CPP-08
FS JEE(M) &
ADVANCED
Chemistry
Chapterwise Practise Problems (CPP) for JEE (Main & Advanced)
Chapter - Redox Reaction
Level-1
SECTION - B
SECTION - A
Multiple Correct Answer Type
Straight Objective Type
This section contains multiple choice questions. Each
This section contains multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONE OR MORE is/are correct.
answer, out of which ONLY ONE is correct.
3. W hich of the following compound does not
1. FeC2O4 solution of same concentration is titrated decolourise an acidified solution of KMnO4 ?
with KMnO4 in presence of HCl and in presence
(A) SO2 (B) FeCl3
of H2SO4 separately. If VHCI and VH2SO4 represent
volume of oxidising agent consumed in the two (C) H2O2 (D) FeSO4
cases respectively, then which of the options is 4. In which of the following reaction, hydrogen is
correct ? (Ignore the reaction between FeC2O4 and acting as an oxidising agent ?
Cl2)
(A) With iodine to give hydrogen iodide
(A) VHCI = VH2SO4 (B) With lithium to give lithium hydride
(C) With nitrogen to give ammonia
(B) VHCI > VH2SO4
1 (D) With sulphur to give hydrogen sulphide
(C) VHCI < VH2SO4 but VHCI VH SO
2 2 4 5. The oxide which cannot act as a reducing agent
is
1
(D) VHCI = V
2 H2SO4 (A) SO2 (B) NO2
2. H2O2 acts as both oxidising as well as reducing (C) CO2 (D) ClO2
agent. As oxidising agent, its product is H2O, but
6. W hich of the following change represents a
as reducing agent, its product is O 2. Volume
disproportionation reaction ?
strength has great significance for chemical
reactions. (A) Cl2 + 2OH– ClO + Cl– + H2O
The strength of ‘10V’ means 1 volume (or litre) of (B) Cu2O + 2H+ Cu + Cu2+ + H2O
1
H2O2 on decomposition (H2O2 H2O + O2 ) (C) 2HCuCl2 Cu + Cu2+ + 4Cl– + 2H+
2
gives 10 volumes (or litre) of oxygen at NTP.
(D) PCl5 PCl 3 + Cl2
15 gm Ba(MnO4)2 sample containing inert impurity
is completely reacting with 100 ml of ‘11.2V’ 7. The oxidation state of sulphur is +6 in
H2O2, in acidic medium then what will be the % (A) peroxomonosulphuric acid
purity of Ba(MnO4)2 in the sample?
(Atomic mass Ba = 137, Mn = 55) (B) peroxodisulphuric acid
(A) 5% (B) 10% (C) pyrosulphuric acid
(C) 50% (D) none (D) thiosulphuric acid
(1)
SECTION-D SECTION-E
Matrix-Match Type
Integer Answer Type
This Section D have “match the following” type question.
Question contains two columns, Col-I and Col-II. Match This section contains Integer type questions. The answer
the entries in Col-I with the entries in Col-II. One or more to each of the questions is a single digit integer, ranging
entries in Col-I may match with one or more entries in from 0 to 9. The appropriate bubbles below the respective
Col-II. question numbers in the ORS have to be darkened. For
8. In column I, some reactions are given and in example, if the correct answers to question numbers X,
column II, the type of some reactions on the basis Y and Z(say) are 6, 0 and 9, respectively, then the correct
of oxidation and reduction processes are given. darkening of bubbles will look like the following :
Match the reaction with their correct type.
Column I Column II X Y Z
(A) 3CaO + 2P2O5 Ca3(PO4)2 (p) Disproportionation
0 0 0
(B) 2Cu+ Cu + Cu2+ (q) Comproportionation
(C) NH 4NO2 N2 + 2H2O (r) Non-redox 1 1 1
(D) CH 4 + 2O2 CO2 + 2H2O (s) Combustion 2 2 2
(t) Redox 3 3 3
4 4 4
9. In column - I, 1.0 mole of some oxidising agents
are given. Match them with the given moles of the 5 5 5
reducing agents given in column - II.
6 6 6
Column I Column II 7 7 7
(A) KMnO4 (H+) (p) 3.0 mole of FeSO4 8 8 8
9 9 9
(B) KMnO4 (q) 0.5 mole of I 2 to
(weakly alkaline) HIO3
(C) MnO2 (H+) (r) 1.0 mole of 11. In alkaline H2O2 medium Cr2O72– changes to CrO83.
K2C2O4 What is the oxidation number of Cr in CrO83– ?
(D) K2CrO4 (H+) (s) 1.5 mole of K2SO3 12. Consider the reaction
10. Some redox reactions are given in column I. Match M+x + MnO–4 MO3– + Mn+2
them with the correct mole ratios of oxidising to If one mole of MnO4– oxidises 1.66 moles of M+x to
reducing agents given in column II. MO3– then the value of x in the reaction is
Column I Column II 13. How many of the following can behave only as an
oxidising agent?
(A) MnO4–+C2O42– MnO2+CO2 (p) 2:1 H2SO3, HNO3, HClO4, SO2, H2S, K2Cr2O7, HNO2,
KMnO4, FeSO4, SnCl 2 , H2O2, H2SO4
(B) ClO–+Fe(OH)3 Cl–+FeO42– (q) 3:1
(C) HO2–+Cr(OH)3– CrO42–+OH– (r) 2:3
(D) N2H4+Cu(OH)2 N2O+Cu (s) 3:2
D:/ Math equation.pm6/aloke/Determinant (2)
Level-2
In a certain experiment 10 ml of 0.05 M K2Cr2O7
SECTION - A
was used for 10 ml of blood sample. Indicate the
Straight Objective Type correct statements from the following about this
reaction.
This section contains multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D) for its (A) The oxidation number of carbon is unchanged
answer, out of which ONLY ONE is correct. in the reaction
1. To a 10mI 1 M aqueous solution of Br2, excess of (B) The equivalent weight of K2Cr2O7 in this reaction
NaOH is added so that all Br2 is disproportionated mol. wt.
is equal to .
to Br– and BrO3 . The resulting solution is freed 6
from Br – , by extraction and excess of OH – (C) The percentage of (mass/volume) of alcohol in
neutralised by acidifing the solution. The resulting
the blood is 0.115
solution is sufficient to react with 1.5 gm of impure
CaC2O4(M=128 gm/mol) sample. The % purity of (D) The weight of CO2 liberated in the given reaction
Oxalate sample is is 9.4 × 10–3 gm
The relevant reaction are SECTION - C
Br2 (aq.) + OH– Br– (aq.) + BrO3 Linked Comprehension Type
This section contains paragraphs. Based upon this
BrO3 + C2 O24 Br– + CO2 paragraph, some multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and
(A) 85.3% (B) 12.5% (D) for its answer, out of which ONE/MORE is/are correct.
(C) 90% (D) 50% Paragraph for Question Nos. 4 to 6
A steel sample is to be analysed for Cr and Mn
SECTION - B simultaneously. By suitable treatment Cr is oxidized as
Multiple Correct Answer Type Cr2O72 and the Mn to MnO4 .
This section contains multiple choice questions. Each Cr Cr2O72
question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct. Mn MnO4
2. Which of the following statement(s) is/are true A 10gm sample of steel is used to produce 250.0 mL
regarding the change CN– CNO– ?
of a solution containing Cr2O72 and MnO4 . A 10 mL
(A) Carbon is losing two electrons per atom portion of this solution is added to a BaCI2 solution and
(B) The oxidation state of carbon changes from by proper adjustment of the acidity, the chromium is
+2 to +4 completely precipitated as BaCrO4, weighing 0.0549 g.
(C) Oxidation state of nitrogen is not changing. H
Cr2O72– BaCrO4
(D) Oxidation state of nitrogen changes from –3 to
–1 A second 10 mL portion of this solution requires
exactly 15.95 mL of 0.0750M standard Fe 2+
3. Alcohol levels in blood can be determined by redox solution for its titration (in acid solution). Mass of
titration with K2Cr2O7 according to the reaction Ba = 137 g, Cr = 52 g, Fe = 56g
4. % of chromium in the steel sample
C2H5 OH 2Cr2 O27 16H (aq)
4Cr 3 (aq) 2CO2 (g) 11H2 O(l)
. (A) 1.496 (B) 2.82
(C) 1.96 (D) 5
(3)
5. Equivalent of Fe2+ required for reduction of MnO4 7. 22.21 ml solution of HIO3 is reacted with excess of
aqueous solution of SO2. The excess of SO2 and
is I2 formed are removed by heating the solution. The
(A) 5.44 × 10–4 (B) 0.544 × 10–2 remaining solution is neutralized by 35.5 ml of 0.16
(N) NaOH solution. The strength of HIO3 in gm/lt.
(C) 1.196 × 10–5 (D) 11.96 × 10–4 (Round off the answer to the nearest whole number)
is
6. Amount of BaCI2 required for conversion of Cr2O72
to BaCrO4 in 10g steel sample 8. xAs2S3 + yNaOH + zNaClO3 pNa3AsO 4 +
qNa2SO4 + rNaClO + sH2O, the value of r is
(A) 0.045 (B) 0.0549
9. 12.18 g of FeSO4 .xH2O crystals was dissolved in
(C) 1.128 (D) 2.82 dil. H2SO4 and volume made upto 500 mL. 25.0 ml
of this solution required 43.85 ml 0.01 M KMnO4
SECTION-E solution to reach the end point. What is value of ‘x’?
Integer Answer Type 10. In acidic medium, change in oxidation number of
chromium of K2Cr2O7 is from +6 to +3. If change in
This section contains Integer type questions. The answer oxidation number of Fe of FeSO4 is from +2 to +3
to each of the questions is a single digit integer, ranging then how many moles of FeSO4 can be oxidised
from 0 to 9. The appropriate bubbles below the respective by one mole of K2Cr2O7?
question numbers in the ORS have to be darkened. For
example, if the correct answers to question numbers X,
Y and Z(say) are 6, 0 and 9, respectively, then the correct
darkening of bubbles will look like the following :
X Y Z
0 0 0
1 1 1
2 2 2
3 3 3
4 4 4
5 5 5
6 6 6
7 7 7
8 8 8
9 9 9
D:/ Math equation.pm6/aloke/Determinant (4)
CPP-08
FS JEE(M) &
ADVANCED
ANSWERS
LEVEL-1
1. (B) 2. (C) 3. (B) 4. (B) 5. (C) 6. (A,B,C)
7. (A,B,C) 8. (A-r,B-p,t,C-q,t,D-s,t) 9. (A-q,B-p ,s ,C-r,D-p,s)
10. (A-r,B-s,C-p,D-q) 11. (5) 12. (2) 13. (5)
LEVEL-2
1. (A) 2. (A,B,C) 3. (B,C) 4. (B) 5. (A) 6. (C)
7. (9) 8. (7) 9. (7) 10. (6)
(5)