5.
STOICHIOMETRY
5.1 (C)
11 .2
Normallty of H O =- N
. ' ' 5.6 ed 2" 100 = 200 rneq =0.2 gram eq
m1III equlvalenls Ba(MnO,), reacted ~ milli equivalents of H,O, react =
Moles of Ba(MnO,) ::> ~; = 0.02 ·. [Link] Ba(MnO,), = 0.02" 375.
2
375 x0.02
% purity of Ba(MnO,), = • 100 = 50%
15
5.2 (C)
15 1000v 3 1000v
60 x100 , +50"100 2
:-x-
10 1000
V1 + V2 60 100
1 1 1
or - V1 + - V2 = - (V1 ; V2 ) or
4 20 6
6V -4V 10V2 -3V2 2V1 7V2 ':!J.. : 7/5
1
-- - -1 = or 24 = 60
or
V2
24 60
5.3 (B)
Mass of water= 105 x 1 = 105 g
let wt. of NH3 is X
X
given x .,. > 100 = 30
105
10x = 3x + 31 5
7x = 315
X: 45
Total mass= 45 + 105 = 150 g
150 1500
Volume of solu tion = mass of solution I density of solution =
0 _9 = 9 = 166.67 ml
5.4 (BJ
SAs,S , 28KMnO + H· - 10H AsO + 28Mn 2 • • SO 2-
J ' J ' '
meq of As2S, = meq. of KMnO,
X
246- y 1000 X 28 : 5Q 1( 0.1 X 5 X = 0.22 g
.,
5.5 (A)
Equlvalenr of K,Cr,01 = equivalent of N 2H4
also equlvalent of KMnO 4 =oquivelent of N,H,
So. eq.,lvalent of K,Cr, O 1 = equivalent of KMnO,
0.1 • 6 • v, = 0 .3 • 5 • v,
50 V, • 2/5 V,
5.6 (0) 5.7 (0)
5.8 (B)
1000
m~. of acid's in 50 ml = m-eq. of Na,co , 25 • 2 + 50 • 4 + 2 • 2 •, = ~ • 25 • I
x " 62.5 ml
5.9 (0)
3 NaOH • FeCI, - > Fe(OH), • 3N8Ct
mili eq, of NaOH = mili eq. of Fe(OH ),
!'\n , rnr FH(OH), mo • N =
W
E • 1000 ( E,-<,,..., •
molwt.)
3
1A25 • 10 • 3
N= = 0.399 = 0.4 N
107
5.10 (C)
eq . of Acid = eq. or base
0.4 0.5
n• -96 • -40 =>
: . At. W1 of A = 96 - 3 = 93
5.11 (D)
2, .5 ·2 5
Na, S 20 , + KBrO, - + Br+ Na, S 4 0 1
v.f = 1 v.f = 6
by m.e. of Na, s,o , = m.e. or KBrO,
molarity or Na, S,O, = 0. 1 M
5.12 (CJ
Mill eq. of FeSO, · 7H 2O in 25 ml= Mili eq. or KMnO, used= 2 Mili eq .
Mill eq. or Feso, · tH 2o in , ooo ml = so Mm t14 .
80 1
mass of FeSO, 7H 20 In solution = - "278" 1000 = 22.24 gm
1
22.24
% of FeSO 4 · 7H 2O = ~ x =
100 = 88.96 89%
5.13 (B)
Let normality of HCI Is N 1 and H 2SO, is N2.
Mill eq. of HCI + Mili eq. of H 2 S0, = Mili eq. of NaOH
25 X N1 + 25 X N2 = 10 X 1 ..(1)
N1 + N2 = 0.4 ...(1)
BY POAC
Moles of c1- = moles of AgCI
20 xN1 0.1435
1000
=- - =10-3
143.5
N,=0.05N
N2 = 0.35 N
5.14 IAJ
KIO, • SKI --- + 31<,O + 31,
mole o.o 1 0.04
LR .
J 0 . 12 w,, = ~ . 25-4 = 6.09 6 g
3 5
'\ =s•n,o e s•0.04 =-5 - =>
5.15 (AJ
meq. or NH, • 10
m.m ole ofN H, = 10
m ,mo le of (NH , ),SO . = 5
5
wt. Of(NH, ), SO, : lOOO • 132 = 0.66
gm
0.6 6
% ol (NH,), SO, = 0. 7 • 100 = 9"4.2
8%
5. 145 (A)
KOH + Na2CO,
a Mill eq . b.M lli eq.
b 1
a+ - = 15 • -20
2
...(I) (In presence of phenolphl hale in)
2a + b = 1.5
~ = 1.2 5 ...(II) (in pre sen ce of Me thy1 ora nge )
a + b = 25 •
2
by solv ing (I) & (ii) a = 0.2 5 Mill eq.
0.2 5
gm
ma ss of KO H = 1000 • 56 = 0.0 14
S.17 (0)
of Na, s ,o, reacteo wilh 1,.
Moles of pur e CuSO, " 0.12 = moles
Mol es of Na, s,o, = 120 • 1O"' • M
= 12 o.
5.18 (CJ
n.
S 1 : It Is a disp rop orti ona tion rea ctio
mo l wt.
s, : Ir Is 6
rea cta nt pro d uct sho uld be kno wn.
S3 • For calc ula tion of val ency fac tor
(t:) "lo (WI WJ osc ,v,' 5► 40 -10 00
5.51 4
144
.. 36;-;
--~ ;;:;--::
m)-; " 100 = 40
144,--
% of car bon = -:- . m 5(1 0-
On solving m =4
5.52 2 ppm .
M,V, = M,V,
1
50 • M I = -50 •0 .1
1
M, (HC01 ·J= _ 3
., ._ n __ ____ __ 25 10
t
mmolos of HCO,- c ,$.,ol • SO = iii
1 ,
mmolos of ca•· = -
,
1000
mmotu:,, uf CaCO.1 •
1 '
0CX>
weight ol CnCO• =
,
- • 1o·• • 100 w 1Oa<
10()()
10
... 1O' C 2 Pl>"'•
hardnoss c (wolgl,t ol C11CO, / weight ol water I• 10' • ,o" N
5 f>3 Balnnce chemical Aquation, ere :
Ca,(PO, ), • 8Mg -♦ Ca.P, • 8MgO
Ca, P, • 6H,O - - • 3Cl(OH), ♦ 2PH,
21'H, • 401 --- P 1 0 1 + 3H,0
MgO • P,O, - + Mg(PO,),
moles ol magnesium used • 0.8 moles
molos or MgO lonnod = 0.8 moles
moles ot Ca, P, formed 0.1 moles
moles ol PH, formed = 0.2 moles
moles ol P 1O, lonned = 0. t mole (limltlng reagent)
moles ot Mg(PO, I, = 0.1 moles
mass ol Mg(PO ,), =18.2 gram
Ans. 18 gl'lm
5.54 99%
Rodox changes ore :
Fe - Fe·• + 2e- ~n H 2S0,)
Fe·2 - , Fe· 3 + e- (with K,Cr2O7)
60 •Cr, •5 - . 2cr· 3
[Link] . or Fe·•• In 20 ml = [Link] . of K2 Cr2O7 = 30 • 1 = 1
30
1x1 00
[Link]. or Fe·• in 100 ml = =5
20
meq ~
[Link] of Fe· 2 = 7t-:- = 1 = 5 = [Link] of Fe
Mass of pure Fe in wire = 5 • 1Cr' • 56 = 0.28 g
0.28
% ol Fe In wire= _ • 100 = 99%
0 2828
5_55 6
4 .44 mg CaCl, is equivalent 10 4 mg CaCO,
1.9 mg MgCI, Is equivalent to 2 mg c aco,
Total wt of Caco, = 6 mg
6 • 10- 3
Hardness in ppm = • HJ• = 6 ppm
103
5.56 12
40 g. 0 • 60 g metal
8 g, 0 • 12 g metal (E)
5.S7 20
PbO, + 4KI - Pb1 2 + 1, + 21<,0
NzH.: • 2J 1 - Nl + 4HI
1 12
~
motes of N 2 lilJ.cr4led - .. s IC 1Q-.l mnlf!I
22.4
1
so mole of 12 reacted= 5 • 1Cr 2 • 2 = 10- mole
mole of PbO, reacted = 1o-• mole
PbO, • 2H, O - Pb(OH),
Pb{OH), + 2Na0H ---+ Na2 (Pb(OH)J or Na2Pb0 2
mole ol NaOH required = 10-1 • 2
2
1 V = _, = 2000 ml Ana.
V .. - JI 10 3 = 2. 10- 1 10
10
5.N ll •2, y • 1
If 11.4 ls molar mass of (CH, ), AICI ,
0.643 •
m(CH,) = 11.4 • 16 = 0 .2,2.
0.643y
and m(AgCI) = 11.4 • 143.5 = 0.996.
ah
d ividing : yx = 2, Also 11.4 = 15• • 27 + 3S.5y = 1Sx + 27 + 2 s 32.75x + 27.
0 .643 • , 16 y. 1 .
222 ll • 1.98 • 2. ~
32.75x • 27 = 0· · :::>
5.59 4
29.2% (wlw) HCI has density= 1.25 g/ml
Now, mole ol HCI required in 0.4 M HCI
= 0.4 • 0.5 mOffl = 0.2 mole
,1 v mol or orglnal HCI solution Is taken
lhen volume of solution = 1.25 v
moo& of Hr.I = (1.25 v • 0.292)
1.25V X 0.292
moie of HCI = _:..::...:..._ :.:.::..:..=. = 0.2
36.5
36.S x 0.2 I
so, V = _29 " 1 _25 mo = 20 ml
0
V/5 = 4.