25-05-2025

2401CJA101001250005 JM

PHYSICS

SECTION - I

1)

(A) 0

(B)

(C)

(D) 1

2) The approximate value of x where x = sin 1° cos 1°, is :

(A)

(B) 2
(C) 1

(D)

3) For the given curve y = x4 find the area under curve from x = 1 to x = 2

(A)

(B) 3

(C)

(D) 13

4) is equal to :

(A)

(B)

(C)

(D) None
5) The velocity of the particle is given as .
Calculate the net force acting on the body at time t = 1 sec, if the mass of the body is 10 kg.

(A) 15 N
(B) 20 N
(C) 25 N
(D) 50 N

6) The minimum value of y = 4x2 – 16x + 9 is :

(A) 7
(B) 0
(C) 2
(D) –7

7) =

(A) 4 cos 3x
(B) 12 sin 3x
(C) 3 cos 3x
(D) 12 cos 3x

8) Which of the following graph can represent the equation y = –3x2 + 5:-

(A)

(B)

(C)
(D)

9)

Value of (sin 15° – cos 15°)2 is:-

(A)

(B)

(C) 1

(D)

10)

Equation for the straight line shown in the figure is:-

(A) ν = – t – 2
(B) ν = t – 2
(C) ν = t + 2
(D) ν = – t + 2

11) Two curves y = x2 and y = x are drawn as shown. Then

(A) Two curves intersects at x = 2

(B) Two curves intersects at x = 3
(C) Area of shaded portion is 5/6
(D) Area of shaded portion is 1/6

12) The maximum value of magnitude of is :

(A) A – B
(B) A
(C) A + B

(D)

13) A particle is moving westward with a velocity = 5 m/s. Its velocity changed to = 5 m/s

northward. The change in velocity vector is :

(A) m/s towards north east

(B) 5 m/s towards north west
(C) zero
(D) m/s towards north west

14) Given, The value of P2 + Q2 is

(A) 2(A2 + B2)

(B) A2 – B2
(C) A2 + B2
(D) 2(A2 – B2)

15) The x coordinate of an object is given as a function of time by x = 4t2 – 3t3, where x is in meters
and t is in seconds. Its average acceleration over the time interval from t = 0 to t = 2s is

(A) – 4 m/s2
(B) 10 m/s2
(C) – 10 m/s2
(D) – 13 m/s2

16) The relation between time t and distance x is given as t = αx2 + βx where α and β are constant.
The retardation will be :

(A) 2αv3
(B) 2βv3
(C) 2αβv3
(D) 2β2v3

17) Position vector of a particle is given by , t is time and r0 and a are constants. The
velocity of particle when it returns to starting point :-

(A)
(B)
(C)
(D)

18) A particle moving along x-axis has acceleration f, at time t, given by , where and
T are constants. The particle at t = 0 has zero velocity. At the instant when f = 0, the particles
velocity is:-

(A)

(B)

(C)

(D)

19) In 1.0 s, a particle goes from point A to point B, moving in a semicircle of radius 1.0 m (see

figure). The magnitude of the average velocity is

(A) 3.14 m/s

(B) 2.0 m/s
(C) 1.0 m/s
(D) Zero

20) Which of the following speed-time (v-t) graphs is physically not possible ?

(A)

(B)

(C)

(D) all of these

SECTION - II
1) How many minimum number of coplanar vectors having different magnitudes can be added to
give zero resultant:-

2) A stone dropped from the top of a tower travels part of height of tower during the last second
of fall. If height of tower is 5Z, find Z. (g = 10 m/s2)

3) A particle starts its motion with the velocity of 1.5 m/s. Its (a – t) graph is given below. Find its

velocity (in m/s) at t = 0.5s .

4) A stone is dropped from a height h = 80 m Simultaneously another stone is thrown up from the
ground with such a velocity so that it can reach a height of 4h. Find the time (in sec.) when two
stones crosses each other.

5) A particle is thrown upwards from ground. It experiences a constant air resistance which can
produce a retardation of 2 m/s2 opposite to the direction of velocity of particle. The ratio of time of

ascent to the time of descent is . Where α and β are integers. Find minimum value of α + β [g =
10 m/s2]

CHEMISTRY

SECTION - I

1) The electronic configuration of the element which is just above the element with atomic number
43 in the same periodic group is :-

(A) 1s2,2s2 2p6, 3s2 3p6 3d5, 4s2

(B) 1s2,2s2 2p6, 3s2 3p6 3d10, 4s2 4p5
(C) 1s2,2s2 2p6, 3s2 3p6 3d6, 4s1
(D) 1s2,2s2 2p6, 3s2 3p6 3d10, 4s1 4p6

2) 4th shell of atom contains 4s, 4p, 4d and 4f subshell, which subshells are not filled in any 4th
period element :-

(A) 4p, 4d, 4f

(B) 4s, 4p
(C) 4p, 4f
(D) 4d, 4f

3) How many g subshells will be required in case element Uuo is discovered :-

(A) 1
(B) 2
(C) 3
(D) None

4) Any p-orbital can accomodate up to

(A) four electrons

(B) Two electrons in parallel spin
(C) Six electrons
(D) Two electrons with opposite spin

5) If atomic numbers 117, 120 are discovered then their blocks will be :

(A) s, p
(B) p, s
(C) p, d
(D) d, p

6) Correct set of four quantum numbers for valence electron of rubidium

(A) 5, 0, 0, +1/2
(B) 5, 1, 0, +1/2
(C) 5, 1, 1, +1/2
(D) 6, 0, 0, +1/2

7)

Find the sum of maximum number of electrons having +1 and –1 value of ‘m’ in Ti

(A) 6
(B) 8
(C) 10
(D) 12

8) The screening effect of d-electrons is :-

(A) much less than s-electrons

(B) much more than s-electrons
(C) equal to s-electrons
(D) equal to p-electrons
9) If Zeff of sodium is 'x' then Zeff of magnesium is :-

(A) x + 0.35
(B) x + 0.65
(C) x – 0.35
(D) x – 0.65

10) In the isoelectronic species, the ionic radii (Å) of N3–, Ne and Al3+ are respectively given by :-

(A) 1.36, 1.40, 1.71

(B) 1.36, 1.71, 1.40
(C) 1.71, 1.40, 1.36
(D) 1.71, 1.36, 1.40

11) The X–X bond length is 1.00 Å amd C–C bond length is 1.54 Å. If electronegativities of 'X' and 'C'
are 3.0 and 2.0 respectively, the C–X bond length is likely to be :-

(A) 1.27 Å
(B) 1.18 Å
(C) 1.08 Å
(D) 1.28 Å

12) Select correct diagram about the size of isoelectronic ions :-

(A)

(B)

(C)

(D)

13) Lanthanoid contraction will not have any influence when we compare size of :-
(A) Zr & Hf
(B) Y & La
(C) Mo & W
(D) Tc & Re

14) The correct order of increasing order of size is

(A) S < O < Se < C

(B) O < C < S < Se
(C) O < Se < S < C
(D) C < O < S < Se

15) Amongst the following elements, the highest I.E. is :-

(A) [Ne] 3s2 3p1

(B) [Ne] 3s2 3p3
(C) [Ne] 3s2 3p2
(D) [Ar] 3d10 4s2 4p3

16) Eka-aluminium and eka-silicon are known as :-

(A) aluminium and silicon

(B) gallium and germanium
(C) scandium and titanium
(D) stable isotopes of aluminium and silicon

17) Diagonal relationship in periodic table is shown by elements of .... and .. periods :-

(A) I and II
(B) II and III
(C) III and IV
(D) I and III

18) The successive ionisation energies (in eV/atom) of an element 'X' are 5.98, 18.82, 28.45, 119.99,
153.82, 190.49 and 241.76 respectively. The element 'X' is likely to be :

(A) Be
(B) Li
(C) Na
(D) Al

19) Which of the following configurations represents atoms of element having a large difference
between first and the second ionisation energy ?

(A) 1s2, 2s2 2p4

(B) 1s2, 2s2 2p6
(C) 1s2, 2s22p6, 3s1
(D) 1s2, 2s22p6,3s2

20) In which case, the energy is not released ?

(A) Cl → Cl–
(B) P → P–
(C) N → N–
(D) C → C–

SECTION - II

1) If each orbital can hold a maximum of three electrons, the number of elements in 9th period of
periodic table (long form) will be :

2) Find the total number of correct orders for the property indicated against them
(i) P > S > F (atomic radius)
(ii) Na > S > N (total number of electron in outermost shell)
(iii) Na < Mg < Ca (Zeff value on last electron)
(iv) s-block < d-block < p-block (total number of non-metal elements)

3) An element has atomic number 29. It belongs to x period and y group. Give value of 2x + y.

4)

Size of H¯ is larger than how many of the elements among these ?

H, Li, Be, B, C, N, O, F, F¯

5) Ionization energy = 201 kJ/mol

Ionization energy = 440 kJ/mol

Ionization energy = 700 kJ/mol

If the difference between IE3 – IE2 is X, then the value of is :-

MATHEMATICS

SECTION - I

1) If a = x + , then x3 + x–3 =

(A) a3 + 3a
(B) a3 – 3a
(C) a3 + 3
(D) a3 – 3

2)

If , then all possible values of x are

(A) –2, 2
(B) ,
(C) 2,
(D)

3) How many integers in between 100 to 1500 (both inclusive) are multiples of 5 or 11?

(A) 408
(B) 26
(C) 382
(D) 380

4) If ,
then number of possible integral values of x is

(A) 6
(B) 3
(C) 4
(D) 5

5) If x2 + y2 + 4z2 – 6x – 2y – 4z + 11 = 0, then xyz is equal to -

(A) 3/2
(B) 4
(C) 6
(D) 3

6) If , then the value of a + b + c (where a, b, c ∈ N and are relatively prime)

(A) 70
(B) 72
(C) 50
(D) 40

7) Consider a function f(x) such that

 then the value of f(2) is equal to

(A) 2
(B) 1
(C)
(D)

8) The number of real solutions of the equation |x|2 – 3|x| + 2 = 0 is -

(A) 4
(B) 1
(C) 2
(D) 3

9) If then the value of expression

(A) 4
(B) 5
(C) 3
(D) 10

10) Sum of the solutions of the equation is

(A) 10
(B) 11
(C) 12
(D) 13

11) Number of values of x that satisfy ||x - 1| - 5| = 3 is

(A) 1
(B) 2
(C) 3
(D) 4

12) Number of solutions of equation |x – 3| + 2|x + 1| = 4 is

(A) 0
(B) 1
(C) 2
(D) Infinite

13) The value of is

(A) 1
(B) 3
(C) 10
(D) 25

14) Let α and β are roots of equation x2 – 13x + 3 = 0, then value of α + β, are respectively :

(A)

(B)

(C)

(D)

15) For the equation 3x2 + px + 3 = 0, p > 0 if one of the roots is square of the other, then p is equal
to:

(A) 1/3
(B) 1
(C) 3
(D) 2/3

16) Let a and b be real numbers such that 4a + 2b + c = 0 and ab > 0. Then the equation ax2 + bx +
c = 0 has

(A) real roots

(B) imaginary roots
(C) exactly one root
(D) none of these

17) Let α and β be the roots of x2 – 3x + 1 = 0. Find a quadratic equation whose roots are and

(A) y2 + 4y + 1 = 0
(B) y2 + 4y – 1 = 0
(C) y2 – 4y – 1 = 0
(D) y2 – 14y + 1 = 0

18) If the roots of the equation x2 – 6x + 7 = 0 are α and β then the value of (α4 + β4) is equal to

(A) 286
(B) 386
(C) 486
(D) 586

19) If one root of the equation x2 + px + 12 = 0 is 4, while the equation x2 + px + q = 0 has equal
roots, then the value of q is -

(A)

(B) 2
(C) 3
(D) 12

20) If , then the set of values of x is :

(A) (–∞, 1) ∪ (2, ∞)

(B) (–∞, 0) ∪ (1, ∞)
(C) (–∞, 3)
(D) [–3, –2) ∪ [2, 3]

SECTION - II

1) If the sum of roots of the equation x4 – 8x2 – 9 = 0 is a then find (a2 + 9).

2) Find sum of square of real roots of equation x (x + 1) (x + 2) (x + 3) = 120

3) If roots of quadratic equation (b – c)x2 + (c – a)x + (a – b)d = 0 are equal, then 4b – 2a – 2c is

equal to

4) If (k – 2)x2 + 2x + 5 = 0 and roots are reciprocal of each other then value of k is

5) If α and β are roots of the equation x2 – 5x + 1 = 0 and an = αn + βn – 1, then value of is

 ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D C A D D D B A B D C A A C A B A B D

SECTION - II

Q. 21 22 23 24 25
A. 3.00 9.00 4.00 1.00 5.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A D D D B A C A B C B A B B B B B D C C

SECTION - II

Q. 46 47 48 49 50
A. 75.00 1.00 19.00 9.00 3.00

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D C D A B A A B B D B A A C A C B A B

SECTION - II

Q. 71 72 73 74 75
A. 9.00 29.00 0.00 7.00 4.80
 SOLUTIONS

PHYSICS

1)

3) area =

4) ⇒

5)

2
v = t + 2t
a = 2t + 2 + 1/t2
at t = 1, a = 5 m/s2
F = ma = 50 N

7) =
= 4 × 3 cos 3x = 12 cos 3x

14) According to the question, representation of vectors A and B can be shown as follows
 Given |A + B| = P
|A + B|2 = P2
P2 = A2 + B2 + 2AB cosθ ...(i)
Also, |A – B| = Q |A – B|2 = Q2
A + B + 2AB cos (180° – θ) = Q2
2 2

A2 + B2 – 2AB cosθ = Q2 ...(ii)

Adding Eqs. (i) and (ii), we get
P2 + Q2 = 2(A2 + B2)

15)

v= = 8t – 9t2
∴ Δv = (16 – 36) – (0) = – 20

∴ aavg =

16)

t = ax2 + bx
Differentiate w.r.t. time

1 = 2αxv + βv
DIfferentiate again

0 = a (2αx + β) + 2αv2

a = –2αv3

17) ⇒t=

∴ = = =

19) Average velocity =

= = 2 m/s .

20)

Speed cannot be negative

22)

.....(i)

.....(ii)
Now,
V2 = V1 + gt

h = 45 m
5z = 45
z=9

24)
 25)

Let a be the retardation produced by resistive force, ta and td be the time of ascent and time of
descent respectively.
If the particle rises upto a height h
By 3rd equation of motion
Initial velocity, …..(1)
and final velocity at the end of the motion …..(2)

by 1st equation of motion and …..(3)

from (1), (2) and (3)

∴ = = =

Ans.

CHEMISTRY

27) 4s → 3d → 4p orbitals are actually filled

32)

Ti = 1s2 2s2 2p6 3s2 3p6 4s2 3d2

So total electrons = 10

34)

35) Size of isoelectronic species N3– > Ne > Al3+

36) dC–X = (rC + rX) – 0.09 (ΔE.N.)

= – (0.09 × 1)
= (0.77 + 0.5) – (0.09) = 1.18 Å

37) Size of isoelectronic ions = P3– > Cl– > K+ > Ca2+
 40)

45) N(g) + e– → N–(g) ; ΔH = +ve

49)

H– is exceptionally very big (comparable to the size of Br atom)

So, all given elements are smaller than H–.

50) I.E1 = 201 kJ/ mol

I.E2 = 440 – 201 = 239 kJ/ mol
I.E3 = 700 – I.E1 – I.E2
= 700 – 201 – 239
= 260 kJ/ mol
IE3 – IE2 (X) = 260 – 239 = 21 kJ/mol

= =3

MATHEMATICS

51)

52)

Let then

∴
⇒ x2 = 4 or x2 = 2
⇒x= or ±2

53) A : Multiple of 5.
A : 100,105,110,....,1495,1500 ⇒ n(A) = 281.
B : Multiple of 11.
B : 110,121,...., ⇒ n(B) = 127.
A ∩ B : Multiple of 55.
A ∩ B : 110, 165,......... ⇒ n(A ∩ B) = 26
∴ Required no. of integers = n(A ∪ B).
= n(A) + n(B) – n(A ∩ B) = 382.

54)

⇒ Number of integers = 5.

55) x2 + y2 + 4z2 – 6x – 2y – 4z + 11 = 0
⇒ x2 – 6x + 9 + y2 – 2y + 1 + 4z2 – 4z + 1 = 0
⇒(x – 3)2 + (y – 1)2 + (2z – 1)2 = 0

⇒ x = 3 , y = 1,

56)

⇒ a + b + c = 72

58)

|x|2 – 3|x| + 2 = 0
⇒ |x| = 1 or |x| = 2 ⇒ x = {±1, ±2}

61) |x - 1| - 5 = 3, - 3
|x - 1| = 8, 2
x - 1 = 8, x - 1 = 2
x = 9, - 7, 3, -1

62) |x – 3| + 2|x + 1| = 4
if x < –1 ⇒ –3x = 3 ⇒ x = –1
if –1 ≤ x < 3 ⇒ x = –1
if x ≥ 3 ⇒ rejected.
⇒ x = –1 only solution.

63)

Hence

64) α + β = 13, αβ = 3

69) 16 + 4p + 12 = 0 ⇒ p = –7

p2 = 4q ⇒ q =

75) α + β = 5 ; αβ = 1
α2 + β2 = (α + β)2 – 2αβ
α2 + β2 = 23
a1 = α + β – 1
a1 = 4