Section-1: Multi Correct

1. The following graph shows the variation in vapour pressure of a solution of

two liquids X and Y as a function of molar composition.

it can be deduced that

(A) pairs of liquids which give rise to this slope of curve evolve heat on
mixing
(B) the curve shows positive deviation from Raoult's law
(C) Y has higher boiling point than X
(D) the two liquids could be ethanol and cyclohexane

2. Among 0.1 M solution of urea and Na3 PO4 and aluminium sulphate
(A) the vapour pressure and freezing point are the highest for urea
(B) the vapour pressure and freezing point are the lowest for 𝑁𝑎3 𝑃𝑂4
(C) the elevation in boiling point is the highest for Al2 (SO4 )3
(D) the depression in freezing point is the highest for Al2 (SO4 )3
3. Consider the following solutions kept at the same temperature of 300 K
(I) 0.01 M aq. solution of K 4 [Fe(CN)6 ]
(II) 0.1 M aq. solution of CaCl2
(III) 0.2 M aq. solution of glucose
(IV) 0.1 M aq. solution of CH3 COOH(K a = 10−5 )
Assuming molarity = molality, select the correct statements of the
following:
(A) Correct order of freezing points : (I) > (IV) > (III) > (II)
(B) Correct order of boiling points is : (I) < (IV) < (III) < (II)
(C) Solution (III) and (IV) are isotonic
(D) V.P. of (II) is highest among all
1 1
4. The plots of vs. (where, 𝑋𝐴 and 𝑌𝐴 are the mole fraction of liquid 𝐴 in
𝑋𝐴 𝑌𝐴
liquid and vapour phase respectively) is linear with slope and intercepts
respectively:
P0A (P0A −P0B )
(A) and
P0B P0B
𝑃𝐴0 (𝑃𝐵0 −𝑃𝐴0 )
(B) 0 and
𝑃𝐵 𝑃𝐵0
P0B (P0A −P0B )
(C) and
P0A P0B
P0B (PB −P0A )
0
(D) and
P0A P0B

5. The diagram given below depicts the boiling point as the function of
composition of the mixture of CCl4 and SiCl4 . Which of the following
statements about the diagram is/are true?
 (A) The point 𝑎 represents the composition of solution and the point 𝑏 that
of the vapour in equilibrium
(B) The proportion of CCl4 in the solution is smaller than that in the vapour
in equilibrium
(C) 𝑏𝑐 represents the condensation of the vapour
(D) The point 𝑐 represents the composition of soution and the point 𝑏 that
of the vapour in equilibriums.

6. Consider the two solutions:

I: 0.5 M NaCl aqueous solution at 25∘ C;
NaCl is completely ionized.
II: 2.0MC6 H5 COOH in benzene at 25∘ C,
C6 H5 COOH dimerizes to the full extent.
Which of the following statements(s) is(are) correct?
(A) Both the solutions display equal osmotic pressure.
(B) Both have equal vapour pressure.
(C) Solution II is hypertonic.
(D) Solution II has greater depression in freezing point than solution I.

Section-2: Paragraph
Read the paragraph carefully and answer the following questions:
The vapour pressure of a solvent in a solution is lower than that of pure
solvent, at the same temperature. A higher temperature is needed to raise
the vapour pressure up to the atmospheric pressure, when boiling begins.
However, increase is small, like 0.1molkg −1 aqueous sucrose solution boils
at 100.05∘ C.
Sea water, an aqueous solution, which is rich in Na+ and Cl− ions, freezes
about 1∘ C lower than frozen water. At the freezing point of a pure solvent,
the rates at which two molecules stick together to form the solid and leave
it to return to liquid state are equal when solute is present. Fewer solvent
molecules are in contact with surface of solid. However, the rate at which
the solvent molecules leave the surface of solid remains unchanged. That is
why temperature is lowered to restore the equilibrium. The freezing point
depression in an ideal solution is proportional to molality of the solute.
 −1
7. An aqueous solution of 0.1 molkg concentration of sucrose should have
freezing point of (K f = 1.86)
(A) −0.2∘ C
(B) 0.2∘ C
(C) 2∘ C
(D) −2 ∘ C

8. When 250 mg of eugenol is added to 100 gm of camphor (𝐾𝑓 = 39.7), it

lowered the freezing point by 0.62∘ C. The molar mass of eugenol is
(A) 1.6 × 102 gm/mole
(B) 1.6 × 104 gm/mole
(C) 1.6 × 103 gm/mole
(D) 200gm/mole

A certain vessel 𝑋 has water and nitrogen gas at a total pressure of 2 atm
and 300 K . All the contents of vessel are transferred to another vessel Y
having half the capacity of the vessel X. The pressure of N2 in this vessel
was 3.8 atm at 300 K . The vessel Y is heated to 320 K and the total pressure
observed was 4.32 atm . Assume that the volume occupied by the gasses in
vessel is equal to the volume of the vessel. Calculate the following:

9. Pressure of H2 O(g) in X at 300 K

(A) 0.1
(B) 0.2
(C) 1.0
(D) 2.0

10. Pressure of N2 at 320 K.

(A) 4.0
(B) 4: 05
(C) 5.05
(D) 1.05
Figure (a) represents the distillation of mixture of liquid A and liquid B
which gives both of pure liquid A and B . While Fig. (b) represents the
azeotopic mixture of HNO3 and H2 O which distillation gives an azeotropic
mixture and either of pure liquid. We cannot separate both the pure liquid,
i.e., H2 O and HNO3 .
11. What is the result of distilling a mixture of 50%HNO3 and 50%H2 O ?
(A) Pure water and azeotropic mixture can be separated.
(B) Pure H2 O and pure HNO3 can be separated.
(C) Pure HNO3 and azeotropic mixture can be separated.
(D) None of these

12. Which of the following statements is/are correct?

i. HNO3 solution is not obeying the Raoult's law.
ii. More the difference in vapour pressure of pure compounds forming a
mixture, easier to separate them through distillation.
iii. In Fig. (a), 𝑇2 is less than 𝑇1 because the liquid of composition 𝑄 is richer
in more volatile component.
(A) (ii) and (iii)
(B) (ii)
(C) (i) and (ii)
(D) (i), (ii) and (iii)

Section-3 Matrix Match

13. Match the Column - I with Column - II:

Column-I Column-II

(A) 0.1MCa3 (PO4 )2 (p) Solution with highest boiling point

(B) 0.1MNaCl (q) Solution with van't Hoff factor greater than 1

(C) 0.1Mglucose (r) Solution with lowest osmotic pressure

(D) 0.1MCaCl2 (s) Solution with lowest freezing point

(t) Van't Hoff factors (1 + 𝛼)

14. 𝑝A = partial pressure of component A in liquid mixture, 𝑃A ∘ = vapour
pressure of A, 𝜒A = mole fraction of A in liquid mixture

Column I Column II

C2 H5 OH
a. p. Azeotropic mixture
+ H2 O

C2 H5 Br
b. q. Obeys Raoult's law
+ C2 H5 I

Non-ideal solution with

c. 𝑝A = 𝜒A 𝑃𝐴∘ r.
positive deviation

Non-ideal solution with

d. H2 O + H2 SO4 s.
negative deviation

t. Ideal solution

Section-4: Numerical

15. A mixture which contains 0.550 g camphor and 0.045 g of an organic solute
freezes at 158∘ C. The solute contains 93.46% of C and 6.54% of H by
weight. What is the molecular formula of the compound?
(Freezing point of camphor = 178.4∘ C and K𝑓 = 37.7∘ )

16. A 0.025 m solution of mono basic acid had a freezing point of −0.06∘ C.
Calculate pK a for the acid at the freezing point. K f for H2 O =
1.86 KMolality −1 . Assume molality equal to molarity.

17. Calculate the boiling point of a solution containing 0.60 g of benzoic acid in
50 g of CS2 (ℓ) assuming 90% association of the acid. The boiling point and
K b CS2 are 46.2∘ C and 2.44 KKgmol−1 respectively.
18. The K sp (25∘ C) of sparingly soluble salt XY2 ( s) is 3.56 × 10−5 ( mollit −1 )3
and at 30∘ C the vapour pressure of its saturated solution in water is
31.78 mm Hg. Calculate the enthalpy change of the reaction.

XY2 ( s) ⇌ X 2+ (aq) + 2Y − (aq)

Given: Vapour pressure of pure water = 31.82 mmHg

19. If boiling point of an aqueous solution is 100.1∘ C. What is its freezing

point? Given latent heat of fusion and vaporization of water are 80calg −1
and 540calg −1 respectively.

20. 100 ml aqueous solution of glucose with osmotic pressure 1.2 atm at 25∘ C
is mixed with 300 ml aqueous solution of urea at 2.4 atm at 25∘ C. Calculate
the osmotic pressure of mixture.
Answer Key:
1 2 3 4 5 6 7 8 9 10
B,D C,D A,B B A,B,C A, A A A B
D
11 12 13 14 15 16 17 18 19 20
A D A. P,Q,S A. P,R 𝐶12 𝐻10 2.5 46.33°𝐶 48.802 𝐽 −0.362°𝐶 1.86
B. Q,T B. Q,T /𝑚𝑜𝑙𝑒 atm
C. R C. Q,T
D. Q D. P,S