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VLE Data Consistency Checks Examples

The document presents three examples of vapor-liquid equilibrium (VLE) data for different chemical systems and checks their thermodynamic consistency using the Redlich-Kister method. Examples 1 and 2 show that the VLE data are thermodynamically consistent, while Example 3 indicates that the data is not consistent. Each example includes specific data points and Antoine constants for the substances involved.

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13 views6 pages

VLE Data Consistency Checks Examples

The document presents three examples of vapor-liquid equilibrium (VLE) data for different chemical systems and checks their thermodynamic consistency using the Redlich-Kister method. Examples 1 and 2 show that the VLE data are thermodynamically consistent, while Example 3 indicates that the data is not consistent. Each example includes specific data points and Antoine constants for the substances involved.

Uploaded by

patelrudra08472
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd

Example-1

• VLE data for the system Acetone(1) / dichloroethylene(2) at


are given below: Do consistency check using Redlich-Kister
method.

x1 0.023 0.053 0.357 0.516 0.883 0.979

γ1 0.608 0.711 0.854 0.917 0.987 1.0

γ2 0.993 0.974 0.934 0.891 0.781 0.694


Example-1,Answer

The VLE data are thermodynamically


consistent.
Example-2
• VLE data for the system 1-propanol (1) / chlorobenzene (2) at
950C are as follows: Do consistency check using Redlich-Kister
method.
P/Torr 350 446 518 574.50 609 632.50 665 681.50 691.50

X1 0.055 0.129 0.212 0.313 0.430 0.520 0.638 0.749 0.872

Y1 0.350 0.511 0.599 0.650 0.697 0.726 0.759 0.813 0.883

• The Antoine constants of 1-propanol (1) / chlorobenzene (2)


are given by:
A B C

1-propanol(1) 8.37895 1788.020 227.438

chlorobenzene(2) 7.17294 1549.200 229.260


Example-2,Answer

The VLE data are thermodynamically


consistent.
Example-3
• VLE data for the system Acetone(1) / carbon tetrachloride(2)
at 450 Torr. Do consistency check using Redlich-Kister method.
T(oC) 55.29 49.50 46.26 44.06 43.05 42.42 41.92 41.54 41.53 41.46

x1 0.049 0.163 0.297 0.447 0.565 0.653 0.741 0.896 0.926 0.945

y1 0.189 0.393 0.515 0.610 0.677 0.728 0.784 0.902 0.927 0.945

• The Antoine constants of 1-propanol (1) / chlorobenzene (2)


are given by:
A B C

Acetone(1) 7.11714 1210.595 229.664

carbon tetrachloride(2) 6.84083 1117.91 220.576


Example-3,Answer
• Not consistent data

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