NATIONAL HR.
SEC SCHOOL – VARATTAMPATTI
FIRST MIDTERM TEST - 2019
XI- STANDARD
CHEMISTRY
Time: 1.15 Hrs MARK: 50
PART - I
Choose the best answers 10X1=10
1. An element X has the following isotopic composition 200X = 90 %, 199X = 8 % and
202
X = 2 %. The weighted average atomic mass of the element X is closest to
(a) 201 (b) 202 u (c) 199 u (d) 200 u
2. Carbon forms two oxides, namely carbon monoxide and carbon dioxide. The equivalent mass of which
element remains constant?
(a) Carbon (b) oxygen (c) both carbon and oxygen (d) neither carbon nor oxygen
3. When 6.3 g of sodium bicarbonate is added to 30 g of acetic acid solution, the residual solution is found to
weigh 33 g. The number of moles of carbon dioxide released in the reaction is
(a) 3 (b) 0.75 (c) 0.075 (d) 0.3
2- 2- 2- , 2-
4. The correct increasing order of the oxidation state of sulphur in the anions SO4 , SO3 , S2 O4 S2 O6 is
2- 2- 2- 2 2- 2- 2- 2-
(a) SO3 < SO4 < S2O4 < S2O6 (b) SO4 < S2O4 < S2O6 < SO3
2- 2- 2- 2- 2- 2- 2-
(c) S2O4 < SO3 < S2O6 < SO4 (d ) S2O6 < S2O4 < SO4 < SO3
5.
Which of the following contain same number of carbon atoms as in 6 g of carbon-12?
a)7.5 g ethane (b) 8 g methane (c) both (a) and (b) (d)none of these
6. The energy of light of wavelength 45 nm is
15 11 –18 –15
a) 6.67 × 10 J b) 6.67 × 10 J c) 4.42 × 10 J d) 4.42 × 10 J
7. splitting of spectral lines in an electric field is called
a) Zeeman effect b) Shielding effect c) Compton effect d) Stark effect
8. According to the Bohr Theory, which of the following transitions in the hydrogen atom will give rise to the least
energetic photon?
a) n = 6 to n = 1 b) n = 5 to n = 4 c) n = 5 to n = 3 d) n = 6 to n = 5
9. Two electrons occupying the same orbital are distinguished by
a) azimuthal quantum number b) spin quantum number c) magnetic quantum number d) orbital quantum
number
10. The electronic configuration of Eu (Atomic no. 63) Gd (Atomic no. 64) and Tb (Atomic no. 65) are
6 1 2 7 1 2 8 1 2 7 2 7 1 2 9 2
a) [Xe] 4f 5d 6s , [Xe] 4f 5d 6s and [Xe] 4f 5d 6s b) [Xe] 4f , 6s , [Xe] 4f 5d 6s and [Xe] 4f 6s
7 2 8 2 8 1 2 6 1 2 7 1 2 9 2
c) [Xe] 4f , 6s , [Xe] 4f 6s and [Xe] 4f 5d 6s d) [Xe] 4f 5d 6s , [Xe] 4f 5d 6s and [Xe] 4f 6s
PART II
ANSWER ANY FIVE. Q NO: 16 IS COMPULSARY 5X2=10
11. Define relative atomic mass.
12. What do you understand by the term oxidation number?
13. Distinguish between oxidation and reduction.
-23
14. Mass of one atom of an element is 6.645 x 10 g. How many moles of element are there in 0.320 kg?
15. Which quantum number reveals information about the shape, energy, orientation and size of orbitals?
2+ 3+
16. Give the electronic configuration of Mn and Cr
17. Describe the Aufbau principle
18. How many radial nodes for 2s, 4p, 5d and 4f orbitals exhibit? How many angular nodes?
PART-III
WRITE ANY FIVE. Q NO: 23 IS COMPULSARY 5X3=15
19. How many orbitals are possible for n =4?
2O. State and explain pauli's exclusion principle.
21. Explain briefly the time independent schrodinger wave equation?
22. For each of the following, give the sub level designation, the allowable m values and the number of
orbital’s
i) n = 4, l =2, ii) n =5, l = 3 iii) n=7, l=0
-3
23) The density of carbon dioxide is equal to 1.965 kgm at 273 K and 1 atm pressure. Calculate the molar
mass of CO2.
24. What is the difference between molecular mass and molar mass? Calculate the molecular mass and molar
mass for carbon monoxide.
25. What is the empirical formula of the following?
I) Fructose (C6H12O6) found in honey
Ii) Caffeine (C8H10N4O2) a substance found in tea and coffee.
25. What do you understand by the term mole?
PART-IV
WRITE ANY THREE 5X3=15
26. In a reaction x + y + z2 xyz2 identify the Limiting reagent if any, in the following reaction mixtures.
(a) 200 atoms of x + 200 atoms of y + 50 molecules of z
(b) 1mol of x + 1 mol of y+3 mol of z2
(c) 50 atoms of x + 25 atoms of y+50 molecules of z2
(d) 2.5 mol of x +5 mol of y+5 mol of z2
27. Calculate the empirical and molecular formula of a compound containing 76.6% carbon, 6.38 % hydrogen
and rest oxygen its vapour density is 47.
28. Balance the following equations by oxidation number method
I) K2Cr2O7 + KI + H2SO4 K2SO4 + Cr2(SO4)3 +I2+H2O
II) KMnO4 + Na2SO3 MnO2 + Na2SO4 + KOH
29. How fast must a 54g tennis ball travel in order to have a de Broglie wavelength that is equal to
that of a photon of green light 5400Å?
6
30. Calculate the uncertainty in position of an electron, if Δv = 0.1% and υ = 2.2 x10 ms-1