01-06-2025

1103CJA101021250025 JA

PHYSICS

SECTION-I

1) Three identical rods AB, CD and PQ are joined as shown. P and Q are mid points of AB and CD
respectively. Ends A, B, C and D are maintained at 0°C, 100°C, 30°C and 60°C respectively. The

direction of heat flow in PQ is

(A) from P to Q
(B) from Q to P
(C) heat does not flow in PQ
(D) data not sufficient

2) A rod CD of thermal resistance 5.0 K W–1 is joined at the middle of an identical rod AB as shown in
figure. The ends A, B and D are maintained at 100°C, 0°C and 25°C respectively. Find the heat

current in CD.

(A) 4.0 W
(B) 5.0 W
(C) 6.0 W
(D) 8.0 W

3) Two thin metallic spherical shells of radii r1 and r2 (r1 < r2) are placed with their centres
coinciding. A material of thermal conductivity K is filled in the space between the shells. The inner
shell is maintained at temperature θ1 and the outer shell at temperature θ2 (θ1 < θ2). Calculate the
rate at which heat flows radially through the material.
(A)

(B)

(C)

(D)

4) A rod of length L and uniform cross-sectional area has varying thermal conductivity which
changes linearly from 2K at end A to K at the other end B. The ends A and B of the rod are
maintained at constant temperature 100°C and 0°C, respectively. At steady state, the graph of
temperature :
T = T(x) where x = distance from end A will be

(A)

(B)

(C)

(D)

5) Two thin walled spheres of different materials, one with double the radius and one-fourth wall
thickness of the other, are filled with ice. If the time taken for complete melting of ice in the sphere
of larger radius is 25 minutes and that for smaller one is 16 minutes, the ratio of thermal
conductivities of the materials of larger sphere to the smaller sphere is :

(A) 4 : 5
(B) 25 : 1
(C) 1 : 25
(D) 8 : 25

6) On a winter day when the atmospheric temperature drops to – 10°C, ice forms on the surface of a
lake. Calculate the rate of increase of thickness of the ice when 10 cm of ice is already formed.
Assume that the temperature of the entire water reaches 0°C before the ice starts forming. Density
of water = 1000 kg/m3, latent heat of fusion of ice = 3.36 × 105 J kg–1 and thermal conductivity of ice
= 1.7 W/m–°C. Neglect the expansion of water on freezing.

(A) 4.5 × 10–7 m/s

(B) 5.0 × 10–7 m/s
(C) 5.5 × 10–7 m/s
(D) 6.0 × 10–7 m/s

7) Graphs give the temperature along an x axis that extends directly through a wall consisting of
three layers with different, nonzero and finite coefficient of thermal conductivities. The air
temperature on both sides of the wall are different and uniform. Out of the situations as shown by
the graphs, which is/are impossible ?

(A)

(B)

(C)

(D)

8) Four rods of same material with different radii r and length ℓ are used to connect two reservoirs
of heat at different temperatures. Which one will conduct most heat ?

(A) r = 2cm, ℓ = 0.5m

(B) r = 2cm, ℓ = 2m
(C) r =0.5cm, ℓ =0.5m
(D) r = 1 cm, ℓ = 1 m

9) A solid copper sphere of diameter 10mm, is cooled to a temperature of 150K and is then placed in
an enclosure at 290 K. Assuming that all interchange of heat is by radiation, calculate the initial rate
of rise of temperature of the sphere. The sphere may be treated as a black body ρcopper = 8.93 × 103
kg/ m3, s = 3.7 × 102 JKg–2K–1 ; σ = 5.7 × 10–8 Wm–2K–4
(A) 0.68 K/s
(B) 0.068 K/s
(C) 0.34 K/s
(D) 0.034 K/s

10) An object is being heated by a heater supplying 60 W heat. Temperature of surrounding is 20°C
and the temperature of object becomes constant at 50°C. Now the heater is switched off. What is the
rate at which the object will lose heat when its temperature has dropped to 30°C

(A) 20 W
(B) 30 W
(C) 40 W
(D) 60 W

11) Consider two long black concentric cylinders of radii Ri and R0 as shown. They are evacuated and
are radiating energy due to their own temperatures. The fraction of radiation emitted by outer

cylinder that falls on itself is_______.

(A)

(B)

(C)

(D)

12) A heated object (at time t = 0 and temperature T = T0) is taken out of the oven to cool and
placed on a table near an open window. Write an expression for its temperature as function of time
T, where TS is the surrounding temperature.

(A)
(B)
(C)
(D)

13) A black thin disc of radius 1 m is kept 0.75 m away from a point source of power 56.7 πW. If the
disc is highly conducting, what is its temperature in steady state ? surrounding is at 0 K.
(A) 100 K
(B) 141 K
(C) 70.5 K
(D) 282 K

14) Radius of two spheres of same material are 1 & 4 m respectively and their temperature are
respectively. Then ratio of emitted energy of spheres per sec. will be -

(A) 1 : 2
(B) 2 : 1
(C) 1 : 1
(D) 4 : 1

15) Total radiations incident on body = 400 J, 20% radiation reflected and 120 J absorbs. Then find
out % of transmittive power

(A) 10
(B) 15
(C) 25
(D) 50

16) The spectral emissive power Eλ for a body at temperature T1 is plotted against the wavelength
and area under the curve is found to be A. At a different temperature T2 the area is found to be 9A.

Then λ1/λ2 =

(A) 3
(B) 1/3
(C)
(D)

17) A body cools from 80°C to 60°C in 5 minutes. The temperature of the surrounding is 20°C. The
time it takes to cool from 60°C to 40°C is (in minutes):

(A) 500
(B) 25/3
(C) 450
(D) 420

18) A body cools in 7 minutes from 60°C to 40°C. The temperature of the surrounding is 10°C. The
temperature of the body after the next 7 minutes will be:

(A) 32°C
(B) 30°C
(C) 28°C
(D) 34°C

19) Four batteries of emf E1 = 4V, E2 = 8V, E3 = 12 V and E4 = 16 V and four identical capacitors
each of 1 µF and four identical resistance are connected in circuit as in figure. Batteries do not have

any internal resistances. At steady state potential difference

across C2 is :

(A) 1V
(B) 5V
(C) 4V
(D) 6V

20) The circuit is completed at t = 0, then total work done by batteries till the capacitor gets full

charged. [q = 64µC and C = 16µF]

(A) 1024 µJ
(B) 512 µJ
(C) 320 µJ
(D) 54 µJ

SECTION-II

1) In the given circuit initially the capacitor is uncharged. At t = 0 the key k is closed. The time
constant of circuit is n times of RC. Find the value of ‘n’.

2) A capacitor C1 (= C) is charged to a potential difference ε is connected to a charging circuit by

changing the switch S as shown. Assume the instant of switching as t = 0. Capacitor C2 is, initially
uncharged, then, the charge on C2(= C) is changing according to equation ; q2 = Q2(1 – e–t/δ). where,
δ is called time constant and Q2 is the steady state charge on C2. Let, Q2 = n2(Cε) and = δ = n1(RC).

Find .

3) The figure shows the face and interface temperature of a composite slab containing of four layers
of two materials having identical thickness. Under steady state condition, find the value of

temperature θ (in °C).

4) Emissivity e is a property of surface. Suppose for a surface, emissivity e varies with kelvin temp. T
as e = CT (C is constant). If energy emission rate at temperature, 800 K from the surface is 64 W,
what will be the energy emission rate (in watt) at 400 K ?

5) A spherical shell of radius R is filled with water. Temperature of atmosphere is (–θ)°C and then it
starts freezing from outer surface towards the centre of the shell. Assume shell to be highly

conducting. If time taken for whole mass of water at 0°C to freeze is find x. (Thermal
conductivity of ice is k and latent heat of fusion is L. Density of water is ρ. Neglect expansion during
fusion)

CHEMISTRY

SECTION-I
1) If 0.01 M solution of an electrolyte has a resistance of 40 ohms in a cell having a cell constant of
0.4cm–1 then its molar conductance in ohm–1 cm2 mol–1 will be :-

(A) 104
(B) 103
(C) 102
(D) 10

2) The same amount of current was passed for same time through molten Al2O3 and molten NaCl. If
1.8 gm of aluminium is liberated in one cell the amount of sodium liberated in the other is (Al → 27,
Na → 23)

(A) 4.6 gm
(B) 2.3 gm
(C) 8.0 gm
(D) 3.6 gm

3) Given ;
Among the following, the strongest reducing agent is :-

(A) Cr
(B) Mn2+
(C) Cr3+
(D) Cl–

4) The standard electrode potential and its temeprature coefficient for a cell are 2V
–4 –1
and –5 × 10 VK at 300 K respectively. The cell reaction is :-
Zn(s) + Cu2+ (aq) → Zn2+ (aq) + Cu(s)
The standard reaction enthalpy at 300 K in kJ mol–1 is,
[Use : R = 8JK–1 mol–1 and F = 96,000 Cmol–1]

(A) –412.8
(B) –384.0
(C) 206.4
(D) 192.0

5) for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm2 mol–1, respectively. If the conductivity
of 0.001 M HA is 5 × 10–5 S cm–1, degree of dissociation of HA is :

(A) 0.75
(B) 0.125
(C) 0.25
(D) 0.50
6) The Gibbs energy for the decomposition of Al2O3 at 500°C is as follows

Al2O3(s) —→ Al(s) + O2(g), ΔrG = +966 kJ mol–1

The potential difference needed for electrolytic reduction of Al2O3 at 500°C is at least :-

(A) 5.0 V
(B) 4.5 V
(C) 3.0 V
(D) 2.5 V

7) A current of 9.65 amp. passing for 16 minute 40 sec through a molten tin salt deposits 5.95 g of
tin. The oxidation state of the tin in the salt is : (at. wt of Sn = 119)

(A) +4
(B) +3
(C) +2
(D) +1

8) What is the standard reduction potential (E°) for Fe3⊕ → Fe? Given that :
Fe2⊕ (aq) + 2e⊝ → Fe(s) ;
Fe3⊕ (aq) + e⊝ → Fe2⊕(aq);

(A) +0.30 V
(B) +0.057 V
(C) –0.057 V
(D) –0.30 V

9) How long (approximate) should water be electrolysed by passing through 100 amperes current so
that the oxygen released can completely burn 27.6 g of diborane?
(Atomic weight of B = 10.8 u)

(A) 0.8 hours

(B) 3.2 hours
(C) 1.6 hours
(D) 6.4 hours

10) If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the
reaction
Zn(s) + Cu2⊕(aq) ⇌ Zn2⊕(aq) + Cu(s)
at 300 K is approximately.
(R = 8 JK–1 mol–1, F = 96000 C mol–1)

(A) e160
(B) e320
(C) e–160
(D) e–80
11) The reagent needed for converting is :

(A) H2 / Lindlar Cat.

(B) Cat. hydrogenation
(C) LiAlH4
(D) Li / NH3

12) CCl3 CH = CH2 P, Identify major product 'P' is :

(A)

(B)

(C)

(D)

13)
Reactions P, Q & R should be-

(A) All are acid catalyzed addition of water to alkene.

Acid catalyzed hydration of alkene, Hydroboration oxidation and oxymercuration-
(B)
Demercuration.
Oxymercuration-Demercuration, Hydroboration-oxidation and acid catalyzed hydration of
(C)
alkene.
Hydroboration-oxidation, oxymercuration-Demercuration and acid catalyzed Hydration of
(D)
alkene.

14) Match the chemical conversions in List-I with the appropritate reagents in List-II and select the
correct answer using the code given below this lists -

List-I List-II

(P) (1) (i) Hg(OAc)2 , H2O (ii) NaBH4

(Q) (2) HBr

(R) (3) HgSO4 + 1% H2SO4

(S) (4) (i) B2H6(THF) (ii) H2O2 /NaOH

(A) (P) - 2; (Q) - 3; (R) - 1; (S) - 4

(B) (P) - 3; (Q) - 2; (R) - 1; (S) - 4
(C) (P) - 2; (Q) - 3; (R) - 4; (S) - 1
(D) (P) - 3; (Q) - 2; (R) - 4; (S) - 1

15) Product

(A)

(B)

(C)

(D) Both (B) & (C) are correct

16) IUPAC name of the major product of the given reaction, HC ≡ C–CH = CH2

(A) 3-chloro but-1-yne

(B) 1-chloro buta-1, 2-diene
(C) 2-chloro buta-1, 2-diene
(D) 2-chloro buta-1, 3-diene

17) What is the final product, C, of the following reaction sequence ?

(A)

(B)

(C)

(D)

18)

In the following reaction, the major product is -

(A)

(B)

(C)

(D)

19) Product

(A)

(B)

(C)

(D)

20)
Arrange the above in the decreasing order of reactivity towards HBr :

(A) a > b > c

(B) b > a > c
(C) b > c > a
(D) a > c > b

SECTION-II

1) The number of optically active product obtained from the complete ozonolysis of given compound
is

2) For the cell reaction

2Ce4⊕ + Co —→ 2Ce3⊕ + Co2⊕
is 1.89 V. If is – 0.28 V, what is the value of ?

3) The reduction potential of hydrogen electrode when placed in a buffer solution is found to
be –0.413V. The pH of the buffer is :-

4) The number of isomeric tetraenes (NOT containing sp-hybridized carbon atoms) that can be
formed from the following reaction sequence is_______________.

5)
How many of the product is/are possible

(A) (B)

(C) (D)
(E) (F)

MATHEMATICS

SECTION-I

1) If the tangent to the curve, y = f(x) = x logex, (x > 0) at a point (c, f(c)) is parallel to the line -
segment joining the points (1, 0) and (e, e), then c is equal to :

(A)

(B)

(C)

(D)

2) Given :
h(x) = {x}
then in [0, 1], Lagranges Mean Value Theorem is NOT applicable to
where [x] and {x} denotes the greatest integer and fractional part function.

(A) f, g, h
(B) h, k
(C) f, g
(D) g, h, k

3) f : R R is defined by f(x) = then which of the following statements is TRUE ?

(A) f is one-one, but NOT onto

(B) f is onto, but NOT one-one
(C) f is BOTH one-one and onto
(D) f is NEITHER one-one NOR onto

4) Consider the function for x = [–2, 3], then

(A) f is discontinuous at x = 1 Rolle's theorem is not applicable in [–2, 3]

(B) Rolle's theorem is not applicable in [–2, 3]
(C) f is not derivable in (–2, 3) Rolle's theorem is not applicable
(D) Rolle's theorem is applicable as f satisfies all the conditions and c of Rolle's theorem is 1/2
5) Consider all rectangles lying in the region

and having one side on the x-axis. The area of the rectangle which has the maximum perimeter
among all such rectangles, is

(A)

(B)

(C)

(D)

6) Let f and g be twice differentiable functions on R such that

Then which of the following is NOT true ?

(A) g(–2) – f(–2) = 20

(B) If –1 < x < 2, then
(C)

(D) There exists such that

7) A helicopter is flying along the curve given by y – x3/2 = 7, . A soldier positioned at the point

wants to shoot down the helicopter when it is nearest to him. Then this nearest distance is :

(A)

(B)

(C)

(D)

8) The sum of the absolute minimum and the absolute maximum values of the function

in the interval [–1, 2] is :

(A)

(B)

(C) 5
(D)

9) Given the curve , then

the slope of normal drawn to the curve at (3, 1) is

(A)

(B)
the value of
(C) the slope of normal drawn to the curve at (3, 1) is 3.
(D) the equation of tangent at (3, 1) to given curve is 3y + x = 0.

10) The number of points on the curve y = 54x5 – 135x4 – 70x3 + 180x2 + 210x at which the normal
lines are parallel to x + 90y + 2 = 0 is :

(A) 2
(B) 3
(C) 4
(D) 0

11) The complete set of values of 'a' for which the function f(x) = sin x – cos x – ax + b decreases for
all real values of x, is

(A)
(B)
(C)
(D)

12) If the equation has a positive root then the equation

has a positive root, which is -

(A) Smaller than

(B) Greater than
(C) Equal to
(D) Greater than or equal to

13) If (x – a)2m (x – b)2n+1, where m and n are positive integers and a > b, is the derivative of a
function f, then -

(A) x = a gives neither a maximum, nor a minimum

(B) x = a gives a maximum
(C) x = b gives neither a maximum nor a minimum
(D) None of these
14) Let where

f(x) is bounded and it takes both of it's bounds and the range of f(x) contains exactly one
(A)
integral point.
f(x) is bounded and it takes both of it's bounds and the range of f(x) contains more than one
(B)
integral point.
(C) f(x) is bounded but minimum and maximum does not exists.
(D) f(x) is not bounded as the upper bound does not exist.

15) The least value of for which for all x > 0, is -

(A)

(B)

(C)

(D)

16) If curve y = 1 – ax2 and y = x2 intersect orthogonally then the value of a is -

(A)

(B)

(C) 2
(D) 3

17) Let S be a sphere with radius r. If we approximate the change of volume of S by

0 0

where A is surface area, when radius is changed from r to (r + h), then the
absolute value of error in our approximation is

(A) h3
(B)
(C)

(D)

18) Water is being filled at the rate of 1 cm3/sec in a right circular conical vessel (vertex downwards)
of height 35 cm and diameter 14 cm. When the height of the water level is 10 cm, the rate (in
cm2/sec) at which the wet conical surface area of the vessel increases is
(A) 5

(B)

(C)

(D)

19) Let f : [0, 1] → R (Set of all real numbers) be a function suppose the function f is twice
differentiable f(0) = f(1) = 0 & satisfies f"(x) - 2f'(x) + f(x) ≽ ex x ∈ [0, 1]. Which of the following is
true for 0 < x < 1 ?

(A) 0 < f(x) <

(B) < f(x) <

(C)
- < f(x) < 1
(D) - < f(x) < 0

20) Let and be two functions defined by f(x) = loge(x2 + 1) – e–x + 1 and

Then, for which of the following range of the inequality

holds?

(A) (2, 3)
(B) (–2, –1)
(C) (1, 2)
(D) (–1, 1)

SECTION-II

1) Given two points A(–2, 0) & B(0, 4) and a line y = x. If the co-ordinates of a point M on this line is
(p, q) so that the perimeter of the is least, then the value of (5p + 3q) is

2) A cylindrical container is to be made from certain solid material with the following constraints. It
has a fixed inner volume of V mm3, has a 2 mm thick solid wall and is open at the top. The bottom of
the container is a solid circular disc of thickness 2 mm and is of radius equal to the outer radius of
the container. If the volume of the material used to make the container is minimum when the inner

radius of the container is 10 mm, then the value of is

3) There is a point (p, q) on the graph of f(x) = x2 and a point (r, s) on the graph of g(x) = where
p > 0 and r > 0. If the line through (p, q) and (r, s) is also tangent to both the curves at these points
respectively then the value of (p + q) is

4) Find the number of integral values of 'a' for which the function,

is strictly increasing at every point of its domain.

5) Water is dripping out from a conical funnel of semi vertical angle at the uniform rate of 2
3
cm /sec through a tiny hole at the vertex at the bottom. When the slant height of the water is 4 cm,

then the rate of decrease of the slant height of the water is given by then the value of
'k' is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A D B D B C A B A D C A C D D A C B B

SECTION-II

Q. 21 22 23 24 25
A. 2.75 2.00 5.00 2.00 6.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A A A B D C C B A D B C A D D A D B B

SECTION-II

Q. 46 47 48 49 50
A. 0.00 2.00 7.00 2.00 3.00

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A C D C B C A B C D A A A C B D C D A

SECTION-II

Q. 71 72 73 74 75
A. 0.00 4.00 20.00 8.00 4.00
 SOLUTIONS

PHYSICS

1) If PQ is not there then

TP = 50°C; TQ = 45°C
Now if PQ is connected we can say correct will from P to Q

2) The thermal resistance of AC is equal to that of CB and is equal to 2.5 K W–1. Suppose, the
temperature at C is θ. The heat currents through AC, CB and CD are

We also have

or,
or, 225°C = 5θ
or, θ = 45°C

Thus, = 4.0 W.

3) Let us draw two spherical shells of radii x and x + dx concentric

with the given system. Let the temperatures at these shells be θ and θ + dθ respectively. The
amount of heat flowing radially inward through the material between x and x + dx is

Thus,

or,

or,
4) k(x) =

Let

dT =

dT =

T(x) – 100 =

T(x) – 100 =

5)

Now

6) Lf = 3.36 × 105 J/kg Kice = 1.7 W/m°C

...(1)
dQ = m f = ρA dx Lf ...(2)
2
 5 × 10–7 m/s

7) Slope =
(3) is not possible as temperature across B is increasing.

8) ∝

9)

Putting value

= 0.068 k/s

10)

60 = K(15) ...(1)
Now at 30° C

...(2)
From (1) and (2)

= 20 W
11) At equilibrium
Radiation emitted by small cylinder

Radiation emitted by outer cylinder

Fraction of radiation emitted by outer cylinder fall on itself

12)

13)

14)
15) Q = Qt + Qr + Qa ⇒ 400 = 80 + 120 + Qt ⇒ Qt = 200.
So % of transmittive power is 50%

16)
E1 = A ⇒ σ eA'T14 = A ....(i)
E2 = 9A ⇒ σeA'T24 = 9A ......(ii)

– from (i) & (ii)

T1λ1 = T2λ2

17) Ans. (A)

Sol. Rate of cooling a Temperature difference

....(i)

....(ii)

⇒ t = 500 seconds

18) Ans. (C)

Sol. using average rate of Newton’s law of cooling

Given … (i)

& … (ii)
From (i) & (ii)
T = 28°C

19)

In steady state, current through branch of capacitor is zero,

Current will flow as shown in the diagram.

For potential difference across C2

Let, F be the reference position,
So, VF = 0

Potential difference across C2, = 5V

20) Equivalent E.M.F.

Final charge stored on capacitor = 16 × 8 µC = 128 µF
Charge flower through battery = (128 – 64)µC = 64µC
Work done by battery w = 8 × 64 = 512 µJ

21) Equivalent resistance across capacitor (after shorting the battery) =

Voltage across capacitor in steady state =

22) After switching

KVL :

IR +

IR + q

Q2 = 2εCeq = 2ε = Cε, n2 = 1

δ = RCeq = R = , n1 =

23) ...(1)

...(2)
1=2
2θ = 10
θ = 5°C

24) Using steafan's law

Energy radiate = σeT4
ΔET = σCT5 e = CT
 25)

CHEMISTRY

26) R = ρ
40 = r × (0.4)

k= = = 10–2

= 10–2 × = 103

27)

Al Na

28)

Smaller the value of reduction potential data of a substance greater is its tendency to get
oxidised.
∴ Substance is a better reducing agent.

29)

Eº = 2V, = – 5 × 10–4 VK–1, ΔSº =

or, ΔSº = – 2 × 96500 × 5 × 10–4
= – 96.5 JK–1.
ΔGº = – = – 2 × 96500 × 2 = –386000 J.
or – 386000 = ΔHº – 300 (–96.5)
⇒ ΔHº = – 414950 J = Ans.

30)
= 425.9 + 100.5 – 126.4 = 400 S cm2mol–1

31)

ΔG = +966 × 1000 = 96000 J mol–1

ΔG = – nFE

966000 = –4 × 96500 × E

E = –2.5 volt So, minimum 2.5 volt battery will be required.

32)

W=

n=2

33)

Fe2⊕ (aq)+ 2e⊖ → Fe (s)

Fe3⊕ (aq) + e⊖ → Fe2⊕ (aq)
Fe3⊕ (aq) + 3e⊖ → Fe (s)

34)

B2H6 (g) + 3O2 —→ B2O3 (s)+ 3H2O

Moles of B2H6 =

∴ Moles of O2 required = 3 × 1 = 3

Equivalent of O2 =
 ⇒ t = 11580 sec (nf of O2 in this reaction is 4)
t = 3.2 hours.

35)

ΔG° = –RT ln K
–2 × 96000 × 2 = –8 × 300 ln K
ln K = 160 K = e160

36)

37)

38)

39)

Conceptual

40)
Both (B) & (C) are product correct answer (C)
41) HC ≡ C–CH = CH2

43)

44)
Mechanism

(1)

(2)
Reaction I is dehydration of alcohol and reaction (2) is non-classical carbocation addition of
Br2 on alkene.
Option A - Incorrect
Option B - Correct
Option C - Incorrect
Option D - Incorrect

45)
Stability of carbocation Q > P > R
Rate of reactivity Q > P > R
Option A incorrect
Option B correct
Option C incorrect
Option D incorrect

46)

None of them is optically active.

47)

48) ey + —→
 49)

50)

3 (A/B/C) Products are possible

MATHEMATICS

51)

f(x) = x loge x

f'(x) = 1 + loge x
52)

f is not differentiable at x =
g is not continuous in [0, 1] at x = 0
h is not continuous in [0, 1] at x = 1
k(x) =

k'(x) =
k'(x) is defined for all x in (0, 1)
∴ k(x) is continuous and differentiable on (0, 1)

53)

f(x) is odd, continuous function

for x ≥ 0, f'(x) = 2x - sin x - x cos x

= x (1 - cos x) + (x - sin x) ≥ 0
for x < 0, f(x) = -2x + sin x + x cos x
= x (cos x - 1) - (x - sin x) > 0 as x < 0
strictly increases in
⇒ f(x) is one-one

So f(x) is onto

54)

f(–2) = f(3) = 0
f(x) is continuous in [-2, 3] and derivable in
(-2, 3) so Rolle's theorem is applicable.
so ∃ c ∈ (-2, 3) such that f'(c) = 0

55)

Perimeter = 2 (2α + 2cos 2α)

P = 4 (α + cos 2α)
for maximum
Area = (2α) (2 cos 2α)

56)

f(2) = 3g(2) = 12 .....(3)

By integrating (1)

At x = 1,
f'(1) = g'(1) + 3 + C
⇒9=4+3+C⇒C=3
∴ f'(x) = g'(x) + 3x2 + 3
Again by integrating,

At x = 2
f(2) = g(2) + 8 + 3(2) + D
⇒ 12 = 4 + 8 + 6 + D ⇒ D = –6
So, f(x) = g(x) + x3 + 3x - 6
⇒ f(x) – g(x) + x3 + 3x - 6
At x = –2,
⇒ g(–2) – f(–2) = 20 (option (1) is true)
Now, for –1 < x < 2
h(x) = f(x) – g(x) = x3 + 3x - 6
⇒ h'(x) = 3x2 + 3
⇒ h(x)↑
So, h(-1) < h(x) < h(2)
⇒ –10 < h(x) < 8
⇒|h(x)| < 10 (option (2) is NOT true)
Now, h'(x) = f'(x) - g'(x) = 3x2 + 3
If |h'(x)| < 6 ⇒|3x2 + 3| < 6
⇒ 3x2 + 3 < 6
⇒ x2 < 1
⇒ –1 < x < 1 (option (3) is true)
If x ∈ (-1, 1) |f'(x) - g'(x) | < 6
option (3) is true and now to solve
f(x) - g(x) = 0
⇒ x3 + 3x - 6 = 0
h(x) = x3 + 3x - 6
here, h(1) = -ve and h = + ve
Now, h'(x) = f'(x) - g'(x) = 3x2 + 3
If |h'(x)| < 6 ⇒|3x2 + 3| < 6
⇒3x2 + 3 < 6
⇒ x2 < 1
⇒ –1 < x < 1 (option (3) is true)
If x ∈ (-1, 1) |f' (x) - g'(x) | < 6
option (3) is true and now to solve
f(x) - g(x) = 0
⇒ x3 + 3x - 6 = 0
h(x) = x3 + 3x – 6

here, h(1) = -ve and h = +ve

So there exists such that

f(x0) = g (x0)
(option (4) is true)

57)

3x2 = 1 - 2x
3x2 + 2x - 1 = 0
3x2 + 3x - x - 1 = 0
(x + 1) (3x - 1) = 0
∴ x = –1 (rejected)
58)

Correct options is (A)

f'(x) = when
f'(x) = 2x - 4 = 0 ⇒ x = 2
f'(x) = 2( x - 2) ⇒f'(x) is always↓
f(2) = 2
f(–1) = 3

f'(x) when
f'(x) = –2x + 2
f'(x) = –2 (x – 1)
f'(x) = 0 when x = 1
f(1) = 3

absolute minimum value =

absolute maximum value = 3

Sum =

59)

Ans (B, C)

Since given equation is homogeneous equation

60)

Normal of line is parallel to line x + 90y + 2 = 0

mN =

Now,

(4) normals

61)

f(x) = sin x - cos x - ax + b

f'(x) = cos x + sin x

62)

f(x) = anxn + an-1xn-1 + ....a1x

one root is ∝ and other root is O
∴ f'(x) = nanxn-1 + n-1an-2 + .........a1 = 0
and f(0) = 0, f(∝) = 0
∴ f(0) = f(∝) = 0
According to Rolle's theorem, root of f'(x) will have root between O and ∝
∴ root of f'(x) is smaller than ∝.

63)

Given, f'(x) = (x - a)2m(x - b)2n + 1

∴ For maxima or minima
f'(x) = 0

Now, f'(a – h) =

and f' (a+h) =

Thus, f'(x) does not change sign as x passes through 'a', so x is not a point of maximum or
minimum

64)
tan x = t

We know that

x=0
f(0) = 0

f(x) is bounded and f(0) = 0 is only integer.

65)
(where α > 0 obviously)

66)

y = 1 - ax2

y = x2

two curves intersect orthogonally if

m1m2 = –1
–2ax × 2x = –1
4ax2 = 1 ----------(1)
from equations of curve
1 – ax2 = x2
From (1) and (2)

67) Volume of sphere = original volume =

=
New volume = S + ΔS

Change in volume = (S + ΔS) - original volume

68)

From figure

Let wet conical surface area = S

When h = 10 then r = 2

69)

......(1)

∴ g(x) is concave
∴ f(0) = f(1) = 0
∴ from (1)
g(0) and g(1) = 0 and g is concave

∴ g(x) is -ve
∴ g(x) = e–x f(x)
↓ ↓ ↓
-ve always +ve has to be -ve
∴ f(x) is -ve

70)

f(x) = loge (x2 + 1) – e–x + 1

⇒ f is strictly increasing

⇒ g is decreasing

Now
71)
To minimize the perimeter.
AM + MB is to be minimized
i.e. A'M+ MB is to be minimized
[where A' is image of A in y = x]
Obviously A'M + MB are minimized
when A, M and B are collinear
i.e. M coincide with origin
∴ M = (0, 0)

72)
Vm = Volume of material used is minimum
when r = 10 mm,
V/250 ⊓ = ?
Here V is constant but r is variable and h is variable such that
V = ⊓r2h .....(1)
Volume of material used is

Now,
73)

Equation at A and B, we get

Now

74)

.....(1)
Case-I :

case-II: if a + 1 > 0
75)
If is represents the surface area, then

Therefore,

when,