1.
A solution of MgCl2 in water has pH
(A) < 7 (B) > 7 (C) 7 (D) 14.2
2. Among the following, the weakest base is
(A) H (B) CH3 (C) CH3O (D) Cl
3. The pH of a buffer containing equal molar concentrations of a weak base and its chloride (K b
forweak base = 2 105 , log 2 = 0.3) is
(A) 5 (B) 9 (C) 7 (D) 9.3
4. A certain buffer solution contains equal concentrations of X and HX. The K a for HX is 108 . The
pH of the buffer is
(A) 3 (B) 8 (C) 11 (D) 14
5. Species acting both as Bronsted acid and base is
(A) HSO4 (B) Na2CO3 (C) NH3 (D) OH
6. 1 M NaCl and 1 M HCl are present in an aqueous solution. The solution is
(A) Not a buffer solution with pH < 7
(B) not a buffer solution with pH > 7
(C) a buffer solution with pH < 7
(D) a buffer solution with pH > 7
7. Which of the following is the buffer solution of strong acidic nature?
(A) HCOOH HCOO (B) CH3COOH CH3COO
(C) H2C2O4 C2O42 (D) H3BO3 BO33
8. The pH of a solution that contains 0.10 M sodium acetate and 0.03 M acetic acid is( pK a for
CH3COOH 4.57 )
(A) 4.09 (B) 6.09 (C) 5.09 (D) 7.09
9. At 80o C, distilled water has hydronium ion (H3O ) concentration equal to 1 106 mol L1 . The value
of K w at this temperature would be
(A) 1 106 (B) 1 1012 (C) 1 109 (D) 1 1014
10. Which of the following aqueous solutions has highest pH?
(A) CH3COOK (B) Na2CO3 (C) NH4Cl (D) NaNO3
11. A solution which is 0.1 N NH4OH and 0.1 N NH4Cl has pH = 9.25. The pK b of NH4OH is
(A) 9.25 (B) 3.75 (C) 4.75 (D) 8.25
12. Solubility of MX2 type electrolyte is 0.5 104 mol L1 . The value of K sp for the electrolyte is
(A) 5 1012 (B) 25 1010 (C) 1 1013 (D) 5 1013
13. The solubility of CaF2 is a mol L1. Its solubility product would be
(A) s2 (B) 4s3 (C) 3s2 (D) s3
14. In hydrolysis of a salt of weak acid and strong base, the hydrolysis constant, K h is equal to
Kw Ka Ka Kw
(A) (B) (C) (D)
Ka Kw C Ka Kb
15. The acid that results when a base accepts a proton is called
(A) Conjugate acid of the base (B) Conjugate base of the acid
(C) Conjugate protonated base (D) None of these
ANSWER KEY
1. (A) 2. (D) 3. (D) 4. (B) 5. (A) 6. (A) 7. (A)
8. (C) 9. (B) 10. (B) 11. (C) 12. (D) 13. (B) 14. (A)
15. (A)