled with dielectric constant 8. The capacity of the capacitor is increased
16 times, the distance between the plates is

(A) 2d
(B) 4d

(C)

(D)

37) When cell of E.M.F. ‘E1’ is connected to potentiometer wire, the balancing length is . Another
cell of E.M.F. ‘ is connected so that two cells oppose each other, then the balancing
length is . The ratio is

(A)

(B)

(C)

(D)

38) When a galvanometer is shunted by a resistance 'S', its current capacity increases 'n' times. If
the same galvanometer is shunted by another resistance S', its current capacity increases to n'. The
value of n' in terms of n, S and S' is

(A)
(B)

(C)

(D)

39) Resistances in the left gap and right gap of a meter bridge are 10 Ω and 30 Ω respectively. If the
resistances in the two gaps are interchanged, the balance point will shift to right by

(A) 30 cm.
(B) 40 cm.
(C) 50 cm.
(D) 60 cm.

40) In the following circuit, a power of 50 watt is absorbed in the section AB of the circuit. The value
of resistance ‘x’ is

(A) 10 Ω
(B) 8 Ω
(C) 6 Ω
(D) 4 Ω

41) The range of voltmeter of resistance ‘G’ is ‘V’ volt. The resistance required to be connected in
series with it in order to convert it into a voltmeter of range ‘nV’ volt, will be

(A)
(B) G/n
(C) nG

(D)

42) In a Wheatstone's bridge, the resistances in four arms are as shown in the figure. The balancing
condition of the bridge is

(A)
(B)

(C)

(D)

43) In potentiometer experiment cells of e.m.f. E1 and E2 are connected in series (E1 > E2) the
balancing length is 80 cm of the wire. If the polarity of E2 is reversed, the balancing length becomes

20 cm. The ratio is

(A) 1 : 2
(B) 2 : 3
(C) 3 : 4
(D) 5 : 3

44) In the given circuit, current flowing through the circuit is

(A) 2 A
(B) 3 A
(C) 4 A
(D) 5 A

45) The potential difference (VA – VB) between the points 'A' and 'B' in the given part of the circuit is

(A) –3 V
(B) 3 V
(C) 6 V
(D) 9 V

46) The figure shows currents in a part of electric circuit. Then current I is
(A) 3.5 A
(B) 1.5 A
(C) 4 A
(D) 2.5 A

47) In an ammeter, 4% of the main current is passing through the galvanometer. If shunt resistance
is 5 Ω, then resistance of galvanometer will be

(A) 60Ω
(B) 120Ω
(C) 240Ω
(D) 480Ω

48) In the following circuit, the current I3 is

(A) 5 A
(B) 3 A
(C) –3 A

(D)

49) An insulated container contains a monoatomic gas of molar mass 'm'. The container is moving
with velocity 'V'. If it is stopped suddenly, the change in temperature is (R = gas constant)

(A)

(B)

(C)

(D)

50) Water rises up to height 'x' in a capillary tube immersed vertically in water. When the whole
arrangement is taken to a depth 'd' in a mine, the water level rises up to height Y. If R is the radius
of the earth then the ratio Y: x is

(A) R: (R+ d)
(B) R:(R-d)
(C) R:(R-d)2
(D) R:(R+d)2

CHEMISTRY

1) Which of the following is a Lewis acid but NOT a Bronsted acid ?

(A) BCl3
(B) HNO3
(C) NH3
(D)

2) What is pH of solution containing 50 mL each of 0.1M sodium acetate and 0.01M acetic acid
(pKaCH3COOH = 4.50)

(A) 2.5
(B) 3.5
(C) 4.5
(D) 5.5

3) The [OH–] in 100.0 mL of 0.016 M-HCl(aq) is:

(A) 5 × 1012 M
(B) 3 × 10–10 M
(C) 6.25 × 10–13 M
(D) 2.0 × 10–9 M

4) Which of the following solutions would have same pH?

(A) 100 mL of 0.2 M HCl + 100 mL of 0.4 M NH3

(B) 50 mL of 0.1 M HCl + 50 mL of 0.2 M NH3
(C) 100 mL of 0.3 M HCl + 100 mL of 0.6 M NH3
(D) All will have same pH

5) 10–6 M HCl is diluted to 100 times. Its pH is:

(A) 6
(B) 8
(C) 6.95
(D) 9.5
6) The solubility of PbSO4 at 25°C is 1.1 × 10–4 mol/L. Then its Ksp is:

(A) 1.21 × 10–8

(B) 12.1 × 10–6
(C) 121 × 10–11
(D) 1.21 × 10–10

7) Which of following is not Lewis acid?

(A) H2O
(B) BF3
(C) H+
(D)

8) Dissociation constant of NH4OH in water is 1.8 × 10–5, then hydrolysis constant of NH4Cl is:

(A) 1.8 × 10–5

(B) 1.8 × 10–10
(C) 5.55 × 10–5
(D) 5.55 × 10–10

9) On dilution a buffer solution, its pH

(A) Increases
(B) Decreases
(C) Remains same
(D) Cannot be predicted

10) According to Bronsted Lowry concept, in given reaction, water will behave as CH3COOH + H2O
⇌ CH3COO⊝ + H3O⊕

(A) Weak acid

(B) Weak base
(C) Strong acid
(D) Strong base

11) Which of the following aqueous solutions of salts will have highest pH value ?

(A) CH3COONH4
(B) Na2CO3
(C) NH4Cl
(D) NaCl

12) The pH of 0.5 M aqueous solution of HF (Ka = 2 × 10–4) is:

(A) 2
(B) 4
(C) 6
(D) 10

13) In a saturated solution of Ag2CO3, silver ion concentration is 2 × 10–4 M. Its solubility product is:

(A) 4 × 10–12
(B) 8 × 10–12
(C) 3.2 × 10–11
(D) 10–12

14) The degree of hydrolysis of which of the following salt is independent of the concentration of salt
solution?

(A) CH3COONa
(B) NH4Cl
(C) CH3COONH4
(D) NaCl

15) Which one is correct statement?

(A) Basicity of H3PO4 and H3PO3 are 3 and 3 respectively.

(B) Acidity of H3PO4 and H3PO3 are 3 and 3 respectively.
(C) Acidity of H3PO4 and H3PO3 are 3 and 2 respectively.
(D) Basicity of H3PO4 and H3PO3 are 3 and 2 respectively.

16) Which is the strongest acid (pKa value is given) ?

(A) HCOOH [3.77]

(B) C6H5COOH [4.22]
(C) CH3COOH [4.7]
(D) CH3CH2COOH [4.88]

17) The pH value of decinormal solution of NH4OH, which is 20%, ionised, is:

(A) 13.3
(B) 14.70
(C) 12.30
(D) 12.95

18) 10–6 M HCl. Find the pH :

(A) 6
(B) 8
(C) 6.95
(D) 9.5

19) The hydrolysis constant of 0.1 M aqueous solution of sodium acetate if Ka of CH3COOH = 1.8 ×
10–5 is

(A) 5.5 × 10–10

(B) 4.5 × 10–8
(C) 5.5 × 10–12
(D) None of these

20) Which of the following is not a buffer?

(A) NH4OH + C6H5COOH

(B) HCOOH + HCOONa
(C) H2CO3 + HCOOK
(D) NH4OH + (NH4)2SO4

21) Among them intensive property is :

(A) Mass
(B) Volume
(C) Surface tension
(D) Enthalpy

22) Heating of phenyl methyl ether with HI produces :

(A) Iodobenzene
(B) Phenol
(C) Benzene
(D) Ethyl Chloride

23) IUPAC name of is

(A) Ethoxybenzene
(B) Phenetole
(C) Anisole
(D) Ethylphenyl ether

24) The most acidic compound among the following is

(A) C2H5OH
(B) H2O
(C)

(D)

25) The compound which does not evolve hydrogen on reaction with sodium is

(A)

(B)

(C)
(D)

26) In the given reaction:

Major product [X] is

(A) Salicylic acid

(B) m-hydroxybenzoic acid
(C) Mixture of 1 and 2
(D) Salicylaldehyde

27) Which of the following alcohols reacts most readily with Lucas reagents?

(A) CH3CH2CH2OH

(B)

(C)

(D)

28) The reaction

C2H5ONa + BrC2H5 → C2H5—O—C2H5 + NaBr is called :-

(A) Frankland reaction

(B) Wurtz reaction
(C) Williamson's synthesis
(D) Cannizzaro reaction

29) The reaction of SOCl2 on alkanols to form alkyl chlorides gives good yields because
(A) Alkyl chlorides are immiscible with SOCl2
(B) The other products of the reaction are gaseous and escape out
(C) Alcohol and SOCl2 are soluble in water
(D) The reaction does not occurs via intermediate formation of an alkyl chloro sulphite

30)

(A)

(B)

(C)

(D)

31) Which of the following reactions does not involve reduction ?

(A)
(B)
(C)

(D)

32) A system is provided 50 J of heat and work done on the system is 10 J. The change in internal
energy during the process is :-

(A) 40 J
(B) 60 J
(C) 80 J
(D) 50 J

33) Which of the following is the best container for gas during isothermal process?

(A) Glass vessel

(B) Wood vessel
(C) Copper vessel
(D) Thermos flask
34) For the reaction,
A(g) + 2B(g) → 2C(g) + 3D(g)
the value of ΔH at 27°C is 19.0 KCal. The value of ΔU for the reaction would be :-

(A) 20.8 KCal

(B) 19.8 KCal
(C) 18.8 KCal
(D) 17.8 KCal

35) What is the change in internal energy ΔU, for a system that does 70 joules of work as it absorbs
45 joules of heat?

(A) 115 J
(B) 25 J
(C) –25 J
(D) –115 J

36) When 1 mol gas is heated at constant volume, temperature is raised from 298 to 308 K. Heat
supplied to the gas is 500 J. Then which statement is correct?

(A) q = w = 500 J, ΔU = 0
(B) q = ΔU = 500 J, w = 0
(C) q = ΔU = –500 J, w = 0
(D) ΔU = 0, q = w = –500 J

37) A state function is that :

(A) which is used in thermochemistry

(B) which obeys all laws of thermodynamics
(C) quantity whose value depends only upon the state of the system
(D) quantity which is used in measuring thermal change

38) In thermodynamics, a process is called reversible when

(A) surroundings and system change into each other

(B) there is no boundary between system and surroundings
(C) the surroundings are always in equilibrium with the system
(D) the system changes into the surroundings spontaneously

39) For which, change ΔH ≠ ΔU

(A) H2(g) + I2(g) → 2HI(g)

(B) HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)
(C) C(s) + O2(g) → CO2(g)
(D) N2(g) + 3H2(g) → 2NH3(g)
40) Which of the following statements is incorrect about internal energy :-

(A) The absolute value of internal energy cannot be determined.

(B) The internal energy of one mole of a substance is same at any temperature and pressure
The measurement of heat change during a reaction by bomb-calorimeter is equal to the internal
(C)
energy change.
(D) Internal energy is extensive property

41) Choose the correct option for free expansion of an ideal gas under adiabatic condition from the
following :

(A) q = 0, ΔT ≠ 0, w = 0
(B) q = 0, ΔT < 0, w ≠ 0
(C) q ≠ 0, ΔT = 0, w = 0
(D) q = 0, ΔT = 0, w = 0

42)
Name of the reaction given above :

(A) Kolbe reaction

(B) Carbylamine reaction
(C) Reimer Tiemann reaction
(D) Haloform reaction

43) The structure of intermediate A in the following reaction is :-

(A)
(B)

(C)

(D)

44) Phenol is heated with phthallic anhydride in presence of concentrated H2SO4. The product gives
a pink colour on reacting with an alkali. The product is:

(A) Salicylic acid

(B) Fluorescein
(C) Fluorescein
(D) Phenolphthalein

45) For the reaction,

C2H5OH + HX —→ C2H5X, the order of reactivity is

(A) HI > HCl > HBr

(B) HI > HBr > HCl
(C) HCl > HBr > HI
(D) HBr > HI > HCl

46) For the reduction of aldehydes and ketones into alcohol the reagent which can be used is/are :

(A) H2 in presence of Ni, Pt or Pd

(B) NaBH4
(C) LiAlH4
(D) All of these

47)
(A) Diethyl ether
(B) Methyl propyl ether
(C) Ethyl methyl ether
(D) Propyl ethyl ether

48) The reaction C2H5ONa + BrC2H5 →C2H5 – O – C2H5 + NaBr is called :-

(A) Frankland reaction

(B) Wurtz reaction
(C) Williamson's synthesis
(D) Cannizzaro reaction

49) Which of the following alcohol will yield alkyl chloride without any rearrangement on reaction
with concentrated HCl and ZnCl2 at room temperature :-

(A) CH3 – CH2 – CH2 – OH

(B)

(C)

(D)

50) When vapours of a secondary alcohol is passed over heated copper at 573 K, the product formed
is:–

(A) A carboxylic acid

(B) An aldehyde
(C) A ketone
(D) An alkene

MATHEMATICS

1) The principal solutions, of the equation , are

(A)

(B)

(C)

(D)
2) In is equal to

(A)

(B)

(C)

(D)

3) If the general solution of the equation

is , then is

(A) 12

(B)

(C) 3
(D) 36

4) If , then is

(A) Equilateral
(B) Right angled
(C) Isosceles
(D) None of these

5) Number of solutions of

in the interval [0, 2π] is :

(A) 2
(B) 4
(C) 0
(D) None of these.

6) If the lengths of the sides of triangle are 3, 5, 7, then the largest angle of the triangle is

(A)

(B)

(C)

(D)
7) General solution of equation =1 is -

(A)

(B)

(C)

(D) None of these

8) The solution(s) of the equation cos2x sin6x = cos3x sin5x in the interval [0,π] is NOT

(A)

(B)

(C)

(D)

9) The general solution of is

(A)

(B)

(C) ϕ

(D)

10) The sides of a triangle are , and for some , then

the greatest angle of a triangle is

(A)

(B)

(C)

(D)

11) The number of solutions of equation

3cos2x – 8sinx = 0 in [0,3π] is

(A) 2
(B) 3
(C) 4
(D) 5
12) In a triangle ABC, with usual notations, if , , then has the
value

(A) b

(B)

(C) 2b
(D) 3b

13) Number of solutions of sec24θ – tan4θ = 1 in [0,π] is

(A) 4
(B) 6
(C) 8
(D) 9

14) If , then

(A)

(B)

(C)

(D) None of these

15) In a . If and are the roots of the equation ax2 + bx + c =

0 , then

(A) a + b = c
(B) b + c = a
(C) a + c = b
(D) b = c

16) The number of solutions of tanx + secx = 2cosx in is

(A) 2
(B) 3
(C) 0
(D) 1

17) The equation esinx - e–sinx = 4 has ______ solutions.

(A) 2
(B) 4
(C) 3
(D) no

18) The number of solution of the equation 3sin2x = 8 cosx in the interval is

(A) 1
(B) 2
(C) 3
(D) 4

19) The length of the longest interval, in which the function is increasing is

(A)

(B)

(C)

(D)

20) If Rolle’s theorem holds for the function on [1,3] with , then
the values of a and b respectively are

(A)
(B) 11,6
(C)
(D)

21) The equation of normal to the curve

at is

(A)
(B)
(C)
(D)

22) The approximate value of is, given that and

(A) 0.8778
(B) 0.7666
(C) 0.7916
(D) 0.8616

23) A stone is dropped into a quiet lake and waves move in circles at speed of 8 cm/sec. At the
instant when the radius of the circular wave is 12cm, how fast is the enclosed area increasing?
(A)
(B)
(C)
(D)

24) If sum of two numbers is 3, then the maximum value of the product of first number and square of
the second number is

(A) 6
(B) 4
(C) 5
(D) 3

25) A ladder 5m long rests against a vertical wall. If its top slides downwards at the rate of
10cm./sec., then the foot of the ladder is sliding at the rate of _______ m/sec., when it is 4m away
from the wall.

(A) 0.75
(B) 7.5
(C) 0.0075
(D) 0.075

26) The equation of the tangent to the curve at the point of intersection with Y-axis is

(A)
(B)
(C)
(D)

27) Let C be a curve given by . If P is a point on C, such that the tangent

at P has slope , then a point through which the normal at P passes, is

(A) (1, 7)
(B) (3, –4)
(C) (4, –3)
(D) (2, 3)

28) If , then it is increasing in

(A) (0, e)
(B)
(C)
(D)
29) The maximum value of is

(A) e
(B) 2e

(C)

(D)

30) If mean value theorem holds for the function

then the values of c as per the theorem are

(A)

(B)

(C)
(D)

31) A square plate is contracting at the uniform rate 3 cm2/sec, then the rate at which the perimeter
is decreasing, when the side of the square is 15 cm, is ____

(A)

(B)

(C)

(D)

32) The approximate value of (3.978)3/2 is

(A) 7.096
(B) 8.096
(C) 7.934
(D) 8.934

33) The equation of the tangent to the curve at

is

(A)

(B)

(C)
(D)

34) The volume of a ball is increasing at the rate of . The rate of increase of the radius,
when the volume is , is

(A)

(B)

(C) 6 cm/sec
(D) 36 cm/sec

35) If y = 4x – 5 is a tangent to the curve y2 = px3 + q at (2, 3), then the values of p and q are
respectively

(A) –2, 7
(B) 2, –7
(C) 7, –2
(D) –7, –2

36) If f(x) = x3 – 6x2 + 9x + 3 is monotonically decreasing function, then x lies in

(A)
(B) (1, 3)
(C)
(D) [0, 3]

37) The maximum value of the function f(x)= 2x3 – l5x2 + 36x – 48 on the set A =
is

(A) –16
(B) –7
(C) 16
(D) 7

38) If has its extremum values at x = -1 and x = 2, then

(A) a = 1, b = -1

(B)

(C)

(D)

39) =
(A)
, where c is a constant of integration.

(B)
, where c is a constant of integration.

(C)
, where c is a constant of integration.

(D)
, where c is a constant of integration.

40) If Where c is a constant of integration,

then the ordered pair (a,b) is equal to

(A) (1, 3)
(B) (3, 1)
(C) (–1, 3)
(D) (–3, 1)

41) is equal to

(A)
, (where c is a constant of integration)

(B)
, (where c is a constant of integration)

(C)
, (where c is a constant of integration)

(D)
, (where c is a constant of integration)

42)

(A)
, where c is a constant of integration.

(B)
, where c is a constant of integration.

(C)
, where c is a constant of integration.

(D)
, where c is a constant of integration.

43) is equal to
(A)
, (where c is a constant of integration)

(B)
, (where c is a constant of integration)

(C)
, (where c is a constant of integration)

(D)
, (where c is a constant of integration)

44) If such that f(2) = 0, then f(x) is equal to

(A)

(B)

(C)

(D)

45)

(A)
, where c is a constant of integration.

(B)
, where c is a constant of integration.

(C)
, where c is a constant of integration.

(D)
, where c is a constant of integration.

46)

(A)

(B)

(C)

(D) None

47) If dx = Ax + B log sin (x – α) + c, then value of (A, B) is-

(A) (sin α, cos α)
(B) (cos α, sin α)
(C) (– sin α, cos α)
(D) (– cos α, sin α)

48)

(A)

(B)

(C)

(D)

49)

If , then

(A)

(B)

(C)
arbitrary constant

(D)
arbitrary constant

50) The value of is equal to :

(A) –cot (exx) +C

(B) tan (ex.x) + C
(C) tan (ex) + C
(D) cot (ex) + C
 ANSWER KEYS

PHYSICS

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D C C C B C D A C C D A D D A D B D C D
Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. D B C B B C B D B B B B C A C C B D C B
Q. 41 42 43 44 45 46 47 48 49 50
A. A D D D D A B D B B

CHEMISTRY

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D C D C A A D C B B A A C D A C A A A
Q. 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A. C B A C D A C C B B D B C D C B C C D B
Q. 91 92 93 94 95 96 97 98 99 100
A. D C A D B D B C D C

MATHEMATICS

Q. 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
A. C A B B C C A C C B C C D C A A D B A D
Q. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
A. C D C B D B A A C B B C A B B B D B C A
Q. 141 142 143 144 145 146 147 148 149 150
A. D C B B C B B A D B
 SOLUTIONS

PHYSICS

1) Terminal velocity

2) PA = 1.01 – 1 = 0.01 Atm

PB = 1.02 – 1 = 0.02 Atm

3)

4)
Applying B.E. at point 1 & 2
5)

⇒ r12(ρ1– ρ) = r22(ρ2 – ρ)

6)

Using law of continuity

A1V1 = A2V2

= 30 cm/s
According to Bernoulli’s principle

⇒ P1-P2 =

= 500 × 10–2 [36–9]

= 5 × 27
P1 – P2 = 135 N/m2

7)

Weight of liquid drop = Force due to surface Tension

F=W

8)

Since the ball rising with constant velocity

Constant velocity
net force = 0
Buoyant force
9)
Given T1 r and h is same

i.e.
Hence,

10)

11) Excess Pressure inside water drop

....(1)

So.

12)

h=0 ...........
Hence, the liquid will either rise nor fall
13) w = [Link]

14)

15)
Here T = 27 + 273 = 300
R = 8.31, Crms = 61 m/s
on solving M = 2

16)

17)
K.E. =
for diatomic gas f = 5

K.E. =
= 1500 cal.

18)

Conceptual

19)

20)

for polyatomic gas

21)

22)
23) We know

From we get

24)
Potential at centre due to all charges are

25)
26)

Here K = 9 × 109
Q = 10–6
R = 10 cm = 0.1 = 10–1m

27)

or

28)

The work done in moving a charge q,

For equipotential surfaces,

W=0

29)

Initially :

= 2.16 J

Finally : = 2.70 J
Change in P.E. = ΔU = Uf – Ui
⇒ ΔU = 0.54 J

30)

31)

In series combination P. D. across the capacitor is inversely proportion to capacitance.

Q = CV;

32)
P.D. Across each capacitor = 2.5V
So VA = 7.5 V

33)

So,

So, V across is 10V

Hence, E = 10 + 20

34)

For air filled capacitor 10μF =

After filling two dielectric
for K1 = 2 for K2 = 4

C1 = C2 =

C1 = C2 =

C1 = C2 = = 20μF
Here C1 & C2 are in parallel
Ceq = C1 & C2
= 10μF + 20μF = 30μF

35)

36)
For dielectric

37)

38) shunt
 G = (n–1)s …(1)

Similarly for shunt

G = (n' – 1)s' …(2)
From (1) & (2)
(n – 1)s = (n' – 1)s'

39) Case I :-

Case II :-

shift = (75 – 25)cm = 50 cm (towards right)

40)

Power = i2
50 W = [2.5]2 R
50 = 6.25 R
8Ώ=R

41)

We know that

The voltmeter gives the full-scale deflection for potential difference V. Its resistance is G.
Hence, Ig = (V/G).
Given that V = nV. Therefore,
42) ....(1)

43)
E1 + E2 = 4E1 – 4E2
3E1 = 5E2

44)

Vnet = 100 – 5 = 95 V
R = 19 Ω

45)

Applying Kirchhoff’s law :

vA –2 × 2 – 3 – 2 × 1 = vB
⇒ vA –vB = 4 + 3 + 2 = 9 V

46)

47)

(2)
 48)

49)

50) In case -1

At depth d

CHEMISTRY

51) BCl3 can accept a pair of electron but does not donate a proton i.e. H+.

52)

=
= 4.5 + 1 = 5.5

53) [H+] = 0.016 M ⇒ [OH–] =

54) (1) pOH = pKb + log

(2) pOH = pKb + log

(3) pOH = pKb + log

55) [HCl] =
or H2O ⇌ H+ + OH¯
10–8 + x x
–14 –8
10 = (10 + x) (x)
On solving we get [H+] = 1.12 × 10–7
⇒ pH= 6.95

56) PbSO4 is a bitary electrolyte, hence its Ksp can calculated as:
Ksp = S2 = [1.1 × 10–4]2 = 1.21 × 10–8

57) acts as Lewis base because it has available electron pair for donation.

58)
Kh = 5.55 × 10–10

59) On dilution, the concentration of both salt and acid decreases.

60)

61) Na2CO3 is the only alkaline solution having highest pH value. It is salt of weak acid (H2CO3)
and strong base (NaOH).

62)
pH = –log10 [H+] = –log10 10–2 = 2

63)

Ag2CO3 → 2Ag+ + CO32–

2S S
–4
= 2 × 10 = 10–4
ksp = (2 × 10–4 )2 × (10–4) = 4 × 10–12

64) It is the salt of weak acid and weak base, hence its degree of hydrolysis will be
independent of concentration.
65)

66) Ka ↑ ⇒ pKa ↓ ⇒ Acid stronger

67) [OH–] = 0.1 × 0.2 = 2 × 10–3 ; pOH = 1.7 pH = 14 – pOH

68) 6

69)

70) Mixture of WB + WA . (not buffer)

(2), (3), and (4) are mixture of WA + Salt of WA/SB (Buffer)

71) Surface tension does not depend on amount of substance

72)

73) : Ethoxybenzene (IUPAC name)

74) Correct order of acidic strength

75) Ether does not react with sodium metal.

76)

77) Tertiary alcohol (3°) reacts most readily with Lucas reagent at room temp.

78)
Williamson Ether Synthesis Reaction

79) The reaction of SOCl2 on alkanols to form alkyl chlorides gives good yields because other
products of reaction are gaseous and escape out.

80)

81)

82) q = + 50 J
w = + 10 J
ΔU = q + w
= + 50 + 10
= 60 J

83) For isothermal process, the container must be a good conductor of heat.

84) Δng = 5 – 3 = 2
ΔH = ΔU + Δng RT
19 = ΔU + 2 × (2 × 10–3) × 300
ΔU = 19 – 1200 × 10–3
= 19 – 1.2 = 17.8 KCal
85) First Law of thermodynamics :
ΔU = q – w (q = 45J heat absorbed)
ΔU = 45 – 70 (w = 70J work done by the system)
ΔU = –25 J (ΔU = Change in internal Energy)

86) First Law of thermodynamics:

ΔU = q + w
w = –PΔV, ΔV = 0, W = 0
ΔU = q = 500 J
w=0
Heat supplied to the system = +ve
[ΔU = 500], [Q = 500]

87)

Quantity whose value depends only upon the state of the system is state function.

88) Fact

89) ΔH = ΔU + ΔnRT
For (D) Δn = 2 – 4 = –2

90)

On changing temperature K.E of molecule change so its internal energy will change.

91) During free expansion of an ideal gas under adiabatic condition q = 0, ΔT = 0, w = 0.

92)

Fact

93)

94) Concept:
Reaction of phenol

Soln/Explanation:
95) C2H5–OH + HX—→C2H5–X
The order of reactivity ⇒ HI > HBr > HCl

96)

97)

98)

Alkoxide + Alkyl Bromide → Ether

99) 3º alcohol reacts with HCl at room temperature

 100)

A. 2° alcohol is oxidised on heating it copper at 573K.

Answer (3)

MATHEMATICS

101)

or

or

102)

But,

103)

104)
Obvious
Trick: Clearly, it is not an equilateral triangle
because does not satisfy the given condition
But if then and

Hence, this equation is satisfied when given triangle is right angled but it is not necessary that
it is iscosceles.

105)

∴ Solution does not exist.

Hence (C) is the correct answer

106)

107)
this is the form of : a =1 ,
b = 1 and c = 1
Divide by i.e.
108) 2 cos2x sin6x = 2 cos3x sin5x
sin8x + sin4x = sin8x – 1 sin 2x
sin 2x = 0

or, cos2x =

109) = tan (2x – x) = 1

tan x = 1 = tan

x = nπ +

110) A = sinq, b = cosq, c =

111) only.

112)

{sin75° = sin(45 +30), )

113) sec24θ – 1 = tan4θ

tan24θ = tan4θ
tan4θ = 0, tan4θ = 1
0 ≤ 4θ ≤ 4π

∴ 4θ = 0, π, 2π, 3π, 4π and 4θ = nπ +

Total solutions 9

114)

Given relation is

115) In

....(i)
ax2 + bx + c = 0

and are the roots.

Also,

from (i)

116) The given equation is defined for

Now,

...........
 in
number of solutions = 2

117)

put y = esinx

y2 – 4y –1 = 0

[ex > 0, for all x Î R]

= log2.71(2+2.2) = log2.71(4.2) > 1,

which is not possible
Hence no solution

118) 3(1 – cos2x) = 8 cosx

⇒
⇒

Number of value of x in is 2

119)

Longest interval in which cos x is positive is .

Longest interval in which cos 3x is positive is

Longest interval in which f(x) is increasing is

120)

As f(x) holds Rolle’s theorem

f(1) = f(3)
a + b + 6 = 3a + 9b + 32
2a + 8b + 26 = 0
a + 4b + 13 = 0 ……(I)
Also,

……a + 4b+ 3 = 0
2b = -12

121)

at

Slope of tangent
Slope of normal = 1

Also, when
Equation of normal

122)

h = 0.00875

= 0.8660 – 0.00875 × 0.5

= 0.8660 – 0.00437
= 0.86163
123)
r = 12 cm

124)

Let numbers are x and 3 – x

product = (3–x)x2
Let f(x) = (3–x)x2
f’(x) = 6x–3x2
f’(x) = 0 given
x = 0, x = 2
Now, f’’(x) = 6 – 6x
At x = 2, f’’(2) < 0
f(x) is maximum at x = 2
\ fmax = (3 – x) (x2)
= (3 – 2)(2)2
=4

125)

x2 + y2 = 25 at x = 4, y = 3

= 0.075 m/sec

126) Point of intersection (y = 0)

tangent at (0, 0)

Equation :

y–0 = (x –0)
127)

4x–3 = 9
x=3
= 1+ 3

slope =

2y – 8 = –3x + 9
3x + 2y – 17 = 0
Option A satisfies above equation

128)

logx < 1
x<e
as (x > 0)

129)

0 = 1 – logx
log(x) = 1
x =e
We know that is increasing

is maximum value

130)

f’(x) = (x – 1)(x – 2) + (x –1)(x – 3)

+ (x –2)(x – 3)

= 3x2 –12x + 11
3x2 – 12x + 8 = 0
131) , L = 15 cm

132)

a = y, h = –0.022

= 8 – 0.066 = 7.934

133)

134) = ,
135)

y2 = px3 + q
y = 4x – 5

at (2, 3)
4 × 2(3) = 3p(2)2 = 3p × 4
q = y2 – px3
q = (3)2 – 2 ×(2)3 = 9 – 16 = –7
(p, q) = (2, –7)

136) f(x) = x3 – 6x2 + 9x + 3

f '(x) = 3x2 – 12x + 9 = 3(x2 – 4x + 3)
= 3(x –1)(x –3)
For decreasing, f '(x) < 0
3(x –1)(x –3) < 0
ie. (x–1)(x–3) < 0
Critical points = 1, 3

137)

Critical points = 4, 5

f(x) = 2x3 – 15x2 + 36x – 48 = 0 … (i)

f '(x) = 6x2 – 30x + 36 = 0
For f(x) to be maximum or minima
f '(x) = 0
6x2 –30x + 36 = 0
x2 – 5x + 6 = 0
(x –2)(x –3) = 0
x = 2 or x = 3
 f(2) = 2(2)3 – 15(2)2 + 36(2) – 48
= 16 – 60 + 72 – 48 = –20
f(3) = 2(3)3 –15(3)2 + 36(3) – 48
= 24 – 135 + 108 – 48 = –21
f(4) = 2(4)3 – 15(4)2 + 36(4) – 48
= 128 – 240 + 144 – 48 = –16
f(5) = 2(5)3 –15(5)2 + 36(5) – 48
= 250 – 375 + 180 – 48 = 7
f(x) is max. at x = 5 i.e. 7

138)

Given that, for x = -1, 2

139) Let 3x = t

140)

Let sinx + cosx = t

cosx - sinx dx = dt
=
So, a = 1, b = 3

141)

Let log x = t

142)

143) I =
N=
=
=
=
=

I=

I=

144) f(x) =
f(2) =

f(x) =

145)

146) dx = +C= +C

= +C

147) Put x – α = t ⇒ dx = dt

⇒ dx =

= sin α + cos α
= sin α . ℓn |sin t| + t cos α + C
= sin α .ℓn|sin (x – α)| + (x – α) cos α + C
⇒ A = cos α & B = sin α.
148) Let 2x + 3 = t
2dx = dt

149)

arbitrary constant.

150)
Put