17/03/2025 Code-A

Corporate Office : AESL, 3rd Floor, Incuspaze Campus-2, Plot No. 13, Sector-18,
Udyog Vihar, Gurugram, Haryana - 122018, Ph.011-47623456

MM : 600 Practice Test for AIATS-10 Time : 180 Min.

Chemistry

1. 2 moles and 3 moles of liquids, A (P

o
= 120 torr) and B 6. If O2 (g) is bubbled through water at 293 K. Calculate the
A

(P = 80 torr) respectively are mixed to form an ideal

o millimoles of O2(g) which would dissolve in 10 mol of
B

solution. The mole fraction of B in vapour phase will be water at oxygen gas pressure of 0.5 atm (KH(O2) at 293 K
is 3.5 × 104 atm).
(1)
2

(1) 0.143
(2) 1

2
(2) 0.234
(3) (3) 1.2
1

(4) 14.3
(4)
3

7. The gas used in tanks by scuba divers for breathing

2. 0.1 molal aqueous solution of weak base (BOH) is 10% contains
ionised. If Kb for water is 0.52 K kg mol–1, the elevation in
(1) 78% N2, 21% O2 and 1% He
boiling point of the solution is
(2) 11.7% He, 58% N2 and 30.3% O2
(1) 0.08 K
(2) 0.057 K (3) 32.1% O2 and 67.1% He

(3) 0.047 K (4) 11.7% He, 56.2% N2 and 32.1% O2

(4) 0.104 K 8. If elevation in boiling point for aqueous Na2SO4 having α
3. Which of the following is independent of temperature? = 40% is ΔTb then its depression in freezing point would
be
(1) Molality
Kb

(2) Molarity (1) ΔTb × Kf

(3) Normality 1.8×Kb

(2) ΔTb × Kf
(4) Volume percentage
ΔTb × Kf
4. 1.5 mole of n-hexane is mixed with 0.5 mole of n-pentane (3) 1.8×Kb

to form an ideal solution at 25°C. If the vapour pressure of

n-hexane and n-pentane at 25°C are 150 mm Hg and (4)
ΔTb × Kf

200 mm of Hg respectively then the vapour pressure of Kb

the resulting solution in mm of Hg will be

9. For an aqueous solution of K4[Fe(CN)6] (strong
(1) 215.5 electrolyte) the van't Hoff factor (i) will be
(2) 250 (1) 4
(3) 162.5 (2) 1
(4) 175 (3) 3
5. 5% (w/v) solution of urea is isotonic with 2% (w/v) solution (4) 5
of a non-electrolyte substance. The molar mass of the
substance is 10. A solution has 2 : 3 mole ratio of hexane and benzene. If
vapour pressure of hexane and benzene at 25°C are 360
(1) 180 g/mol mm and 300 mm of Hg respectively then the mole fraction
(2) 24 g/mol of hexane in the vapour phase would be

(3) 120 g/mol (1) 0.44

(4) 30 g/mol (2) 0.55

(3) 0.35
(4) 0.72
11. Mass of a non-volatile solute (molar mass = 45 g mol–1) 17. If molality of a dilute solution is doubled then the value of
that should be dissolved in 90 g water to reduce its molal elevation constant (Kb) becomes
vapour pressure to 75% is
(1) Doubled
(1) 75 g
(2) Halved
(2) 45 g
(3) Tripled
(3) 25 g
(4) Unchanged
(4) 15 g
18. Incorrect thermodynamic property for ideal solution is
12. 0.3 molal aqueous solution of a salt AX2 is 40% ionized.
(1) Δmix H = 0
If Kb for water is 0.52 K kg mol–1 then the boiling point of
(2) Δmix G < 0
the solution will be
(1) 100.28°C (3) Δmix S = 0

(2) 101.42°C (4) Δmix V = 0

(3) 100.61°C 19. Select the incorrect statement regarding ideal solution of
(4) 101.81°C components A and B
Intermolecular attractive force between A – A and B –
13. The molecular weight of benzoic acid in benzene is (1)
B are equal to those between A – B
determined by depression in the freezing point method
corresponds to (2) Δmix H = 0 at constant T and P
(1) Tetramerisation of benzoic acid (3) Δmix V = 0 at constant T and P
(2) Dimerisation of benzoic acid
(4) Δmix S = 0 at constant T and P
(3) Trimerisation of benzoic acid
20. 100 ml of 2 M H2SO4 is diluted by water so that the final
(4) Ionisation of benzoic acid
molarity becomes 0.4 M. The volume of water added to
14. If the mole fraction of acetone in ethyl alcohol is 0.2 then the initial solution is
the molality of acetone in the solution is (1) 500 mL
(1) 5.9 m (2) 350 mL
(2) 5.4 m (3) 550 mL
(3) 7.8 m (4) 400 mL
(4) 2.7 m
21. If the mass percentage of urea in an aqueous solution is
15. Given below are two statements, one is assertion (A) 20% then molality of the solution will be
other is reason (R). (1) 5.25 m
Assertion (A) : The freezing point of 0.1 m glucose
solution is higher than that of 0.1 m NaCl solution. (2) 2.35 m
Reason (R) : Depression in freezing point is inversly
(3) 4.17 m
proportional to the number of moles of non-volatile solute
particles present in the solution. (4) 4.31 m
In the light of above statements, choose the correct
answer. 22. Mass percentage of urea in 0.5 molal aqueous solution of
urea is
Both Assertion & Reason are true and the reason is
(1) (1) 15.2%
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is (2) 2.9%
(2)
not the correct explanation of the assertion (3) 5.1%
(3) Assertion is true statement but Reason is false (4) 20.9%
(4) Both Assertion and Reason are false statements
23. 45 g of ethylene glycol (C2H6O2) is mixed with 600 g of
16. Aqueous solution of which of the following has lowest water. Calculate (a) the freezing point depression and (b)
freezing point? (Kf(H2O) = 1.86 K molal–1) the freezing point of the solution

(1) 0.1 m NaCl

(2) 0.01 m NaCl
(3) 0.001 m NaCl
(4) 0.0001 m NaCl
24. Given below are two statements one is assertion (A) other 30. If a solute dimerizes to 40% then its van’t Hoff factor (i)
is reason (R) will be
Assertion (A): Aquatic species are more comfortable in
cold water than in warm water. (1) 0.2
Reason (R): Solubility of oxygen in water decreases with (2) 0.6
increase in temperature.
In the light of above statements choose the correct (3) 0.8
answer. (4) 0.5
Both assertion and reason are correct statements, and
(1) 31. A 0.2 molal aqueous solution of electrolyte AB2 freezes at
reason is the correct explanation of the assertion.
–0.88°C. If Kf for H2O is 1.86 K kg mol–1 then degree of
Both assertion and reason are correct statements, but
(2) dissociation of AB2 is
reason is not the correct explanation of the assertion.
(3) Assertion is correct, but reason is wrong statement. (1) 0.52

(4) Assertion is wrong, but reason is correct statement. (2) 0.68

25. The vapour pressures of pure liquids A and B (3) 0.76

respectively are 600 torr and 500 torr. In a binary solution (4) 0.84
of A and B, mole fraction of A is 0.25 then total pressure of
the solution (in torr) will be 32. The concentration term(s) which depends on temperature
is/are
(1) 625
(1) Molarity
(2) 530
(2) Weight volume percent
(3) 525
(3) Normality
(4) 575
(4) All of these
26. Among the following solutions, the correct order of
increasing boiling point can be given as (assuming 33. Arrange the following aq. dilute solution in the increasing
complete dissociation) order of vapour pressure
a. 0.01 M NaCl (a) 10% (w/v) glucose
b. 0.05 M glucose (b) 10% (w/v) sucrose
c. 0.01 M CaCl2 (c) 10% (w/v) urea
d. 0.02 M KCl (1) (a) < (b) < (c)
(1) a > b > c > d (2) (a) < (c) < (b)
(2) b > d > c > a (3) (c) < (b) < (a)
(3) a > c > d > b (4) (c) < (a) < (b)
(4) d > c > b > a 34. The freezing point of 0.1 molal solution of X in water is
27. Which one of the following electrolytes has the maximum greater than equimolal solution of Y in water. Which one
value of van't Hoff factor? of the following conclusion can be drawn regarding X and
Y?
(1) K4 [Fe (CN)6 ], 50% ionised
(1) X undergoes dissociation while Y does not
(2) K2 SO4 , 80% ionised
(2) X undergoes association while Y does not
(3) K3 [Fe (CN) ], 60% ionised Degree of dissociation of X is higher than degree of
6
(3)
association of Y
(4) Al ( NO3 )3 , 70% ionised
(4) Both X and Y do not dissociate or associate
28. Aqueous solution of which of the following has lowest
35. Select the incorrect statement
freezing point? (Kf(H2O) = 1.86 K molal–1)
Elevation in boiling point is the result of lowering in
(1) 0.1 m NaCl (1) vapour pressure, when a non-volatile solute is added
(2) 0.01 m NaCl to a solvent

(3) 0.001 m NaCl Lowering of vapour pressure for a dilute solution of

(2) non-volatile solute is directly proportional to the mole
(4) 0.0001 m NaCl fraction of the solute

29. The freezing point (in °C) of solution containing 0.18 g of Boiling point of the sugar solution is larger than that of
(3)
the pure solvent
glucose in 100 g water is (Kf = 1.86 K kg mol–1) is
Vapour pressure of the sugar solution is greater than
(1) –3.7 × 10–2 (4)
that of pure solvent

(2) –5.7 × 10–2

(3) –1.86 × 10–2

(4) –1.2 × 10–2

36. (Ethanol + water) mixture can form 43. A solution containing 20 g per dm3 of urea is isotonic with
Minimum boiling azeotrope having same composition 10% solution (w/v) of a non-volatile solute. The molecular
(1) mass of non volatile solute is
in liquid and vapour phase
Maximum boiling azeotrope which boils at a constant (1) 100
(2)
temperature (2) 200
Maximum boiling azeotrope which shows a large (3) 300
(3)
positive deviation from Raoult’s law
(4) 400
Minimum boiling azeotrope which shows a large
(4)
negative deviation from Raoult’s law 44. A : In an ideal solution the interaction forces of solute-
solvent are same as solute-solute and solvent-solvent.
37. If two liquids A (P
0
= 100 torr) and B (P
B
0
= 200 torr) are R : Chloroform in benzene is a non ideal solution.
A

completely immiscible with each other (each one will

Both Assertion & Reason are true and the reason is
behave independently of the other) are present in a (1)
the correct explanation of the assertion
closed vessel. The total vapour pressure of the system
will be Both Assertion & Reason are true but the reason is
(2)
not the correct explanation of the assertion
(1) Less than 100 torr
(3) Assertion is true statement but Reason is false
(2) Greater than 200 torr
(4) Both Assertion and Reason are false statements
(3) Between 100 to 200 torr
(4) 300 torr 45. Consider the following statements
I. Pressure does not have any significant effect on
38. A mixture showing negative deviation from Raoult's law is solubility of solids in liquids.
II. Higher the value of KH at a given pressure, the lower is
(1) Hexane + Heptane
the solubility of the gas in the liquid.
(2) Benzene + Toluene III. At high altitudes the partial pressure of oxygen is high
than that at the ground level.
(3) Water + Ethanol The correct statement(s) is/are
(4) Nitric acid + Water (1) Only I
39. Osmotic pressure of 0.2 M CH3COOH(aq) solution at (2) I and II
27°C is (assuming CH3COOH ionize to 10%)
(3) Only III
(1) 5.42 atm
(4) II and III
(2) 10.84 atm
46. The van’t Hoff factor of 0.01 M weak monobasic acid in
(3) 2.71 atm aqueous solution is 1.041. The dissociation constant of
acid is approximately
(4) 1.36 atm
(1) 1 × 10–7
40. Which solution will show positive deviation from Raoult’s
law?
(2) 2 × 10–6
(1) Chloroform and acetone
(3) 1 × 10–6
(2) Acetone and aniline
(3) Chloroform and diethyl ether (4) 2 × 10–5

(4) Acetone and ethanol 47. The ratio of van’t Hoff factors of acetic acid in benzene
and water (assuming complete association and
41. In the following question, a statement of assertion (A) dissociation respectively) is equal to
is followed by a statement of reason (R).
A : Dilute solution of n-hexane and n-heptane is an ideal (1) 1
solution.
R : Ideal solution has it’s ∆Vmix = 0. (2) 1

Both Assertion & Reason are true and the reason is (3) 2
(1)
the correct explanation of the assertion (4) 1

Both Assertion & Reason are true but the reason is

(2) 48. Solubility of a gas in a liquid is increased by
not the correct explanation of the assertion
(3) Assertion is true statement but Reason is false (1) Increase in temperature

(4) Both Assertion and Reason are false statements (2) Increase in pressure

42. At 25°C, the highest value of molal depression constant is (3) Increase in KH value
for which solution?
(4) Increase in amount of liquid
(1) 0.1 M of glucose
(2) 0.2 M of NaCl
(3) 0.3 M of CaCl2

(4) All the above have same values

49. For a dilute solution ratio between vapour pressure of 56. If the molality of NaOH in D2O is 20 m, then difference
solution and solvent is 7:8. If solvent is water then molality between mole fractions of D2O and NaOH will be
of solution will be
(1) 7.94 m (1) 2

(2) 17.2 m (2) 5

(3) 3.97 m
(3) 1

(4) 16.8 m 7

50. 0.1 molal aqueous solutions of an electrolyte AB3 is 90% (4) 3

ionized. The boiling point of solution at 1 atm is (Kb = 57. When phenol and aniline are mixed, such a liquid pair
0.52 K kg/mol) will exhibits
(1) 273.19 K (1) Positive deviation from Raoult's law
(2) 374.92 K (2) Negative deviation from Raoult's law
(3) 376.4 K (3) No deviation from Raoult's law
(4) 373.19 K Positive deviation from Raoult's law at low
(4)
concentration
51. If vapour pressure of solution of 5 g non electrolytic solute
in 100 g of water is 720 mm Hg and the vapour pressure 58. When mercuric iodide is added to the aqueous solution of
of pure water at same temperature is 740 mm Hg, then potassium iodide, the
the molar mass of the solute is
(1) Boiling point of solution remains same
(1) 33.3 g
(2) Freezing point of solution remains same
(2) 32.4 g
(3) Freezing point of solution is raised
(3) 66.6 g
(4) Freezing point of solution is lowered
(4) 64.8 g
59. A : People taking a lot of salt or salty food experience
52. 24 g of difluoroacetic acid in 400 g of water has observed water retention in tissue cells and intercellular space.
freezing point depression by 1.4°C. The van't Hoff factor R : There is phenomena of osmosis in tissue cells and
for difluoroacetic acid is (Kf of water = 1.86 K kg mol–1; intercellular space.
Atomic weight of F = 19) Both Assertion & Reason are true and the reason is
(1)
(1) 1.20 the correct explanation of the assertion

(2) 1.05 Both Assertion & Reason are true but the reason is
(2)
not the correct explanation of the assertion
(3) 1.45
(3) Assertion is true statement but Reason is false
(4) 0.85
(4) Both Assertion and Reason are false statements
53. Which among the following aqueous solutions has
highest freezing point? (Given Kf of water = 1.86 K kg 60. Among the following given property of solution all are
colligative property except
mol–1)
(1) Vapour pressure of pure solvent
(1) 0.1 m glucose solution
(2) Boiling point elevation
(2) 0.1 m NaCl solution
(3) Freezing point depression
(3) 0.1 m CaCl2 solution
(4) Osmotic pressure
(4) 0.2 m NaOH solution
61. A : For 0.1 M aq. NaOH and for 0.1 M aq. CH3COOH
54. The rate constant of a reaction depends on solution, the ebullioscopic constant is different.
R : Ebullioscopic constant depends on the nature of
(1) Activation energy of reaction
solute.
(2) Time of reaction
Both Assertion & Reason are true and the reason is
(1)
(3) Temperature of reaction the correct explanation of the assertion
(4) Both (1) and (3) Both Assertion & Reason are true but the reason is
(2)
not the correct explanation of the assertion
55. A : Solubility of gases in liquid decreases with rise in
temperature. (3) Assertion is true statement but Reason is false
R : Solubility of gases in liquid is an exothermic process (4) Both Assertion and Reason are false statements
so solubility decreases with rise in temperature,
according to Le-chatelier's principle.
Both Assertion & Reason are true and the reason is
(1)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is
(2)
not the correct explanation of the assertion
(3) Assertion is true statement but Reason is false
(4) Both Assertion and Reason are false statements
62. A : Osmotic pressure of 0.1 M NaCl is equal to that of 0.1 68. If two liquids A and B are completely immiscible with each
M glucose solution. other at constant temperature and pressure are present in
R : When molarity of two solutions is same then their a closed vessel having PÅ= 125 torr and P = 275 torr.
∘ 0
B
osmotic pressure are same.
The total vapour pressure of the system will be
Both Assertion & Reason are true and the reason is
(1) (1) Between 125 to 275 torr
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is (2) Greater than 275 torr
(2)
not the correct explanation of the assertion (3) Less than 125 torr
(3) Assertion is true statement but Reason is false (4) 400 torr
(4) Both Assertion and Reason are false statements
69. A : An increase in surface area increases the rate of
63. A 0.008 M solution of Na2SO4 is isotonic with 0.01 M evaporation.
solution of urea at same temperature. The apparent R : Stronger the inter-molecular attractive forces, slower is
degree of dissociation of Na2SO4 is the rate of evaporation at a given temperature.
Both Assertion and Reason are true and the reason is
(1) 12.5% (1)
the correct explanation of the assertion
(2) 25% Both Assertion and Reason are true but the reason is
(2)
(3) 18.5% not the correct explanation of the assertion

(4) 85% (3) Assertion is true statement but Reason is false

64. The mass percentage of an element M is 53 in its oxide of (4) Both Assertion and Reason are false statements
molecular formula M2O3. The atomic mass of M is 70. A solution containing 18 g/dm3 of glucose is isotonic with
(1) 45 5% ( ) solution of a nonvolatile, nonelectrolytic solute.
w

(2) 27 The molar mass of the solute is

(3) 18 (1) 250 g mol–1

(4) 36 (2) 150 g mol–1
65. The van’t Hoff factor (i) for infinitely dilute aqueous
(3) 400 g mol–1
solution of Al2(SO4)3 is

(1) 2 (4) 500 g mol–1

(2) 3 71. Select the incorrect statement among the following.

(3) 4 Solutions which show a large positive deviation from
(1) Raoult's law form minimum boiling azeotrope at a
(4) 5
specific composition
66. The van’t Hoff factor (i) for a dilute solution of strong (2) Azerotropes solution have constant boiling point
electrolyte K [Fe (CN) ]
4 6
At azeotropic composition, the liquid and vapour have
(1) 1 (3)
the same composition
(2) 2 Azeotropes can be separated into components by
(4)
fractional distillation
(3) 4
(4) 5 72. A 5 M aqueous solution of AgNO3 and 10 M aqueous
solution of NaCl are connected by a semipermeable
67. The total vapour pressure of a binary solution is given by membrane as shown in the figure.
P = (120XA + 250XB) mm Hg where XA and XB are the
mole fraction of components A and B in solution
respectively. This indicates that the
Vapour pressure of solution is less than that of pure
(1)
component A
Vapour pressure of solution is more than that of pure
(2)
component B
Vapour pressure of pure A and B are 250 mm Hg and
(3)
120 mm Hg respectively
Vapour pressure of pure A is 120 mm Hg and that of
(4)
pure B is 250 mm Hg
The precipitate of AgCl will be formed in
(1) Chamber 1
(2) Chamber 2
(3) Simultaneously in both the chambers
(4) None of the chambers
73. van’t Hoff factor, i, for K4[Fe(CN)6], if it is 80% dissociated 79. The colligative property widely used to determine molar
at 300 K, is mass of polymers is

(1) 5 (1) Osmotic pressure

(2) 4.2 (2) Elevation in boiling point

(3) 4.8 (3) Depression in freezing point

(4) 3.6 (4) Relative lowering of vapour pressure

74. A : In case of negative deviations from Raoult's law, the 80. What is the molality of CH3OH in water solution which will
intermolecular attractive forces between A – A and B – B freeze at –20°C? [Mol. wt. of CH3OH = 32, Kf for water =
are weaker than those between A – B. 1.86]
R : Abnormal molar mass, which is related to van't Hoff
factor, is the experimentally determined molar mass. (1) 10.75 m

Both Assertion & Reason are true and the reason is (2) 37.2 m
(1)
the correct explanation of the assertion (3) 1.07 m
Both Assertion & Reason are true but the reason is (4) 5.3 m
(2)
not the correct explanation of the assertion
81. Calculate the vapour pressure of pure B If Ptotal = 0.172
(3) Assertion is true statement but Reason is false
XA + 0.215 atm at 306 K
(4) Both Assertion and Reason are false statements
(1) 0.38 atm
75. Which has maximum osmotic pressure?
(2) 0.04 atm
(1) 200 mL of 0.2 M NaCl solution
(3) 0.215 atm
(2) 200 mL of 0.1 M glucose solution
(4) 0.172 atm
(3) 200 mL of 0.2 M sucrose solution
82. Which among the following is an incorrect statement
(4) 200 mL of 0.2 M urea solution about Henry’s law constant (KH)?
76. If XA and XB are mole fractions of volatile components A Different gases have different KH values at same
and B in binary solution then mole fraction of A in vapour (1)
temperature
mixture is
P
∘
XA
(2) KH is a function of nature of the gas
(1) YA =
A

∘
PB XB
Higher is the value of KH at a given temperature and
(3)
P
∘
XA pressure, higher is the solubility of the gas
(2) YA =
A

XB
KH value of a particular gas increases with increase
(4)
P
∘
XA in temperature at constant pressure
(3) YA =
P
∘
A

XA + P
∘
XB
A B

83. Which solution is isotonic to blood cells?

∘
P
(4) YA =
P
∘
A

+P
∘ (1) 9% (w/v) NaCl
A B

(2) 0.9% (w/v) NaCl

77. Under constant pressure and temperature condition, most
soluble gas in water will be (KH : Henry’s cosntant) (3) 19% (w/v) NaCl

(1) Argon (KH = 40.3 kbar) (4) 30% (w/v) NaCl

(2) CO2 (KH = 1.67 kbar) 84. If two volatile liquids A(P ° = 540 torr) and B(P ° = 420
A B
torr) are mixed in the molar ratio of 2 : 1 then total vapour
(3) Methane (KH = 0.413 kbar)
pressure of solution is
(4) Vinyl chloride (KH = 0.611 kbar) (1) 100 torr
78. Consider the following Assertion (A) and Reason (R) and (2) 200 torr
choose the correct option.
Assertion (A) : More the value of KH (Henry's Law (3) 600 torr
Constant) , lesser will be solubility of gas in water. (4) 500 torr
Reason (R) : CO2 is more soluble than H2 in water
85. The solution which forms minimum boiling azeotrope is
Both Assertion & Reason are true and the reason is
(1)
the correct explanation of the assertion (1) CHCl3 + CHBr3

Both Assertion & Reason are true but the reason is (2) HNO3 + H2O
(2)
not the correct explanation of the assertion
(3) HCl + H2O
(3) Assertion is true statement but Reason is false
(4) C6H5OH + H2O
(4) Both Assertion and Reason are false statements
86. Which of the following is not equal to zero for a solution of 93. A : For dilute solutions, partial pressure of the gas is
n-hexane and n- heptane? directly proportional to the mole fraction of the dissolved
gas in the solution.
(1) ΔHmix R : At a given temperature, He gas is less soluble than
CO2 gas in water.
(2) ΔVmix
Both Assertion & Reason are true and the reason is
(3) ΔP = Hobserved – PRaoult (1)
the correct explanation of the assertion
(4) ΔGmix Both Assertion & Reason are true but the reason is
(2)
not the correct explanation of the assertion
87. What will be the value of P if total pressure of the
o
B

solution is given by PTotal = 75 + 150XB mm Hg? (3) Assertion is true statement but Reason is false

(1) 225 mm Hg (4) Both Assertion and Reason are false statements

(2) 200 mm Hg 94. Relative lowering of vapor pressure of a solution

containing non-volatile solute can be expressed as (A -
(3) 75 mm Hg solvent, B - solute)
(4) 150 mm Hg (1) Both (C) and (D)
88. If an azeotropic solution of two liquids has higher boiling (2) Ps = P
∘
A
XB

point than either of solute and solvent, then the solution

0
P − Ps

(1) Is immiscible (3) A

=
nB

nA
Ps

(2) Shows positive deviation from Raoult’s law ∘

PA − Ps nB
(4) =
(3) Shows negative deviation from Raoult’s law
∘
PA nA

(4) Follow Raoult’s law 95. A : Osmosis involves movement of solvent molecules
from higher concentration of solution to its lower
89. For an ideal solution of two volatile liquids A and B, the concentration.
graph of vs gives intercept equal to (x and y are
1

yA
1

xA
R : Solutions having different osmotic pressures are
mole fractions in liquid and vapour phase) called isotonic solutions.
Both Assertion & Reason are true and the reason is
(1)
p
o
−p
o
(1)
the correct explanation of the assertion
A B

o
p
A

Both Assertion & Reason are true but the reason is

p
o
−p
o
(2)
(2) B

p
o
A
not the correct explanation of the assertion
B

o
(3) Assertion is true statement but Reason is false
p

(3) p
B

o
(4) Both Assertion and Reason are false statements
A

p
o
96. When CO2 (g) is dissolved in water, heat is liberated. The
(4) A

o
p
B solubility of CO2 (g) will increase at
90. Which of the following aqueous solutions will have (1) High pressure, low temperature
highest freezing point?
(2) Low pressure, low temperature
(1) 0.015 m Urea
(3) Low pressure, high temperature
(2) 0.01 m KNO3
(4) High pressure, high temperature
(3) 0.10 m Na2SO4
97. If 'i' is the van't Hoff factor and 'α' is degree of dissociation
(4) 0.025 m Glucose of weak electrolyte AxBy, then relation between 'α' and 'i'
91. If the density of H2SO4 solution is 1.84 gm/cc and is
contains solute 49% by mass, then the molarity of H2SO4 (1) α =
i−1

(x+y)
solution is
i−1
(1) 18.4 (2) α =
(x+y−1)

(2) 10.8 1−i

(3) α =
(3) 9.2
(x+y−1)

(4) 4.9 (4) α =

i−1

(x+y+1)

92. A : Ethylene glycol is used as coolant in car radiators

under the name of coolant Prestone.
R : Lower the vapour pressure of a given substance,
smaller will be its boiling point.
Both Assertion & Reason are true and the reason is
(1)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is
(2)
not the correct explanation of the assertion
(3) Assertion is true statement but Reason is false
(4) Both Assertion and Reason are false statements
98. A : The breathing apparatus used by Scuba divers [Link] common salt is dissolved in water, the vapour pressure
contains air diluted with helium. of the solution will
R : Presence of helium reduces the high concentration of
(1) Increase
nitrogen in blood and the painful medical condition
''bends'' is avoided. (2) Decrease
Both Assertion & Reason are true and the reason is (3) Remain unchanged
(1)
the correct explanation of the assertion
(4) Can not be predicted
Both Assertion & Reason are true but the reason is
(2) [Link] a homogeneous solution, the uniformity is observed in
not the correct explanation of the assertion
its
(3) Assertion is true statement but Reason is false
(1) Composition as well as properties
(4) Both Assertion and Reason are false statements
(2) Only composition
99. If two liquids A (boiling point = t1°C) and B (boiling point =
(3) Only properties
t2°C) on mixing forms azeotropic solution which shows
positive deviation from Raoult's law, then boiling point of (4) Neither composition nor properties
azeotropic solution will be [Given, t1 > t2)
106.A solution of urea received from some research
(1) > t1 laboratory has been marked mole fraction (x) and molality
(m) at 10°C. While calculating its molality and mole
(2) > (t1 + t2) fraction in the laboratory at 24°C, you will find

(3) = t1 (1) Mole fraction (x) and molality (m)

(2) Mole fraction (2x) and molality (2m)
(4) < t2
(3) Mole fraction (x/2) and molality (m/2)
[Link] of the nature of solution which of the
following expression is always true. (4) Mole fraction (x) and molality (2m)

(1) ΔHmix > 0 [Link] colligative property which is preferred for determining
molar masses of proteins and polymers is
(2) ΔVmix > 0
(1) Relative lowering of vapour pressure
(3) ΔSmix > 0 (2) Elevation in boiling point
(4) Both (A) & (B) (3) Depression in freezing point
[Link] two solutions of concentration C1 and C2 (C1 > (4) Osmotic pressure
C2) are separated by semipermeable membrane then
[Link] liquids A and B are mixed in a ratio of 2 : 3. If
= 100mmHg and = 300 mmHg, then the mole
(1) Flow of solvent molecules occurs from C2 to C1 only
∘ ∘
P P
A B

fraction of A in vapour phase will be

(2) Flow of solvent molecules occurs from C1 to C2 only
(1) 2

Flow of solvent molecules occurs from C1 to C2 and 11

(3)
C2 to C1 also (2) 10

11

(4) Flow of solute molecules occurs from C1 to C2 (3) 3

[Link] boiling azeotrope

(4) 2

5
(1) Shows positive deviation from Raoult’s law
[Link] vapour pressure of two liquids X and Y are 100 and
(2) Shows negative deviation from Raoult’s law
200 torr respectively. The total vapour pressure of
(3) Follows Raoult’s law solution containing 20 mol of X and 10 mol of Y is
(4) Has unequal composition in liquid and vapour states (1) 100 torr

[Link] : When 10 ml of benzene is mixed with 20 ml of (2) 133.3 torr

toluene then net volume of solution is 30 ml. (3) 150 torr
Reason : Benzene and toluene on mixing form ideal
solution. (4) 166.7 torr
Both Assertion & Reason are true and the reason is [Link] degree of dissociation of CH3COOH is 0.2 then its
(1)
the correct explanation of the assertion abnormal molar mass is
Both Assertion & Reason are true but the reason is
(2) (1) 30 g mol–1
not the correct explanation of the assertion
(3) Assertion is true statement but Reason is false (2) 48 g mol–1
(4) Both Assertion and Reason are false statements (3) 50 g mol–1

(4) 72 g mol–1
111. The order of freezing points of equimolal aqueous [Link] molar mass of acetic acid which is dimerizes
solutions is C < A < B. 75% in benzene solvent, is
The correct order of their boiling point is
(1) 60
(1) A < C < B
(2) 96
(2) B < C < A
(3) 37.5
(3) B < A < C
(4) 30
(4) A < B < C
119.A : 68% nitric acid and 32% water by mass forms
[Link] volatile liquids A and B are mixed in the molar ratio minimum boiling azeotrope.
of 2 : 3. If vapour pressure of pure liquids A and B is 300 R : Decreasing escaping tendency of molecules for each
mm Hg and 400 mm Hg respectively then the vapour component in mixture decreases the vapour pressure as
pressure of the solution in mm Hg will be well as boiling point of mixture.
(1) 360 Both Assertion & Reason are true and the reason is
(1)
the correct explanation of the assertion
(2) 380
Both Assertion & Reason are true but the reason is
(3) 340 (2)
not the correct explanation of the assertion
(4) 390 (3) Assertion is true statement but Reason is false
113.A : Swelling is shown by a living cell, if kept in a (4) Both Assertion and Reason are false statements
hypertonic solution.
R : Hypertonic solution is comparatively lower in osmotic [Link] gases A, B, C, D having their Henry’s law constant
pressure and higher in concentration as compared to value at a particular temperature in water are 0.611, 40.3,
other. 1.83 × 10–5 and 1.67 K bar respectively. The least
Both Assertion & Reason are true and the reason is soluble gas among the following is
(1)
the correct explanation of the assertion (1) A
Both Assertion & Reason are true but the reason is (2) B
(2)
not the correct explanation of the assertion
(3) C
(3) Assertion is true statement but Reason is false
(4) D
(4) Both Assertion and Reason are false statements
[Link] cells do not shrink in blood because blood is
[Link] van’t Hoff factor for 0.1 M Ba(NO3)2 is 2.74.
Percentage degree of dissociation is (1) Hypertonic

(1) 91.3% (2) Isotonic

(2) 87% (3) Equimolar

(3) 75% (4) Hypotonic

(4) 63.5% [Link] of the following aqueous solutions has highest

vapour pressure?
115.A solution which will show positive deviation from
Raoult’s law is (1) 0.02 M glucose at 20°C

(1) Ethanol-acetone (2) 0.005 M MgCl2 at 15°C

(2) Water-nitric acid (3) 0.05 M KCl at 60°C
(3) Chloroform -acetone (4) 0.005 M MgCl2 at 60°C
(4) Benzene-toluene [Link] solution which forms minimum boiling azeotrope is
[Link] elevation of boiling point of 0.1 molal aq CaCl2 (1) CHCl3 + CHBr3
solution is
(2) HNO3 + H2O
(1) Kb
(3) HCl + H2O
(2) 2 Kb
(4) C6H5OH + H2O
(3) 0.3 Kb
124.A : Nitric acid and water form maximum boiling azeotrope.
(4) 10 Kb R : The solutions that show negative deviation from
Raoult’s law form maximum boiling azeotrope.
117.A : Osmotic pressure is proportional to the molality of the
solution. If both Assertion & Reason are true and the reason is
(1)
R : Osmotic pressure is independent of temperature. the correct explanation of the assertion.
Both Assertion & Reason are true and the reason is If both Assertion & Reason are true but the reason is
(1) (2)
the correct explanation of the assertion not the correct explanation of the assertion.
Both Assertion & Reason are true but the reason is (3) If Assertion is true statement but Reason is false.
(2)
not the correct explanation of the assertion
(4) If both Assertion and Reason are false statements.
(3) Assertion is true statement but Reason is false
(4) Both Assertion and Reason are false statements
125.A : Azeotropic mixture cannot be separated by fractional [Link] graph between PTotal (Total vapour pressure of
distillation. solution) and XB (mole fraction of solute) is given below (
R : Mole fraction of each component in vapour and
o o
solution phase are equal for azeotropic mixture. P is Vapour pressure of pure liquid A and P is vapour
A B

If both Assertion & Reason are true and the reason is pressure of pure liquid B)
(1)
the correct explanation of the assertion.
If both Assertion & Reason are true but the reason is
(2)
not the correct explanation of the assertion.
(3) If Assertion is true statement but Reason is false.
(4) If both Assertion and Reason are false statements.

[Link] correct order of solubility of He, CO2 and O2 in water

at 298 K and 1 atm is
(1) He > O2 > CO2

(2) O2 > CO2 > He

(3) CO2 > O2 > He

The slope of graph is
(4) CO2 > He > O2
o o
(1) P − P
[Link] (A) : At azeotropic point boiling point of A B

solution is constant.
Reason (R) : Azeotropic solutions may have boiling o
(2) P − P
o
B A
points either greater than both the components or lesser
than both the components.
o o
(3) P + P
Both Assertion & Reason are true and the reason is A B
(1)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is
o o

(2) (4) P
A
+ P
B
not the correct explanation of the assertion 2

(3) Assertion is true statement but Reason is false

[Link] of sea water can be done by
(4) Both Assertion and Reason are false statements
(1) Filtration
[Link] of solution on mixing (2) Osmosis
(1) Increases for both ideal and non-ideal solution (3) Reverse osmosis
(2) Decreases for both ideal and non-ideal solution (4) Diffusion
Increases for ideal solution but decreases for non-
(3) [Link] osmotic pressure of a solution of a non-electrolyte
ideal solutions
containing 20 g L–1 of y (molecular mass = 60 g mol–1)
Decreases for ideal solution but increases for non- is equal to that of a 10% solution (w/v) of a non-volatile,
(4)
ideal solutions non-electrolyte solute at 30°C. The molar mass of the
solute is
[Link] liquids ‘A’ and ‘B’ form a solution and it is observed
experimentally that P < x P and P < x P . Solution
A A
o
A B B
o
B (1) 60 g mol–1
will show
(2) 600 g mol–1
(1) Lower boiling point than expected
Weaker forces of interaction between A and B than (3) 400 g mol–1
(2)
those of A-A and B-B
(4) 300 g mol–1
(3) Volume of the solution phase decrease
[Link] below are two statements one is assertion (A) other
(4) Positive deviation
is reason (R)
[Link] below are two statements, one is Assertion other is Assertion (A): The composition of the components in
Reason. vapour phase is same as that of in the liquid phase of an
Assertion (A) : Azeotropic mixture cannot be separated azeotropic mixture.
by fractional distillation. Reason (R): Azeotropic mixture strictly follows Raoult's
Reason (R) : Nitric acid and water can form maximum law.
boiling azeotrope. In the light of above statements choose the correct
In the light of above statements, choose the correct answer.
option. Both Assertion & Reason are true and the reason is
(1)
Both Assertion & Reason are true and the reason is the correct explanation of the assertion
(1)
the correct explanation of the assertion Both Assertion & Reason are true but the reason is
(2)
Both Assertion & Reason are true but the reason is not the correct explanation of the assertion
(2)
not the correct explanation of the assertion (3) Assertion is true statement but Reason is false
(3) Assertion is true statement but Reason is false (4) Both Assertion and Reason are false statements
(4) Both Assertion and Reason are false statements
135.A dilute solution of a non-volatile solute in water freezes [Link] osmotic pressure of equimolar solutions of glucose,
at – 0.2°C. At what temperature (in °C) the same solution KCl, MgCl2 follows the order
will boil? (Kf for H2O = 1.86°C m–1 and Kb for H2O =
(1) MgCl2 > KCl > Glucose
0.52°C m–1)
(2) Glucose > KCl > MgCl2
(1) 100.121
(3) KCl > MgCl2 > Glucose
(2) 100.217
(3) 100.056 (4) MgCl2 > Glucose > KCl

(4) 101.562 [Link] 50% of acetic acid dimerises in a solvent and rest
ionises, then its van’t Hoff factor is
[Link] below are two statements one is assertion(A) other
is reason (R). (1) 1
Assertion (A): Mixture of chloroform and acetone shows (2) 1.25
positive deviation from Raoult’s law.
Reason (R): Chloroform and acetone form intermolecular (3) 0.75
hydrogen bond.
(4) 2
In the light of above statements, choose the correct
answer. 142.0.25 M BaCl2 solution is isotonic with 0.5 M sucrose
Both assertion and reason are correct statements, and solution at a temperature of 298 K. The percentage
(1) ionisation of BaCl2 solution is
reason is the correct explanation of the assertion.
Both assertion and reason are correct statements, but (1) 50%
(2)
reason is not the correct explanation of the assertion.
(2) 75%
(3) Assertion is correct, but reason is wrong statement.
(3) 45%
(4) Assertion is wrong, but reason is correct statement.
(4) 85%
[Link] mass of urea required in making 5 kg of 5 molal
[Link] pressure of a binary solution of A and B (in mm
aqueous solution is
Hg) is equal to 140 + 120XA. Pure form vapour pressures
(1) 1500 g of A and B respectively are
(2) 1000 g (1) 140 mm Hg, 260 mm Hg
(3) 1154 g (2) 260 mm Hg, 140 mm Hg
(4) 1254 g (3) 240 mm Hg, 120 mm Hg
[Link] Henry’s Law constant for some gases in water. (4) 120 mm Hg, 240 mm Hg
Gas Temperature/K KH /Kbar [Link] a binary solute the value of Van't Hoff factor (i) if it is
Ar 298 40.3 50% dimerise and 50% dissociate, is
CO2 298 1.67 (1) 1
(2) 1.25
HCHO 298 1.83 × 10–5
CH4 298 0.413 (3) 1.5

Arrange these gases in increasing order of solubility in (4) 0.5

water
145.A mixture showing negative deviation from Raoult's law is
(1) CO2 < Ar < HCHO < CH4 (1) Hexane + Heptane
(2) Ar < CO2 < HCHO < CH4 (2) Benzene + Toluene
(3) CO2 < Ar < CH4 < HCHO (3) Water + Ethanol

(4) Ar < CO2 < CH4 < HCHO (4) Nitric acid + Water

[Link] of Ebullioscopic constant is [Link] of aqueous solution of urea is 3. The mass

percentage of urea in the solution is
(1) K mol kg–1 (1) 10.5%

(2) K kgmol–1 (2) 25.25%

(3) 12.25%
(3) kg mol–1
(4) 15.25%
(4) kg mol g–1
[Link] mixing of acetone and ethanol, which of the
following is not observed?
(1) Δ Hmix > 0

(2) Δ Smix > 0

(3) Δ Gmix > 0

(4) Δ Vmix > 0

[Link] condition is not satisfied for negative deviation of a [Link] osmotic pressure of 60% solution of glucose is 1.2 atm
binary solution? and that of 6.84% solution of cane sugar is 2.5 atm. The
osmotic pressure of the mixture containing equal volumes
(1) (ΔG)sol < 0 of the two solution is
(2) (ΔH)sol > 0 (1) 7.40 atm

(3) (ΔS)sol > 0 (2) 3.70 atm

(3) 1.85 atm
(4) (ΔV)sol < 0
(4) 2.50 atm
[Link] 0.1 molal aqueous solution of Al2(SO4)3 is 30%
dissociated then the van’t Hoff factor of the salt is
(1) 1.5
(2) 2.2
(3) 4.5
(4) 3.8