DISCLEAN

Wilhelmsen Ships Service AS

Part Number: 571687 Issue Date: 04/01/2022
Version No: 12.16 Print Date: 18/10/2023
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) [Link]

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Product name DISCLEAN

Chemical Name Not Applicable

Synonyms Product Part Number: 571687 (25 liter)
Proper shipping name PHOSPHORIC ACID, SOLUTION
Chemical formula Not Applicable
Other means of
571687
identification

1.2. Relevant identified uses of the substance or mixture and uses advised against
Chemical Product
PC35 Washing and cleaning products
Category

Sectors of Use SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites

Relevant identified uses Use according to manufacturer's directions.

Uses advised against No specific uses advised against are identified.

1.3. Details of the manufacturer or supplier of the safety data sheet

Outback (M)SDS portal:
Wilhelmsen Ships Service AS*
Registered company name Wilhelmsen Ships Service AS [Link]
Central Warehouse
/autologin?login=wilhelmsen
--------Use our Outback portal to obtain our
(M)SDSs in other languages and/or
Strandveien 20 Lysaker 1366 format.--------- For questions relating to our Willem Barentszstraat 50 Rotterdam
Address
Norway SDSs please use Email: Netherlands
[Link]@[Link]
--------- Norway

Telephone +47 67 58 40 00 Not Available +31 10 4877 777

Fax Not Available Not Available Not Available
Website [Link] [Link] [Link]
Email [Link]@[Link] [Link]@[Link] [Link]@[Link]

Registered company name Wilhelmsen Ships Service AS* Central Warehouse

Address Willem Barentszstraat 50 Rotterdam Netherlands
Telephone +31 10 4877 777
Fax Not Available
Website [Link]
Email [Link]@[Link]

1.4. Emergency telephone number

Page 1 continued...
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Association / Organisation Giftinformasjonssentralen - 24 timer 24hrs - Chemwatch Dutch nat. poison centre
Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers

Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Association / Organisation Dutch nat. poison centre CHEMWATCH EMERGENCY RESPONSE (24/7)

Emergency telephone
+ 31 30 274 88 88 +47 23 25 25 84
numbers

Other emergency
+ 31-10-4877700 +61 3 9573 3188
telephone numbers

Once connected and if the message is not in your preferred language then please dial 01

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Classified as Dangerous Goods for
transport purposes.

Classification according to
regulation (EC) No
H314 - Skin Corrosion/Irritation Category 1B, H290 - Corrosive to Metals Category 1, H302 - Acute Toxicity (Oral) Category 4
1272/2008 [CLP] and
amendments [1]

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

2.2. Label elements

Hazard pictogram(s)

Signal word Danger

Hazard statement(s)
H314 Causes severe skin burns and eye damage.
H290 May be corrosive to metals.
H302 Harmful if swallowed.

Supplementary statement(s)
Not Applicable

CLP classification (additional)

Not Applicable

Precautionary statement(s) Prevention

P260 Do not breathe mist/vapours/spray.
P264 Wash all exposed external body areas thoroughly after handling.
P280 Wear protective gloves, protective clothing, eye protection and face protection.

Precautionary statement(s) Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If more than 15 mins from Doctor, INDUCE VOMITING (if conscious).
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Precautionary statement(s) Storage

P405 Store locked up.
Continued...
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DISCLEAN

2.3. Other hazards

Skin contact may produce health damage*.

Cumulative effects may result following exposure*.

2-(2-butoksyethoxy)ethanol Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply)

SECTION 3 Composition / information on ingredients

[Link]
See 'Composition on ingredients' in Section 3.2

[Link]
1. CAS No Classification according to
[Link] No regulation (EC) No Nanoform Particle
%[weight] Name SCL / M-Factor
[Link] No 1272/2008 [CLP] and Characteristics
[Link] No amendments

Skin Corr. 1B; H314: C ≥

1. 7664-38-2
25 % | Skin Irrit. 2; H315:
2.231-633-2 Skin Corrosion/Irritation
30-60 phosphoric acid * 10 % ≤ C < 25 % | Eye Not Available
3.015-011-00-6 Category 1B; H314 [2]
Irrit. 2; H319: 10 % ≤ C <
[Link] Available
25 %
1. 112-34-5*
2.203-961-6 2-(2-butoksyethoxy)ethanol Serious Eye Damage/Eye
1-5 *
Not Available Not Available
3.603-096-00-8 Irritation Category 2; H319 [1]
[Link] Available

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

SECTION 4 First aid measures

4.1. Description of first aid measures

If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

If skin or hair contact occurs:

Immediately flush body and clothes with large amounts of water, using safety shower if available.
Skin Contact Quickly remove all contaminated clothing, including footwear.
Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
Transport to hospital, or doctor.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
Inhalation procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor, without delay.

IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.

For advice, contact a Poisons Information Centre or a doctor.
Urgent hospital treatment is likely to be needed.
In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive
measures as indicated by the patient's condition.
If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a
copy of the SDS should be provided. Further action will be the responsibility of the medical specialist.
If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the
Ingestion SDS.

Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or
unless instructed otherwise:
INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side
(head-down position, if possible) to maintain open airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.

Continued...
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See Section 11

4.3. Indication of any immediate medical attention and special treatment needed
for phosphate salts intoxication:
All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure
to materials other than this product may have occurred.
Ingestion of large quantities of phosphate salts (over 1.0 grams for an adult) may cause an osmotic catharsis resulting in diarrhoea and probable abdominal
cramps. Larger doses such as 4-8 grams will almost certainly cause these effects in everyone. In healthy individuals most of the ingested salt will be excreted
in the faeces with the diarrhoea and, thus, not cause any systemic toxicity. Doses greater than 10 grams hypothetically may cause systemic toxicity.
Treatment should take into consideration both anionic and cation portion of the molecule.
All phosphate salts, except calcium salts, have a hypothetical risk of hypocalcaemia, so calcium levels should be monitored.
For acute or short term repeated exposures to strong acids:
Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.
Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling
Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.
Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in
specific tissues.
INGESTION:
Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.
DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury.
Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult.
Charcoal has no place in acid management.
Some authors suggest the use of lavage within 1 hour of ingestion.
SKIN:
Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping.
Deep second-degree burns may benefit from topical silver sulfadiazine.
EYE:
Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT
use neutralising agents or any other additives. Several litres of saline are required.
Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears
may be indicated dependent on the severity of the injury.
Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).

[Ellenhorn and Barceloux: Medical Toxicology]

SECTION 5 Firefighting measures

5.1. Extinguishing media

Water spray or fog.
Foam.
Dry chemical powder.

5.2. Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

5.3. Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Fire Fighting Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.

Non combustible.
Not considered to be a significant fire risk.
Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.
Fire/Explosion Hazard Decomposition may produce toxic fumes of:
,
phosphorus oxides (POx)
May emit poisonous fumes.

SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See section 8

6.2. Environmental precautions

See section 12

Continued...
6.3. Methods and material for containment and cleaning up
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Avoid breathing vapours and contact with skin and eyes.

Control personal contact with the substance, by using protective equipment.
Environmental hazard - contain spillage.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Chemical Class:acidic compounds, inorganic
For release onto land: recommended sorbents listed in order of priority.

SORBENT
RANK APPLICATION COLLECTION LIMITATIONS
TYPE

LAND SPILL - SMALL

foamed glass - pillows 1 throw pitchfork R, P, DGC, RT

expanded mineral - particulate 2 shovel shovel R, I, W, P, DGC

foamed glass - particulate 2 shovel shovel R, W, P, DGC

Major Spills LAND SPILL - MEDIUM

expanded mineral -particulate 1 blower skiploader R, I, W, P, DGC

foamed glass- particulate 2 blower skiploader R, W, P, DGC

foamed glass - particulate 3 throw skiploader R, W, P, DGC

Legend
DGC: Not effective where ground cover is dense
R; Not reusable
I: Not incinerable
P: Effectiveness reduced when rainy
RT:Not effective where terrain is rugged
SS: Not for use within environmentally sensitive sites
W: Effectiveness reduced when windy
Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;
R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988

6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

7.1. Precautions for safe handling

Avoid all personal contact, including inhalation.
Safe handling Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.

Fire and explosion

See section 5
protection

Store in original containers.

Other information Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.

7.2. Conditions for safe storage, including any incompatibilities

DO NOT use aluminium or galvanised containers
Lined metal can, lined metal pail/ can.
Plastic pail.
Polyliner drum.
For low viscosity materials
Suitable container Drums and jerricans must be of the non-removable head type.
Where a can is to be used as an inner package, the can must have a screwed enclosure.
For materials with a viscosity of at least 2680 cSt.

All inner and sole packagings for substances that have been assigned to Packaging Groups I or II on the basis of inhalation
toxicity criteria, must be hermetically sealed.

Phosphoric acid:
is a medium-strong acid which produces violent reaction with bases
may produce violent react when water is added to the concentrated form
reacts violently with solutions containing ammonia or bleach, azo compounds, epoxides and other polymerisable compounds
reacts, possibly violently with amines, aldehydes, alkanolamines, alcohols, alkylene oxides, amides, ammonia, ammonia
Storage incompatibility hydroxide, calcium oxide, cyanides, epichlorohydrin, esters, halogenated organics, isocyanates, ketones, oleum, organic
anhydrides, sodium tetraborate, sulfides, sulfuric acid, strong oxidisers, vinyl acetate
forms explosive mixtures with nitromethane Continued...
at elevated temperatures attacks many metals producing hydrogen gas
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Inorganic acids are generally soluble in water with the release of hydrogen ions. The resulting solutions have pH's of less
than 7.0.
Inorganic acids neutralise chemical bases (for example: amines and inorganic hydroxides) to form salts - neutralisation can
generate dangerously large amounts of heat in small spaces.
Reacts vigorously with alkalis
Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may form an explosive mixture with air.
Phosphates are incompatible with oxidising and reducing agents.
Phosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing
agents such as hydrides.
Partial oxidation of phosphates by oxidizing agents may result in the release of toxic phosphorus oxides.
Hazard categories in
accordance with
Not Available
Regulation (EC) No
1272/2008

Qualifying quantity
(tonnes) of dangerous
substances as referred to Not Available
in Article 3(10) for the
application of

+ x o x + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.

7.3. Specific end use(s)

See section 1.2

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
Dermal 2.33 mg/kg bw/day (Systemic, Chronic)
Inhalation 8.23 mg/m³ (Systemic, Chronic)
Inhalation 1 mg/m³ (Local, Chronic)
Dermal 134.5 mg/kg bw/day (Systemic, Acute)
Inhalation 948.6 mg/m³ (Systemic, Acute)
Inhalation 1 mg/m³ (Local, Acute)
Dermal 1.9 mg/kg bw/day (Systemic, Chronic) *
phosphoric acid Not Available
Inhalation 3.3 mg/m³ (Systemic, Chronic) *
Oral 0.1 mg/kg bw/day (Systemic, Chronic) *
Inhalation 0.36 mg/m³ (Local, Chronic) *
Dermal 67.3 mg/kg bw/day (Systemic, Acute) *
Inhalation 233.9 mg/m³ (Systemic, Acute) *
Oral 67.3 mg/kg bw/day (Systemic, Acute) *
Inhalation 1 mg/m³ (Local, Acute) *

Dermal 24.5 mg/kg bw/day (Systemic, Chronic) 1.1 mg/L (Water (Fresh))
Inhalation 8.64 mg/m³ (Systemic, Chronic) 11 mg/L (Water - Intermittent release)
Inhalation 67.5 mg/m³ (Local, Chronic) 0.11 mg/L (Water (Marine))
2-(2-butoksyethoxy)ethanol Inhalation 101.2 mg/m³ (Local, Acute) 4.4 mg/kg sediment dw (Sediment (Fresh Water))
Dermal 8.75 mg/kg bw/day (Systemic, Chronic) * 0.44 mg/kg sediment dw (Sediment (Marine))
Inhalation 1.52 mg/m³ (Systemic, Chronic) * 0.32 mg/kg soil dw (Soil)
Oral 0.875 mg/kg bw/day (Systemic, Chronic) * 56 mg/kg food (Oral)

* Values for General Population

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

EU Consolidated List of
Continued...
Indicative Occupational Not Not
phosphoric acid Ortophosphoric acid 1 mg/m3 2 mg/m3
Exposure Limit Values Available Available
Part Number: 571687 Page 7 of 15 Issue Date: 04/01/2022
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Source Ingredient Material name TWA STEL Peak Notes

Norway regulations on action
rvalues o​ a nd limitf values ​
physical and chemical
Not
factors in the work phosphoric acid Fosforsyre 1 mg/m3 Not Available E
Available
environment and infection
risk groups for biological
factors (Norwegian)

EU Consolidated List of
Indicative Occupational 2-(2-Butoxyethoxy) 10 ppm / 67.5 101.2 mg/m3 / Not Not
2-(2-butoksyethoxy)ethanol
Exposure Limit Values ethanol mg/m3 15 ppm Available Available
(IOELVs)
Norway regulations on action
rvalues o​ a nd limitf values ​
physical and chemical
10 ppm / 68 Not
factors in the work 2-(2-butoksyethoxy)ethanol 2-2(butoksyetoksy)etanol Not Available E
mg/m3 Available
environment and infection
risk groups for biological
factors (Norwegian)

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

phosphoric acid Not Available Not Available Not Available

2-(2-butoksyethoxy)ethanol 30 ppm 33 ppm 200 ppm

Ingredient Original IDLH Revised IDLH

phosphoric acid 1,000 mg/m3 Not Available
2-(2-butoksyethoxy)ethanol Not Available Not Available

MATERIAL DATA
The saturated vapour concentration of phosphoric acid exceeds the TLV. The TLV-TWA is based by analogy from comparable experience and data for sulfuric
acid. Exposure at or below this limit is thought to prevent throat irritation amongst unacclimatised workers.

8.2. Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
8.2.1. Appropriate
provide this high level of protection.
engineering controls
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.

8.2.2. Individual protection

measures, such as
personal protective
equipment

Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]

Eye and face protection Full face shield may be required for supplementary but never for primary protection of eyes.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants.

Skin protection See Hand protection below

Wear chemical protective gloves, e.g. PVC.

Hands/feet protection Wear safety footwear or safety gumboots, e.g. Rubber
When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.

Body protection See Other protection below

Overalls.
Other protection Eyewash unit.
Barrier cream.

Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computer-generated selection:
DISCLEAN

Material CPI
NAT+NEOPR+NITRILE A Continued...
NATURAL RUBBER A
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NEOPRENE A
NEOPRENE/NATURAL A

NITRILE A
NITRILE+PVC A

PE A
PVC A

SARANEX-23 A

* CPI - Chemwatch Performance Index

A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of
gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

8.2.3. Environmental exposure controls

See section 12

SECTION 9 Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Yellow

Relative density (Water =

Physical state Liquid 1.255-1.275
1)
Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) Not Applicable Not Available
temperature (°C)

Melting point / freezing

Not Available Viscosity (cSt) Not Available
point (°C)

Initial boiling point and

>100-760 Molecular weight (g/mol) Not Available
boiling range (°C)

Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available BuAC = 1 Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Surface Tension (dyn/cm

Upper Explosive Limit (%) Not Available Not Available
or mN/m)

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Miscible pH as a solution (1%) 2

Vapour density (Air = 1) Not Available VOC g/L Not Available

Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics

Particle Size Not Available

9.2. Other information

Not Available

SECTION 10 Stability and reactivity

[Link] See section 7.2

Unstable in the presence of incompatible materials.

10.2. Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
10.3. Possibility of
See section 7.2 Continued...
hazardous reactions
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10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products

SECTION 11 Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may produce severely toxic
effects. Relatively small amounts absorbed from the lungs may prove fatal.
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial
number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first
removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect
mammalian lungs from foreign matter and antigens, may however, produce further lung damage resulting in the impairment of
gas exchange, the primary function of the lungs.

Inhaled Strong evidence exists that exposure to the material may produce serious irreversible damage (other than carcinogenesis,
mutagenesis and teratogenesis) following a single exposure by inhalation.

Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage. Symptoms of
exposure may include dizziness, headache, nausea and weakness. In more severe exposures, pulmonary oedema may be
evident either immediately or after a latent period of 5-72 hours.
Inhalation of phosphoric acid vapour or mist may cause choking, coughing, headache, weakness and dizziness. Prolonged or
repeated inhalation of vapour or mist may cause pulmonary oedema (lung damage) and cyanosis
Exposure to high concentrations causes bronchitis and is characterised by the onset of haemorrhagic pulmonary oedema.
The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.
Strong evidence exists that exposure to the material may produce serious irreversible damage (other than carcinogenesis,
mutagenesis and teratogenesis) following a single exposure by swallowing.
The material is not thought to produce adverse health effects following ingestion (as classified by EC Directives using animal
models). Nevertheless, adverse systemic effects have been produced following exposure of animals by at least one other route
and good hygiene practice requires that exposure be kept to a minimum.

Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous membranes of the
mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident. Oedema of the
epiglottis may produce respiratory distress and possibly, asphyxia.
Ingestion
Phosphates are slowly and incompletely absorbed from the gastrointestinal tract and are unlikely (other than in abuse) to
produce the systemic effects which occur when introduced by other routes. Such effects include vomiting, lethargy, fever,
diarrhoea, falls in blood pressure, slow pulse, cyanosis, carpal spasm, coma and tetany. These effects result following
sequestration of blood calcium.
Ingestion of large quantity of phosphoric acid may cause severe abdominal pains, thirst, acidaemia, difficult breathing,
convulsions, collapse, shock and death.
Although less hazardous than nitric and sulfuric acid, phosphoric acid has equal corrosive action upon ingestion. Death of an
individual 19 days after ingestion of phosphoric acid was due to recurrent internal haemorrhage.
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be
fatal or may produce serious damage to the health of the individual.
Skin contact with the material may be harmful; systemic effects may result following absorption.
The material can produce chemical burns following direct contact with the skin.

Strong evidence exists that exposure to the material may produce serious irreversible damage (other than carcinogenesis,
mutagenesis and teratogenesis) following a single exposure by skin contact.
Skin Contact
Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with
the formation of scar tissue.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

The material can produce chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.
Irritation of the eyes may produce a heavy secretion of tears (lachrymation).
Eye
Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the epithelia
generally recover rapidly and completely. Severe burns produce long-lasting and possible irreversible damage.
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic
problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving
organs or biochemical systems.
Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth
Chronic and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Gastrointestinal disturbances may also occur.
Dogs given daily doses of sodium phosphate dibasic for 9-22 weeks showed calcium deposits in the kidneys (nephrocalcinosis)
with disseminated atrophy of the proximal tubule. Animals fed on sodium phosphate dibasic and potassium dihydrogen
phosphate, in both short- and long-term studies, showed increased bone porosity; hyperparathyroidism and soft tissue
calcification were also evident. Continued...
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Not Available Not Available

TOXICITY IRRITATION
Dermal (rabbit) LD50: >1260 mg/kg[2] Eye (rabbit): 119 mg - SEVERE [Monsanto]*

phosphoric acid Inhalation(Rat) LC50: 0.026 mg/L4h[2] Eye: adverse effect observed (irritating)[1]

Oral (Rat) LD50: 1530 mg/kg[2] Skin (rabbit):595 mg/24h - SEVERE

Skin: adverse effect observed (corrosive)[1]

TOXICITY IRRITATION

2-(2-butoksyethoxy)ethanol Dermal (rabbit) LD50: 4120 mg/kg[2] Eye (rabbit): 20 mg/24h moderate

Oral (Rat) LD50: 5660 mg/kg[2] Eye (rabbit): 5 mg - SEVERE

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

phosphoric acid ( 85%) No significant acute toxicological data identified in literature search.
The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis
PHOSPHORIC ACID (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.
Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
Prolonged contact is unlikely, given the severity of response, but repeated exposures may produce severe ulceration.

For diethylene glycol monoalkyl ethers and their acetates:

This category includes diethylene glycol ethyl ether (DGEE), diethylene glycol propyl ether (DGPE) diethylene glycol butyl ether
(DGBE) and diethylene glycol hexyl ether (DGHE) and their acetates.
2-(2-butoksyethoxy)ethanol Acute toxicity: There are adequate oral, inhalation and/or dermal toxicity studies on the category members. Oral LD50 values in
rats for all category members are all > 3000 mg/kg bw, with values generally decreasing with increasing molecular weight. Four
to eight hour acute inhalation toxicity studies were conducted for all category members except DGPE in rats at the highest
vapour concentrations achievable.
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a
non-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
DISCLEAN & irritant.
PHOSPHORIC ACID for acid mists, aerosols, vapours
Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when the pH falls
to about 6.5. Cells from the respiratory tract have not been examined in this respect. Mucous secretion may protect the cells of
the airways from direct exposure to inhaled acidic mists, just as mucous plays an important role in protecting the gastric
epithelium from its auto-secreted hydrochloric acid.

PHOSPHORIC ACID &

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
2-(2-butoksyethoxy)ethanol
irritants may produce conjunctivitis.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

11.2 Information on other hazards

11.2.1. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

11.2.2. Other information

See Section 11.1

SECTION 12 Ecological information

12.1. Toxicity

Endpoint Test Duration (hr) Species Value

Continued...
Source
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Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants 77.9mg/l 2

phosphoric acid EC50 48h Crustacea >100mg/l 2

LC50 96h Fish 67.94-113.76mg/L 4

NOEC(ECx) 72h Algae or other aquatic plants <7.5mg/l 2

Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants 1101mg/l 2

EC50 48h Crustacea >100mg/l 1

2-(2-butoksyethoxy)ethanol
EC50 96h Algae or other aquatic plants >100mg/l 1
LC50 96h Fish 1300mg/l 2

NOEC(ECx) 96h Algae or other aquatic plants >=100mg/l 1

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

On the basis of available evidence concerning either toxicity, persistence, potential to accumulate and or observed environmental fate and behaviour, the material
may present a danger, immediate or long-term and /or delayed, to the structure and/ or functioning of natural ecosystems.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning
equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
Ecotoxicity:
The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines are between
6.0 and almost 9. Acute testing with fish showed 96h-LC50 at about pH 3.5
For Phosphate: The principal problems of phosphate contamination of the environment relates to eutrophication processes in lakes and ponds. Phosphorus is an
essential plant nutrient and is usually the limiting nutrient for blue-green algae.
Aquatic Fate: Lakes overloaded with phosphates is the primary catalyst for the rapid growth of algae in surface waters.
DO NOT discharge into sewer or waterways.

12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
phosphoric acid HIGH HIGH

2-(2-butoksyethoxy)ethanol LOW LOW

12.3. Bioaccumulative potential

Ingredient Bioaccumulation
phosphoric acid LOW (LogKOW = -0.7699)

2-(2-butoksyethoxy)ethanol LOW (BCF = 0.46)

12.4. Mobility in soil

Ingredient Mobility
phosphoric acid HIGH (KOC = 1)

2-(2-butoksyethoxy)ethanol LOW (KOC = 10)

12.5. Results of PBT and vPvB assessment

P B T

Relevant available data Not Available Not Available Not Available

PBT

vPvB

PBT Criteria fulfilled? No

vPvB No

12.6. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.
Continued...
12.7. Other adverse effects
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SECTION 13 Disposal considerations

13.1. Waste treatment methods

Containers may still present a chemical hazard/ danger when empty.
Return to supplier for reuse/ recycling if possible.
Otherwise:
If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
Product / Packaging DO NOT allow wash water from cleaning or process equipment to enter drains.
disposal It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
treatment or disposal facility can be identified.
Treat and neutralise at an approved treatment plant.

Waste treatment options Not Available

Sewage disposal options Not Available

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

Land transport (ADR-RID)

14.1. UN number or ID
1805
number

14.2. UN proper shipping

PHOSPHORIC ACID, SOLUTION
name

14.3. Transport hazard Class 8

class(es) Subsidiary Hazard Not Applicable

14.4. Packing group III

14.5. Environmental
Not Applicable
hazard

Hazard identification (Kemler) 80

Classification code C1

14.6. Special precautions Hazard Label 8

for user Special provisions Not Applicable

Limited quantity 5L

Tunnel Restriction Code E

Air transport (ICAO-IATA / DGR)

14.1. UN number 1805

14.2. UN proper shipping

Phosphoric acid, solution
name

ICAO/IATA Class 8
14.3. Transport hazard
ICAO / IATA Subsidiary Hazard Not Applicable
class(es)
ERG Code 8L

14.4. Packing group III

14.5. Environmental
Not Applicable
hazard

Special provisions A3 A803

14.6. Special precautions Cargo Only Packing Instructions 856 Continued...

for user Cargo Only Maximum Qty / Pack 60 L
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Passenger and Cargo Maximum Qty / Pack 5L

Passenger and Cargo Limited Quantity Packing Instructions Y841

Passenger and Cargo Limited Maximum Qty / Pack 1L

Sea transport (IMDG-Code / GGVSee)

14.1. UN number 1805

14.2. UN proper shipping

PHOSPHORIC ACID SOLUTION
name

14.3. Transport hazard IMDG Class 8

class(es) IMDG Subsidiary Hazard Not Applicable

14.4. Packing group III

14.5 Environmental hazard Not Applicable

EMS Number F-A, S-B

14.6. Special precautions
Special provisions 223
for user
Limited Quantities 5L

Inland waterways transport (ADN)

14.1. UN number 1805
14.2. UN proper shipping
PHOSPHORIC ACID, SOLUTION
name

14.3. Transport hazard

8 Not Applicable
class(es)

14.4. Packing group III

14.5. Environmental
Not Applicable
hazard

Classification code C1
Special provisions Not Applicable
14.6. Special precautions
Limited quantity 5L
for user
Equipment required PP, EP
Fire cones number 0

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group

phosphoric acid Not Available

2-(2-butoksyethoxy)ethanol Not Available

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type

phosphoric acid Not Available

2-(2-butoksyethoxy)ethanol Not Available

SECTION 15 Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

phosphoric acid is found on the following regulatory lists

EU Consolidated List of Indicative Occupational Exposure Limit Values European Union (EU) Regulation (EC) No 1272/2008 on Classification,
(IOELVs) Labelling and Packaging of Substances and Mixtures - Annex VI
Europe EC Inventory dNorway regulations on n action values ​ and limit
a values ​ for physical
Continued...
European Union - European Inventory of Existing Commercial Chemical chemical factors in the work environment and infection risk groups for
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2-(2-butoksyethoxy)ethanol is found on the following regulatory lists

EU Consolidated List of Indicative Occupational Exposure Limit Values European Union - European Inventory of Existing Commercial Chemical
(IOELVs) Substances (EINECS)
EU REACH Regulation (EC) No 1907/2006 - Annex XVII - Restrictions on the European Union (EU) Regulation (EC) No 1272/2008 on Classification,
manufacture, placing on the market and use of certain dangerous substances, Labelling and Packaging of Substances and Mixtures - Annex VI
mixtures and articles dNorway regulations on n action values ​ and limit
a values ​ for physical
Europe EC Inventory chemical factors in the work environment and infection risk groups for
biological factors (Norwegian)

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

Information according to 2012/18/EU (Seveso III):

Seveso Category Not Available

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

National Inventory Status

National Inventory Status

Australia - AIIC / Australia

Yes
Non-Industrial Use

Canada - DSL Yes

Canada - NDSL No (phosphoric acid; 2-(2-butoksyethoxy)ethanol)
China - IECSC Yes

Europe - EINEC / ELINCS /

Yes
NLP

Japan - ENCS Yes

Korea - KECI Yes
New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA Yes
Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - FBEPH Yes

Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 04/01/2022

Initial Date 02/05/2018

CONTACT POINT
- For quotations contact your local Customer Services - [Link] - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Compliance Manager, - Email: Email: [Link]@[Link] - Telephone: Tel.: +47 67584000

Full text Risk and Hazard codes

H319 Causes serious eye irritation.

SDS Version Summary

Version Date of Update Sections Updated
11.16 04/01/2022 Composition / information on ingredients - Ingredients

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.
Continued...
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For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

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end of SDS